KR102205993B1 - 충격 공중합체를 위한 전촉매 입자 및 중합 방법 - Google Patents
충격 공중합체를 위한 전촉매 입자 및 중합 방법 Download PDFInfo
- Publication number
- KR102205993B1 KR102205993B1 KR1020167016790A KR20167016790A KR102205993B1 KR 102205993 B1 KR102205993 B1 KR 102205993B1 KR 1020167016790 A KR1020167016790 A KR 1020167016790A KR 20167016790 A KR20167016790 A KR 20167016790A KR 102205993 B1 KR102205993 B1 KR 102205993B1
- Authority
- KR
- South Korea
- Prior art keywords
- propylene
- micrometers
- particles
- polymerization
- forming
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/647—Catalysts containing a specific non-metal or metal-free compound
- C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
- C08F4/6493—Catalysts containing a specific non-metal or metal-free compound organic containing halogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/651—Pretreating with non-metals or metal-free compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/06—Catalyst characterized by its size
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361909461P | 2013-11-27 | 2013-11-27 | |
| US61/909,461 | 2013-11-27 | ||
| PCT/US2014/067703 WO2015081254A1 (en) | 2013-11-27 | 2014-11-26 | Procatalyst particles and polymerization process for impact copolymers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20160091952A KR20160091952A (ko) | 2016-08-03 |
| KR102205993B1 true KR102205993B1 (ko) | 2021-01-21 |
Family
ID=53199650
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020167016790A Active KR102205993B1 (ko) | 2013-11-27 | 2014-11-26 | 충격 공중합체를 위한 전촉매 입자 및 중합 방법 |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US10059784B2 (enExample) |
| EP (1) | EP3074435B1 (enExample) |
| JP (2) | JP6573885B2 (enExample) |
| KR (1) | KR102205993B1 (enExample) |
| CN (2) | CN105764936B (enExample) |
| BR (1) | BR112016012033B1 (enExample) |
| ES (1) | ES2901954T3 (enExample) |
| PL (1) | PL3074435T3 (enExample) |
| RU (1) | RU2709203C1 (enExample) |
| SA (1) | SA516371206B1 (enExample) |
| WO (1) | WO2015081254A1 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3074435B1 (en) * | 2013-11-27 | 2021-11-10 | W.R. Grace & CO. - CONN. | Procatalyst particles and polymerization process for impact copolymers |
| JP7536447B2 (ja) | 2016-08-30 | 2024-08-20 | ダブリュー・アール・グレース・アンド・カンパニー-コーン | 低灰含量を有するポリオレフィン及び同ポリオレフィンを作製する方法 |
| CN110382563B (zh) * | 2017-03-17 | 2022-08-26 | Sabic环球技术有限责任公司 | 用于制备用于烯烃聚合的主催化剂的方法 |
| WO2019094216A1 (en) * | 2017-11-13 | 2019-05-16 | W.R. Grace & Co.-Conn. | Catalyst components for propylene polymerization |
| WO2019094347A1 (en) * | 2017-11-13 | 2019-05-16 | W.R. Grace & Co.-Conn. | Catalyst components for propylene polymerization |
| KR20230091125A (ko) * | 2020-10-23 | 2023-06-22 | 더블유.알. 그레이스 앤드 캄파니-콘. | Voc 함량이 감소한 충격 저항성 폴리프로필렌 중합체 조성물 |
| US12319756B2 (en) | 2021-06-25 | 2025-06-03 | Braskem S. A. | Propylene preliminary polymerization |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050054792A1 (en) | 2001-05-29 | 2005-03-10 | Kilty Peter A. | Olefin polymerization catalyst compositions and method of preparation |
| US20100173769A1 (en) | 2008-12-31 | 2010-07-08 | Gonzalez Kelly A | Enhanced Procatalyst Composition and Process |
| JP6573885B2 (ja) | 2013-11-27 | 2019-09-11 | ダブリュー・アール・グレース・アンド・カンパニー−コーンW R Grace & Co−Conn | プロ触媒粒子及びインパクトコポリマーの重合方法 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4882380A (en) | 1987-07-07 | 1989-11-21 | Union Carbide Chemicals And Plastics Company Inc. | Process for the production of impact polypropylene copolymers |
| JPH0693061A (ja) * | 1992-09-16 | 1994-04-05 | Sumitomo Chem Co Ltd | ポリプロピレンブロック共重合体及びそのフィルム |
| US5885924A (en) * | 1995-06-07 | 1999-03-23 | W. R. Grace & Co.-Conn. | Halogenated supports and supported activators |
| FI981717L (fi) * | 1998-08-07 | 2000-02-08 | Borealis As | Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektronidonorin, sen valmistus ja käyttö |
| FI981718A7 (fi) | 1998-08-07 | 2000-02-08 | Borealis As | Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektrodonorin, sen valmistus ja käyttö |
| US7381779B2 (en) * | 2003-09-23 | 2008-06-03 | Dow Global Technologies Inc | Self limiting catalyst composition with dicarboxylic acid ester internal donor and propylene polymerization process |
| US8067510B2 (en) | 2007-08-24 | 2011-11-29 | Union Carbide Chemicals & Plastics Technology Llc | High melt flow propylene impact copolymer and method |
| US8788826B1 (en) | 2008-06-06 | 2014-07-22 | Marvell International Ltd. | Method and apparatus for dynamically allocating a mobile network prefix to a mobile terminal |
