KR102505086B1 - 촉매 - Google Patents

촉매 Download PDF

Info

Publication number
KR102505086B1
KR102505086B1 KR1020197017336A KR20197017336A KR102505086B1 KR 102505086 B1 KR102505086 B1 KR 102505086B1 KR 1020197017336 A KR1020197017336 A KR 1020197017336A KR 20197017336 A KR20197017336 A KR 20197017336A KR 102505086 B1 KR102505086 B1 KR 102505086B1
Authority
KR
South Korea
Prior art keywords
group
catalyst
hydrocarbyl
solution
groups
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020197017336A
Other languages
English (en)
Korean (ko)
Other versions
KR20190085534A (ko
Inventor
노레딘 아젤랄
루이지 레스코니
브야체슬라브 브이 이즈메르
드미트리 에스 코노노비치
알렉산더 젯 보스코보이니코브
빌레 비르쿠넨
Original Assignee
보레알리스 아게
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 보레알리스 아게 filed Critical 보레알리스 아게
Publication of KR20190085534A publication Critical patent/KR20190085534A/ko
Application granted granted Critical
Publication of KR102505086B1 publication Critical patent/KR102505086B1/ko
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/385—Saturated compounds containing a keto group being part of a ring
    • C07C49/417—Saturated compounds containing a keto group being part of a ring polycyclic
    • C07C49/423—Saturated compounds containing a keto group being part of a ring polycyclic a keto group being part of a condensed ring system
    • C07C49/427—Saturated compounds containing a keto group being part of a ring polycyclic a keto group being part of a condensed ring system having two rings
    • C07C49/443—Saturated compounds containing a keto group being part of a ring polycyclic a keto group being part of a condensed ring system having two rings the condensed ring system containing eight or nine carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6498—Catalysts containing a specific non-metal or metal-free compound organic containing another heteroatom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04—One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
KR1020197017336A 2016-11-18 2017-11-17 촉매 Active KR102505086B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP16199646 2016-11-18
EP16199646.7 2016-11-18
PCT/EP2017/079662 WO2018091684A1 (en) 2016-11-18 2017-11-17 Catalysts

Publications (2)

Publication Number Publication Date
KR20190085534A KR20190085534A (ko) 2019-07-18
KR102505086B1 true KR102505086B1 (ko) 2023-02-28

Family

ID=57389239

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020197017336A Active KR102505086B1 (ko) 2016-11-18 2017-11-17 촉매

Country Status (6)

Country Link
US (1) US11352376B2 (https=)
EP (1) EP3541823B1 (https=)
JP (1) JP7037562B2 (https=)
KR (1) KR102505086B1 (https=)
CN (1) CN110177798B (https=)
WO (1) WO2018091684A1 (https=)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102505086B1 (ko) 2016-11-18 2023-02-28 보레알리스 아게 촉매
JP7130644B2 (ja) 2016-12-15 2022-09-05 ボレアリス エージー 高温溶液重合プロセスでポリエチレンコポリマーを製造する為の新規な触媒系
EP3555149B1 (en) 2016-12-15 2025-11-12 Borealis GmbH New catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process
EP3562831B1 (en) 2016-12-29 2021-10-20 Borealis AG Catalysts
CN110770264B (zh) * 2017-07-07 2022-10-14 博里利斯股份公司 制备多相丙烯共聚物的方法
EP3768735B1 (en) 2018-03-19 2021-12-29 Borealis AG Catalysts for olefin polymerization
WO2019215120A1 (en) * 2018-05-09 2019-11-14 Borealis Ag Process for preparing propylene polymers
KR20210027401A (ko) 2018-06-28 2021-03-10 보레알리스 아게 촉매
EP3647356B8 (en) 2018-10-31 2022-03-30 Borealis AG Polyolefin composition with improved balance of properties
US12312368B2 (en) * 2019-05-29 2025-05-27 Borealis Ag Preparation of catalyst system
EP4034579B8 (en) 2019-09-25 2025-08-27 Borealis GmbH Catalysts
WO2025051400A1 (en) * 2023-09-07 2025-03-13 Borealis Ag Methods of producing metallocene catalyst components
WO2025016568A1 (en) 2023-07-14 2025-01-23 Borealis Ag Metallocenes for the manufacture of polypropylene
WO2025016569A1 (en) 2023-07-14 2025-01-23 Borealis Ag Metallocenes for the manufacture of polypropylene
WO2025016566A1 (en) * 2023-07-14 2025-01-23 Borealis Ag Metallocenes for the manufacture of polypropylene
WO2025016564A1 (en) 2023-07-14 2025-01-23 Borealis Ag Metallocenes for the manufacture of polypropylene
WO2025016570A1 (en) 2023-07-14 2025-01-23 Borealis Ag Catalysts for olefin polymerization
WO2025016565A1 (en) 2023-07-14 2025-01-23 Borealis Ag Catalysts for olefin polymerization
KR20250026537A (ko) * 2023-08-17 2025-02-25 한화솔루션 주식회사 전이금속 화합물을 이용한 에틸렌-α-올레핀 공중합체의 용액중합방법
WO2025190884A1 (en) 2024-03-13 2025-09-18 Borealis Gmbh Metallocenes for the manufacture of propylene copolymers

