KR101858310B1 - 고활성의 큰 결정 zsm-5의 합성 - Google Patents

고활성의 큰 결정 zsm-5의 합성 Download PDF

Info

Publication number
KR101858310B1
KR101858310B1 KR1020147018034A KR20147018034A KR101858310B1 KR 101858310 B1 KR101858310 B1 KR 101858310B1 KR 1020147018034 A KR1020147018034 A KR 1020147018034A KR 20147018034 A KR20147018034 A KR 20147018034A KR 101858310 B1 KR101858310 B1 KR 101858310B1
Authority
KR
South Korea
Prior art keywords
zsm
sio
reaction mixture
less
molar ratio
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1020147018034A
Other languages
English (en)
Korean (ko)
Other versions
KR20140108665A (ko
Inventor
웨나이 프랑크 라이
머시 에이 해밀톤
Original Assignee
엑손모빌 리서치 앤드 엔지니어링 컴퍼니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 엑손모빌 리서치 앤드 엔지니어링 컴퍼니 filed Critical 엑손모빌 리서치 앤드 엔지니어링 컴퍼니
Publication of KR20140108665A publication Critical patent/KR20140108665A/ko
Application granted granted Critical
Publication of KR101858310B1 publication Critical patent/KR101858310B1/ko
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/123—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/12—After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation
    • B01J2229/123—After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation in order to deactivate outer surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/32—Reaction with silicon compounds, e.g. TEOS, siliconfluoride
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020147018034A 2011-12-01 2012-11-27 고활성의 큰 결정 zsm-5의 합성 Expired - Fee Related KR101858310B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161565635P 2011-12-01 2011-12-01
US61/565,635 2011-12-01
PCT/US2012/066588 WO2013081994A1 (en) 2011-12-01 2012-11-27 Synthesis of high activity large crystal zsm-5

Publications (2)

Publication Number Publication Date
KR20140108665A KR20140108665A (ko) 2014-09-12
KR101858310B1 true KR101858310B1 (ko) 2018-05-15

Family

ID=47279156

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020147018034A Expired - Fee Related KR101858310B1 (ko) 2011-12-01 2012-11-27 고활성의 큰 결정 zsm-5의 합성

Country Status (9)

Country Link
US (1) US8900547B2 (enExample)
EP (1) EP2785645B1 (enExample)
JP (1) JP5990594B2 (enExample)
KR (1) KR101858310B1 (enExample)
CN (1) CN103958411B (enExample)
BR (1) BR112014012577A2 (enExample)
CA (1) CA2855875C (enExample)
SG (1) SG11201402190SA (enExample)
WO (1) WO2013081994A1 (enExample)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102220082B1 (ko) 2019-07-23 2021-02-25 노경태 신규 구조 및 타래형 모폴로지를 갖는 알루미노실리케이트 구조체, 이의 제조방법 및 이를 고정상으로 충진한 hplc 컬럼
CN114426455B (zh) * 2020-09-28 2024-07-23 中国石油化工股份有限公司 一种苯和乙烯烷基化反应
CN114478274B (zh) * 2020-10-27 2024-06-28 中国石油化工股份有限公司 一种制备一乙醇胺并联产二甘醇的方法
CN114620743A (zh) * 2020-12-11 2022-06-14 中国科学院大连化学物理研究所 一种大晶粒rho-sapo分子筛、其制备方法及其应用
FR3141080B1 (fr) 2022-10-19 2025-05-02 Arkema France Procédé de synthèse de zéolithe zsm-5 en continu
CN116459786B (zh) * 2023-04-27 2024-12-24 金宏气体股份有限公司 去除八甲基环四硅氧烷中的六甲基环三硅氧烷的吸附剂

