KR101760661B1 - 산 염료 - Google Patents

산 염료 Download PDF

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Publication number
KR101760661B1
KR101760661B1 KR1020117002373A KR20117002373A KR101760661B1 KR 101760661 B1 KR101760661 B1 KR 101760661B1 KR 1020117002373 A KR1020117002373 A KR 1020117002373A KR 20117002373 A KR20117002373 A KR 20117002373A KR 101760661 B1 KR101760661 B1 KR 101760661B1
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KR
South Korea
Prior art keywords
alkyl
group
unsubstituted
substituted
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1020117002373A
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English (en)
Korean (ko)
Other versions
KR20110031359A (ko
Inventor
라이너 누써
울리히 가이거
루드비히 하제만
Original Assignee
아르크로마 아이피 게엠베하
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Publication of KR20110031359A publication Critical patent/KR20110031359A/ko
Application granted granted Critical
Publication of KR101760661B1 publication Critical patent/KR101760661B1/ko
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/39—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using acid dyes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B29/00—Monoazo dyes prepared by diazotising and coupling
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B29/00—Monoazo dyes prepared by diazotising and coupling
    • C09B29/34—Monoazo dyes prepared by diazotising and coupling from other coupling components
    • C09B29/36—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B35/00—Disazo and polyazo dyes of the type A<-D->B prepared by diazotising and coupling
    • C09B35/02—Disazo dyes
    • C09B35/021—Disazo dyes characterised by two coupling components of the same type
    • C09B35/03—Disazo dyes characterised by two coupling components of the same type in which the coupling component is a heterocyclic compound
    • C09B35/031—Disazo dyes characterised by two coupling components of the same type in which the coupling component is a heterocyclic compound containing a six membered ring with one nitrogen atom as the only ring hetero atom
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B35/00—Disazo and polyazo dyes of the type A<-D->B prepared by diazotising and coupling
    • C09B35/02—Disazo dyes
    • C09B35/039—Disazo dyes characterised by the tetrazo component
    • C09B35/205—Disazo dyes characterised by the tetrazo component the tetrazo component being a derivative of a diaryl- or triaryl- alkane or-alkene
    • C09B35/21—Disazo dyes characterised by the tetrazo component the tetrazo component being a derivative of a diaryl- or triaryl- alkane or-alkene of diarylmethane or triarylmethane
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B35/00—Disazo and polyazo dyes of the type A<-D->B prepared by diazotising and coupling
    • C09B35/02—Disazo dyes
    • C09B35/039—Disazo dyes characterised by the tetrazo component
    • C09B35/26—Disazo dyes characterised by the tetrazo component the tetrazo component being a derivative of a diaryl urea
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B35/00—Disazo and polyazo dyes of the type A<-D->B prepared by diazotising and coupling
    • C09B35/02—Disazo dyes
    • C09B35/039—Disazo dyes characterised by the tetrazo component
    • C09B35/28—Disazo dyes characterised by the tetrazo component the tetrazo component containing two aryl nuclei linked by at least one of the groups —CON<, —SO2N<, —SO2—, or —SO2—O—
    • C09B35/30—Disazo dyes characterised by the tetrazo component the tetrazo component containing two aryl nuclei linked by at least one of the groups —CON<, —SO2N<, —SO2—, or —SO2—O— from two identical coupling components
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/30—Inkjet printing inks
    • C09D11/32—Inkjet printing inks characterised by colouring agents
    • C09D11/328—Inkjet printing inks characterised by colouring agents characterised by dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/001—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated using acid dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02—Material containing basic nitrogen
    • D06P3/021—Material containing basic nitrogen using acid dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02—Material containing basic nitrogen
    • D06P3/04—Material containing basic nitrogen containing amide groups
    • D06P3/06—Material containing basic nitrogen containing amide groups using acid dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02—Material containing basic nitrogen
    • D06P3/04—Material containing basic nitrogen containing amide groups
    • D06P3/14—Wool
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02—Material containing basic nitrogen
    • D06P3/04—Material containing basic nitrogen containing amide groups
    • D06P3/14—Wool
    • D06P3/16—Wool using acid dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02—Material containing basic nitrogen
    • D06P3/04—Material containing basic nitrogen containing amide groups
    • D06P3/24—Polyamides; Polyurethanes
    • D06P3/241—Polyamides; Polyurethanes using acid dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02—Material containing basic nitrogen
    • D06P3/04—Material containing basic nitrogen containing amide groups
    • D06P3/32—Material containing basic nitrogen containing amide groups leather skins
    • D06P3/3206—Material containing basic nitrogen containing amide groups leather skins using acid dyes
    • D06P3/3226—Material containing basic nitrogen containing amide groups leather skins using acid dyes dis-polyazo
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58—Material containing hydroxyl groups
    • D06P3/60—Natural or regenerated cellulose
    • D06P3/6008—Natural or regenerated cellulose using acid dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/30—Ink jet printing
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/28—Colorants ; Pigments or opacifying agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10—Organic non-cellulose fibres
    • D21H13/20—Organic non-cellulose fibres from macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H13/26—Polyamides; Polyimides