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015009473A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
JP2016506402A (ja) 2012-12-21 2016-03-03 ボレアリス エージー 触媒

Family Cites Families (55)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5332706A (en) 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
FI96866C (fi) 1993-11-05 1996-09-10 Borealis As Tuettu olefiinipolymerointikatalyytti, sen valmistus ja käyttö
US5756609A (en) 1995-10-19 1998-05-26 Amoco Corporation Homogeneous metallocene-based olefin polymerization system with increased activity
DE19544828A1 (de) 1995-12-01 1997-06-05 Hoechst Ag Hochmolekulare Copolymere
KR100624632B1 (ko) 1997-03-07 2006-09-15 타고르 게엠베하 메탈로센 및 그의 제조 방법
US6252019B1 (en) 1997-05-13 2001-06-26 Montell Technology Company Bv Process for polymerizing tactioselective polyolefins in condensed phase using hafnocenes
DE69902548T2 (de) 1998-08-11 2003-04-10 The Dow Chemical Co., Midland Katalysatoraktivatorverbindung
KR100621299B1 (ko) 1998-10-23 2006-09-13 엑손모빌 케미칼 패턴츠 인코포레이티드 브릿지된 하프노센에 의한 올레핀 공중합 방법
ES2233109T3 (es) 1998-10-23 2005-06-01 Exxonmobil Chemical Patents Inc. Metalocenos puenteados para la copolimerizacion de olefinas.
JP2004502699A (ja) * 2000-06-30 2004-01-29 エクソンモービル・ケミカル・パテンツ・インク 架橋ビス（インデニル）メタロセン化合物
AU2002362036A1 (en) 2001-12-05 2003-06-23 Exxonmobil Chemical Patents Inc. Bulky borate activations
DE60132827D1 (de) 2001-12-10 2008-03-27 Exxon Chemical Patents Inc Metallocene und von ihnen abgeleitete katalysatorzusammensetzungen
EP1323747A1 (en) 2001-12-19 2003-07-02 Borealis Technology Oy Production of olefin polymerisation catalysts
US6756455B2 (en) 2002-05-31 2004-06-29 Equistar Chemicals, Lp High-temperature solution process for polyolefin manufacture
WO2004029062A1 (ja) 2002-09-27 2004-04-08 Mitsui Chemicals, Inc. オレフィン重合用の架橋メタロセン化合物およびそれを用いたオレフィンの重合方法
US7285608B2 (en) 2004-04-21 2007-10-23 Novolen Technology Holdings C.V. Metallocene ligands, metallocene compounds and metallocene catalysts, their synthesis and their use for the polymerization of olefins
US20050288461A1 (en) 2004-06-25 2005-12-29 Jensen Michael D Polymerization catalysts for producing polymers with low levels of long chain branching
KR101286307B1 (ko) 2004-12-31 2013-07-15 보레알리스 테크놀로지 오와이. 공정
RU2410388C2 (ru) 2005-03-18 2011-01-27 Базелль Полиолефине Гмбх Металлоценовые соединения
US7799880B2 (en) 2005-03-23 2010-09-21 Basell Polyolefine Gmbh Process for the polymerization of olefins
US7834205B2 (en) * 2006-04-12 2010-11-16 Basell Polyolifine GmbH Metallocene compounds
EP2010580B1 (en) 2006-04-21 2016-07-13 Basell Polyolefine GmbH Process for the preparation of ethylene copolymers
US7429635B2 (en) 2006-09-28 2008-09-30 Equistar Chemicals, Lp Preparation of ultra high molecular weight linear low density polyethylene
ATE547439T1 (de) 2007-10-25 2012-03-15 Lummus Novolen Technology Gmbh Racemoselektive synthese von ansa-metallocen- verbindungen, ansa-metallocen-verbindungen, diese enthaltende katalysatoren, verfahren zur herstellung eines olefinpolymers durch verwendung der katalysatoren und olefinhomopolymere und - copolymere
WO2010052264A1 (en) 2008-11-07 2010-05-14 Borealis Ag Solid catalyst composition
ES2619729T3 (es) 2008-11-07 2017-06-26 Borealis Ag Composición de catalizador sólida
EP2361267B1 (en) 2008-11-07 2015-03-04 Borealis AG Process to prepare a solid catalyst composition
EP2516484A1 (en) 2009-12-22 2012-10-31 Borealis AG Preparation of polypropylene in the presence of a single-site catalyst
WO2011076780A1 (en) 2009-12-22 2011-06-30 Borealis Ag Catalysts
US8729206B2 (en) 2010-04-28 2014-05-20 Borealis Ag Solid particulate catalysts comprising bridged metallocenes
KR101626069B1 (ko) 2010-04-28 2016-05-31 보레알리스 아게 브릿지된 메탈로센을 포함하는 고체 미립자 촉매
ES2565438T3 (es) 2010-07-01 2016-04-04 Borealis Ag Proceso para la polimerización de olefinas usando metalocenos del grupo 4 como catalizadores
EP2402353B1 (en) 2010-07-01 2018-04-25 Borealis AG Group 4 metallocenes useful as catalysts for the polymerization of olefins
CA2724943A1 (en) 2010-12-10 2012-06-10 Nova Chemicals Corporation Catalyst activation in a dual reactor process
EP2655431A1 (en) 2010-12-22 2013-10-30 Borealis AG Bridged metallocene catalysts
EP2532687A3 (en) 2011-06-10 2013-04-10 Borealis AG Bridged Metallocene Catalysts
CN103649101A (zh) 2011-07-08 2014-03-19 博瑞立斯有限公司 催化剂
ES2550044T3 (es) 2012-04-25 2015-11-04 Borealis Ag Polipropileno moldeado con alto contenido de forma beta
EP2722346A1 (en) 2012-10-18 2014-04-23 Borealis AG Polymerisation process and catalyst
WO2014096282A1 (en) 2012-12-21 2014-06-26 Borealis Ag Catalyst
JP5710035B2 (ja) 2013-02-27 2015-04-30 日本ポリエチレン株式会社 メタロセン化合物およびオレフィン重合体の製造方法
ES2589053T3 (es) 2013-06-10 2016-11-08 Borealis Ag Procedimiento para la preparación de un polímero de propileno
EP2829558B1 (en) * 2013-07-24 2016-12-14 Borealis AG Process
WO2015158790A2 (en) 2014-04-17 2015-10-22 Borealis Ag Improved catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process
EP2933277A1 (en) 2014-04-17 2015-10-21 Borealis AG New catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process
EP2995629B1 (en) 2014-09-12 2018-03-07 Borealis AG Process for producing propylene copolymers in gas phase
WO2016038211A1 (en) 2014-09-12 2016-03-17 Borealis Ag Process for the preparation of copolymers of propylene
US11059918B2 (en) 2016-05-27 2021-07-13 Exxonmobil Chemical Patents Inc. Metallocene catalyst compositions and polymerization process therewith
KR102505086B1 (ko) 2016-11-18 2023-02-28 보레알리스 아게 촉매
JP7130644B2 (ja) 2016-12-15 2022-09-05 ボレアリス エージー 高温溶液重合プロセスでポリエチレンコポリマーを製造する為の新規な触媒系
EP3555149B1 (en) 2016-12-15 2025-11-12 Borealis GmbH New catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process
EP3562831B1 (en) 2016-12-29 2021-10-20 Borealis AG Catalysts
US11370904B2 (en) 2017-06-29 2022-06-28 Borealis Ag Process for preparing a polypropylene composition
EP3456776B1 (en) 2017-09-13 2019-12-11 Borealis AG Polypropylene composition
EP3768735B1 (en) 2018-03-19 2021-12-29 Borealis AG Catalysts for olefin polymerization