| US8604118B2 (en) * | 2008-12-26 | 2013-12-10 | Dow Global Technologies Llc | Antifoulant for impact copolymers and method |
| MX2011007139A (es) * | 2008-12-31 | 2011-09-27 | Dow Global Technologies Llc | Composicion de procatalizador con donador interno de diéster aromático de 1,2-fenileno sustituido y método. |
| JP5448702B2 (ja) * | 2009-10-14 | 2014-03-19 | 日本ポリプロ株式会社 | プロピレン系ブロック共重合体の製造方法 |
| US20120157295A1 (en) | 2010-12-21 | 2012-06-21 | Linfeng Chen | Process for Producing Procatalyst Composition with Alkoxyalkyl Ester Internal Electron Donor and Product |
| US20120157645A1 (en) * | 2010-12-21 | 2012-06-21 | Linfeng Chen | Procatalyst Composition with Alkoxypropyl Ester Internal Electron Donor and Polymer From Same |
| JP2014500384A (ja) * | 2010-12-21 | 2014-01-09 | ダウ グローバル テクノロジーズ エルエルシー | アルコキシアルキルエステル内部電子供与体を有するプロ触媒組成物の製造方法および製品 |
| US10358505B2 (en) * | 2010-12-21 | 2019-07-23 | W. R. Grace & Co.-Conn. | Process for production of high melt flow propylene-based polymer and product from same |
| US9133286B2 (en) * | 2011-08-30 | 2015-09-15 | W. R. Grace & Co.-Conn | Production of substituted phenylene dibenzoate internal electron donor and procatalyst with same |
-
2014
- 2014-11-26 EP EP14865185.4A patent/EP3074435B1/en active Active
- 2014-11-26 CN CN201480064998.XA patent/CN105764936B/zh active Active
- 2014-11-26 JP JP2016534668A patent/JP6573885B2/ja active Active
- 2014-11-26 US US15/036,365 patent/US10059784B2/en active Active
- 2014-11-26 KR KR1020167016790A patent/KR102205993B1/ko active Active
- 2014-11-26 WO PCT/US2014/067703 patent/WO2015081254A1/en not_active Ceased
- 2014-11-26 PL PL14865185T patent/PL3074435T3/pl unknown
- 2014-11-26 RU RU2016125244A patent/RU2709203C1/ru active
- 2014-11-26 ES ES14865185T patent/ES2901954T3/es active Active
- 2014-11-26 BR BR112016012033-7A patent/BR112016012033B1/pt active IP Right Grant
- 2014-11-26 CN CN201810337337.XA patent/CN108503734B/zh active Active
-
2016
- 2016-05-26 SA SA516371206A patent/SA516371206B1/ar unknown
-
2018
- 2018-06-27 US US16/019,693 patent/US20180305479A1/en not_active Abandoned
-
2019
- 2019-02-07 JP JP2019020934A patent/JP6869276B2/ja active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050054792A1 (en) | 2001-05-29 | 2005-03-10 | Kilty Peter A. | Olefin polymerization catalyst compositions and method of preparation |
| US20100173769A1 (en) | 2008-12-31 | 2010-07-08 | Gonzalez Kelly A | Enhanced Procatalyst Composition and Process |
| JP2012514126A (ja) | 2008-12-31 | 2012-06-21 | ダウ グローバル テクノロジーズ エルエルシー | 強化されたプロ触媒組成物及びプロセス |
| JP6573885B2 (ja) | 2013-11-27 | 2019-09-11 | ダブリュー・アール・グレース・アンド・カンパニー−コーンW R Grace & Co−Conn | プロ触媒粒子及びインパクトコポリマーの重合方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| RU2016125244A (ru) | 2018-01-09 |
| JP6573885B2 (ja) | 2019-09-11 |
| US10059784B2 (en) | 2018-08-28 |
| RU2709203C1 (ru) | 2019-12-17 |
| JP6869276B2 (ja) | 2021-05-12 |
| CN108503734B (zh) | 2021-09-03 |
| EP3074435A4 (en) | 2017-06-28 |
| SA516371206B1 (ar) | 2019-07-31 |
| BR112016012033B1 (pt) | 2021-02-09 |
| EP3074435A1 (en) | 2016-10-05 |
| ES2901954T3 (es) | 2022-03-24 |
| WO2015081254A1 (en) | 2015-06-04 |
| US20180305479A1 (en) | 2018-10-25 |
| CN105764936B (zh) | 2018-05-11 |
| PL3074435T3 (pl) | 2022-01-24 |
| CN105764936A (zh) | 2016-07-13 |
| EP3074435B1 (en) | 2021-11-10 |
| US20160297906A1 (en) | 2016-10-13 |
| JP2019131811A (ja) | 2019-08-08 |
| JP2016538396A (ja) | 2016-12-08 |
| CN108503734A (zh) | 2018-09-07 |
| KR20160091952A (ko) | 2016-08-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0105 | International application |
Patent event date: 20160623 Patent event code: PA01051R01D Comment text: International Patent Application |
|
| PG1501 | Laying open of application | ||
| PA0201 | Request for examination |
Patent event code: PA02012R01D Patent event date: 20191126 Comment text: Request for Examination of Application |
|
| E701 | Decision to grant or registration of patent right | ||
| PE0701 | Decision of registration |
Patent event code: PE07011S01D Comment text: Decision to Grant Registration Patent event date: 20201113 |
|
| PR0701 | Registration of establishment |
Comment text: Registration of Establishment Patent event date: 20210115 Patent event code: PR07011E01D |
|
| PR1002 | Payment of registration fee |
Payment date: 20210118 End annual number: 3 Start annual number: 1 |
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| PG1601 | Publication of registration | ||
| PR1001 | Payment of annual fee |
Payment date: 20241226 Start annual number: 5 End annual number: 5 |