KR102138986B1 - 올레핀 중합용 촉매 성분들 - Google Patents
올레핀 중합용 촉매 성분들 Download PDFInfo
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- KR102138986B1 KR102138986B1 KR1020187011146A KR20187011146A KR102138986B1 KR 102138986 B1 KR102138986 B1 KR 102138986B1 KR 1020187011146 A KR1020187011146 A KR 1020187011146A KR 20187011146 A KR20187011146 A KR 20187011146A KR 102138986 B1 KR102138986 B1 KR 102138986B1
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- solid catalyst
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
- C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
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- C—CHEMISTRY; METALLURGY
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/12—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
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- C—CHEMISTRY; METALLURGY
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
- C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/651—Pretreating with non-metals or metal-free compounds
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- C—CHEMISTRY; METALLURGY
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
- C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
- C08F4/6545—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium and metals of C08F4/64 or compounds thereof
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/657—Pretreating with metals or metal-containing compounds with metals or metal-containing compounds, not provided for in groups C08F4/653 - C08F4/656
- C08F4/6574—Pretreating with metals or metal-containing compounds with metals or metal-containing compounds, not provided for in groups C08F4/653 - C08F4/656 and magnesium or compounds thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/657—Pretreating with metals or metal-containing compounds with metals or metal-containing compounds, not provided for in groups C08F4/653 - C08F4/656
- C08F4/6576—Pretreating with metals or metal-containing compounds with metals or metal-containing compounds, not provided for in groups C08F4/653 - C08F4/656 and aluminium or compounds thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/658—Pretreating with metals or metal-containing compounds with metals or metal-containing compounds, not provided for in a single group of groups C08F4/653 - C08F4/657
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- C—CHEMISTRY; METALLURGY
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/12—Melt flow index or melt flow ratio
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP14159900 | 2014-03-14 | ||
| EP14159900.1 | 2014-03-14 | ||
| PCT/EP2015/054900 WO2015135903A1 (en) | 2014-03-14 | 2015-03-10 | Catalyst components for the polymerization of olefins |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020167026837A Division KR20170003528A (ko) | 2014-03-14 | 2015-03-10 | 올레핀 중합용 촉매 성분들 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20180042471A KR20180042471A (ko) | 2018-04-25 |
| KR102138986B1 true KR102138986B1 (ko) | 2020-07-29 |
Family
ID=50277081
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020187011146A Active KR102138986B1 (ko) | 2014-03-14 | 2015-03-10 | 올레핀 중합용 촉매 성분들 |
| KR1020167026837A Ceased KR20170003528A (ko) | 2014-03-14 | 2015-03-10 | 올레핀 중합용 촉매 성분들 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020167026837A Ceased KR20170003528A (ko) | 2014-03-14 | 2015-03-10 | 올레핀 중합용 촉매 성분들 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US10113012B2 (enExample) |
| EP (1) | EP3116921B1 (enExample) |
| JP (1) | JP6470302B2 (enExample) |
| KR (2) | KR102138986B1 (enExample) |
| CN (1) | CN106170500B (enExample) |
| BR (1) | BR112016020160B1 (enExample) |
| ES (1) | ES2974931T3 (enExample) |
| FI (1) | FI3116921T3 (enExample) |
| RU (1) | RU2649386C2 (enExample) |
| WO (1) | WO2015135903A1 (enExample) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102059756B1 (ko) * | 2015-08-06 | 2019-12-26 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 프로필렌-에틸렌-1-부텐 터폴리머를 포함하는 필름 |
| EP3347384B1 (en) * | 2015-09-10 | 2020-03-25 | Basell Poliolefine Italia S.r.l. | Catalyst for the polymerization of olefins |
| CN107949587B (zh) * | 2015-09-11 | 2020-04-28 | 巴塞尔聚烯烃意大利有限公司 | 用于制备烯烃聚合用催化剂组分的工艺 |
| RU2721529C2 (ru) * | 2015-11-05 | 2020-05-19 | Базелл Полиолефин Италия С.Р.Л. | Гетерофазные пропиленовые сополимеры |
| US10556972B2 (en) | 2016-11-04 | 2020-02-11 | Basell Poliolefine Italia S.R.L. | Process for the polymerization of olefins |
| US11466107B2 (en) | 2018-02-05 | 2022-10-11 | Basell Poliolefine Italia S.R.L. | Components and catalysts for the polymerization of olefins |
