KR101448565B1 - 가스 스트림으로부터 ｃｏ₂ 포착 중 아민 분해를 억제하는 방법 - Google Patents

가스 스트림으로부터 ｃｏ₂ 포착 중 아민 분해를 억제하는 방법 Download PDF

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KR101448565B1
KR101448565B1 KR1020107013576A KR20107013576A KR101448565B1 KR 101448565 B1 KR101448565 B1 KR 101448565B1 KR 1020107013576 A KR1020107013576 A KR 1020107013576A KR 20107013576 A KR20107013576 A KR 20107013576A KR 101448565 B1 KR101448565 B1 KR 101448565B1
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kmol
knac
amine
amount
gas stream
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KR20100092958A (ko
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라파엘 이뎀
파이툰 톤티와치우티쿨
친타나 사이완
티라레트 스팝
프라체트 피티푸에츠
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더 유니버서티 오브 레지나
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493—Selection of liquid materials for use as absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/30—Alkali metal compounds
    • B01D2251/304—Alkali metal compounds of sodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/30—Alkali metal compounds
    • B01D2251/306—Alkali metal compounds of potassium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/90—Chelants
    • B01D2251/902—EDTA
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20405—Monoamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20421—Primary amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20478—Alkanolamines
    • B01D2252/20484—Alkanolamines with one hydroxyl group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/60—Additives
    • B01D2252/604—Stabilisers or agents inhibiting degradation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Gas Separation By Absorption (AREA)
  • Treating Waste Gases (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
KR1020107013576A 2007-11-20 2008-11-19 가스 스트림으로부터 ｃｏ₂ 포착 중 아민 분해를 억제하는 방법 Expired - Fee Related KR101448565B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US98926907P 2007-11-20 2007-11-20
US60/989,269 2007-11-20
PCT/CA2008/002038 WO2009065218A1 (en) 2007-11-20 2008-11-19 Method for inhibiting amine degradation during co2 capture from a gas stream

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Publication Number Publication Date
KR20100092958A KR20100092958A (ko) 2010-08-23
KR101448565B1 true KR101448565B1 (ko) 2014-10-08

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Country Link
US (1) US8105420B2 (enExample)
EP (1) EP2225011B1 (enExample)
JP (1) JP5536659B2 (enExample)
KR (1) KR101448565B1 (enExample)
CN (1) CN101918105B (enExample)
AU (1) AU2008328486B2 (enExample)
CA (1) CA2644088C (enExample)
PL (1) PL2225011T3 (enExample)
WO (1) WO2009065218A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024154935A1 (ko) * 2023-01-18 2024-07-25 주식회사 파나시아 이산화탄소 포집용 흡수제

