KR102941906B1 - 반도체 디바이스용 선택형 분극을 갖는 유전체 재료의 형성 방법 - Google Patents

반도체 디바이스용 선택형 분극을 갖는 유전체 재료의 형성 방법

Info

Publication number
KR102941906B1
KR102941906B1 KR1020237002323A KR20237002323A KR102941906B1 KR 102941906 B1 KR102941906 B1 KR 102941906B1 KR 1020237002323 A KR1020237002323 A KR 1020237002323A KR 20237002323 A KR20237002323 A KR 20237002323A KR 102941906 B1 KR102941906 B1 KR 102941906B1
Authority
KR
South Korea
Prior art keywords
film
processing method
substrate processing
heat
thickness
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020237002323A
Other languages
English (en)
Korean (ko)
Other versions
KR20230048000A (ko
Inventor
디나 에이치. 트리요소
로버트 디. 클라크
스티븐 콘시글리오
칸다바라 타필리
Original Assignee
도쿄엘렉트론가부시키가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 도쿄엘렉트론가부시키가이샤 filed Critical 도쿄엘렉트론가부시키가이샤
Publication of KR20230048000A publication Critical patent/KR20230048000A/ko
Application granted granted Critical
Publication of KR102941906B1 publication Critical patent/KR102941906B1/ko
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D1/00Resistors, capacitors or inductors
    • H10D1/60Capacitors
    • H10D1/68Capacitors having no potential barriers
    • H10D1/682Capacitors having no potential barriers having dielectrics comprising perovskite structures
    • H10D1/684Capacitors having no potential barriers having dielectrics comprising perovskite structures the dielectrics comprising multiple layers, e.g. comprising buffer layers, seed layers or gradient layers
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/60Formation of materials, e.g. in the shape of layers or pillars of insulating materials
    • H10P14/63Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the formation processes
    • H10P14/6326Deposition processes
    • H10P14/6328Deposition from the gas or vapour phase
    • H10P14/6334Deposition from the gas or vapour phase using decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition
    • H10P14/6339Deposition from the gas or vapour phase using decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition deposition by cyclic CVD, e.g. ALD, ALE or pulsed CVD
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/60Formation of materials, e.g. in the shape of layers or pillars of insulating materials
    • H10P14/65Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by treatments performed before or after the formation of the materials
    • H10P14/6516Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by treatments performed before or after the formation of the materials of treatments performed after formation of the materials
    • H10P14/6544Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by treatments performed before or after the formation of the materials of treatments performed after formation of the materials to change the morphology of the insulating materials, e.g. transformation of an amorphous layer into a crystalline layer
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/60Formation of materials, e.g. in the shape of layers or pillars of insulating materials
    • H10P14/66Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the type of materials
    • H10P14/662Laminate layers, e.g. stacks of alternating high-k metal oxides
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/60Formation of materials, e.g. in the shape of layers or pillars of insulating materials
    • H10P14/69Inorganic materials
    • H10P14/692Inorganic materials composed of oxides, glassy oxides or oxide-based glasses
    • H10P14/6938Inorganic materials composed of oxides, glassy oxides or oxide-based glasses the material containing at least one metal element, e.g. metal oxides, metal oxynitrides or metal oxycarbides
    • H10P14/6939Inorganic materials composed of oxides, glassy oxides or oxide-based glasses the material containing at least one metal element, e.g. metal oxides, metal oxynitrides or metal oxycarbides characterised by the metal
    • H10P14/69392Inorganic materials composed of oxides, glassy oxides or oxide-based glasses the material containing at least one metal element, e.g. metal oxides, metal oxynitrides or metal oxycarbides characterised by the metal the material containing hafnium, e.g. HfO2
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/60Formation of materials, e.g. in the shape of layers or pillars of insulating materials
    • H10P14/69Inorganic materials
    • H10P14/692Inorganic materials composed of oxides, glassy oxides or oxide-based glasses
    • H10P14/6938Inorganic materials composed of oxides, glassy oxides or oxide-based glasses the material containing at least one metal element, e.g. metal oxides, metal oxynitrides or metal oxycarbides
    • H10P14/6939Inorganic materials composed of oxides, glassy oxides or oxide-based glasses the material containing at least one metal element, e.g. metal oxides, metal oxynitrides or metal oxycarbides characterised by the metal
    • H10P14/69395Inorganic materials composed of oxides, glassy oxides or oxide-based glasses the material containing at least one metal element, e.g. metal oxides, metal oxynitrides or metal oxycarbides characterised by the metal the material containing zirconium, e.g. ZrO2
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/60Formation of materials, e.g. in the shape of layers or pillars of insulating materials
    • H10P14/69Inorganic materials
    • H10P14/692Inorganic materials composed of oxides, glassy oxides or oxide-based glasses
    • H10P14/6938Inorganic materials composed of oxides, glassy oxides or oxide-based glasses the material containing at least one metal element, e.g. metal oxides, metal oxynitrides or metal oxycarbides
    • H10P14/6939Inorganic materials composed of oxides, glassy oxides or oxide-based glasses the material containing at least one metal element, e.g. metal oxides, metal oxynitrides or metal oxycarbides characterised by the metal
    • H10P14/69397Inorganic materials composed of oxides, glassy oxides or oxide-based glasses the material containing at least one metal element, e.g. metal oxides, metal oxynitrides or metal oxycarbides characterised by the metal the material containing two or more metal elements

