KR101866918B1 - 아산화질소 재생가능 실온 정제기 및 방법 - Google Patents
아산화질소 재생가능 실온 정제기 및 방법 Download PDFInfo
- Publication number
- KR101866918B1 KR101866918B1 KR1020147028597A KR20147028597A KR101866918B1 KR 101866918 B1 KR101866918 B1 KR 101866918B1 KR 1020147028597 A KR1020147028597 A KR 1020147028597A KR 20147028597 A KR20147028597 A KR 20147028597A KR 101866918 B1 KR101866918 B1 KR 101866918B1
- Authority
- KR
- South Korea
- Prior art keywords
- purifier
- room temperature
- regenerable
- nickel
- oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 title abstract description 20
- 238000000034 method Methods 0.000 title abstract description 17
- 239000001272 nitrous oxide Substances 0.000 title abstract description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 58
- 239000000463 material Substances 0.000 claims abstract description 30
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 26
- 229910000480 nickel oxide Inorganic materials 0.000 claims abstract description 26
- 238000000746 purification Methods 0.000 claims abstract description 23
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000007670 refining Methods 0.000 claims abstract description 10
- 230000008929 regeneration Effects 0.000 claims description 9
- 238000011069 regeneration method Methods 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 239000000395 magnesium oxide Substances 0.000 claims description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 4
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims 1
- 239000007789 gas Substances 0.000 description 16
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 230000008569 process Effects 0.000 description 10
- 238000001994 activation Methods 0.000 description 7
- 239000012535 impurity Substances 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000011159 matrix material Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000002808 molecular sieve Substances 0.000 description 2
- 230000007420 reactivation Effects 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000007791 dehumidification Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/20—Nitrogen oxides; Oxyacids of nitrogen; Salts thereof
- C01B21/22—Nitrous oxide (N2O)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0462—Temperature swing adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/62—Carbon oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/112—Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
- B01D2253/1122—Metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/112—Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
- B01D2253/1124—Metal oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/80—Water
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/96—Regeneration, reactivation or recycling of reactants
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2210/00—Purification or separation of specific gases
- C01B2210/0001—Separation or purification processing
- C01B2210/0009—Physical processing
- C01B2210/0014—Physical processing by adsorption in solids
- C01B2210/0015—Physical processing by adsorption in solids characterised by the adsorbent
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2210/00—Purification or separation of specific gases
- C01B2210/0043—Impurity removed
- C01B2210/005—Carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2210/00—Purification or separation of specific gases
- C01B2210/0043—Impurity removed
- C01B2210/0051—Carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2210/00—Purification or separation of specific gases
- C01B2210/0043—Impurity removed
- C01B2210/0062—Water
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/10—Capture or disposal of greenhouse gases of nitrous oxide (N2O)
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Emergency Medicine (AREA)
- Environmental & Geological Engineering (AREA)
- Biomedical Technology (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Catalysts (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Separation Of Gases By Adsorption (AREA)
- Gas Separation By Absorption (AREA)
- Treating Waste Gases (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT000676A ITMI20120676A1 (it) | 2012-04-24 | 2012-04-24 | Metodo e dispositivo rigenerabile di purificazione a temperatura ambiente per monossido di diazoto |
| ITMI2012A000676 | 2012-04-24 | ||
| US13/866,875 US20140000456A1 (en) | 2012-04-24 | 2013-04-19 | Nitrous oxide regenerable room temperature purifier and method |
| US13/866,875 | 2013-04-19 | ||
| PCT/IB2013/000753 WO2013160746A1 (en) | 2012-04-24 | 2013-04-23 | Nitrous oxide regenerable room temperature purifier and method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20150013450A KR20150013450A (ko) | 2015-02-05 |
| KR101866918B1 true KR101866918B1 (ko) | 2018-06-15 |
Family
ID=46262175
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020147028597A Active KR101866918B1 (ko) | 2012-04-24 | 2013-04-23 | 아산화질소 재생가능 실온 정제기 및 방법 |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US20140000456A1 (enExample) |
| EP (1) | EP2841377B1 (enExample) |
