KR102510436B1 - 분지형 폴리올레핀의 제조 방법 - Google Patents

분지형 폴리올레핀의 제조 방법 Download PDF

Info

Publication number
KR102510436B1
KR102510436B1 KR1020177020264A KR20177020264A KR102510436B1 KR 102510436 B1 KR102510436 B1 KR 102510436B1 KR 1020177020264 A KR1020177020264 A KR 1020177020264A KR 20177020264 A KR20177020264 A KR 20177020264A KR 102510436 B1 KR102510436 B1 KR 102510436B1
Authority
KR
South Korea
Prior art keywords
hydrocarbyl
group
metal
bis
aluminum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020177020264A
Other languages
English (en)
Korean (ko)
Other versions
KR20170108958A (ko
Inventor
로버트 두샤또
밀루드 부야히
리디아 야신스카-발츠
마틴 알렉산더 주이드벨트
Original Assignee
사빅 글로벌 테크놀러지스 비.브이.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 사빅 글로벌 테크놀러지스 비.브이. filed Critical 사빅 글로벌 테크놀러지스 비.브이.
Publication of KR20170108958A publication Critical patent/KR20170108958A/ko
Application granted granted Critical
Publication of KR102510436B1 publication Critical patent/KR102510436B1/ko
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14Monomers containing five or more carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/09Long chain branches

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
KR1020177020264A 2014-12-23 2015-12-23 분지형 폴리올레핀의 제조 방법 Active KR102510436B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP14200125.4A EP3037438A1 (en) 2014-12-23 2014-12-23 Process for the preparation of a branched polyolefin
EP14200125.4 2014-12-23
PCT/EP2015/081203 WO2016102690A1 (en) 2014-12-23 2015-12-23 Process for the preparation of a branched polyolefin

Publications (2)

Publication Number Publication Date
KR20170108958A KR20170108958A (ko) 2017-09-27
KR102510436B1 true KR102510436B1 (ko) 2023-03-14

Family

ID=52130160

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020177020264A Active KR102510436B1 (ko) 2014-12-23 2015-12-23 분지형 폴리올레핀의 제조 방법

Country Status (7)

Country Link
US (1) US10450388B2 (https=)
EP (2) EP3037438A1 (https=)
JP (1) JP6770960B2 (https=)
KR (1) KR102510436B1 (https=)
CN (1) CN107207660B (https=)
SA (1) SA517381805B1 (https=)
WO (1) WO2016102690A1 (https=)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108137748B (zh) * 2015-07-23 2021-05-04 Sabic环球技术有限责任公司 用于制备具有一个或多个侧官能团的聚烯烃的方法
US10618988B2 (en) 2015-08-31 2020-04-14 Exxonmobil Chemical Patents Inc. Branched propylene polymers produced via use of vinyl transfer agents and processes for production thereof
JP2018525507A (ja) * 2015-08-31 2018-09-06 エクソンモービル・ケミカル・パテンツ・インク ビニル連鎖移動剤の使用によって製造されたポリマー
US9982067B2 (en) 2015-09-24 2018-05-29 Exxonmobil Chemical Patents Inc. Polymerization process using pyridyldiamido compounds supported on organoaluminum treated layered silicate supports
WO2017097568A1 (en) 2015-12-09 2017-06-15 Sabic Global Technologies B.V. Process for the preparation of polyolefin-based graft copolymers comprising a first long chain branched polyolefin block and one or multiple polymer side chains
US10927196B2 (en) 2016-06-30 2021-02-23 Exxonmobil Chemical Patents Inc. Long chain branched polypropylene via polymerization with aluminum vinyl transfer agent
US10562987B2 (en) 2016-06-30 2020-02-18 Exxonmobil Chemical Patents Inc. Polymers produced via use of quinolinyldiamido transition metal complexes and vinyl transfer agents
WO2018160276A1 (en) * 2017-02-28 2018-09-07 Exxonmobil Chemical Patents Inc. Polymers produced via use of quinolinyldiamido transition metal complexes and vinyl transfer agents
WO2018160277A1 (en) * 2017-02-28 2018-09-07 Exxonmobil Chemical Patents Inc. Branched propylene polymers produced via use of vinyl transfer agents and processes for production thereof
US10626200B2 (en) 2017-02-28 2020-04-21 Exxonmobil Chemical Patents Inc. Branched EPDM polymers produced via use of vinyl transfer agents and processes for production thereof
US10676551B2 (en) 2017-03-01 2020-06-09 Exxonmobil Chemical Patents Inc. Branched ethylene copolymers produced via use of vinyl transfer agents and processes for production thereof
EP3728345A1 (en) 2017-12-22 2020-10-28 SABIC Global Technologies B.V. Process for preparation of amorphous polyolefinic ionomers
WO2019122455A1 (en) 2017-12-22 2019-06-27 Sabic Global Technologies B.V. Process for preparation of amorphous functionalized olefin copolymer
KR102320012B1 (ko) * 2018-01-12 2021-11-02 주식회사 엘지화학 리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물
SG11202107067RA (en) * 2018-12-28 2021-07-29 Dow Global Technologies Llc Organometallic chain transfer agents
CN111116811B (zh) * 2020-01-03 2022-07-05 天津大学 一种1-丁烯/降冰片烯共聚物及其制备方法
WO2022029213A1 (en) * 2020-08-06 2022-02-10 Total Research & Technology Feluy Process for preparing ethylene polymers having long chain branches
JP7697239B2 (ja) * 2021-03-22 2025-06-24 日本ポリエチレン株式会社 エチレン重合用触媒の製造方法および前記エチレン重合用触媒を含むエチレン重合体またはエチレンとα-オレフィンとの共重合体の製造方法。
US20250170805A1 (en) * 2022-02-23 2025-05-29 Sealed Air Corporation (Us) Bulk cheese barrier bag

