KR102297100B1 - Cha 프레임워크 형을 갖는 알루미노실리케이트 분자체의 제조 방법 - Google Patents
Cha 프레임워크 형을 갖는 알루미노실리케이트 분자체의 제조 방법 Download PDFInfo
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- KR102297100B1 KR102297100B1 KR1020177015973A KR20177015973A KR102297100B1 KR 102297100 B1 KR102297100 B1 KR 102297100B1 KR 1020177015973 A KR1020177015973 A KR 1020177015973A KR 20177015973 A KR20177015973 A KR 20177015973A KR 102297100 B1 KR102297100 B1 KR 102297100B1
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- molecular sieve
- reaction mixture
- framework type
- cha framework
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- 239000002808 molecular sieve Substances 0.000 title claims abstract description 61
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 title claims abstract description 61
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 229910000323 aluminium silicate Inorganic materials 0.000 title claims abstract description 18
- 238000000034 method Methods 0.000 title claims description 12
- -1 trimethylphenylammonium cation Chemical class 0.000 claims abstract description 21
- 239000011541 reaction mixture Substances 0.000 claims description 25
- 239000013078 crystal Substances 0.000 claims description 17
- 239000010457 zeolite Substances 0.000 claims description 14
- 238000002425 crystallisation Methods 0.000 claims description 13
- 230000008025 crystallization Effects 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 229910021536 Zeolite Inorganic materials 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 10
- 230000000737 periodic effect Effects 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000012535 impurity Substances 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 239000010703 silicon Substances 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 13
- 239000000047 product Substances 0.000 description 12
- 239000008367 deionised water Substances 0.000 description 10
- 229910021641 deionized water Inorganic materials 0.000 description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 238000002441 X-ray diffraction Methods 0.000 description 7
- 239000012265 solid product Substances 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 5
- 239000004809 Teflon Substances 0.000 description 5
- 229920006362 Teflon® Polymers 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000005119 centrifugation Methods 0.000 description 5
- 238000000921 elemental analysis Methods 0.000 description 5
- 239000000499 gel Substances 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 238000001144 powder X-ray diffraction data Methods 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- HADKRTWCOYPCPH-UHFFFAOYSA-M trimethylphenylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C1=CC=CC=C1 HADKRTWCOYPCPH-UHFFFAOYSA-M 0.000 description 5
- 150000001450 anions Chemical class 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 239000008119 colloidal silica Substances 0.000 description 3
- 238000005216 hydrothermal crystallization Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000000634 powder X-ray diffraction Methods 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 150000001242 acetic acid derivatives Chemical class 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- 150000004679 hydroxides Chemical class 0.000 description 2
- 150000002739 metals Chemical group 0.000 description 2
- 238000010899 nucleation Methods 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 150000003891 oxalate salts Chemical class 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229910018626 Al(OH) Inorganic materials 0.000 description 1
- 229910017090 AlO 2 Inorganic materials 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000010960 commercial process Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000000017 hydrogel Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910052605 nesosilicate Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 150000004762 orthosilicates Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000006303 photolysis reaction Methods 0.000 description 1
- 230000015843 photosynthesis, light reaction Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
- C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7015—CHA-type, e.g. Chabazite, LZ-218
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14/553,672 US9708192B2 (en) | 2014-11-25 | 2014-11-25 | Method for preparing aluminosilicate molecular sieves having the CHA framework type |
| US14/553,672 | 2014-11-25 | ||
| PCT/US2015/029461 WO2016085538A1 (en) | 2014-11-25 | 2015-05-06 | Method for preparing aluminosilicate molecular sieves having the cha framework type |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20170088886A KR20170088886A (ko) | 2017-08-02 |
| KR102297100B1 true KR102297100B1 (ko) | 2021-09-01 |
Family