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008027510A2 (en) * 2006-09-01 2008-03-06 Novum Energy Technology, Llc Sour-gas sweetening solutions and methods
US8192530B2 (en) 2007-12-13 2012-06-05 Alstom Technology Ltd System and method for regeneration of an absorbent solution
CN102548639B (zh) 2009-09-24 2015-04-29 株式会社东芝 二氧化碳吸收液
US20110186441A1 (en) * 2010-01-29 2011-08-04 Conocophillips Company Electrolytic recovery of retained carbon dioxide
CN102834162B (zh) * 2010-02-19 2015-04-01 联邦科学与工业研究组织 溶剂处理方法
CN101822932B (zh) * 2010-06-12 2013-01-02 中国石油集团工程设计有限责任公司 一种脱除天然气中二氧化碳的复配型脱碳溶剂
EP2632567B1 (en) * 2010-10-29 2019-08-07 MECS, Inc. Regenerative recovery of sulfur dioxide from effluent gases
FR2970424B1 (fr) * 2011-01-19 2013-11-08 IFP Energies Nouvelles Solution absorbante contenant une combinaison d'inhibiteurs de degradation comportant un derive du thiadiazole et procede d'absorption de composes acides contenus dans un effluent gazeux
FR2970423B1 (fr) * 2011-01-19 2013-11-08 IFP Energies Nouvelles Solution absorbante contenant une combinaison d'hinhibiteurs de degradation comportant un derive d'un triazole ou d'un tetrazole et procede d'absorption de composes acides contenus dans un gaz
US9133407B2 (en) 2011-02-25 2015-09-15 Alstom Technology Ltd Systems and processes for removing volatile degradation products produced in gas purification
WO2012125894A2 (en) * 2011-03-17 2012-09-20 Board Of Regents, The University Of Texas System Oxidation inhibitors for amine degradation
CN103813982A (zh) * 2011-09-02 2014-05-21 艺科环球科技私人有限公司 碳化二氧化碳的方法及其应用
US8864878B2 (en) 2011-09-23 2014-10-21 Alstom Technology Ltd Heat integration of a cement manufacturing plant with an absorption based carbon dioxide capture process
US8911538B2 (en) 2011-12-22 2014-12-16 Alstom Technology Ltd Method and system for treating an effluent stream generated by a carbon capture system
US9028654B2 (en) 2012-02-29 2015-05-12 Alstom Technology Ltd Method of treatment of amine waste water and a system for accomplishing the same
EP2653208A1 (de) * 2012-04-17 2013-10-23 Siemens Aktiengesellschaft Aminwaschlösung zur Absorption von Kohlendioxid mit Oxidationsinhibitoren
FR2994861B1 (fr) * 2012-08-30 2014-08-22 IFP Energies Nouvelles Procede d'absorption de composes acides contenus dans un effluent gazeux au moyen d'une solution aqueuse a base d'amine
US9101912B2 (en) 2012-11-05 2015-08-11 Alstom Technology Ltd Method for regeneration of solid amine CO2 capture beds
US9604889B2 (en) * 2012-11-08 2017-03-28 Energy Recovery, Inc. Isobaric pressure exchanger in amine gas processing
US9440895B2 (en) * 2012-11-08 2016-09-13 Energy Recovery, Inc. Isobaric pressure exchanger controls in amine gas processing
CN104226079A (zh) * 2013-06-18 2014-12-24 中国石油化工股份有限公司 一种用于有机胺型脱碳溶液的抗氧化剂
JP2017032146A (ja) * 2014-01-31 2017-02-09 日揮株式会社 液化ガス製造設備及び液化ガス製造方法
US9675928B2 (en) 2014-02-25 2017-06-13 The University Of Kentucky Research Foundation Method of inhibiting nitrosation of an aqueous amine solution used in a process of removing carbon dioxide from a flue gas
WO2015138940A1 (en) 2014-03-13 2015-09-17 Fluor Technologies Corporation Removal of metals from co2 capture solvents
CN113174603A (zh) * 2021-04-28 2021-07-27 河钢集团有限公司 用于捕获并电解co2的组合物以及方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010049513A (ko) * 1999-06-10 2001-06-15 조안 엠. 젤사 ; 로버트 지. 호헨스타인 ; 도로시 엠. 보어 복합 아민 혼합물에 의해 이산화탄소를 회수하는 방법
KR20120055802A (ko) * 2010-11-24 2012-06-01 한국에너지기술연구원 아민계 첨가제 및 암모니아수를 포함하는 이산화탄소 흡수용 조성물 및 상기 조성물을 사용하는 방법
KR20130106680A (ko) * 2012-03-20 2013-09-30 서강대학교산학협력단 이산화탄소 흡수제 및 이의 사용 방법

