KR101829116B1 - 에텐으로부터 적어도 부텐 및 옥텐의 조합 제조 - Google Patents

에텐으로부터 적어도 부텐 및 옥텐의 조합 제조 Download PDF

Info

Publication number
KR101829116B1
KR101829116B1 KR1020160005836A KR20160005836A KR101829116B1 KR 101829116 B1 KR101829116 B1 KR 101829116B1 KR 1020160005836 A KR1020160005836 A KR 1020160005836A KR 20160005836 A KR20160005836 A KR 20160005836A KR 101829116 B1 KR101829116 B1 KR 101829116B1
Authority
KR
South Korea
Prior art keywords
ethene
fraction
butene
synthesis
hexene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1020160005836A
Other languages
English (en)
Korean (ko)
Other versions
KR20160089283A (ko
Inventor
귀도 슈토히니올
슈테판 파이츠
디트리히 마슈마이어
헬레네 레커
외르크 샬렌베르크
Original Assignee
에보닉 데구사 게엠베하
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 에보닉 데구사 게엠베하 filed Critical 에보닉 데구사 게엠베하
Publication of KR20160089283A publication Critical patent/KR20160089283A/ko
Application granted granted Critical
Publication of KR101829116B1 publication Critical patent/KR101829116B1/ko
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/08—Alkenes with four carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/08—Alkenes with four carbon atoms
    • C07C11/09—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/10—Catalytic processes with metal oxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/24—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/04—Purification; Separation; Use of additives by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
KR1020160005836A 2015-01-19 2016-01-18 에텐으로부터 적어도 부텐 및 옥텐의 조합 제조 Expired - Fee Related KR101829116B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP15151624.2A EP3045438B1 (de) 2015-01-19 2015-01-19 Kombinierte Herstellung von zumindest Buten und Octen aus Ethen
EP15151624.2 2015-01-19

Publications (2)

Publication Number Publication Date
KR20160089283A KR20160089283A (ko) 2016-07-27
KR101829116B1 true KR101829116B1 (ko) 2018-02-13

Family

ID=52432651

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020160005836A Expired - Fee Related KR101829116B1 (ko) 2015-01-19 2016-01-18 에텐으로부터 적어도 부텐 및 옥텐의 조합 제조

Country Status (14)

Country Link
US (1) US10647630B2 (enExample)
EP (1) EP3045438B1 (enExample)
JP (1) JP6095808B2 (enExample)
KR (1) KR101829116B1 (enExample)
CN (1) CN105801330B (enExample)
CA (1) CA2918121C (enExample)
ES (1) ES2660618T3 (enExample)
MX (1) MX371094B (enExample)
MY (1) MY172349A (enExample)
NO (1) NO3045438T3 (enExample)
PL (1) PL3045438T3 (enExample)
SG (1) SG10201600311WA (enExample)
TR (1) TR201802617T4 (enExample)
TW (1) TWI603942B (enExample)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3170805B1 (de) 2015-11-19 2018-09-12 Evonik Degussa GmbH Beeinflussung der viskosität von auf n-buten basierenden estergemischen durch gezielten einsatz von ethen bei der herstellung der ester-vorprodukte
PL3255029T3 (pl) 2016-06-10 2019-04-30 Evonik Degussa Gmbh Oligomeryzacja etenu w warunkach nadkrytycznych
EP3266757B1 (de) 2016-07-08 2019-12-25 Evonik Operations GmbH Herstellung von zumindest 1-hexen und octen aus ethen
KR102728965B1 (ko) * 2019-02-22 2024-11-13 퍼블릭 조인트 스톡 컴퍼니 “시부르 홀딩” 올레핀 올리고머화 생성물(변이체)의 분리 방법
KR102780340B1 (ko) 2019-03-13 2025-03-11 티피씨 그룹 엘엘씨 상이한 선형 알파 올레핀을 선택적으로 생산하기 위한 유연 제조 시스템
KR102592638B1 (ko) * 2019-08-21 2023-10-23 주식회사 엘지화학 알파 올레핀 제조 방법 및 알파 올레핀 제조 장치
CN110627604A (zh) * 2019-10-31 2019-12-31 胜帮科技股份有限公司 一种乙烯齐聚合成1-辛烯和1-己烯的生产系统及生产方法
US11230514B1 (en) * 2021-05-25 2022-01-25 Chevron Phillips Chemical Company, Lp Methods for recycling ethylene in an ethylene oligomerization reactor system

