KR102205993B1 - 충격 공중합체를 위한 전촉매 입자 및 중합 방법 - Google Patents

충격 공중합체를 위한 전촉매 입자 및 중합 방법 Download PDF

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KR102205993B1
KR102205993B1 KR1020167016790A KR20167016790A KR102205993B1 KR 102205993 B1 KR102205993 B1 KR 102205993B1 KR 1020167016790 A KR1020167016790 A KR 1020167016790A KR 20167016790 A KR20167016790 A KR 20167016790A KR 102205993 B1 KR102205993 B1 KR 102205993B1
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propylene
micrometers
particles
polymerization
forming
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KR20160091952A (ko
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에그몬드 잔 더블유 반
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더블유.알. 그레이스 앤드 캄파니-콘.
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/001Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6493Catalysts containing a specific non-metal or metal-free compound organic containing halogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651Pretreating with non-metals or metal-free compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06Catalyst characterized by its size

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
KR1020167016790A 2013-11-27 2014-11-26 충격 공중합체를 위한 전촉매 입자 및 중합 방법 Active KR102205993B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201361909461P 2013-11-27 2013-11-27
US61/909,461 2013-11-27
PCT/US2014/067703 WO2015081254A1 (en) 2013-11-27 2014-11-26 Procatalyst particles and polymerization process for impact copolymers

Publications (2)

Publication Number Publication Date
KR20160091952A KR20160091952A (ko) 2016-08-03
KR102205993B1 true KR102205993B1 (ko) 2021-01-21

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020167016790A Active KR102205993B1 (ko) 2013-11-27 2014-11-26 충격 공중합체를 위한 전촉매 입자 및 중합 방법

Country Status (11)

Country Link
US (2) US10059784B2 (enExample)
EP (1) EP3074435B1 (enExample)
JP (2) JP6573885B2 (enExample)
KR (1) KR102205993B1 (enExample)
CN (2) CN105764936B (enExample)
BR (1) BR112016012033B1 (enExample)
ES (1) ES2901954T3 (enExample)
PL (1) PL3074435T3 (enExample)
RU (1) RU2709203C1 (enExample)
SA (1) SA516371206B1 (enExample)
WO (1) WO2015081254A1 (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3074435B1 (en) * 2013-11-27 2021-11-10 W.R. Grace & CO. - CONN. Procatalyst particles and polymerization process for impact copolymers
JP7536447B2 (ja) 2016-08-30 2024-08-20 ダブリュー・アール・グレース・アンド・カンパニー-コーン 低灰含量を有するポリオレフィン及び同ポリオレフィンを作製する方法
CN110382563B (zh) * 2017-03-17 2022-08-26 Sabic环球技术有限责任公司 用于制备用于烯烃聚合的主催化剂的方法
WO2019094216A1 (en) * 2017-11-13 2019-05-16 W.R. Grace & Co.-Conn. Catalyst components for propylene polymerization
WO2019094347A1 (en) * 2017-11-13 2019-05-16 W.R. Grace & Co.-Conn. Catalyst components for propylene polymerization
KR20230091125A (ko) * 2020-10-23 2023-06-22 더블유.알. 그레이스 앤드 캄파니-콘. Voc 함량이 감소한 충격 저항성 폴리프로필렌 중합체 조성물
US12319756B2 (en) 2021-06-25 2025-06-03 Braskem S. A. Propylene preliminary polymerization

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050054792A1 (en) 2001-05-29 2005-03-10 Kilty Peter A. Olefin polymerization catalyst compositions and method of preparation
US20100173769A1 (en) 2008-12-31 2010-07-08 Gonzalez Kelly A Enhanced Procatalyst Composition and Process
JP6573885B2 (ja) 2013-11-27 2019-09-11 ダブリュー・アール・グレース・アンド・カンパニー−コーンW R Grace & Co−Conn プロ触媒粒子及びインパクトコポリマーの重合方法