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016506402A (ja) 2012-12-21 2016-03-03 ボレアリス エージー 触媒
WO2015009473A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts

Also Published As

Publication number Publication date
US11352376B2 (en) 2022-06-07
CN110177798B (zh) 2022-08-30
EP3541823A1 (en) 2019-09-25
JP7037562B2 (ja) 2022-03-16
CN110177798A (zh) 2019-08-27
US20190308995A1 (en) 2019-10-10
EP3541823B1 (en) 2020-12-30
JP2019536779A (ja) 2019-12-19
WO2018091684A1 (en) 2018-05-24
KR20190085534A (ko) 2019-07-18

Similar Documents

Publication Publication Date Title
KR102505086B1 (ko) 촉매
CN110352195B (zh) 催化剂
US9630980B2 (en) Asymmetrical ligands
US9469699B2 (en) Catalysts
JP6193398B2 (ja) 触媒
JP6178864B2 (ja) 触媒
CN103380151A (zh) 桥连茂金属催化剂
US11078304B2 (en) Process for preparing heterophasic propylene copolymers
CN111902436A (zh) 用于制备丙烯聚合物的方法
JP2015532346A (ja) 触媒

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

A201 Request for examination
PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

R18-X000 Changes to party contact information recorded

St.27 status event code: A-3-3-R10-R18-oth-X000

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

PN2301 Change of applicant

St.27 status event code: A-5-5-R10-R13-asn-PN2301

St.27 status event code: A-5-5-R10-R11-asn-PN2301

R11 Change to the name of applicant or owner or transfer of ownership requested

Free format text: ST27 STATUS EVENT CODE: A-5-5-R10-R11-ASN-PN2301 (AS PROVIDED BY THE NATIONAL OFFICE)

R13 Change to the name of applicant or owner recorded

Free format text: ST27 STATUS EVENT CODE: A-5-5-R10-R13-ASN-PN2301 (AS PROVIDED BY THE NATIONAL OFFICE)