Landscapes

  • Formation Of Insulating Films (AREA)
  • Semiconductor Memories (AREA)
  • Chemical Vapour Deposition (AREA)
  • Insulated Gate Type Field-Effect Transistor (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
KR1020237002323A 2020-08-10 2021-07-30 반도체 디바이스용 선택형 분극을 갖는 유전체 재료의 형성 방법 Active KR102941906B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US202063063840P 2020-08-10 2020-08-10
US63/063,840 2020-08-10
PCT/US2021/043952 WO2022035618A1 (en) 2020-08-10 2021-07-30 Methods for forming dielectric materials with selected polarization for semiconductor devices

Publications (2)

Publication Number Publication Date
KR20230048000A KR20230048000A (ko) 2023-04-10
KR102941906B1 true KR102941906B1 (ko) 2026-03-19

Family

ID=80115248

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020237002323A Active KR102941906B1 (ko) 2020-08-10 2021-07-30 반도체 디바이스용 선택형 분극을 갖는 유전체 재료의 형성 방법

Country Status (5)

Country Link
US (1) US12588434B2 (https=)
JP (1) JP7743144B2 (https=)
KR (1) KR102941906B1 (https=)
TW (1) TWI907477B (https=)
WO (1) WO2022035618A1 (https=)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023191981A1 (en) * 2022-03-29 2023-10-05 Tokyo Electron Limited Bilayer stack for a ferroelectric tunnel junction and method of forming

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080087890A1 (en) 2006-10-16 2008-04-17 Micron Technology, Inc. Methods to form dielectric structures in semiconductor devices and resulting devices
JP2010283040A (ja) 2009-06-02 2010-12-16 Panasonic Corp 半導体装置及びその製造方法
US20200020762A1 (en) 2018-07-11 2020-01-16 International Business Machines Corporation Fast recrystallization of hafnium or zirconium based oxides in insulator-metal structures
JP2021180276A (ja) 2020-05-15 2021-11-18 キオクシア株式会社 記憶装置

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4449226B2 (ja) * 2000-05-22 2010-04-14 東京エレクトロン株式会社 金属酸化膜の改質方法、金属酸化膜の成膜方法及び熱処理装置
US6441417B1 (en) 2001-03-28 2002-08-27 Sharp Laboratories Of America, Inc. Single c-axis PGO thin film on ZrO2 for non-volatile memory applications and methods of making the same
KR100877100B1 (ko) 2007-04-16 2009-01-09 주식회사 하이닉스반도체 비휘발성 메모리 소자 제조 방법
US7709359B2 (en) 2007-09-05 2010-05-04 Qimonda Ag Integrated circuit with dielectric layer
US8304823B2 (en) 2008-04-21 2012-11-06 Namlab Ggmbh Integrated circuit including a ferroelectric memory cell and method of manufacturing the same
US9269785B2 (en) 2014-01-27 2016-02-23 Globalfoundries Inc. Semiconductor device with ferroelectric hafnium oxide and method for forming semiconductor device
US9391162B2 (en) * 2014-04-04 2016-07-12 Taiwan Semiconductor Manufacturing Company, Ltd. Tunnel MOSFET with ferroelectric gate stack
US9147689B1 (en) 2014-04-16 2015-09-29 Micron Technology, Inc. Methods of forming ferroelectric capacitors
US20160181091A1 (en) 2014-12-19 2016-06-23 Intermolecular, Inc. Methods for Forming Ferroelectric Phases in Materials and Devices Utilizing the Same
US10153155B2 (en) 2015-10-09 2018-12-11 University Of Florida Research Foundation, Incorporated Doped ferroelectric hafnium oxide film devices
US20170365719A1 (en) 2016-06-15 2017-12-21 Taiwan Semiconductor Manufacturing Co., Ltd. Negative Capacitance Field Effect Transistor
TWI604605B (zh) 2016-12-15 2017-11-01 國立交通大學 半導體裝置及其製造方法
US11670699B2 (en) 2016-12-15 2023-06-06 National Yang Ming Chiao Tung University Semiconductor device and method of manufacturing the same
US10276697B1 (en) * 2017-10-27 2019-04-30 Taiwan Semiconductor Manufacturing Co., Ltd. Negative capacitance FET with improved reliability performance
US10784362B2 (en) * 2017-10-30 2020-09-22 Taiwan Semiconductor Manufacturing Co., Ltd. Semiconductor device and manufacturing method thereof
US10461095B2 (en) 2018-03-28 2019-10-29 Sandisk Technologies Llc Ferroelectric non-volatile memory
US10861973B2 (en) * 2018-06-27 2020-12-08 Taiwan Semiconductor Manufacturing Co., Ltd. Negative capacitance transistor with a diffusion blocking layer
US10991876B2 (en) 2018-10-31 2021-04-27 Taiwan Semiconductor Manufacturing Company, Ltd. Methods to improve magnetic tunnel junction memory cells by treating native oxide
KR102880299B1 (ko) * 2019-11-12 2025-10-31 삼성전자주식회사 유전체 물질층을 포함하는 박막 구조체 및 그 제조 방법, 이를 포함하는 전자소자