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Coloring (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Pyridine Compounds (AREA)
  • Ink Jet (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
KR1020117002373A 2008-07-02 2009-07-01 산 염료 Expired - Fee Related KR101760661B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP08011926 2008-07-02
EP08011926.6 2008-07-02
EP08160083.5 2008-07-10
EP08160083 2008-07-10
PCT/EP2009/058264 WO2010000780A1 (en) 2008-07-02 2009-07-01 Acid dyes

Publications (2)

Publication Number Publication Date
KR20110031359A KR20110031359A (ko) 2011-03-25
KR101760661B1 true KR101760661B1 (ko) 2017-07-24

Family

ID=41011821

Family Applications (2)

Application Number Title Priority Date Filing Date
KR1020117002373A Expired - Fee Related KR101760661B1 (ko) 2008-07-02 2009-07-01 산 염료
KR1020117002376A Expired - Fee Related KR101649484B1 (ko) 2008-07-02 2009-07-01 산 염료의 용도

Family Applications After (1)

Application Number Title Priority Date Filing Date
KR1020117002376A Expired - Fee Related KR101649484B1 (ko) 2008-07-02 2009-07-01 산 염료의 용도

Country Status (10)

Country Link
EP (2) EP2307509B1 (enExample)
JP (3) JP2011526636A (enExample)
KR (2) KR101760661B1 (enExample)
CN (2) CN102076779B (enExample)
BR (2) BRPI0914939B1 (enExample)
ES (2) ES2383581T3 (enExample)
MX (2) MX2010014526A (enExample)
PT (2) PT2307509E (enExample)
TW (2) TWI461408B (enExample)
WO (2) WO2010000779A1 (enExample)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2258683A1 (en) * 2009-05-14 2010-12-08 Clariant International Ltd. Bisazo compounds
PT2258685E (pt) * 2009-05-14 2013-12-10 Clariant Finance Bv Ltd Compostos bisazo
EP2418256B1 (en) * 2010-07-29 2013-03-27 Clariant Finance (BV) Limited Acid dyes
ES2497191T3 (es) * 2011-10-22 2014-09-22 Clariant International Ltd. Colorantes ácidos trisazoicos basados en piridonas
DE102013012244A1 (de) * 2013-07-24 2015-01-29 Clariant International Ltd. Verwendung von Disazoverbindungen für Color Filter
DE102013012855A1 (de) 2013-08-01 2015-02-05 Clariant International Ltd. Zusammensetzungen, enthaltend Disazofarbstoffe und Pigmente
EP2868705A1 (en) 2013-10-29 2015-05-06 DyStar Colours Distribution GmbH Metal free acid dyes, process for their production and their use
EP2868708A1 (en) 2013-10-29 2015-05-06 DyStar Colours Distribution GmbH Metal-free acid dyes, process for the production thereof and their use
WO2015062929A1 (en) 2013-10-29 2015-05-07 Dystar Colours Distribution Gmbh Acid dyes, process for the production thereof and their use
EP2868709A1 (en) 2013-10-29 2015-05-06 DyStar Colours Distribution GmbH Metal free acid dyes, process for the production thereof and their use
MX353410B (es) * 2013-10-29 2018-01-10 Dystar Colours Distrib Gmbh Tinturas ácidas, proceso para su producción y su uso.
EP2868715A1 (en) 2013-10-29 2015-05-06 DyStar Colours Distribution GmbH Metal free acid dyes, process for the production thereof and their use
EP2868712A1 (en) 2013-10-29 2015-05-06 DyStar Colours Distribution GmbH Metal free acid dyes, process for the production thereof and their use
CN104629401B (zh) * 2014-12-30 2017-03-29 南京工业大学 一种双偶氮分散染料及其制备方法和用途
TWI659138B (zh) * 2017-10-25 2019-05-11 Everlight Chemical Industrial Corporation 酸性染料組成物及其於染尼龍織物上的用途
CN116023795A (zh) * 2022-12-22 2023-04-28 苏州科法曼化学有限公司 一种染料化合物及其制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1296857A (enExample) 1968-11-12 1972-11-22
GB1331445A (en) 1970-03-31 1973-09-26 Ici Ltd Azo dyestuffs
WO2008012322A1 (en) * 2006-07-28 2008-01-31 Clariant International Ltd Basic bisazo compounds

