HRP20191735T1 - Katalizator i postupak oksikloriranja etilena u dikloroetan - Google Patents
Katalizator i postupak oksikloriranja etilena u dikloroetan Download PDFInfo
- Publication number
- HRP20191735T1 HRP20191735T1 HRP20191735TT HRP20191735T HRP20191735T1 HR P20191735 T1 HRP20191735 T1 HR P20191735T1 HR P20191735T T HRP20191735T T HR P20191735TT HR P20191735 T HRP20191735 T HR P20191735T HR P20191735 T1 HRP20191735 T1 HR P20191735T1
- Authority
- HR
- Croatia
- Prior art keywords
- alkaline earth
- catalyst
- aqueous solution
- alkali metal
- earth metal
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims 17
- 239000003054 catalyst Substances 0.000 title claims 13
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims 3
- 239000005977 Ethylene Substances 0.000 title claims 3
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 title 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 10
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 10
- 150000001342 alkaline earth metals Chemical class 0.000 claims 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 9
- 150000001340 alkali metals Chemical class 0.000 claims 9
- 239000007864 aqueous solution Substances 0.000 claims 9
- 229910052802 copper Inorganic materials 0.000 claims 9
- 239000010949 copper Substances 0.000 claims 9
- 229910052723 transition metal Inorganic materials 0.000 claims 4
- 150000003624 transition metals Chemical class 0.000 claims 4
- 239000000243 solution Substances 0.000 claims 3
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 claims 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- -1 alkali metal salt Chemical class 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 239000012530 fluid Substances 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- 229910052748 manganese Inorganic materials 0.000 claims 1
- 239000011572 manganese Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
- C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
- C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/10—Magnesium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/72—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/889—Manganese, technetium or rhenium
- B01J23/8892—Manganese
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/19—Catalysts containing parts with different compositions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/633—Pore volume less than 0.5 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/635—0.5-1.0 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C19/00—Acyclic saturated compounds containing halogen atoms
- C07C19/01—Acyclic saturated compounds containing halogen atoms containing chlorine
- C07C19/043—Chloroethanes
- C07C19/045—Dichloroethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Claims (14)
1. Postupak oksikloriranja gdje je etilen pretvoren u 1,2-dikloroetan u prisustvu bakrovog katalizatora na nosaču, obuhvaćajući korak korištenja katalizatora na nosaču pripremljenog (i) impregnacijom, u prvom koraku, nosača aluminijevog oksida s prvom vodenastom otopinom koja sadrži bakar i dodatan prijelazni metal, time tvoreći prvu komponentu katalizatora; i (ii) impregnacijom, unutar dodatnog koraka, prve komponente katalizatora s drugom vodenastom otopinom koja sadrži bakar i zemnoalkalijski metal time tvoreći katalizator na nosaču.
2. Postupak iz zahtjeva 1, gdje je postupak oksikloriranja proveden u reaktoru s tekućim ležištem.
3. Postupak iz zahtjeva 2, gdje je reaktor s tekućim ležištem reaktor sa skretnim ležištem.
4. Postupak iz zahtjeva 1, gdje je katalizator na nosaču odabran od (i) od 5,0 do 12 težinskog postotka bakra, (ii) od 0,25 do 3,0 težinskog postotka zemnoalkalijskog metala, i (iii) od 0,5 do 2,25 težinskog postotka prijelaznog metala.
5. Postupak iz zahtjeva 1, gdje katalizator na nosaču uključuje od 0,25 do 1,6 težinskog postotka zemnoalkalijskog metala.
6. Postupak iz zahtjeva 1, gdje je zemnoalkalijski metal magnezij.
7. Postupak iz zahtjeva 1, gdje prva otopina uključuje alkalijski metal i zemnoalkalijski metal.
8. Postupak iz zahtjeva 7, gdje je alkalijski metal kalij.
9. Postupak iz zahtjeva 7, gdje je druga vodenasta otopina značajno bez alkalijskog metala i gdje druga vodenasta otopina uključuje molarni omjer zemnoalkalijskog metala naspram bakra veći od 0,19.
