KR101288803B1 - 고온 강도 및 투과도가 우수한 폴리에틸렌 미세다공막 - Google Patents
고온 강도 및 투과도가 우수한 폴리에틸렌 미세다공막 Download PDFInfo
- Publication number
- KR101288803B1 KR101288803B1 KR1020070092495A KR20070092495A KR101288803B1 KR 101288803 B1 KR101288803 B1 KR 101288803B1 KR 1020070092495 A KR1020070092495 A KR 1020070092495A KR 20070092495 A KR20070092495 A KR 20070092495A KR 101288803 B1 KR101288803 B1 KR 101288803B1
- Authority
- KR
- South Korea
- Prior art keywords
- temperature
- permeability
- polyethylene
- battery
- darcy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
- B29C55/10—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial
- B29C55/12—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial
- B29C55/14—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial successively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
- B29C55/10—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial
- B29C55/12—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial
- B29C55/16—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial simultaneously
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/403—Manufacturing processes of separators, membranes or diaphragms
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/411—Organic material
- H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
- H01M50/417—Polyolefins
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/489—Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/489—Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
- H01M50/491—Porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/04—Polymers of ethylene
- B29K2023/06—PE, i.e. polyethylene
- B29K2023/0608—PE, i.e. polyethylene characterised by its density
- B29K2023/065—HDPE, i.e. high density polyethylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0058—Liquid or visquous
- B29K2105/0073—Solution
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/04—Condition, form or state of moulded material or of the material to be shaped cellular or porous
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/04—Condition, form or state of moulded material or of the material to be shaped cellular or porous
- B29K2105/041—Microporous
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249978—Voids specified as micro
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Cell Separators (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020070092495A KR101288803B1 (ko) | 2007-09-12 | 2007-09-12 | 고온 강도 및 투과도가 우수한 폴리에틸렌 미세다공막 |
| US12/232,112 US8486521B2 (en) | 2007-09-12 | 2008-09-11 | Microporous polyethylene film with good property of strength and permeability at high temperature |
| EP08016152.4A EP2036699B1 (en) | 2007-09-12 | 2008-09-12 | Method for preparing a microporous polyethylene film with good property of strength and permeability at high temperature |
| JP2008234436A JP5221258B2 (ja) | 2007-09-12 | 2008-09-12 | 高温強度及び透気度に優れているポリエチレン微多孔膜 |
| CN2008102119679A CN101386686B (zh) | 2007-09-12 | 2008-09-12 | 在高温时具有良好的强度特性和渗透特性的微孔聚乙烯膜 |
| EP20140170095 EP2777913A1 (en) | 2007-09-12 | 2008-09-12 | Microporous polyethylene film with good property of strength and permeability at high temperature |