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100359687B1 (ko) 1993-11-16 2003-01-24 더 비.에프. 굿리치 컴파니 노르보르넨작용성단량체로부터유도된부가중합체및이것의제조방법
JP2003246820A (ja) * 2002-02-26 2003-09-05 Japan Polychem Corp プロピレン−アルケニルジアルキルアルミニウム共重合体
JP2005320420A (ja) 2004-05-07 2005-11-17 Takeshi Shiono 環状オレフィン/アルケニルジアルキルアルミニウム共重合体

Family Cites Families (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5106806A (en) 1990-10-18 1992-04-21 Shell Oil Company Olefin polymerization catalyst
US5077357A (en) 1990-10-22 1991-12-31 Shell Oil Company Olefin polymerization catalyst
CA1141093A (en) 1979-05-17 1983-02-08 Brian L. Goodall Olefin polymerization catalyst compositions and a process for the polymerization of olefins employing such compositions
JPS61151202A (ja) 1984-12-26 1986-07-09 Toa Nenryo Kogyo Kk プロピレン重合体の製造法
IT1227259B (it) 1988-09-30 1991-03-28 Himont Inc Catalizzatori per la polimerizzazione di olefine.
US5556820A (en) 1989-12-28 1996-09-17 Idemitsu Petrochemical Co., Ltd. Catalyst component for olefin polymerization and process for producing polyolefins
US5374696A (en) 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
NL9201970A (nl) 1992-11-11 1994-06-01 Dsm Nv Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
US5472785A (en) 1994-04-12 1995-12-05 Minnesota Mining And Manufacturing Company Reactive wax-containing moisture curable hot melt composition
JP3719727B2 (ja) 1994-10-13 2005-11-24 三井化学株式会社 末端に官能基を有するポリオレフィンの製造方法
DE69502028T2 (de) 1994-10-31 1998-12-10 Dsm N.V., Heerlen Katalytische zusammensetzung und verfahren zur olefinpolymerisation
WO1996032426A1 (en) 1995-04-10 1996-10-17 Dsm N.V. Method for the preparation of a catalyst suitable for the polymerisation of an olefine
JP3584092B2 (ja) 1995-09-07 2004-11-04 三井化学株式会社 粉体定量供給装置
US5756416A (en) * 1995-11-28 1998-05-26 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition having improved comonomer reactivity
EP0896596A1 (en) 1996-05-03 1999-02-17 Dsm N.V. Process for the production of functional polyolefins
KR20000010949A (ko) 1996-05-03 2000-02-25 윌리암 로엘프 드 보에르 α-올레핀의 중합화 방법
US6248837B1 (en) 1996-07-15 2001-06-19 The Penn State Research Foundation Process for preparing polyolefin diblock copolymers involving borane chain transfer reaction in transition metal-mediated olefin polymerization
JP2002503732A (ja) * 1998-02-11 2002-02-05 ザ ダウ ケミカル カンパニー 改良されたオレフィン重合方法
EP1092730B1 (en) 1999-01-22 2005-03-23 Mitsui Chemicals, Inc. Process for producing olefin polymer and olefin polymer
US6342622B1 (en) 1999-06-11 2002-01-29 Dsm B.V. Indenyl compounds for the polymerization of olefins
EP1086961A1 (en) 1999-09-27 2001-03-28 Dsm N.V. Process for the preparation of a catalyst component for the polymerisation of an olefin
BR0204687B1 (pt) 2001-03-30 2012-12-11 componente de catalisador sólido para a polimerização de olefinas, catalisador para a polimerização de olefinas, e, copolìmero em bloco de propileno.
US7087686B2 (en) 2001-08-06 2006-08-08 Bp Chemicals Limited Chain growth reaction process
US20060287449A1 (en) 2003-03-10 2006-12-21 Koichi Miyamoto Ultrahigh-molecular ethylene polymer
NZ549262A (en) * 2004-03-17 2010-08-27 Dow Global Technologies Inc Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation
JP4982365B2 (ja) 2004-07-30 2012-07-25 サウディ ベーシック インダストリーズ コーポレイション 高透明性のプロピレンコポリマー組成物
SG156614A1 (en) * 2005-09-15 2009-11-26 Dow Global Technologies Inc Catalytic olefin block copolymers via polymerizable shuttling agent
JP5529533B2 (ja) 2006-05-24 2014-06-25 サウディ ベーシック インダストリーズ コーポレイション プロピレン重合のための触媒成分を調製する方法
CA2768987A1 (en) 2009-07-29 2011-02-03 Dow Global Technologies Llc Multifunctional chain shuttling agents
US8570160B2 (en) 2010-04-09 2013-10-29 William Howard Speegle Methods and systems for controlling devices via power lines
US9587047B2 (en) 2011-12-12 2017-03-07 Saudi Basic Industries Corporation Process for the production of bimodal polyethylene in the presence of this catalyst system
CA2877754C (en) 2012-08-03 2018-12-11 Exxonmobil Chemical Patents Inc. Catalysts comprising salan ligands
WO2014022010A2 (en) 2012-08-03 2014-02-06 Exxonmobil Chemical Patents Inc. Non-symmetric catalysts comprising salan ligands
US9045568B2 (en) 2012-08-03 2015-06-02 Exxonmobil Chemical Patents Inc. Vinyl terminated polyethylene with long chain branching

