KR101877069B1 - 비닐 방향족 단량체 중합을 저해하는 방법 및 조성물 - Google Patents

비닐 방향족 단량체 중합을 저해하는 방법 및 조성물 Download PDF

Info

Publication number
KR101877069B1
KR101877069B1 KR1020127031218A KR20127031218A KR101877069B1 KR 101877069 B1 KR101877069 B1 KR 101877069B1 KR 1020127031218 A KR1020127031218 A KR 1020127031218A KR 20127031218 A KR20127031218 A KR 20127031218A KR 101877069 B1 KR101877069 B1 KR 101877069B1
Authority
KR
South Korea
Prior art keywords
vinyl aromatic
alkyl
monomer
polymerization
quinone methide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020127031218A
Other languages
English (en)
Korean (ko)
Other versions
KR20130122517A (ko
Inventor
비노드 쿠마르 라이
쉐리프 엘딘
메리 킹
존 린크
알라가르사미 에이 수비아
에이치 켈리 헤링톤
Original Assignee
제너럴 일렉트릭 캄파니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 제너럴 일렉트릭 캄파니 filed Critical 제너럴 일렉트릭 캄파니
Publication of KR20130122517A publication Critical patent/KR20130122517A/ko
Application granted granted Critical
Publication of KR101877069B1 publication Critical patent/KR101877069B1/ko
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/20—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Analytical Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
KR1020127031218A 2010-06-03 2011-05-10 비닐 방향족 단량체 중합을 저해하는 방법 및 조성물 Active KR101877069B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12/793,226 US8298440B2 (en) 2010-06-03 2010-06-03 Methods and compositions for inhibiting vinyl aromatic monomer polymerization
US12/793,226 2010-06-03
PCT/US2011/035934 WO2011152961A2 (en) 2010-06-03 2011-05-10 Methods and compositions for inhibiting vinyl aromatic monomer polymerization

Publications (2)

Publication Number Publication Date
KR20130122517A KR20130122517A (ko) 2013-11-07
KR101877069B1 true KR101877069B1 (ko) 2018-07-10

Family

ID=44626629

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020127031218A Active KR101877069B1 (ko) 2010-06-03 2011-05-10 비닐 방향족 단량체 중합을 저해하는 방법 및 조성물

Country Status (14)

Country Link
US (2) US8298440B2 (enExample)
EP (1) EP2576718B1 (enExample)
JP (1) JP5683692B2 (enExample)
KR (1) KR101877069B1 (enExample)
AR (1) AR081555A1 (enExample)
BR (1) BR112012028981B1 (enExample)
CA (1) CA2800495C (enExample)
ES (1) ES2621605T3 (enExample)
MX (1) MX2012014075A (enExample)
MY (1) MY158328A (enExample)
PL (1) PL2576718T3 (enExample)
SG (1) SG185758A1 (enExample)
TW (1) TWI501947B (enExample)
WO (1) WO2011152961A2 (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8901362B2 (en) * 2012-02-02 2014-12-02 General Electric Company Methods and compositions for styrene inhibition via in situ generation of quinone methides
ES2686127T3 (es) 2012-08-24 2018-10-16 Dorf Ketal Chemicals (India) Private Limited Composición de derivados de métido de quinona y aminas para el control y la inhibición de la polimerización de monómeros, y procedimiento de preparación y uso de la misma
US20150361013A1 (en) * 2013-02-19 2015-12-17 General Electric Company Use of aliphatic nitroso compounds as inhibitors of radical polymerization of activated vinyl monomers
KR102091718B1 (ko) * 2016-02-13 2020-03-20 도르프 케탈 케미칼즈 (인디아) 프라이비트 리미티드 비닐 방향족 모노머의 중합의 조절 및 억제를 위한 조성물, 및 이의 사용 방법
CN109651040A (zh) * 2017-10-12 2019-04-19 中国石油化工股份有限公司 高级炔烃复配阻聚剂
CN110878209A (zh) * 2018-09-05 2020-03-13 中国石油化工股份有限公司 用于苯乙烯精馏系统的环保阻聚剂及其应用
CN116553996A (zh) * 2023-07-07 2023-08-08 吉林金海化工新材料有限公司 一种阻聚剂及其应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4040911A (en) * 1976-01-02 1977-08-09 Gulf Research & Development Company Process for inhibiting the polymerization of styrene
US5616774A (en) * 1995-04-14 1997-04-01 Ciba-Geigy Corporation Inhibition of unsaturated monomers with 7-aryl quinone methides
KR20000068400A (ko) * 1996-09-04 2000-11-25 그래햄 이. 테일러 폴리올레핀에 유리 라디칼 억제제를 혼입하여 열화를 억제하는방법