| US13/403,324 US8354185B2 (en) | 2007-09-12 | 2012-02-23 | Microporous polyethylene film with good property of strength and permeability at high temperature |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020070092495A KR101288803B1 (ko) | 2007-09-12 | 2007-09-12 | 고온 강도 및 투과도가 우수한 폴리에틸렌 미세다공막 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020130078585A Division KR101327442B1 (ko) | 2013-07-04 | 2013-07-04 | 고온 강도 및 투과도가 우수한 폴리에틸렌 미세다공막 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20090027345A KR20090027345A (ko) | 2009-03-17 |
| KR101288803B1 true KR101288803B1 (ko) | 2013-07-23 |
Family
ID=40220187
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020070092495A Active KR101288803B1 (ko) | 2007-09-12 | 2007-09-12 | 고온 강도 및 투과도가 우수한 폴리에틸렌 미세다공막 |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US8486521B2 (https=) |
| EP (2) | EP2036699B1 (https=) |
| JP (1) | JP5221258B2 (https=) |
| KR (1) | KR101288803B1 (https=) |
| CN (1) | CN101386686B (https=) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101640777B1 (ko) * | 2008-11-17 | 2016-07-19 | 도레이 배터리 세퍼레이터 필름 주식회사 | 미세다공성 막, 이러한 막의 제조방법 및 사용방법 |
| CN101735474B (zh) * | 2009-12-23 | 2011-09-07 | 中国石油天然气股份有限公司 | 一种亲水性聚乙烯微孔膜及其制备方法 |
| KR101336593B1 (ko) * | 2010-04-20 | 2013-12-05 | 에스케이이노베이션 주식회사 | 생산성이 우수하며 물성조절이 용이한 폴리올레핀계 미세다공막 제조방법 |
| CN103493252B (zh) * | 2011-04-04 | 2016-08-10 | 阿普柔斯公司 | 改进的电池隔片及其形成方法 |
| KR101383606B1 (ko) * | 2011-07-04 | 2014-04-10 | 주식회사 엘지화학 | 전기화학소자의 세퍼레이터 제조용 조성물, 전기화학소자의 세퍼레이터 제조방법, 및 이를 이용한 전기화학소자 |
| WO2013005987A2 (ko) * | 2011-07-04 | 2013-01-10 | 주식회사 엘지화학 | 전기화학소자의 세퍼레이터 제조용 조성물, 전기화학소자의 세퍼레이터 제조방법, 및 이를 이용한 전기화학소자 |
| US10206122B2 (en) * | 2014-02-25 | 2019-02-12 | Mediatek Inc. | Direction finding positioning in wireless local area networks |
| US11021584B2 (en) | 2014-08-21 | 2021-06-01 | William Winchin Yen | Microporous sheet product and methods for making and using the same |
| JP6202062B2 (ja) * | 2014-09-30 | 2017-09-27 | 住友化学株式会社 | 偏光フィルムの強度測定方法及び偏光板 |
| US10829600B2 (en) | 2014-11-05 | 2020-11-10 | William Winchin Yen | Microporous sheet product and methods for making and using the same |
| JP2017535642A (ja) | 2014-11-05 | 2017-11-30 | イエン,ウイリアム・ウインチン | 微孔性シート製品、ならびに、その製造方法及び使用方法 |
| US10707465B2 (en) * | 2015-10-30 | 2020-07-07 | Sumitomo Chemical Company, Limited | Film manufacturing method, film manufacturing apparatus, and film |
| CN105445313A (zh) * | 2015-11-30 | 2016-03-30 | 深圳市星源材质科技股份有限公司 | 一种电池隔膜的热稳定性检测方法 |
| US12110382B2 (en) * | 2019-03-04 | 2024-10-08 | Asahi Kasei Kabushiki Kaisha | Polyolefin microporous membrane |
| KR20240165057A (ko) * | 2023-05-15 | 2024-11-22 | 에스케이이노베이션 주식회사 | 폴리에틸렌 미세다공막, 이의 제조방법 및 상기 미세다공막을 포함하는 분리막 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1121362A (ja) * | 1997-07-07 | 1999-01-26 | Mitsubishi Chem Corp | ポリエチレン樹脂製多孔性フィルム |
| KR20010079905A (ko) * | 1998-10-01 | 2001-08-22 | 요코쿠라 타다시 | 폴리올레핀 미세다공성 막과 그것의 제조방법 |
| KR20060106102A (ko) * | 2005-04-06 | 2006-10-12 | 에스케이 주식회사 | 물성, 생산성 및 품질 균일도가 우수한 폴리에틸렌 미세다공막 및 그 제조방법 |
| KR20060118668A (ko) * | 2005-05-16 | 2006-11-24 | 에스케이 주식회사 | 액-액 상분리에 의하여 제조된 폴리에틸렌 미세다공막 및그 제조방법 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57117951A (en) * | 1981-01-16 | 1982-07-22 | Mitsubishi Rayon Co | Porous polyethylene film and its manufacture |
| US5641565A (en) * | 1991-07-05 | 1997-06-24 | Asahi Kasei Kogyo Kabushiki Kaisha | Separator for a battery using an organic electrolytic solution and method for preparing the same |
| US5759678A (en) * | 1995-10-05 | 1998-06-02 | Mitsubishi Chemical Corporation | High-strength porous film and process for producing the same |