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100359687B1 (ko) 1993-11-16 2003-01-24 더 비.에프. 굿리치 컴파니 노르보르넨작용성단량체로부터유도된부가중합체및이것의제조방법
JP2003246820A (ja) * 2002-02-26 2003-09-05 Japan Polychem Corp プロピレン−アルケニルジアルキルアルミニウム共重合体
JP2005320420A (ja) 2004-05-07 2005-11-17 Takeshi Shiono 環状オレフィン/アルケニルジアルキルアルミニウム共重合体

Also Published As

Publication number Publication date
JP6770960B2 (ja) 2020-10-21
JP2018500431A (ja) 2018-01-11
EP3037438A1 (en) 2016-06-29
US10450388B2 (en) 2019-10-22
EP3237460A1 (en) 2017-11-01
KR20170108958A (ko) 2017-09-27
US20170355786A1 (en) 2017-12-14
SA517381805B1 (ar) 2021-01-14
CN107207660B (zh) 2020-02-14
WO2016102690A1 (en) 2016-06-30
CN107207660A (zh) 2017-09-26

Similar Documents

Publication Publication Date Title
KR102510436B1 (ko) 분지형 폴리올레핀의 제조 방법
KR102470347B1 (ko) 1개 또는 다수개의 말단-기능성화된 분지를 가지는 폴리올레핀의 제조 방법
JP6698088B2 (ja) 第1のポリオレフィンブロック及び第2のポリマーブロックを含むブロック共重合体の調製方法並びにそれから得られる生成物
EP0822946B1 (en) Azaborolinyl metal complexes as olefin polymerization catalysts
EP3233977B1 (en) A process for the preparation of a graft copolymer comprising a polyolefin main chain and one or a multiple polymer side chains
JP6866346B2 (ja) 一又は複数の懸垂官能基を有するポリオレフィンの調製方法
EP3114149A1 (en) Catalyst comprising a metallocene complex and a co-catalyst
WO2017097570A1 (en) Process for the preparation of polyolefin-based graft copolymers comprising a first long chain branched polyolefin block and one or multiple polymer side chains
CN109843948B (zh) 用于制备具有极性基团的烯属共聚物的方法和由此获得的产物
EP3387047B1 (en) Process for the preparation of polyolefin-based graft copolymers comprising a first long chain branched polyolefin block and one or multiple polymer side chains
TW202330558A (zh) 金屬—配位基錯合物、含有該金屬—配位基錯合物之用於生產乙烯系聚合物之觸媒組成物、以及使用該觸媒組成物來生產乙烯系聚合物之方法

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

R17-X000 Change to representative recorded

St.27 status event code: A-3-3-R10-R17-oth-X000

A201 Request for examination
P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

D13-X000 Search requested

St.27 status event code: A-1-2-D10-D13-srh-X000

D14-X000 Search report completed

St.27 status event code: A-1-2-D10-D14-srh-X000

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-OTH-PR1001 (AS PROVIDED BY THE NATIONAL OFFICE)

Year of fee payment: 4