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080087890A1 (en) 2006-10-16 2008-04-17 Micron Technology, Inc. Methods to form dielectric structures in semiconductor devices and resulting devices
JP2010283040A (ja) 2009-06-02 2010-12-16 Panasonic Corp 半導体装置及びその製造方法
US20200020762A1 (en) 2018-07-11 2020-01-16 International Business Machines Corporation Fast recrystallization of hafnium or zirconium based oxides in insulator-metal structures
JP2021180276A (ja) 2020-05-15 2021-11-18 キオクシア株式会社 記憶装置

Also Published As

Publication number Publication date
JP7743144B2 (ja) 2025-09-24
US20220044922A1 (en) 2022-02-10
KR20230048000A (ko) 2023-04-10
TWI907477B (zh) 2025-12-11
WO2022035618A1 (en) 2022-02-17
US12588434B2 (en) 2026-03-24
TW202215603A (zh) 2022-04-16
JP2023538535A (ja) 2023-09-08

Similar Documents

Publication Publication Date Title
US10811249B2 (en) Atomic layer deposition of GeO2
US7304004B2 (en) System and method for forming a gate dielectric
US9178031B2 (en) Methods of atomic-layer deposition of hafnium oxide/erbium oxide bi-layer as advanced gate dielectrics
TWI624060B (zh) 具有鎢閘極電極的半導體裝置及其製造方法
US10629496B2 (en) Methods for forming transistor gates with hafnium oxide layers and lanthanum oxide layers
US8440520B2 (en) Diffused cap layers for modifying high-k gate dielectrics and interface layers
US20080057659A1 (en) Hafnium aluminium oxynitride high-K dielectric and metal gates
US8927438B2 (en) Methods for manufacturing high dielectric constant films
KR20130047048A (ko) 고유전층 및 금속게이트를 갖는 반도체장치, cmos 회로 및 그 제조 방법
US20150255267A1 (en) Atomic Layer Deposition of Aluminum-doped High-k Films
US20220328308A1 (en) Treatments to enhance material structures
JP7803625B2 (ja) 電気デバイス及びそれを含む半導体装置
US8735305B2 (en) Methods of forming fluorinated hafnium oxide gate dielectrics by atomic layer deposition
KR102941906B1 (ko) 반도체 디바이스용 선택형 분극을 갖는 유전체 재료의 형성 방법
US7279392B2 (en) Thin film structure, capacitor, and methods for forming the same
JP7210682B2 (ja) 材料構造を改良するための処理
US20080211065A1 (en) Semiconductor devices and methods of manufacture thereof
CN105336784B (zh) 半导体器件及其制造方法
JP4643902B2 (ja) 半導体装置とその製造方法
US9064694B2 (en) Nitridation of atomic layer deposited high-k dielectrics using trisilylamine
JP2012186349A (ja) 半導体装置及びその製造方法
US7256145B2 (en) Manufacture of semiconductor device having insulation film of high dielectric constant
US20240128308A1 (en) Method for fabricating a ferroelectric device
US20220093466A1 (en) Epitaxial high-k etch stop layer for backside reveal integration

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

PN2301 Change of applicant

St.27 status event code: A-3-3-R10-R13-asn-PN2301

St.27 status event code: A-3-3-R10-R11-asn-PN2301

A201 Request for examination
E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

P22-X000 Classification modified

St.27 status event code: A-2-2-P10-P22-nap-X000

D13-X000 Search requested

St.27 status event code: A-1-2-D10-D13-srh-X000

D14-X000 Search report completed

St.27 status event code: A-1-2-D10-D14-srh-X000

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

P11 Amendment of application requested

Free format text: ST27 STATUS EVENT CODE: A-2-2-P10-P11-NAP-X000 (AS PROVIDED BY THE NATIONAL OFFICE)

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P22-X000 Classification modified

St.27 status event code: A-2-2-P10-P22-nap-X000

D22 Grant of ip right intended

Free format text: ST27 STATUS EVENT CODE: A-1-2-D10-D22-EXM-PE0701 (AS PROVIDED BY THE NATIONAL OFFICE)

PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

F11 Ip right granted following substantive examination

Free format text: ST27 STATUS EVENT CODE: A-2-4-F10-F11-EXM-PR0701 (AS PROVIDED BY THE NATIONAL OFFICE)

PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

U12 Designation fee paid

Free format text: ST27 STATUS EVENT CODE: A-2-2-U10-U12-OTH-PR1002 (AS PROVIDED BY THE NATIONAL OFFICE)

Year of fee payment: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

Q13 Ip right document published

Free format text: ST27 STATUS EVENT CODE: A-4-4-Q10-Q13-NAP-PG1601 (AS PROVIDED BY THE NATIONAL OFFICE)