| US10722874B2 (en) | 2018-04-16 | 2020-07-28 | Chevron Phillips Chemical Company Lp | Methods of preparing a catalyst utilizing hydrated reagents |
| BR112021000518A2 (pt) | 2018-08-14 | 2021-04-06 | Basell Poliolefine Italia S.R.L. | Componentes e catalisadores para a polimerização de olefinas |
| CN110938161B (zh) * | 2018-09-25 | 2022-05-24 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂体系和预聚合催化剂组合物及它们的应用 |
| CN113179643B (zh) * | 2019-01-09 | 2024-07-05 | 巴塞尔聚烯烃意大利有限公司 | 用于烯烃聚合的催化剂组分 |
| CN114269794B (zh) * | 2019-09-17 | 2023-03-28 | 巴塞尔聚烯烃意大利有限公司 | 用于烯烃聚合的催化剂组分 |
| CN112707989B (zh) * | 2019-10-25 | 2022-08-19 | 中国石油化工股份有限公司 | 一种不含塑化剂的乙丙无规共聚物和应用 |
| CN112707991B (zh) * | 2019-10-25 | 2022-08-19 | 中国石油化工股份有限公司 | 一种乙丙无规共聚物及其制备方法 |
| KR102495156B1 (ko) | 2019-11-20 | 2023-02-06 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 촉매 성분의 제조 공정 및 그로부터 얻어지는 성분 |
| US12012476B2 (en) | 2019-12-04 | 2024-06-18 | Basell Poliolefine Italia S.R.L. | Catalyst for the polymerization of olefins |
| KR102564046B1 (ko) * | 2021-01-26 | 2023-09-06 | 엘에스일렉트릭(주) | 인버터 모듈 |
| CN117467044A (zh) * | 2022-07-21 | 2024-01-30 | 中国石油化工股份有限公司 | 烯烃聚合用催化剂载体及其制备方法与应用 |
| CN117467045A (zh) * | 2022-07-21 | 2024-01-30 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分与催化剂及其应用 |
| CN117467037A (zh) * | 2022-07-21 | 2024-01-30 | 中国石油化工股份有限公司 | 烯烃聚合用催化剂载体及其制备方法与应用 |
| CN117467043A (zh) * | 2022-07-21 | 2024-01-30 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分与用于烯烃聚合的催化剂及其应用 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2818642A1 (de) | 1977-04-30 | 1978-11-02 | Mitsubishi Petrochemical Co | Verfahren zur herstellung von olefinpolymeren |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS53134888A (en) * | 1977-04-30 | 1978-11-24 | Mitsubishi Petrochem Co Ltd | Preparation of olefin polymer |
| JPS5490382A (en) * | 1977-12-28 | 1979-07-18 | Mitsubishi Petrochem Co Ltd | Preparation of olefin polymer |
| JPS54158489A (en) * | 1978-06-05 | 1979-12-14 | Mitsubishi Petrochem Co Ltd | Polymerization of olefin |
| JPS5582103A (en) | 1978-12-15 | 1980-06-20 | Mitsubishi Petrochem Co Ltd | Production of alpha-olefin polymer |
| CN1086191C (zh) | 1998-03-17 | 2002-06-12 | 中国石油化工集团公司 | 用于乙烯聚合或共聚合的催化剂及其制法 |
| WO1999048929A1 (en) * | 1998-03-23 | 1999-09-30 | Montell Technology Company B.V. | Prepolymerized catalyst components for the polymerization of olefins |
| JP5069414B2 (ja) | 2002-12-18 | 2012-11-07 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 二塩化マグネシウムベースの付加物およびそれから得られる触媒成分 |
| ES2368425T3 (es) | 2002-12-18 | 2011-11-17 | Basell Poliolefine Italia S.R.L. | Aductos basados en dicloruro magnésico y componentes catalíticos obtenidos a partir de ellos. |
| JP5490382B2 (ja) * | 2008-07-17 | 2014-05-14 | サイエンス株式会社 | 水熱源式ヒートポンプ |
| WO2012041944A1 (en) * | 2010-09-30 | 2012-04-05 | Basell Poliolefine Italia S.R.L. | Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom |
| CN102453181A (zh) * | 2010-10-29 | 2012-05-16 | 中国石油化工股份有限公司 | 一种丙烯乙烯无规共聚物 |
| CN103270056B (zh) * | 2010-12-24 | 2019-02-12 | 巴塞尔聚烯烃意大利有限责任公司 | 氯化镁-乙醇加合物和由其获得的催化剂组分 |
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2015
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- 2015-03-10 EP EP15711084.2A patent/EP3116921B1/en active Active
- 2015-03-10 FI FIEP15711084.2T patent/FI3116921T3/fi active
- 2015-03-10 CN CN201580012807.XA patent/CN106170500B/zh active Active
- 2015-03-10 KR KR1020187011146A patent/KR102138986B1/ko active Active
- 2015-03-10 KR KR1020167026837A patent/KR20170003528A/ko not_active Ceased
- 2015-03-10 US US15/123,108 patent/US10113012B2/en active Active
- 2015-03-10 BR BR112016020160-4A patent/BR112016020160B1/pt active IP Right Grant
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2818642A1 (de) | 1977-04-30 | 1978-11-02 | Mitsubishi Petrochemical Co | Verfahren zur herstellung von olefinpolymeren |
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|---|---|
| CN106170500B (zh) | 2020-06-12 |
| EP3116921B1 (en) | 2024-01-10 |
| KR20170003528A (ko) | 2017-01-09 |
| KR20180042471A (ko) | 2018-04-25 |
| US20170066851A1 (en) | 2017-03-09 |
| EP3116921A1 (en) | 2017-01-18 |
| BR112016020160A2 (enExample) | 2017-08-15 |
| ES2974931T3 (es) | 2024-07-02 |
| FI3116921T3 (fi) | 2024-02-14 |
| RU2649386C2 (ru) | 2018-04-03 |
| BR112016020160B1 (pt) | 2021-12-14 |
| RU2016138464A (ru) | 2018-04-02 |
| CN106170500A (zh) | 2016-11-30 |
| WO2015135903A1 (en) | 2015-09-17 |
| US10113012B2 (en) | 2018-10-30 |
| JP6470302B2 (ja) | 2019-02-13 |
| JP2017507222A (ja) | 2017-03-16 |
| RU2016138464A3 (enExample) | 2018-04-02 |
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