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US4882380A (en) 1987-07-07 1989-11-21 Union Carbide Chemicals And Plastics Company Inc. Process for the production of impact polypropylene copolymers
JPH0693061A (ja) * 1992-09-16 1994-04-05 Sumitomo Chem Co Ltd ポリプロピレンブロック共重合体及びそのフィルム
US5885924A (en) * 1995-06-07 1999-03-23 W. R. Grace & Co.-Conn. Halogenated supports and supported activators
FI981717L (fi) * 1998-08-07 2000-02-08 Borealis As Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektronidonorin, sen valmistus ja käyttö
FI981718A7 (fi) 1998-08-07 2000-02-08 Borealis As Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektrodonorin, sen valmistus ja käyttö
US7381779B2 (en) * 2003-09-23 2008-06-03 Dow Global Technologies Inc Self limiting catalyst composition with dicarboxylic acid ester internal donor and propylene polymerization process
US8067510B2 (en) 2007-08-24 2011-11-29 Union Carbide Chemicals & Plastics Technology Llc High melt flow propylene impact copolymer and method
US8788826B1 (en) 2008-06-06 2014-07-22 Marvell International Ltd. Method and apparatus for dynamically allocating a mobile network prefix to a mobile terminal
US8604118B2 (en) * 2008-12-26 2013-12-10 Dow Global Technologies Llc Antifoulant for impact copolymers and method
MX2011007139A (es) * 2008-12-31 2011-09-27 Dow Global Technologies Llc Composicion de procatalizador con donador interno de diéster aromático de 1,2-fenileno sustituido y método.
JP5448702B2 (ja) * 2009-10-14 2014-03-19 日本ポリプロ株式会社 プロピレン系ブロック共重合体の製造方法
US20120157295A1 (en) 2010-12-21 2012-06-21 Linfeng Chen Process for Producing Procatalyst Composition with Alkoxyalkyl Ester Internal Electron Donor and Product
US20120157645A1 (en) * 2010-12-21 2012-06-21 Linfeng Chen Procatalyst Composition with Alkoxypropyl Ester Internal Electron Donor and Polymer From Same
JP2014500384A (ja) * 2010-12-21 2014-01-09 ダウ グローバル テクノロジーズ エルエルシー アルコキシアルキルエステル内部電子供与体を有するプロ触媒組成物の製造方法および製品
US10358505B2 (en) * 2010-12-21 2019-07-23 W. R. Grace & Co.-Conn. Process for production of high melt flow propylene-based polymer and product from same
US9133286B2 (en) * 2011-08-30 2015-09-15 W. R. Grace & Co.-Conn Production of substituted phenylene dibenzoate internal electron donor and procatalyst with same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050054792A1 (en) 2001-05-29 2005-03-10 Kilty Peter A. Olefin polymerization catalyst compositions and method of preparation
US20100173769A1 (en) 2008-12-31 2010-07-08 Gonzalez Kelly A Enhanced Procatalyst Composition and Process
JP2012514126A (ja) 2008-12-31 2012-06-21 ダウ グローバル テクノロジーズ エルエルシー 強化されたプロ触媒組成物及びプロセス
JP6573885B2 (ja) 2013-11-27 2019-09-11 ダブリュー・アール・グレース・アンド・カンパニー−コーンW R Grace & Co−Conn プロ触媒粒子及びインパクトコポリマーの重合方法

Also Published As

Publication number Publication date
RU2016125244A (ru) 2018-01-09
JP6573885B2 (ja) 2019-09-11
US10059784B2 (en) 2018-08-28
RU2709203C1 (ru) 2019-12-17
JP6869276B2 (ja) 2021-05-12
CN108503734B (zh) 2021-09-03
EP3074435A4 (en) 2017-06-28
SA516371206B1 (ar) 2019-07-31
BR112016012033B1 (pt) 2021-02-09
EP3074435A1 (en) 2016-10-05
ES2901954T3 (es) 2022-03-24
WO2015081254A1 (en) 2015-06-04
US20180305479A1 (en) 2018-10-25
CN105764936B (zh) 2018-05-11
PL3074435T3 (pl) 2022-01-24
CN105764936A (zh) 2016-07-13
EP3074435B1 (en) 2021-11-10
US20160297906A1 (en) 2016-10-13
JP2019131811A (ja) 2019-08-08
JP2016538396A (ja) 2016-12-08
CN108503734A (zh) 2018-09-07
KR20160091952A (ko) 2016-08-03

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