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2004487C3 (de) * 1970-01-31 1979-12-06 Basf Ag, 6700 Ludwigshafen Wasserlösliche Azofarbstoffe, Verfahren zu ihrer Herstellung und ihre Verwendung
GB1331261A (en) * 1970-03-23 1973-09-26 Ici Ltd Water-soluble azo dyestuffs containaing hydroxypyridine residues
US3932122A (en) * 1970-10-23 1976-01-13 Ciba-Geigy Ag Azo compounds, their manufacture and use
DE2964693D1 (en) * 1978-04-28 1983-03-17 Ciba Geigy Ag Salts of sulphonated azo dyes and their use
US4359418A (en) * 1979-03-12 1982-11-16 Ciba-Geigy Corporation Amine salts of azo dyestuffs of the pyridone series
CH649092A5 (en) * 1979-09-24 1985-04-30 Ciba Geigy Ag Disazo compounds
CH667464A5 (de) * 1985-03-30 1988-10-14 Sandoz Ag Sulfonsaeuregruppenfreie basische azoverbindungen.
US5352334A (en) * 1985-03-30 1994-10-04 Sandoz Ltd. The use of metal-free sulfo group free basic disazo compounds containing two identical 6-hydroxypyrid-2-one coupling component radicals for producing colored paper
DE4227590A1 (de) * 1992-08-20 1994-02-24 Basf Ag Azofarbstoffe mit einer Kupplungskomponente aus der Reihe der N-(Hydroxysulfonylphenylalkyl)pyridone
GB0103240D0 (en) * 2001-02-09 2001-03-28 Clariant Int Ltd Organic compounds
EP1368431B1 (en) * 2001-03-09 2007-12-05 Ciba SC Holding AG Pyridone dyes, a process for their preparation and their use in the production of coloured plastics or polymeric colour particles
ATE411364T1 (de) * 2001-05-07 2008-10-15 Ciba Holding Inc Pyridonfarbstoffe, verfahren zu deren herstellung und deren verwendung zur herstellung gefärbter kunststoffe oder polymerer farbpartikel
US6713614B2 (en) * 2002-06-27 2004-03-30 Xerox Corporation Dimeric azo pyridone colorants

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1296857A (enExample) 1968-11-12 1972-11-22
GB1331445A (en) 1970-03-31 1973-09-26 Ici Ltd Azo dyestuffs
WO2008012322A1 (en) * 2006-07-28 2008-01-31 Clariant International Ltd Basic bisazo compounds

Also Published As

Publication number Publication date
BRPI0913833B1 (pt) 2018-06-12
TW201012802A (en) 2010-04-01
ES2383580T3 (es) 2012-06-22
EP2307510A1 (en) 2011-04-13
WO2010000779A1 (en) 2010-01-07
KR101649484B1 (ko) 2016-08-19
MX2010014525A (es) 2011-02-22
EP2307509B1 (en) 2012-02-29
TW201005043A (en) 2010-02-01
PT2307509E (pt) 2012-04-12
JP2011526636A (ja) 2011-10-13
PT2307510E (pt) 2012-04-12
KR20110039542A (ko) 2011-04-19
JP2015038264A (ja) 2015-02-26
CN102076779B (zh) 2013-08-21
EP2307509A1 (en) 2011-04-13
BRPI0914939B1 (pt) 2018-06-19
BRPI0913833A2 (pt) 2015-10-20
KR20110031359A (ko) 2011-03-25
CN102076780B (zh) 2013-08-21
EP2307510B1 (en) 2012-02-29
ES2383581T3 (es) 2012-06-22
BRPI0914939A2 (pt) 2015-10-20
JP2011526635A (ja) 2011-10-13
CN102076780A (zh) 2011-05-25
WO2010000780A1 (en) 2010-01-07
TWI461408B (zh) 2014-11-21
MX2010014526A (es) 2011-02-22
TWI588214B (zh) 2017-06-21
CN102076779A (zh) 2011-05-25

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