CN103958411B - 高活性大晶体zsm-5的合成 - Google Patents

高活性大晶体zsm-5的合成 Download PDF

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Publication number
CN103958411B
CN103958411B CN201280059159.XA CN201280059159A CN103958411B CN 103958411 B CN103958411 B CN 103958411B CN 201280059159 A CN201280059159 A CN 201280059159A CN 103958411 B CN103958411 B CN 103958411B
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Prior art keywords
zsm
reaction mixture
source
crystal
sio
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Chinese (zh)
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CN103958411A (zh
Inventor
文伊赫·法兰克·赖
梅尔奇·A·汉密尔顿
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ExxonMobil Technology and Engineering Co
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ExxonMobil Research and Engineering Co
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/123—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/12—After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation
    • B01J2229/123—After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation in order to deactivate outer surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/32—Reaction with silicon compounds, e.g. TEOS, siliconfluoride
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201280059159.XA 2011-12-01 2012-11-27 高活性大晶体zsm-5的合成 Active CN103958411B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161565635P 2011-12-01 2011-12-01
US61/565,635 2011-12-01
PCT/US2012/066588 WO2013081994A1 (en) 2011-12-01 2012-11-27 Synthesis of high activity large crystal zsm-5

Publications (2)

Publication Number Publication Date
CN103958411A CN103958411A (zh) 2014-07-30
CN103958411B true CN103958411B (zh) 2016-08-24

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Family Applications (1)

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CN201280059159.XA Active CN103958411B (zh) 2011-12-01 2012-11-27 高活性大晶体zsm-5的合成

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US (1) US8900547B2 (enExample)
EP (1) EP2785645B1 (enExample)
JP (1) JP5990594B2 (enExample)
KR (1) KR101858310B1 (enExample)
CN (1) CN103958411B (enExample)
BR (1) BR112014012577A2 (enExample)
CA (1) CA2855875C (enExample)
SG (1) SG11201402190SA (enExample)
WO (1) WO2013081994A1 (enExample)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102220082B1 (ko) 2019-07-23 2021-02-25 노경태 신규 구조 및 타래형 모폴로지를 갖는 알루미노실리케이트 구조체, 이의 제조방법 및 이를 고정상으로 충진한 hplc 컬럼
CN114426455B (zh) * 2020-09-28 2024-07-23 中国石油化工股份有限公司 一种苯和乙烯烷基化反应
CN114478274B (zh) * 2020-10-27 2024-06-28 中国石油化工股份有限公司 一种制备一乙醇胺并联产二甘醇的方法
CN114620743A (zh) * 2020-12-11 2022-06-14 中国科学院大连化学物理研究所 一种大晶粒rho-sapo分子筛、其制备方法及其应用
FR3141080B1 (fr) 2022-10-19 2025-05-02 Arkema France Procédé de synthèse de zéolithe zsm-5 en continu
CN116459786B (zh) * 2023-04-27 2024-12-24 金宏气体股份有限公司 去除八甲基环四硅氧烷中的六甲基环三硅氧烷的吸附剂

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4088605A (en) * 1976-09-24 1978-05-09 Mobil Oil Corporation ZSM-5 containing aluminum-free shells on its surface
US5164169A (en) * 1991-06-14 1992-11-17 Mobil Oil Corporation Zeolite Beta
CN1732127A (zh) * 2002-12-30 2006-02-08 Sk株式会社 在没有有机模板下采用可变温度制备zsm－5的方法
CN101722033A (zh) * 2008-10-28 2010-06-09 中国石油化工股份有限公司 核壳型芳烃转化催化剂及其制备方法和用途
CN101945823A (zh) * 2008-02-22 2011-01-12 埃克森美孚化学专利公司 大晶体分子筛及其制备

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3354078A (en) 1965-02-04 1967-11-21 Mobil Oil Corp Catalytic conversion with a crystalline aluminosilicate activated with a metallic halide
US3702886A (en) 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3676063A (en) * 1971-03-11 1972-07-11 Nalco Chemical Co Process for preparing synthetic crystalline zeolitic sodium aluminosilicate
US3941871A (en) 1973-11-02 1976-03-02 Mobil Oil Corporation Crystalline silicates and method of preparing the same
NZ193928A (en) 1979-06-11 1982-09-07 Mobil Oil Corp Preparation of large crystal zeolite zsm-5
AU559968B2 (en) * 1982-04-29 1987-03-26 Mobil Oil Corp. Controlled morphology high silica zeolites
JPH0227283B2 (ja) * 1982-10-01 1990-06-15 Toray Industries Ketsushoseiaruminoshirikeetozeoraitonoseizoho
US4797267A (en) * 1987-12-23 1989-01-10 Mobil Oil Corporation Method of producing rod-shaped ZSM-5 zeolite
JP2618021B2 (ja) * 1988-10-03 1997-06-11 工業技術院長 真球状ペンタシル型ゼオライト粉体の合成方法
JP2844098B2 (ja) * 1989-12-20 1999-01-06 旭化成工業株式会社 Ｚｓｍ―５微粒子体の製造法
EP0842117B1 (en) * 1995-06-06 2002-04-10 Exxonmobil Oil Corporation Large crystal zsm-5, its synthesis and use
US20020011429A1 (en) * 1997-09-30 2002-01-31 Akira Iino Iron-containing crystalline aluminosilicate
JP4909497B2 (ja) * 2001-05-10 2012-04-04 アルベマーレ ネザーランズ ビー．ブイ． 無機固体粒子の効率的な転化のための連続プロセス及び装置
AU2003286975A1 (en) * 2002-12-30 2004-07-22 Sk Corporation Method of preparing zsm-5 using variable temperature without organic template

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4088605A (en) * 1976-09-24 1978-05-09 Mobil Oil Corporation ZSM-5 containing aluminum-free shells on its surface
US5164169A (en) * 1991-06-14 1992-11-17 Mobil Oil Corporation Zeolite Beta
CN1732127A (zh) * 2002-12-30 2006-02-08 Sk株式会社 在没有有机模板下采用可变温度制备zsm－5的方法
CN101945823A (zh) * 2008-02-22 2011-01-12 埃克森美孚化学专利公司 大晶体分子筛及其制备
CN101722033A (zh) * 2008-10-28 2010-06-09 中国石油化工股份有限公司 核壳型芳烃转化催化剂及其制备方法和用途

Also Published As

Publication number Publication date
CA2855875C (en) 2018-08-14
KR20140108665A (ko) 2014-09-12
US20130144100A1 (en) 2013-06-06
CN103958411A (zh) 2014-07-30
EP2785645B1 (en) 2017-06-14
SG11201402190SA (en) 2014-09-26
JP2015507591A (ja) 2015-03-12
JP5990594B2 (ja) 2016-09-14
BR112014012577A2 (pt) 2017-06-06
EP2785645A1 (en) 2014-10-08
WO2013081994A1 (en) 2013-06-06
CA2855875A1 (en) 2013-06-06
KR101858310B1 (ko) 2018-05-15
US8900547B2 (en) 2014-12-02

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