| JP (1) | JP6027227B2 (enExample) |
| KR (1) | KR101866918B1 (enExample) |
| CN (1) | CN104245574B (enExample) |
| IT (1) | ITMI20120676A1 (enExample) |
| WO (1) | WO2013160746A1 (enExample) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3862067B1 (en) * | 2020-02-10 | 2025-05-14 | Clariant Catalysts (Japan) K.K. | Method for removing co2 and o2 |
| GB202103659D0 (en) * | 2021-03-17 | 2021-04-28 | Johnson Matthey Plc | Getter activation and use |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008088043A (ja) * | 2006-10-05 | 2008-04-17 | Japan Pionics Co Ltd | 不活性ガスの処理方法及び精製方法、並びにガス処理筒 |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1596425A (enExample) * | 1968-12-27 | 1970-06-15 | ||
| DE3149672C2 (de) * | 1981-12-15 | 1986-11-13 | Didier-Werke Ag, 6200 Wiesbaden | Verfahren zum Klimatisieren unter Anwendung von mittels Wassersorption arbeitenden Speichermedien |
| US4713224A (en) * | 1986-03-31 | 1987-12-15 | The Boc Group, Inc. | One-step process for purifying an inert gas |
| US5268021A (en) * | 1989-11-20 | 1993-12-07 | Dynotec Corporation | Fluid fractionator |
| JP3359928B2 (ja) * | 1991-11-06 | 2002-12-24 | 日本パイオニクス株式会社 | アンモニアの精製方法 |
| IT1270875B (it) * | 1993-04-29 | 1997-05-13 | Getters Spa | Procedimento di purificazione dell'idrogeno e purificatore relativo |
| US5547648A (en) * | 1992-04-15 | 1996-08-20 | Mobil Oil Corporation | Removing SOx, NOX and CO from flue gases |
| JP3260826B2 (ja) * | 1992-06-26 | 2002-02-25 | 日本パイオニクス株式会社 | 亜酸化窒素の精製方法 |
| RU2123971C1 (ru) * | 1993-04-29 | 1998-12-27 | Саес Геттерс С.П.А. | Способ удаления газообразных примесей из потока водорода и устройство для его осуществления |
| US6436352B1 (en) * | 1993-04-29 | 2002-08-20 | Saes Getter, S.P.A. | Hydrogen purification |
| JP3294390B2 (ja) * | 1993-07-26 | 2002-06-24 | 日本エア・リキード株式会社 | 超高純度亜酸化窒素製造方法及び装置 |
| ATE151400T1 (de) * | 1993-09-20 | 1997-04-15 | Fina Research | Verfahren zur entfernung von arsien und carbonylsulfid aus leichten olefinen enthaltender kohlenwasserstoffbeschickungen |
| JP3582141B2 (ja) * | 1995-03-06 | 2004-10-27 | 堺化学工業株式会社 | 窒素酸化物除去法 |
| US6517797B1 (en) * | 1997-02-26 | 2003-02-11 | Calgon Carbon Corporation | Process for separation of NOx from N2O in a mixture |
| US5983667A (en) * | 1997-10-31 | 1999-11-16 | Praxair Technology, Inc. | Cryogenic system for producing ultra-high purity nitrogen |
| US6080226A (en) * | 1998-09-30 | 2000-06-27 | Uop Llc | Nitrous oxide purification by pressure swing adsorption |
| US7070746B1 (en) * | 1999-05-26 | 2006-07-04 | Solutia Inc. | Process for nitrous oxide purification |
| US6521192B1 (en) * | 1999-08-06 | 2003-02-18 | Saes Pure Gas, Inc. | Rejuvenable ambient temperature purifier |
| JP3934885B2 (ja) * | 2000-09-27 | 2007-06-20 | 昭和電工株式会社 | 余剰麻酔ガスの処理装置 |
| US6511526B2 (en) * | 2001-01-12 | 2003-01-28 | Vbox, Incorporated | Pressure swing adsorption gas separation method and apparatus |
| US20030064014A1 (en) * | 2001-08-03 | 2003-04-03 | Ravi Kumar | Purification of gases by pressure swing adsorption |
| US6824589B2 (en) * | 2001-10-31 | 2004-11-30 | Matheson Tri-Gas | Materials and methods for the purification of inert, nonreactive, and reactive gases |
| US7101415B2 (en) * | 2002-08-30 | 2006-09-05 | Matheson Tri-Gas, Inc. | Methods for regenerating process gas purifier materials |
| EP1417995A1 (en) * | 2002-10-30 | 2004-05-12 | Air Products And Chemicals, Inc. | Process and device for adsorption of nitrous oxide from a feed gas stream |
| US7201841B2 (en) * | 2003-02-05 | 2007-04-10 | Water Visions International, Inc. | Composite materials for fluid treatment |
| US7314506B2 (en) * | 2004-10-25 | 2008-01-01 | Matheson Tri-Gas, Inc. | Fluid purification system with low temperature purifier |
| JP5103757B2 (ja) * | 2006-03-08 | 2012-12-19 | トヨタ自動車株式会社 | 燃料電池の酸化剤ガス浄化装置 |
-
2012
- 2012-04-24 IT IT000676A patent/ITMI20120676A1/it unknown
-
2013
- 2013-04-19 US US13/866,875 patent/US20140000456A1/en not_active Abandoned
- 2013-04-23 JP JP2015507616A patent/JP6027227B2/ja active Active
- 2013-04-23 EP EP13726862.9A patent/EP2841377B1/en not_active Not-in-force
- 2013-04-23 CN CN201380021354.8A patent/CN104245574B/zh active Active
- 2013-04-23 KR KR1020147028597A patent/KR101866918B1/ko active Active
- 2013-04-23 WO PCT/IB2013/000753 patent/WO2013160746A1/en not_active Ceased
-
2016
- 2016-10-17 US US15/295,978 patent/US9643845B2/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008088043A (ja) * | 2006-10-05 | 2008-04-17 | Japan Pionics Co Ltd | 不活性ガスの処理方法及び精製方法、並びにガス処理筒 |
Also Published As
| Publication number | Publication date |
|---|---|
| ITMI20120676A1 (it) | 2013-10-25 |
| CN104245574B (zh) | 2016-07-06 |
| EP2841377B1 (en) | 2016-02-24 |
| CN104245574A (zh) | 2014-12-24 |
| KR20150013450A (ko) | 2015-02-05 |
| US20140000456A1 (en) | 2014-01-02 |
| US20170029273A1 (en) | 2017-02-02 |
| EP2841377A1 (en) | 2015-03-04 |
| WO2013160746A1 (en) | 2013-10-31 |
| JP2015519192A (ja) | 2015-07-09 |
| US9643845B2 (en) | 2017-05-09 |
| JP6027227B2 (ja) | 2016-11-16 |
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