| JP3054088B2 (ja) | 1996-11-15 | 2000-06-19 | 株式会社内田洋行 | パネル付センターコア |
| WO1999048959A1 (fr) | 1998-03-24 | 1999-09-30 | Asahi Kasei Kogyo Kabushiki Kaisha | Film polyolefinique microporeux |
| JP4098401B2 (ja) | 1998-05-19 | 2008-06-11 | 旭化成ケミカルズ株式会社 | ポリオレフィン製の電池セパレーター用微多孔膜 |
| JP2001144910A (ja) | 1999-11-12 | 2001-05-25 | Ricoh Co Ltd | 画像処理装置および画像形成装置 |
| WO2002092677A1 (fr) * | 2001-05-17 | 2002-11-21 | Asahi Kasei Kabushiki Kaisha | Film polyolefinique microporeux |
| JP2003119306A (ja) | 2001-10-11 | 2003-04-23 | Nitto Denko Corp | 低収縮性微多孔膜およびその製法 |
| TW200417563A (en) | 2002-09-12 | 2004-09-16 | Teijin Ltd | Porous membrane of poly(metaphenylene isophthalamide) and process for producing the same |
| US6949315B1 (en) * | 2004-05-12 | 2005-09-27 | Garrin Samii | Shutdown separators with improved properties |
| US7332531B2 (en) * | 2004-06-11 | 2008-02-19 | Sk Corporation | Microporous high density polyethylene film |
| US7435761B2 (en) * | 2004-07-06 | 2008-10-14 | Sk Energy Co., Ltd. | Microporous polyethylene film and method of producing the same |
| US20060008636A1 (en) * | 2004-07-06 | 2006-01-12 | Lee Young K | Microporous polyethylene film and method of producing the same |
| US20060148915A1 (en) * | 2004-12-30 | 2006-07-06 | Floyd Robert M | Microporous materials and methods of making |
| US20070092705A1 (en) * | 2005-06-18 | 2007-04-26 | Young-Keun Lee | Microporous polyethylene film through liquid-liquid phase separation mechanism and preparing method thereof |
| CA2611274A1 (en) | 2005-06-24 | 2006-12-28 | Tonen Chemical Corporation | Method for producing polyolefin microporous polyolefin membrane |
| JP5196752B2 (ja) | 2005-09-16 | 2013-05-15 | 東レバッテリーセパレータフィルム株式会社 | ポリエチレン微多孔膜及びその製造方法、並びに電池用セパレータ |
| KR101432146B1 (ko) * | 2007-11-28 | 2014-08-28 | 에스케이이노베이션 주식회사 | 물성과 고온 열안정성이 우수한 폴리올레핀 미세다공막 |
-
2007
- 2007-09-12 KR KR1020070092495A patent/KR101288803B1/ko active Active
-
2008
- 2008-09-11 US US12/232,112 patent/US8486521B2/en active Active
- 2008-09-12 JP JP2008234436A patent/JP5221258B2/ja active Active
- 2008-09-12 CN CN2008102119679A patent/CN101386686B/zh active Active
- 2008-09-12 EP EP08016152.4A patent/EP2036699B1/en active Active
- 2008-09-12 EP EP20140170095 patent/EP2777913A1/en not_active Withdrawn
-
2012
- 2012-02-23 US US13/403,324 patent/US8354185B2/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1121362A (ja) * | 1997-07-07 | 1999-01-26 | Mitsubishi Chem Corp | ポリエチレン樹脂製多孔性フィルム |
| KR20010079905A (ko) * | 1998-10-01 | 2001-08-22 | 요코쿠라 타다시 | 폴리올레핀 미세다공성 막과 그것의 제조방법 |
| KR20060106102A (ko) * | 2005-04-06 | 2006-10-12 | 에스케이 주식회사 | 물성, 생산성 및 품질 균일도가 우수한 폴리에틸렌 미세다공막 및 그 제조방법 |
| KR20060118668A (ko) * | 2005-05-16 | 2006-11-24 | 에스케이 주식회사 | 액-액 상분리에 의하여 제조된 폴리에틸렌 미세다공막 및그 제조방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20090075049A1 (en) | 2009-03-19 |
| EP2036699B1 (en) | 2015-12-23 |
| US8354185B2 (en) | 2013-01-15 |
| KR20090027345A (ko) | 2009-03-17 |
| JP5221258B2 (ja) | 2013-06-26 |
| EP2036699A1 (en) | 2009-03-18 |
| EP2036699A8 (en) | 2009-05-06 |
| EP2777913A1 (en) | 2014-09-17 |
| JP2009070823A (ja) | 2009-04-02 |
| CN101386686B (zh) | 2011-11-09 |
| US20120156570A1 (en) | 2012-06-21 |
| US8486521B2 (en) | 2013-07-16 |
| CN101386686A (zh) | 2009-03-18 |
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