KR102403518B1 - 에틸렌계 중합체를 제조하기 위한 고압, 자유 라디칼 중합 - Google Patents
에틸렌계 중합체를 제조하기 위한 고압, 자유 라디칼 중합 Download PDFInfo
- Publication number
- KR102403518B1 KR102403518B1 KR1020197001375A KR20197001375A KR102403518B1 KR 102403518 B1 KR102403518 B1 KR 102403518B1 KR 1020197001375 A KR1020197001375 A KR 1020197001375A KR 20197001375 A KR20197001375 A KR 20197001375A KR 102403518 B1 KR102403518 B1 KR 102403518B1
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- South Korea
- Prior art keywords
- ethylene
- mwd
- polymer
- reaction zone
- fed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920000642 polymer Polymers 0.000 title claims abstract description 196
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- HGXJDMCMYLEZMJ-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOOC(=O)C(C)(C)C HGXJDMCMYLEZMJ-UHFFFAOYSA-N 0.000 description 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
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- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
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- WYKYCHHWIJXDAO-UHFFFAOYSA-N tert-butyl 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(C)C WYKYCHHWIJXDAO-UHFFFAOYSA-N 0.000 description 2
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- DALNRYLBTOJSOH-UHFFFAOYSA-N 3,3,5,7,7-pentamethyl-1,2,4-trioxepane Chemical compound CC1CC(C)(C)OOC(C)(C)O1 DALNRYLBTOJSOH-UHFFFAOYSA-N 0.000 description 1
- QRIQYQXNFSXNGR-UHFFFAOYSA-N 3,3,6,6,9,9-hexamethyl-1,2,4,5-tetraoxonane Chemical compound CC1(C)CCC(C)(C)OOC(C)(C)OO1 QRIQYQXNFSXNGR-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2400/00—Characteristics for processes of polymerization
- C08F2400/02—Control or adjustment of polymerization parameters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/03—Narrow molecular weight distribution, i.e. Mw/Mn < 3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/08—Low density, i.e. < 0.91 g/cm3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/12—Melt flow index or melt flow ratio
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/18—Bulk density
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP16382297.6 | 2016-06-24 | ||
| EP16382297.6A EP3260473A1 (en) | 2016-06-24 | 2016-06-24 | High pressure, free radical polymerizations to produce ethylene-based polymers |
| PCT/US2017/038777 WO2017223329A1 (en) | 2016-06-24 | 2017-06-22 | High pressure, free radical polymerizations to produce ethylene-based polymers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20190021330A KR20190021330A (ko) | 2019-03-05 |
| KR102403518B1 true KR102403518B1 (ko) | 2022-06-02 |
Family
ID=56235769
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020197001375A Active KR102403518B1 (ko) | 2016-06-24 | 2017-06-22 | 에틸렌계 중합체를 제조하기 위한 고압, 자유 라디칼 중합 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US10774159B2 (cg-RX-API-DMAC7.html) |
| EP (2) | EP3260473A1 (cg-RX-API-DMAC7.html) |
| JP (2) | JP7495207B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR102403518B1 (cg-RX-API-DMAC7.html) |
| CN (1) | CN109312008B (cg-RX-API-DMAC7.html) |
| ES (1) | ES2842551T3 (cg-RX-API-DMAC7.html) |
| WO (1) | WO2017223329A1 (cg-RX-API-DMAC7.html) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES3037298T3 (en) * | 2019-09-24 | 2025-09-30 | Nova Chemicals International Sa | Steam generation in oxidative dehydrogenation |
| CN114502602B (zh) * | 2019-09-30 | 2024-02-06 | 埃克森美孚化学专利公司 | 用于改进的线材涂覆产品的高压聚乙烯管式反应器方法 |
| EP4396245A1 (en) * | 2021-09-01 | 2024-07-10 | ExxonMobil Chemical Patents Inc. | Variable temperature tubular reactor profiles and intermediate density polyethylene compositions produced therefrom |
| WO2024002393A1 (zh) * | 2022-07-01 | 2024-01-04 | 中国石油化工股份有限公司 | 烯烃自由基聚合的方法与烯烃自由基聚合装置 |
| EP4375304A1 (en) | 2022-11-28 | 2024-05-29 | International Technical Excellence Centers, Llc | Process for producing ethylene copolymers at high pressure in a tubular reactor |
| EP4608882A1 (en) | 2022-10-26 | 2025-09-03 | International Technical Excellence Centers, Inc. | Process for producing ethylene copolymers at high pressure in a tubular reactor |
| WO2025072132A1 (en) * | 2023-09-29 | 2025-04-03 | Dow Global Technologies Llc | High pressure free radical tubular reactor configuration for improving ldpe product capability and plant capacity |
| WO2025181065A1 (en) * | 2024-02-29 | 2025-09-04 | Basell Polyolefine Gmbh | Film with high weathering resistance |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012505292A (ja) | 2008-10-07 | 2012-03-01 | ダウ グローバル テクノロジーズ エルエルシー | 高活性連鎖移動剤を使用して製造される改良された光学特性を備える高圧低密度ポリエチレン樹脂 |
Family Cites Families (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1370101A (en) | 1971-10-11 | 1974-10-09 | Exxon Research Engineering Co | Production of polyethylene |
| GB1419012A (en) | 1973-03-29 | 1975-12-24 | Ici Ltd | Production of polyethylene |
| US4135044A (en) | 1977-08-08 | 1979-01-16 | Exxon Research & Engineering Co. | Process for achieving high conversions in the production of polyethylene |
| JPS6137010A (ja) | 1984-07-30 | 1986-02-21 | 三菱農機株式会社 | トラクタの耕深制御装置 |
| DD276598A3 (de) | 1988-04-12 | 1990-03-07 | Leuna Werke Veb | Verfahren zur einstellung und regelung der einsatzgasstroeme fuer mehrzonenrohrreaktoren |
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2017
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- 2017-06-22 US US16/302,830 patent/US10774159B2/en active Active
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- 2017-06-22 JP JP2018564220A patent/JP7495207B2/ja active Active
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| JP2012505292A (ja) | 2008-10-07 | 2012-03-01 | ダウ グローバル テクノロジーズ エルエルシー | 高活性連鎖移動剤を使用して製造される改良された光学特性を備える高圧低密度ポリエチレン樹脂 |
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| JP2019518842A (ja) | 2019-07-04 |
| WO2017223329A1 (en) | 2017-12-28 |
| US20190177443A1 (en) | 2019-06-13 |
| EP3260473A1 (en) | 2017-12-27 |
| US10774159B2 (en) | 2020-09-15 |
| CN109312008B (zh) | 2021-04-09 |
| ES2842551T3 (es) | 2021-07-14 |
| EP3475316A1 (en) | 2019-05-01 |
| CN109312008A (zh) | 2019-02-05 |
| EP3475316B1 (en) | 2020-11-18 |
| JP7495207B2 (ja) | 2024-06-04 |
| JP2022064936A (ja) | 2022-04-26 |
| KR20190021330A (ko) | 2019-03-05 |
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