10. Postupak iz zahtjeva 1, gdje je dodatan prijelazni metal mangan.
11. Postupak proizvodnje katalizatora za oksikloriranje etilena u 1,2-dikloroetan, postupak obuhvaćajući korake:
(i) impregnacije, u prvom koraku, nosača aluminijevog oksida s prvom vodenastom otopinom koja sadrži bakar i dodatan prijelazni metal, time tvoreći prvu komponentu katalizatora; i
(ii) impregnacije, unutar dodatnog koraka, prve komponente katalizatora s drugom vodenastom otopinom koja sadrži bakar i zemnoalkalijski metal time tvoreći katalizator na nosaču.
12. Postupak iz zahtjeva 11, gdje prva otopina dalje uključuje alkalijski metal i zemnoalkalijski metal.
13. Postupak iz zahtjeva 12, gdje je druga vodenasta otopina značajno bez alkalijskog metala i gdje druga vodenasta otopina uključuje molarni omjer zemnoalkalijskog metala naspram bakra veći od 0,19.
14. Postupak iz zahtjeva 1, gdje prva otopina dalje uključuje alkalijski metal i zemnoalkalijski metal, i gdje je koncentracija bilo kojeg alkalijskog metala, ili soli alkalijskog metala, unutar druge vodenaste otopine manja nego količina koja bi pružala bakrovom katalizatoru na nosaču, nakon sušenja, dodatnu koncentraciju alkalijskog metala od 0,5 wt% alkalijskog metala.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201462015732P | 2014-06-23 | 2014-06-23 | |
| EP15744396.1A EP3157670B1 (en) | 2014-06-23 | 2015-06-23 | Catalyst and process for oxychlorination of ethylene to dichloroethane |
| PCT/US2015/037104 WO2015200270A1 (en) | 2014-06-23 | 2015-06-23 | Catalyst and process for oxychlorination of ethylene to dichloroethane |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HRP20191735T1 true HRP20191735T1 (hr) | 2019-12-27 |
Family
ID=53761489
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HRP20191735TT HRP20191735T1 (hr) | 2014-06-23 | 2019-09-25 | Katalizator i postupak oksikloriranja etilena u dikloroetan |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US11453630B2 (hr) |
| EP (1) | EP3157670B1 (hr) |
| JP (1) | JP6553093B2 (hr) |
| KR (1) | KR102359088B1 (hr) |
| CN (1) | CN106458796B (hr) |
| BR (1) | BR112016028625B1 (hr) |
| ES (1) | ES2750654T3 (hr) |
| HR (1) | HRP20191735T1 (hr) |
| HU (1) | HUE046713T2 (hr) |
| MX (1) | MX2016016219A (hr) |
| MY (1) | MY195083A (hr) |
| PL (1) | PL3157670T3 (hr) |
| PT (1) | PT3157670T (hr) |
| RU (1) | RU2687091C2 (hr) |
| WO (1) | WO2015200270A1 (hr) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111437816B (zh) * | 2019-01-16 | 2023-05-02 | 中国石油化工股份有限公司 | 负载型银催化剂及其制备方法和应用 |
| WO2023141486A1 (en) | 2022-01-19 | 2023-07-27 | Oxy Vinyls, Lp | Oxychlorination process |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2125748A5 (hr) * | 1971-02-19 | 1972-09-29 | Pechiney Saint Gobain | |
| EP0039723B1 (en) * | 1979-11-05 | 1984-04-11 | The B.F. GOODRICH Company | Improved alumina-supported copper catalyst compositions for fluid-bed hydrocarbon oxyhydrochlorination |