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3741906A (en) * 1971-12-17 1973-06-26 Exxon Research Engineering Co Hindered phenoxy radicals
US4032547A (en) 1976-02-23 1977-06-28 Gulf Research & Development Company Quinone alkide synthesis system
US4929778A (en) 1989-06-05 1990-05-29 Betz Laboratories, Inc. Methods and compositions for inhibiting styrene polymerization
US5470440A (en) 1994-04-19 1995-11-28 Betz Laboratories, Inc. Method for inhibiting vinyl aromatic monomer polymerization
EP0744392A1 (en) * 1995-05-26 1996-11-27 Ciba-Geigy Ag A new one-pot process for the preparation of 7-aryl-2,6-disubstituted quinone methides
JPH09227608A (ja) * 1996-02-22 1997-09-02 Asahi Chem Ind Co Ltd スチレンーアクリロニトリル系樹脂の製造方法
US6024894A (en) 1998-03-25 2000-02-15 Betzdearborn Inc. Compositions and methods for inhibiting vinyl aromatic monomer polymerization
JP4248875B2 (ja) * 2000-10-16 2009-04-02 ケムチュア コーポレイション 重合抑制剤としての、キノンアルカイドとニトロキシル化合物の混合物
US20030065177A1 (en) * 2001-08-08 2003-04-03 Crompton Corporation, A Corporation Of The State Of Delaware High boiling inhibitors for distillable, polymerizable monomers
US6960279B2 (en) * 2002-05-06 2005-11-01 Fina Technology, Inc. Method for stabilizing vinyl aromatic monomers using selected polymerization inhibitors and polymers prepared therewith
US6926820B2 (en) 2002-09-20 2005-08-09 G.E. Betz, Inc. Inhibition of viscosity increase and fouling in hydrocarbon streams including unsaturation
JP4790414B2 (ja) * 2003-03-17 2011-10-12 伯東株式会社 芳香族ビニル化合物の重合抑制剤および重合抑制方法
JP2004352735A (ja) * 2003-05-27 2004-12-16 Techno Network Shikoku Co Ltd ラジカル重合体の製造方法
US7128826B2 (en) 2003-07-31 2006-10-31 General Electric Company Polymerization inhibitor for styrene dehydrogenation units
DE102007052891A1 (de) * 2007-11-02 2009-05-07 Evonik Degussa Gmbh Verfahren zur Stabilisierung von olefinisch ungesättigten Monomeren
JP5139103B2 (ja) * 2008-02-05 2013-02-06 京セラドキュメントソリューションズ株式会社 電子写真感光体及び画像形成装置
JP5266991B2 (ja) * 2008-09-11 2013-08-21 コニカミノルタビジネステクノロジーズ株式会社 電子写真感光体とそれを用いた画像形成装置

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4040911A (en) * 1976-01-02 1977-08-09 Gulf Research & Development Company Process for inhibiting the polymerization of styrene
US5616774A (en) * 1995-04-14 1997-04-01 Ciba-Geigy Corporation Inhibition of unsaturated monomers with 7-aryl quinone methides
KR20000068400A (ko) * 1996-09-04 2000-11-25 그래햄 이. 테일러 폴리올레핀에 유리 라디칼 억제제를 혼입하여 열화를 억제하는방법

Also Published As

Publication number Publication date
US8298440B2 (en) 2012-10-30
CA2800495C (en) 2019-07-09
SG185758A1 (en) 2012-12-28
JP5683692B2 (ja) 2015-03-11
PL2576718T3 (pl) 2017-11-30
MX2012014075A (es) 2013-01-25
TW201202192A (en) 2012-01-16
US20130030225A1 (en) 2013-01-31
EP2576718A2 (en) 2013-04-10
JP2013539473A (ja) 2013-10-24
KR20130122517A (ko) 2013-11-07
TWI501947B (zh) 2015-10-01
BR112012028981A2 (pt) 2016-07-26
WO2011152961A3 (en) 2013-08-22
CA2800495A1 (en) 2011-12-08
WO2011152961A2 (en) 2011-12-08
BR112012028981B1 (pt) 2020-10-20
ES2621605T3 (es) 2017-07-04
MY158328A (en) 2016-09-30
US20110297878A1 (en) 2011-12-08
AR081555A1 (es) 2012-10-03
EP2576718B1 (en) 2017-01-11

Similar Documents

Publication Publication Date Title
KR101877069B1 (ko) 비닐 방향족 단량체 중합을 저해하는 방법 및 조성물
CA1323634C (en) Methods and compositions for inhibiting styrene polymerization
KR100500179B1 (ko) 비닐방향족단량체의중합억제용조성물및중합억제방법
US5648574A (en) Compositions and methods for inhibiting vinyl aromatic monomer polymerization
CA2888957C (en) Quinone compounds for inhibiting monomer polymerization
KR101660610B1 (ko) 퀴논 메타이드의 인-시튜 생성을 통한 스티렌 억제 방법 및 조성물
MXPA03000704A (es) Inhibidor de polimerizacion para materiales que contienen vinilo.
EP2958949A1 (en) Use of aliphatic nitroso compounds as inhibitors of radical polymerization of activated vinyl monomers
RU2039757C1 (ru) Способ ингибирования полимеризации винилароматических мономеров
JP2000504022A (ja) 重合防止剤組成物
JPS5941971B2 (ja) 芳香族ビニル化合物の重合抑制方法

Legal Events

Date Code Title Description
PA0105 International application

Patent event date: 20121129

Patent event code: PA01051R01D

Comment text: International Patent Application

PG1501 Laying open of application
PA0201 Request for examination

Patent event code: PA02012R01D

Patent event date: 20160412

Comment text: Request for Examination of Application

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

Comment text: Notification of reason for refusal

Patent event date: 20171101

Patent event code: PE09021S01D

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

Patent event code: PE07011S01D

Comment text: Decision to Grant Registration

Patent event date: 20180502

GRNT Written decision to grant
PR0701 Registration of establishment

Comment text: Registration of Establishment

Patent event date: 20180704

Patent event code: PR07011E01D

PR1002 Payment of registration fee

Payment date: 20180704

End annual number: 3

Start annual number: 1

PG1601 Publication of registration
PR1001 Payment of annual fee

Payment date: 20210625

Start annual number: 4

End annual number: 4

PR1001 Payment of annual fee

Payment date: 20220623

Start annual number: 5

End annual number: 5

PR1001 Payment of annual fee

Payment date: 20240620

Start annual number: 7

End annual number: 7

PR1001 Payment of annual fee

Payment date: 20250619

Start annual number: 8

End annual number: 8