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3354078A (en) 1965-02-04 1967-11-21 Mobil Oil Corp Catalytic conversion with a crystalline aluminosilicate activated with a metallic halide
US3702886A (en) 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3676063A (en) * 1971-03-11 1972-07-11 Nalco Chemical Co Process for preparing synthetic crystalline zeolitic sodium aluminosilicate
US3941871A (en) 1973-11-02 1976-03-02 Mobil Oil Corporation Crystalline silicates and method of preparing the same
US4088605A (en) * 1976-09-24 1978-05-09 Mobil Oil Corporation ZSM-5 containing aluminum-free shells on its surface
NZ193928A (en) 1979-06-11 1982-09-07 Mobil Oil Corp Preparation of large crystal zeolite zsm-5
AU559968B2 (en) * 1982-04-29 1987-03-26 Mobil Oil Corp. Controlled morphology high silica zeolites
JPH0227283B2 (ja) * 1982-10-01 1990-06-15 Toray Industries Ketsushoseiaruminoshirikeetozeoraitonoseizoho
US4797267A (en) * 1987-12-23 1989-01-10 Mobil Oil Corporation Method of producing rod-shaped ZSM-5 zeolite
JP2618021B2 (ja) * 1988-10-03 1997-06-11 工業技術院長 真球状ペンタシル型ゼオライト粉体の合成方法
JP2844098B2 (ja) * 1989-12-20 1999-01-06 旭化成工業株式会社 Ｚｓｍ―５微粒子体の製造法
US5164169A (en) * 1991-06-14 1992-11-17 Mobil Oil Corporation Zeolite Beta
CA2222585C (en) * 1995-06-06 2007-10-02 Mobil Oil Corporation Large crystal zsm-5, its synthesis and use
US20020011429A1 (en) * 1997-09-30 2002-01-31 Akira Iino Iron-containing crystalline aluminosilicate
CN100444951C (zh) * 2001-05-10 2008-12-24 阿克佐诺贝尔股份有限公司 有效转化无机固体颗粒的连续方法和设备
KR100528672B1 (ko) * 2002-12-30 2005-11-15 학교법인 건국대학교 유기 템플레이트 배제 하에서 가변 온도를 이용하여ｚｓｍ-5를 제조하는 방법
EP1587756A4 (en) * 2002-12-30 2011-07-06 Sk Energy Co Ltd PROCESS FOR THE PREPARATION OF ZSM-5 BY VARIABLE TEMPERATURE WITHOUT ORGANIC STENCIL MATERIAL
SG188173A1 (en) * 2008-02-22 2013-03-28 Exxonmobil Chem Patents Inc Large crystal molecular sieves and their manufacture
CN101722033A (zh) * 2008-10-28 2010-06-09 中国石油化工股份有限公司 核壳型芳烃转化催化剂及其制备方法和用途

Also Published As

Publication number Publication date
KR20140108665A (ko) 2014-09-12
JP2015507591A (ja) 2015-03-12
CA2855875C (en) 2018-08-14
JP5990594B2 (ja) 2016-09-14
CN103958411B (zh) 2016-08-24
US20130144100A1 (en) 2013-06-06
WO2013081994A1 (en) 2013-06-06
CN103958411A (zh) 2014-07-30
US8900547B2 (en) 2014-12-02
EP2785645B1 (en) 2017-06-14
CA2855875A1 (en) 2013-06-06
EP2785645A1 (en) 2014-10-08
BR112014012577A2 (pt) 2017-06-06
SG11201402190SA (en) 2014-09-26

Similar Documents

Publication Publication Date Title
JP5823295B2 (ja) Ｕｚｍ−３５アルミノシリケートゼオライト、ｕｚｍ−３５の製造方法及びそれを用いる方法
KR100978979B1 (ko) 분자체의 고 처리량 제조 방법
KR101858310B1 (ko) 고활성의 큰 결정 zsm-5의 합성
CN102822125B (zh) 使用uzm-37硅铝酸盐沸石的芳烃烷基化法
KR102291455B1 (ko) Zsm-48 결정의 합성
JP6106759B2 (ja) Ｍｓｅフレームワーク型モレキュラーシーブの合成
US20110117007A1 (en) Method for making mfi-type molecular sieves
JP5852749B2 (ja) Ｕｚｍ−３９アルミノシリケートゼオライトを用いた芳香族化合物の転化反応
JP6005878B2 (ja) Ｕｚｍ−３９アルミノケイ酸塩ゼオライトを用いた芳香族トランスアルキル化反応
KR20150066584A (ko) Uzm-44 알루미노실리케이트 제올라이트를 사용하는 방향족 트랜스알킬화
CN110914195A (zh) 分子筛ssz-112、其合成及应用
JP2011121859A (ja) アルミノシリケートの製造方法
CN102482176A (zh) 使用uzm-35来进行芳烃烷基化的方法
JP2010090025A (ja) Ｍｔｗ構造型のゼオライトの調製方法
JP2020522453A (ja) ナノ結晶ベータゼオライトの合成、合成方法、及び触媒用途におけるその使用
WO2018080640A1 (en) Synthesis of mtw framework type molecular sieves
US5683673A (en) Process for the manufacture of a zeolite
CN107531587B (zh) 使用uzm-53的烃转化
CA2872869C (en) Zeolite zsm-18, its synthesis and its use
KR102667235B1 (ko) 분자체 ssz-63을 제조하는 방법

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

A201 Request for examination
A302 Request for accelerated examination
E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

PA0302 Request for accelerated examination

St.27 status event code: A-1-2-D10-D17-exm-PA0302

St.27 status event code: A-1-2-D10-D16-exm-PA0302

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 20210510

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20210510

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000