KR102359088B1 - 디클로로에탄으로의 에틸렌의 옥시염소화를 위한 촉매 및 공정 - Google Patents

디클로로에탄으로의 에틸렌의 옥시염소화를 위한 촉매 및 공정 Download PDF

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KR102359088B1
KR102359088B1 KR1020177001376A KR20177001376A KR102359088B1 KR 102359088 B1 KR102359088 B1 KR 102359088B1 KR 1020177001376 A KR1020177001376 A KR 1020177001376A KR 20177001376 A KR20177001376 A KR 20177001376A KR 102359088 B1 KR102359088 B1 KR 102359088B1
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catalyst
alkaline earth
copper
metal
another embodiment
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KR20170023966A (ko
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케잇 크라머
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옥시 비닐스, 엘.피.
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/10—Magnesium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • B01J35/023—
    • B01J35/1019—
    • B01J35/1038—
    • B01J35/1042—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
    • C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C19/00—Acyclic saturated compounds containing halogen atoms
    • C07C19/01—Acyclic saturated compounds containing halogen atoms containing chlorine
    • C07C19/043—Chloroethanes
    • C07C19/045—Dichloroethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/10—Constitutive chemical elements of heterogeneous catalysts of Group I (IA or IB) of the Periodic Table
    • B01J2523/13—Potassium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/20—Constitutive chemical elements of heterogeneous catalysts of Group II (IIA or IIB) of the Periodic Table
    • B01J2523/22—Magnesium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/30—Constitutive chemical elements of heterogeneous catalysts of Group III (IIIA or IIIB) of the Periodic Table
    • B01J2523/31—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/70—Constitutive chemical elements of heterogeneous catalysts of Group VII (VIIB) of the Periodic Table
    • B01J2523/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/70—Constitutive chemical elements of heterogeneous catalysts of Group VII (VIIB) of the Periodic Table
    • B01J2523/74—Rhenium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020177001376A 2014-06-23 2015-06-23 디클로로에탄으로의 에틸렌의 옥시염소화를 위한 촉매 및 공정 Active KR102359088B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201462015732P 2014-06-23 2014-06-23
US62/015,732 2014-06-23
PCT/US2015/037104 WO2015200270A1 (en) 2014-06-23 2015-06-23 Catalyst and process for oxychlorination of ethylene to dichloroethane

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KR20170023966A KR20170023966A (ko) 2017-03-06
KR102359088B1 true KR102359088B1 (ko) 2022-02-08

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US (1) US11453630B2 (enExample)
EP (1) EP3157670B1 (enExample)
JP (1) JP6553093B2 (enExample)
KR (1) KR102359088B1 (enExample)
CN (1) CN106458796B (enExample)
BR (1) BR112016028625B1 (enExample)
ES (1) ES2750654T3 (enExample)
HR (1) HRP20191735T1 (enExample)
HU (1) HUE046713T2 (enExample)
MX (1) MX378507B (enExample)
MY (1) MY195083A (enExample)
PL (1) PL3157670T3 (enExample)
PT (1) PT3157670T (enExample)
RU (1) RU2687091C2 (enExample)
WO (1) WO2015200270A1 (enExample)

Families Citing this family (2)

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Publication number Priority date Publication date Assignee Title
CN111437816B (zh) * 2019-01-16 2023-05-02 中国石油化工股份有限公司 负载型银催化剂及其制备方法和应用
CN118748989A (zh) 2022-01-19 2024-10-08 氧乙烯有限合伙公司 氧氯化工艺

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1981001284A1 (en) 1979-11-05 1981-05-14 Goodrich Co B F Improved alumina-supported copper catalyst compositions for fluid-bed hydrocarbon oxyhydrochlorination
JP2004298871A (ja) 2003-03-31 2004-10-28 Sud Chem Mt Srl エチレンの１，２−ジクロロエタンへのオキシクロル化用触媒
US20060129008A1 (en) 2004-12-02 2006-06-15 Sud-Chemie Catalysts Italia S.R.L. Catalysts for oxychlorination of ethylene to 1,2-dichlorethane
JP2009504711A (ja) 2005-08-18 2009-02-05 アルベマール・ネーザーランズ・ベー・ブイ 接触的オキシ塩素化
WO2014071423A1 (en) 2012-11-05 2014-05-08 Basf Corporation Catalyst for the oxychlorination of ethylene to 1, 2-dichloroethane

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2125748A5 (enExample) * 1971-02-19 1972-09-29 Pechiney Saint Gobain
DE2949530A1 (de) 1979-12-08 1981-06-11 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von 1,2-dichlorethan
US5292703A (en) 1992-07-28 1994-03-08 The Geon Company Catalyst and process for oxychlorination of ethylene to EDC
TWI341218B (en) 2005-11-14 2011-05-01 Oxy Vinyls Lp Catalyst compositions and process for oxychlorination
EP2070898B1 (de) 2007-12-03 2013-02-20 Basf Se Katalysator zur Oxichlorierung
US9248434B2 (en) * 2012-11-06 2016-02-02 Basf Corporation Catalyst for the oxychlorination of ethylene to 1, 2-dichloroethane

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1981001284A1 (en) 1979-11-05 1981-05-14 Goodrich Co B F Improved alumina-supported copper catalyst compositions for fluid-bed hydrocarbon oxyhydrochlorination
JP2004298871A (ja) 2003-03-31 2004-10-28 Sud Chem Mt Srl エチレンの１，２−ジクロロエタンへのオキシクロル化用触媒
US20060129008A1 (en) 2004-12-02 2006-06-15 Sud-Chemie Catalysts Italia S.R.L. Catalysts for oxychlorination of ethylene to 1,2-dichlorethane
JP2009504711A (ja) 2005-08-18 2009-02-05 アルベマール・ネーザーランズ・ベー・ブイ 接触的オキシ塩素化
WO2014071423A1 (en) 2012-11-05 2014-05-08 Basf Corporation Catalyst for the oxychlorination of ethylene to 1, 2-dichloroethane

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WO2015200270A1 (en) 2015-12-30
CN106458796B (zh) 2020-02-14
US11453630B2 (en) 2022-09-27
MX378507B (es) 2025-03-11
ES2750654T3 (es) 2020-03-26
MX2016016219A (es) 2017-03-28
EP3157670A1 (en) 2017-04-26
RU2017101810A (ru) 2018-07-23
RU2687091C2 (ru) 2019-05-07
PL3157670T3 (pl) 2020-02-28
BR112016028625B1 (pt) 2022-05-03
HRP20191735T1 (hr) 2019-12-27
BR112016028625A2 (pt) 2020-11-03
JP6553093B2 (ja) 2019-07-31
RU2017101810A3 (enExample) 2018-11-16
CN106458796A (zh) 2017-02-22
KR20170023966A (ko) 2017-03-06
EP3157670B1 (en) 2019-07-24
PT3157670T (pt) 2019-10-31
US20170137351A1 (en) 2017-05-18
MY195083A (en) 2023-01-09
HUE046713T2 (hu) 2020-03-30
JP2017520541A (ja) 2017-07-27

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