| DE2949530A1 (de) * | 1979-12-08 | 1981-06-11 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung von 1,2-dichlorethan |
| US5292703A (en) * | 1992-07-28 | 1994-03-08 | The Geon Company | Catalyst and process for oxychlorination of ethylene to EDC |
| ITMI20030630A1 (it) | 2003-03-31 | 2004-10-01 | Sued Chemie Mt Srl | Catalizzatori per ossiclorurazione dell'etilene a 1,2-dicloroetano. |
| ITMI20042317A1 (it) * | 2004-12-02 | 2005-03-02 | Sued Chemie Mt Srl | Catalizzatori per l'ossiclorurazione dell'etilene a 1,2-dicloroetano |
| EP1917102A1 (en) * | 2005-08-18 | 2008-05-07 | Albemarle Netherlands B.V. | Catalytic oxychlorination |
| TWI341218B (en) | 2005-11-14 | 2011-05-01 | Oxy Vinyls Lp | Catalyst compositions and process for oxychlorination |
| EP2070898B1 (de) | 2007-12-03 | 2013-02-20 | Basf Se | Katalysator zur Oxichlorierung |
| RU2664799C2 (ru) * | 2012-11-05 | 2018-08-22 | Басф Корпорейшн | Катализатор для оксихлорирования этилена до 1,2-дихлорэтана |
| US9248434B2 (en) * | 2012-11-06 | 2016-02-02 | Basf Corporation | Catalyst for the oxychlorination of ethylene to 1, 2-dichloroethane |
-
2015
- 2015-06-23 EP EP15744396.1A patent/EP3157670B1/en active Active
- 2015-06-23 ES ES15744396T patent/ES2750654T3/es active Active
- 2015-06-23 MY MYPI2016704734A patent/MY195083A/en unknown
- 2015-06-23 BR BR112016028625-1A patent/BR112016028625B1/pt active IP Right Grant
- 2015-06-23 JP JP2016571374A patent/JP6553093B2/ja active Active
- 2015-06-23 HU HUE15744396A patent/HUE046713T2/hu unknown
- 2015-06-23 KR KR1020177001376A patent/KR102359088B1/ko active IP Right Grant
- 2015-06-23 PT PT157443961T patent/PT3157670T/pt unknown
- 2015-06-23 MX MX2016016219A patent/MX2016016219A/es unknown
- 2015-06-23 WO PCT/US2015/037104 patent/WO2015200270A1/en active Application Filing
- 2015-06-23 RU RU2017101810A patent/RU2687091C2/ru active
- 2015-06-23 CN CN201580031414.3A patent/CN106458796B/zh active Active
- 2015-06-23 PL PL15744396T patent/PL3157670T3/pl unknown
- 2015-06-23 US US15/321,770 patent/US11453630B2/en active Active
-
2019
- 2019-09-25 HR HRP20191735TT patent/HRP20191735T1/hr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| MX2016016219A (es) | 2017-03-28 |
| JP6553093B2 (ja) | 2019-07-31 |
| ES2750654T3 (es) | 2020-03-26 |
| CN106458796A (zh) | 2017-02-22 |
| WO2015200270A1 (en) | 2015-12-30 |
| PL3157670T3 (pl) | 2020-02-28 |
| RU2017101810A3 (hr) | 2018-11-16 |
| BR112016028625B1 (pt) | 2022-05-03 |
| BR112016028625A2 (pt) | 2020-11-03 |
| RU2017101810A (ru) | 2018-07-23 |
| EP3157670B1 (en) | 2019-07-24 |
| KR102359088B1 (ko) | 2022-02-08 |
| US20170137351A1 (en) | 2017-05-18 |
| PT3157670T (pt) | 2019-10-31 |
| JP2017520541A (ja) | 2017-07-27 |
| CN106458796B (zh) | 2020-02-14 |
| HUE046713T2 (hu) | 2020-03-30 |
| US11453630B2 (en) | 2022-09-27 |
| RU2687091C2 (ru) | 2019-05-07 |
| KR20170023966A (ko) | 2017-03-06 |
| EP3157670A1 (en) | 2017-04-26 |
| MY195083A (en) | 2023-01-09 |
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