KR101208433B1 - 메타크릴산 제조용 촉매 및 그의 제조방법 - Google Patents

메타크릴산 제조용 촉매 및 그의 제조방법 Download PDF

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Publication number
KR101208433B1
KR101208433B1 KR1020077021745A KR20077021745A KR101208433B1 KR 101208433 B1 KR101208433 B1 KR 101208433B1 KR 1020077021745 A KR1020077021745 A KR 1020077021745A KR 20077021745 A KR20077021745 A KR 20077021745A KR 101208433 B1 KR101208433 B1 KR 101208433B1
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KR
South Korea
Prior art keywords
catalyst
antimony
methacrylic acid
coating
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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KR1020077021745A
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English (en)
Korean (ko)
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KR20070114362A (ko
Inventor
아츠시 스도
타츠히코 쿠라카미
토시타케 코지마
시게오 하야시모토
Original Assignee
니폰 가야꾸 가부시끼가이샤
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Publication of KR20070114362A publication Critical patent/KR20070114362A/ko
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Publication of KR101208433B1 publication Critical patent/KR101208433B1/ko
Expired - Fee Related legal-status Critical Current
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0221—Coating of particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0219—Coating the coating containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B61/00—Other general methods
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/51—Spheres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020077021745A 2005-03-29 2006-03-28 메타크릴산 제조용 촉매 및 그의 제조방법 Expired - Fee Related KR101208433B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JPJP-P-2005-00094734 2005-03-29
JP2005094734A JP4756890B2 (ja) 2005-03-29 2005-03-29 メタクリル酸製造用触媒及びその製造方法

Related Child Applications (1)

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KR1020127009218A Division KR101223590B1 (ko) 2005-03-29 2006-03-28 메타크릴산 제조용 촉매 및 그의 제조방법

Publications (2)

Publication Number Publication Date
KR20070114362A KR20070114362A (ko) 2007-12-03
KR101208433B1 true KR101208433B1 (ko) 2012-12-05

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KR1020127009218A Expired - Fee Related KR101223590B1 (ko) 2005-03-29 2006-03-28 메타크릴산 제조용 촉매 및 그의 제조방법

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Country Status (10)

Country Link
US (1) US8716523B2 (enExample)
EP (2) EP2204234A1 (enExample)
JP (1) JP4756890B2 (enExample)
KR (2) KR101208433B1 (enExample)
CN (2) CN101829589B (enExample)
BR (1) BRPI0608759A2 (enExample)
CA (1) CA2603005A1 (enExample)
MY (1) MY143359A (enExample)
TW (1) TW200642757A (enExample)
WO (1) WO2006104155A1 (enExample)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006314923A (ja) * 2005-05-12 2006-11-24 Nippon Kayaku Co Ltd メタクリル酸製造用触媒の製造方法
US8178718B2 (en) 2007-02-05 2012-05-15 Saudi Basic Industries Corporation Catalyst for oxidation of saturated and unsaturated aldehydes to unsaturated carboxylic acid, method of making and method of using thereof
KR20110092272A (ko) * 2008-11-06 2011-08-17 니폰 가야꾸 가부시끼가이샤 메타크릴산의 제조방법 및 메타크릴산 제조용 촉매
JP5261231B2 (ja) * 2009-03-04 2013-08-14 三菱レイヨン株式会社 不飽和カルボン酸合成用触媒の製造方法
JP5570142B2 (ja) * 2009-05-26 2014-08-13 日本化薬株式会社 メタクリル酸製造触媒の製造方法およびメタクリル酸の製造方法
JP5387297B2 (ja) * 2009-09-30 2014-01-15 住友化学株式会社 複合酸化物触媒の製造方法
CN105665020B (zh) * 2009-11-30 2019-09-06 日本化药株式会社 异丁烯酸制造催化剂的制造方法及异丁烯酸的制造方法
JP2012110806A (ja) * 2010-11-22 2012-06-14 Nippon Kayaku Co Ltd メタクリル酸製造触媒の製造方法およびメタクリル酸の製造方法
CN103945938B (zh) * 2011-11-17 2016-08-24 日本化药株式会社 甲基丙烯酸制造用催化剂及使用该催化剂的甲基丙烯酸的制造方法
CN104302391A (zh) * 2012-05-18 2015-01-21 日本化药株式会社 甲基丙烯酸制造用催化剂、其制造方法及使用该催化剂的甲基丙烯酸的制造方法
WO2015053269A1 (ja) 2013-10-10 2015-04-16 日本化薬株式会社 不飽和カルボン酸の製造方法、及び担持触媒
CN106140239A (zh) * 2015-04-23 2016-11-23 北京化工大学 一种用于油品脱硫的多酸基负载型催化剂及其制备方法
WO2018217961A1 (en) 2017-05-25 2018-11-29 Rohm And Haas Company Process for preparing methacrolein
CN115888779B (zh) * 2022-10-31 2024-05-28 鞍山七彩化学股份有限公司 一种丁二酸制备丁二腈的催化剂及丁二腈的制备方法

Citations (1)

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JP4093194B2 (ja) * 2004-03-23 2008-06-04 住友化学株式会社 メタクリル酸の製造方法
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Publication number Publication date
JP2006272151A (ja) 2006-10-12
EP1867387A1 (en) 2007-12-19
TWI374056B (enExample) 2012-10-11
TW200642757A (en) 2006-12-16
EP2204234A1 (en) 2010-07-07
BRPI0608759A2 (pt) 2010-01-26
EP1867387A4 (en) 2009-09-02
KR20120043152A (ko) 2012-05-03
EP1867387B1 (en) 2013-12-04
CN101829589B (zh) 2013-08-21
US20090234158A1 (en) 2009-09-17
CN101829589A (zh) 2010-09-15
CN101175568A (zh) 2008-05-07
CN101175568B (zh) 2011-05-25
WO2006104155A1 (ja) 2006-10-05
MY143359A (en) 2011-04-29
JP4756890B2 (ja) 2011-08-24
KR101223590B1 (ko) 2013-01-17
CA2603005A1 (en) 2006-10-05
US8716523B2 (en) 2014-05-06
KR20070114362A (ko) 2007-12-03

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