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3137654A (en) * 1961-03-28 1964-06-16 Wayne W Johnson Stabilization of aqueous alkanolamine solutions in gas treating processes
US3959170A (en) * 1971-11-22 1976-05-25 Union Carbide Corporation Corrosion inhibitors for alkanolamine gas treating system
US3896044A (en) * 1971-11-22 1975-07-22 Union Carbide Corp Nitro-substituted aromatic acid corrosion inhibitors for alkanolamine gas treating system
US4405584A (en) * 1982-02-02 1983-09-20 Exxon Research And Engineering Co. Process for removing acidic gases
US4575455A (en) * 1984-11-23 1986-03-11 Atlantic Richfield Company Process for removing hydrogen sulfide with reduced fouling
MX9702676A (es) * 1994-10-13 1998-02-28 Catachem Inc Metodo para minimizar la degradacion de solvente y la corrosion en sistemas de tratamiento de solvente de amina.
US5648054A (en) * 1995-01-31 1997-07-15 Gas Research Institute Double loop liquid-liquid H2 S removal process
US6059992A (en) * 1995-10-10 2000-05-09 Veldman; Ray R. Gas treating solution corrosion inhibitor
WO2001005489A1 (en) * 1999-07-19 2001-01-25 Ebara Corporation Apparatus and method for cleaning acidic gas
CN1381301A (zh) * 2001-12-20 2002-11-27 南化集团研究院 抑制回收低分压co2溶剂降解的抗氧化剂
US7056482B2 (en) * 2003-06-12 2006-06-06 Cansolv Technologies Inc. Method for recovery of CO2 from gas streams
US7214358B2 (en) * 2003-08-13 2007-05-08 Cansolv Technologies Inc. Low energy regenerable SO2 scrubbing process
JP2005179709A (ja) * 2003-12-17 2005-07-07 Toyo Tanso Kk ガス発生装置
DE102004011427A1 (de) * 2004-03-09 2005-09-29 Basf Ag Absorptionsmittel mit verbesserter Oxidationsbeständigkeit und Verfahren zum Entsäuern von Fluidströmen
CN100352536C (zh) * 2004-12-17 2007-12-05 南化集团研究院 抑制一乙醇胺回收二氧化碳系统中溶剂降解的方法
US7384616B2 (en) * 2005-06-20 2008-06-10 Cansolv Technologies Inc. Waste gas treatment process including removal of mercury
CN1887405A (zh) * 2005-06-27 2007-01-03 成都华西化工研究所 从烟道气中脱除和回收二氧化碳的方法
CN101417200B (zh) * 2007-10-22 2012-06-27 辽河石油勘探局 锅炉烟道气回收二氧化碳、氮气的方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010049513A (ko) * 1999-06-10 2001-06-15 조안 엠. 젤사 ; 로버트 지. 호헨스타인 ; 도로시 엠. 보어 복합 아민 혼합물에 의해 이산화탄소를 회수하는 방법
KR20120055802A (ko) * 2010-11-24 2012-06-01 한국에너지기술연구원 아민계 첨가제 및 암모니아수를 포함하는 이산화탄소 흡수용 조성물 및 상기 조성물을 사용하는 방법
KR20130106680A (ko) * 2012-03-20 2013-09-30 서강대학교산학협력단 이산화탄소 흡수제 및 이의 사용 방법

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024154935A1 (ko) * 2023-01-18 2024-07-25 주식회사 파나시아 이산화탄소 포집용 흡수제

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EP2225011A4 (en) 2011-10-05
EP2225011A1 (en) 2010-09-08
CA2644088C (en) 2013-01-22
JP2011503216A (ja) 2011-01-27
AU2008328486B2 (en) 2013-06-20
US8105420B2 (en) 2012-01-31
EP2225011B1 (en) 2016-03-16
PL2225011T3 (pl) 2016-11-30
CN101918105B (zh) 2014-02-19
JP5536659B2 (ja) 2014-07-02
AU2008328486A1 (en) 2009-05-28
CA2644088A1 (en) 2009-05-20
CN101918105A (zh) 2010-12-15
WO2009065218A1 (en) 2009-05-28
US20090205496A1 (en) 2009-08-20
KR20100092958A (ko) 2010-08-23

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