CN106458796B - 用于将乙烯氧氯化为二氯乙烷的催化剂和方法 - Google Patents

用于将乙烯氧氯化为二氯乙烷的催化剂和方法 Download PDF

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CN106458796B
CN106458796B CN201580031414.3A CN201580031414A CN106458796B CN 106458796 B CN106458796 B CN 106458796B CN 201580031414 A CN201580031414 A CN 201580031414A CN 106458796 B CN106458796 B CN 106458796B
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catalyst
copper
alkaline earth
metal
aqueous solution
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CN106458796A (zh
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K·克雷默
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Oxy Vinyls LP
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Oxy Vinyls LP
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
    • C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/10—Magnesium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
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    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C19/00—Acyclic saturated compounds containing halogen atoms
    • C07C19/01—Acyclic saturated compounds containing halogen atoms containing chlorine
    • C07C19/043—Chloroethanes
    • C07C19/045—Dichloroethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/10—Constitutive chemical elements of heterogeneous catalysts of Group I (IA or IB) of the Periodic Table
    • B01J2523/13—Potassium
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/20—Constitutive chemical elements of heterogeneous catalysts of Group II (IIA or IIB) of the Periodic Table
    • B01J2523/22—Magnesium
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    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/70—Constitutive chemical elements of heterogeneous catalysts of Group VII (VIIB) of the Periodic Table
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    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/70—Constitutive chemical elements of heterogeneous catalysts of Group VII (VIIB) of the Periodic Table
    • B01J2523/74—Rhenium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201580031414.3A 2014-06-23 2015-06-23 用于将乙烯氧氯化为二氯乙烷的催化剂和方法 Active CN106458796B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201462015732P 2014-06-23 2014-06-23
US62/015,732 2014-06-23
PCT/US2015/037104 WO2015200270A1 (en) 2014-06-23 2015-06-23 Catalyst and process for oxychlorination of ethylene to dichloroethane

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CN106458796A CN106458796A (zh) 2017-02-22
CN106458796B true CN106458796B (zh) 2020-02-14

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US (1) US11453630B2 (enExample)
EP (1) EP3157670B1 (enExample)
JP (1) JP6553093B2 (enExample)
KR (1) KR102359088B1 (enExample)
CN (1) CN106458796B (enExample)
BR (1) BR112016028625B1 (enExample)
ES (1) ES2750654T3 (enExample)
HR (1) HRP20191735T1 (enExample)
HU (1) HUE046713T2 (enExample)
MX (1) MX378507B (enExample)
MY (1) MY195083A (enExample)
PL (1) PL3157670T3 (enExample)
PT (1) PT3157670T (enExample)
RU (1) RU2687091C2 (enExample)
WO (1) WO2015200270A1 (enExample)

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Publication number Priority date Publication date Assignee Title
CN111437816B (zh) * 2019-01-16 2023-05-02 中国石油化工股份有限公司 负载型银催化剂及其制备方法和应用
EP4466244B1 (en) 2022-01-19 2026-07-08 Oxy Vinyls, LP Oxychlorination process

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1981001284A1 (en) * 1979-11-05 1981-05-14 Goodrich Co B F Improved alumina-supported copper catalyst compositions for fluid-bed hydrocarbon oxyhydrochlorination
EP1666145A1 (en) * 2004-12-02 2006-06-07 Süd Chemie - Catalysts Italia S.R.L. Catalysts for oxychlorination of ethylene to 1,2-dichlorethane
WO2014071423A1 (en) * 2012-11-05 2014-05-08 Basf Corporation Catalyst for the oxychlorination of ethylene to 1, 2-dichloroethane

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2125748A5 (enExample) * 1971-02-19 1972-09-29 Pechiney Saint Gobain
DE2949530A1 (de) 1979-12-08 1981-06-11 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von 1,2-dichlorethan
US5292703A (en) * 1992-07-28 1994-03-08 The Geon Company Catalyst and process for oxychlorination of ethylene to EDC
ITMI20030630A1 (it) * 2003-03-31 2004-10-01 Sued Chemie Mt Srl Catalizzatori per ossiclorurazione dell'etilene a 1,2-dicloroetano.
JP5256036B2 (ja) * 2005-08-18 2013-08-07 アルベマール・ネーザーランズ・ベー・ブイ 接触的オキシ塩素化
TWI341218B (en) 2005-11-14 2011-05-01 Oxy Vinyls Lp Catalyst compositions and process for oxychlorination
EP2070898B1 (de) 2007-12-03 2013-02-20 Basf Se Katalysator zur Oxichlorierung
US9248434B2 (en) * 2012-11-06 2016-02-02 Basf Corporation Catalyst for the oxychlorination of ethylene to 1, 2-dichloroethane

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1981001284A1 (en) * 1979-11-05 1981-05-14 Goodrich Co B F Improved alumina-supported copper catalyst compositions for fluid-bed hydrocarbon oxyhydrochlorination
EP1666145A1 (en) * 2004-12-02 2006-06-07 Süd Chemie - Catalysts Italia S.R.L. Catalysts for oxychlorination of ethylene to 1,2-dichlorethane
WO2014071423A1 (en) * 2012-11-05 2014-05-08 Basf Corporation Catalyst for the oxychlorination of ethylene to 1, 2-dichloroethane

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WO2015200270A1 (en) 2015-12-30
HUE046713T2 (hu) 2020-03-30
PL3157670T3 (pl) 2020-02-28
MX2016016219A (es) 2017-03-28
EP3157670B1 (en) 2019-07-24
RU2687091C2 (ru) 2019-05-07
RU2017101810A (ru) 2018-07-23
ES2750654T3 (es) 2020-03-26
MX378507B (es) 2025-03-11
RU2017101810A3 (enExample) 2018-11-16
KR102359088B1 (ko) 2022-02-08
HRP20191735T1 (hr) 2019-12-27
MY195083A (en) 2023-01-09
BR112016028625A2 (pt) 2020-11-03
US20170137351A1 (en) 2017-05-18
EP3157670A1 (en) 2017-04-26
BR112016028625B1 (pt) 2022-05-03
JP6553093B2 (ja) 2019-07-31
PT3157670T (pt) 2019-10-31
US11453630B2 (en) 2022-09-27
KR20170023966A (ko) 2017-03-06
JP2017520541A (ja) 2017-07-27
CN106458796A (zh) 2017-02-22

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