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070185362A1 (en) 2006-02-03 2007-08-09 Lattner James R Process for generating alpha olefin comonomers
US20070191661A1 (en) 2005-09-30 2007-08-16 Brown Stephen H Oligomerization reaction
US20120016097A1 (en) 2009-03-27 2012-01-19 Weber Michael W Olefin Oligomerization Reaction Processes Exhibiting Reduced Fouling

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB619231A (en) 1945-06-15 1949-03-07 Phillips Petroleum Co Improvements in or relating to catalytic polymerization of olefins
US4717782A (en) 1985-09-13 1988-01-05 Mobil Oil Corporation Catalytic process for oligomerizing ethene
DE19906518A1 (de) 1999-02-17 2000-08-31 Oxeno Olefinchemie Gmbh Verfahren zur Fraktionierung von Dibuten
US6689928B2 (en) * 2000-04-04 2004-02-10 Exxonmobil Research And Engineering Company Transition metal complexes and oligomers therefrom
US6531555B2 (en) * 2000-12-19 2003-03-11 Univation Technologies, Llp Olefin oligomerization catalysts, their production and use
JP2003326169A (ja) * 2002-03-08 2003-11-18 Rikogaku Shinkokai オリゴマー化触媒及びそれを用いたオリゴマーの製造方法
EP1756024B1 (en) 2004-06-18 2018-08-15 Sasol Technology (Pty) Ltd Oligomerisation of olefinic compounds in an aliphatic medium
WO2005123884A2 (en) 2004-06-18 2005-12-29 Sasol Technology (Pty) Limited Oligomerisation in the presence of both a tetramerisation catalyst and a further oligomerisation catalyst
US7803978B2 (en) * 2004-12-16 2010-09-28 Uop Llc Process and apparatus for oligomerization in multiple stages with single fractionation column
DE602006015779D1 (de) * 2005-03-09 2010-09-09 Exxon Mobil Chem Patents Inc Verfahren zur oligomerisation von olefinen
US8003839B2 (en) * 2006-02-03 2011-08-23 Exxonmobil Chemical Patents Inc. Process for generating linear apha olefin comonomers
CN101460428B (zh) * 2006-06-07 2013-08-28 巴斯夫欧洲公司 共二聚烯烃的方法
CA2705155C (en) * 2007-11-07 2015-12-29 Sasol Technology (Proprietary) Limited Process for polymerising or oligomerising a hydrocarbon
DE102008007081B4 (de) 2008-01-31 2018-12-06 Evonik Degussa Gmbh Verfahren zur Herstellung von n-Buten-Oligomeren und 1-Buten aus technischen Mischungen I von C4-Kohlenwasserstoffen
EP2305378A4 (en) 2008-07-23 2012-01-18 Mitsui Chemicals Inc CATALYST FOR OLIGOMERIZATION OF ETHYLENE AND USE THEREOF
WO2010057905A1 (de) * 2008-11-19 2010-05-27 Basf Se Oligomerisierung von olefinen
EP2196444A1 (en) 2008-12-11 2010-06-16 Total Petrochemicals Research Feluy Process to make alpha olefins from ethanol
BRPI1013710A2 (pt) 2009-03-31 2016-04-05 Uop Llc processo para oligomerizar etileno, e, aparelho
WO2011157674A1 (de) 2010-06-15 2011-12-22 Basf Se Verfahren zur co-oligomerisierung von olefinen
FR2979836B1 (fr) 2011-09-08 2014-08-08 IFP Energies Nouvelles Nouvelle composition catalytique a base de nickel et procede d'oligomerisation des olefines utilisant ladite composition
FR2984311B1 (fr) 2011-12-20 2015-01-30 IFP Energies Nouvelles Procede de production d'octenes mettant en oeuvre la dimerisation de l'ethylene en butenes et la dimerisation des butenes en octenes
CA2869701C (en) * 2012-05-09 2020-01-07 Sasol Technology (Proprietary) Limited A process for oligomerising a hydrocarbon to form at least one co-monomer product
FR2992962B1 (fr) * 2012-07-04 2015-06-26 Axens Procede de separation de l'hexene-1 a partir d'un melange de produits issus d'une zone de trimerisation de l'ethylene
WO2014154798A1 (en) 2013-03-28 2014-10-02 Bp P.L.C. Production of middle distillate hydrocarbon composition
US9771533B2 (en) * 2014-10-30 2017-09-26 Battelle Memorial Institute Systems and processes for conversion of ethylene feedstocks to hydrocarbon fuels