ID=53177386
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020177015973A Active KR102297100B1 (ko) | 2014-11-25 | 2015-05-06 | Cha 프레임워크 형을 갖는 알루미노실리케이트 분자체의 제조 방법 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9708192B2 (enExample) |
| EP (1) | EP3224198B1 (enExample) |
| JP (1) | JP6383881B2 (enExample) |
| KR (1) | KR102297100B1 (enExample) |
| CN (1) | CN107108243B (enExample) |
| ES (1) | ES2857029T3 (enExample) |
| WO (1) | WO2016085538A1 (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9981853B2 (en) * | 2016-10-05 | 2018-05-29 | Chevron U.S.A. Inc. | Molecular sieve SSZ-107, its synthesis and use |
| JP2020502020A (ja) | 2016-12-21 | 2020-01-23 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 無溶媒ゼオライト転換によってゼオライト材料を製造する方法 |
| US10604413B2 (en) * | 2018-03-09 | 2020-03-31 | Chevron U.S.A. Inc. | Synthesis of *MRE framework type molecular sieves |
| US11267717B2 (en) | 2018-03-21 | 2022-03-08 | Basf Corporation | CHA zeolite material and related method of synthesis |
| EP3830032A1 (en) * | 2018-08-02 | 2021-06-09 | Basf Se | Process for a continuous synthesis of zeolitic materials using seed crystals loaded with organotemplate |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070043249A1 (en) | 2005-08-18 | 2007-02-22 | Guang Cao | Synthesis of molecular sieves having the chabazite framework type and their use in the conversion of oxygenates to olefins |
| US20070100185A1 (en) | 2005-10-31 | 2007-05-03 | Guang Cao | Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins |
| US20140147378A1 (en) | 2012-11-25 | 2014-05-29 | Chevron U.S.A. Inc. | Method for preparing cha-type molecular sieves using colloidal aluminosilicate |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4544538A (en) | 1982-07-09 | 1985-10-01 | Chevron Research Company | Zeolite SSZ-13 and its method of preparation |
| US7402297B2 (en) | 2004-11-29 | 2008-07-22 | Chevron U.S.A. Inc. | High-silica molecular sieve CHA |
| US7754187B2 (en) | 2005-10-31 | 2010-07-13 | Exxonmobil Chemical Patents Inc. | Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins |
| KR101398291B1 (ko) * | 2006-09-25 | 2014-05-22 | 셰브런 유.에스.에이.인크. | 구조지향제 및 n,n,n-트리알킬 벤질 4차 암모늄 양이온을 이용한 분자체 제조 방법 |
| US20080159950A1 (en) | 2006-12-27 | 2008-07-03 | Miller Stephen J | Preparation of molecular sieve ssz-13 |
| JP5417969B2 (ja) * | 2008-12-17 | 2014-02-19 | 東ソー株式会社 | N,n,n−トリメチル−ベンジルアンモニウムイオンを用いたチャバザイトの製造方法 |
| AU2010232555B2 (en) | 2009-04-02 | 2013-11-28 | Chevron U.S.A. Inc. | Method for preparing CHA-type molecular sieves using novel structure directing agents |
| US8734758B2 (en) * | 2010-11-05 | 2014-05-27 | Chevron U.S.A. Inc. | Method for preparing molecular sieves |
| JP5895510B2 (ja) | 2010-12-22 | 2016-03-30 | 東ソー株式会社 | チャバザイト型ゼオライト及びその製造方法、銅が担持されている低シリカゼオライト、及び、そのゼオライトを含む窒素酸化物還元除去触媒、並びに、その触媒を使用する窒素酸化物還元除去方法 |
| US9636667B2 (en) * | 2012-06-04 | 2017-05-02 | Basf Se | CHA-type zeolite materials and methods for their preparation using cycloalkyammonium compounds |
| CN105339343B (zh) * | 2013-03-08 | 2017-08-29 | 英国石油化学品有限公司 | 羰基化催化剂和方法 |
| US9643854B2 (en) * | 2014-11-14 | 2017-05-09 | Chevron U.S.A. Inc. | Method for making MAZ framework type zeolites |
| EP3313782B1 (en) * | 2015-06-29 | 2019-07-31 | Chevron U.S.A. Inc. | Synthesis of aluminosilicate zeolite ssz-98 |
-
2014
- 2014-11-25 US US14/553,672 patent/US9708192B2/en active Active
-
2015
- 2015-05-06 EP EP15722405.6A patent/EP3224198B1/en active Active
- 2015-05-06 KR KR1020177015973A patent/KR102297100B1/ko active Active
- 2015-05-06 CN CN201580069886.8A patent/CN107108243B/zh active Active
- 2015-05-06 WO PCT/US2015/029461 patent/WO2016085538A1/en not_active Ceased
- 2015-05-06 ES ES15722405T patent/ES2857029T3/es active Active
- 2015-05-06 JP JP2017545850A patent/JP6383881B2/ja active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070043249A1 (en) | 2005-08-18 | 2007-02-22 | Guang Cao | Synthesis of molecular sieves having the chabazite framework type and their use in the conversion of oxygenates to olefins |
| US20070100185A1 (en) | 2005-10-31 | 2007-05-03 | Guang Cao | Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins |
| US20140147378A1 (en) | 2012-11-25 | 2014-05-29 | Chevron U.S.A. Inc. | Method for preparing cha-type molecular sieves using colloidal aluminosilicate |
Also Published As
| Publication number | Publication date |
|---|---|
| JP6383881B2 (ja) | 2018-08-29 |
| JP2017538655A (ja) | 2017-12-28 |
| EP3224198B1 (en) | 2020-12-09 |
| CN107108243A (zh) | 2017-08-29 |
| US9708192B2 (en) | 2017-07-18 |
| US20160145111A1 (en) | 2016-05-26 |
| EP3224198A1 (en) | 2017-10-04 |
| ES2857029T3 (es) | 2021-09-28 |
| CN107108243B (zh) | 2019-04-02 |
| WO2016085538A1 (en) | 2016-06-02 |
| KR20170088886A (ko) | 2017-08-02 |
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