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070191661A1 (en) 2005-09-30 2007-08-16 Brown Stephen H Oligomerization reaction
US20070185362A1 (en) 2006-02-03 2007-08-09 Lattner James R Process for generating alpha olefin comonomers
US20120016097A1 (en) 2009-03-27 2012-01-19 Weber Michael W Olefin Oligomerization Reaction Processes Exhibiting Reduced Fouling

Also Published As

Publication number Publication date
MX371094B (es) 2020-01-16
CA2918121A1 (en) 2016-07-19
CA2918121C (en) 2018-02-20
EP3045438A1 (de) 2016-07-20
US10647630B2 (en) 2020-05-12
JP6095808B2 (ja) 2017-03-15
MX2016000507A (es) 2016-07-18
NO3045438T3 (enExample) 2018-04-28
MY172349A (en) 2019-11-21
SG10201600311WA (en) 2016-08-30
US20160207849A1 (en) 2016-07-21
TW201641473A (zh) 2016-12-01
CN105801330B (zh) 2019-01-04
JP2016132670A (ja) 2016-07-25
CN105801330A (zh) 2016-07-27
EP3045438B1 (de) 2017-11-29
TR201802617T4 (tr) 2018-03-21
ES2660618T3 (es) 2018-03-23
PL3045438T3 (pl) 2018-05-30
KR20160089283A (ko) 2016-07-27
TWI603942B (zh) 2017-11-01

Similar Documents

Publication Publication Date Title
KR101829116B1 (ko) 에텐으로부터 적어도 부텐 및 옥텐의 조합 제조
JP6095809B2 (ja) エテンからブテン及びオクテンを組み合わせて製造する方法
US9682898B2 (en) Oligomerization of C4 streams with very low 1 butene content
KR20180006327A (ko) 에텐으로부터의 적어도 1-헥센 및 옥텐의 제조
WO2007040812A9 (en) Oligomerization reaction
KR20210023743A (ko) 최적화된 증류를 사용하는 올레핀의 올리고머화 방법
KR102051421B1 (ko) 부텐의 올리고머의 제조 방법
TWI821432B (zh) 以具有降低的烯烴含量的流使烯烴低聚合的方法
US20150344383A1 (en) Process for simultaneous production of alcohols and oligomer product from hydrocarbon feed stock
TWI826689B (zh) 控制待寡聚烴流中寡聚物含量的烯烴寡聚方法
KR20210023744A (ko) 최적화된 증류를 사용하는 올레핀의 올리고머화 방법
US12172952B2 (en) Ethylene maximization with propylene metathesis

Legal Events

Date Code Title Description
A201 Request for examination
P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0109 Patent application

St.27 status event code: A-0-1-A10-A12-nap-PA0109

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U11-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

PN2301 Change of applicant

St.27 status event code: A-5-5-R10-R13-asn-PN2301

St.27 status event code: A-5-5-R10-R11-asn-PN2301

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 20220208

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20220208