CN101175568B - 用于制备甲基丙烯酸的催化剂及其制备方法 - Google Patents

用于制备甲基丙烯酸的催化剂及其制备方法 Download PDF

Info

Publication number
CN101175568B
CN101175568B CN2006800093175A CN200680009317A CN101175568B CN 101175568 B CN101175568 B CN 101175568B CN 2006800093175 A CN2006800093175 A CN 2006800093175A CN 200680009317 A CN200680009317 A CN 200680009317A CN 101175568 B CN101175568 B CN 101175568B
Authority
CN
China
Prior art keywords
catalyst
antimony
methacrylic acid
methacrolein
slurry
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN2006800093175A
Other languages
English (en)
Chinese (zh)
Other versions
CN101175568A (zh
Inventor
須藤渥
倉上竜彦
小島利丈
林本成生
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Kayaku Co Ltd
Original Assignee
Nippon Kayaku Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Kayaku Co Ltd filed Critical Nippon Kayaku Co Ltd
Publication of CN101175568A publication Critical patent/CN101175568A/zh
Application granted granted Critical
Publication of CN101175568B publication Critical patent/CN101175568B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0221—Coating of particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0219—Coating the coating containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B61/00—Other general methods
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/51—Spheres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN2006800093175A 2005-03-29 2006-03-28 用于制备甲基丙烯酸的催化剂及其制备方法 Expired - Fee Related CN101175568B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2005094734A JP4756890B2 (ja) 2005-03-29 2005-03-29 メタクリル酸製造用触媒及びその製造方法
JP094734/2005 2005-03-29
PCT/JP2006/306318 WO2006104155A1 (ja) 2005-03-29 2006-03-28 メタクリル酸製造用触媒及びその製造方法

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN201010143947XA Division CN101829589B (zh) 2005-03-29 2006-03-28 用于制备甲基丙烯酸的催化剂及其制备方法

Publications (2)

Publication Number Publication Date
CN101175568A CN101175568A (zh) 2008-05-07
CN101175568B true CN101175568B (zh) 2011-05-25

Family

ID=37053411

Family Applications (2)

Application Number Title Priority Date Filing Date
CN2006800093175A Expired - Fee Related CN101175568B (zh) 2005-03-29 2006-03-28 用于制备甲基丙烯酸的催化剂及其制备方法
CN201010143947XA Expired - Fee Related CN101829589B (zh) 2005-03-29 2006-03-28 用于制备甲基丙烯酸的催化剂及其制备方法

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN201010143947XA Expired - Fee Related CN101829589B (zh) 2005-03-29 2006-03-28 用于制备甲基丙烯酸的催化剂及其制备方法

Country Status (10)

Country Link
US (1) US8716523B2 (enExample)
EP (2) EP1867387B1 (enExample)
JP (1) JP4756890B2 (enExample)
KR (2) KR101208433B1 (enExample)
CN (2) CN101175568B (enExample)
BR (1) BRPI0608759A2 (enExample)
CA (1) CA2603005A1 (enExample)
MY (1) MY143359A (enExample)
TW (1) TW200642757A (enExample)
WO (1) WO2006104155A1 (enExample)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006314923A (ja) * 2005-05-12 2006-11-24 Nippon Kayaku Co Ltd メタクリル酸製造用触媒の製造方法
US8178718B2 (en) * 2007-02-05 2012-05-15 Saudi Basic Industries Corporation Catalyst for oxidation of saturated and unsaturated aldehydes to unsaturated carboxylic acid, method of making and method of using thereof
JP5574434B2 (ja) * 2008-11-06 2014-08-20 日本化薬株式会社 メタクリル酸の製造方法及びメタクリル酸製造用触媒
JP5261231B2 (ja) * 2009-03-04 2013-08-14 三菱レイヨン株式会社 不飽和カルボン酸合成用触媒の製造方法
JP5570142B2 (ja) * 2009-05-26 2014-08-13 日本化薬株式会社 メタクリル酸製造触媒の製造方法およびメタクリル酸の製造方法
JP5387297B2 (ja) * 2009-09-30 2014-01-15 住友化学株式会社 複合酸化物触媒の製造方法
EP2508256A4 (en) * 2009-11-30 2013-07-10 Nippon Kayaku Kk METHOD FOR PRODUCING A CATALYST FOR USE IN THE PREPARATION OF METHACRYLIC ACID AND METHACRYLIC ACID METHOD OF PREPARING THEREOF
JP2012110806A (ja) * 2010-11-22 2012-06-14 Nippon Kayaku Co Ltd メタクリル酸製造触媒の製造方法およびメタクリル酸の製造方法
KR20140099453A (ko) * 2011-11-17 2014-08-12 닛뽄 가야쿠 가부시키가이샤 메타크릴산 제조용 촉매 및 그것을 이용한 메타크릴산의 제조 방법
EP2851119A4 (en) * 2012-05-18 2016-01-20 Nippon Kayaku Kk CATALYST FOR USE IN THE PREPARATION OF METACRYLIC ACID, METHOD FOR THE PRODUCTION OF THE CATALYST AND METHACRYLIC ACID PROCESS FOR THE PREPARATION OF THIS CATALYST
KR20160068763A (ko) 2013-10-10 2016-06-15 닛뽄 가야쿠 가부시키가이샤 불포화 카본산의 제조 방법, 및 담지 촉매
CN106140239A (zh) * 2015-04-23 2016-11-23 北京化工大学 一种用于油品脱硫的多酸基负载型催化剂及其制备方法
BR112019023830B1 (pt) 2017-05-25 2023-02-28 Rohm And Haas Company Processo para preparar metacroleína
CN115888779B (zh) * 2022-10-31 2024-05-28 鞍山七彩化学股份有限公司 一种丁二酸制备丁二腈的催化剂及丁二腈的制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4225466A (en) * 1973-12-29 1980-09-30 Nippon Shokubai Kagaku Kogyo Co. Ltd. Catalytic oxide composition for preparing methacrylic acid

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2626887B2 (de) * 1976-06-16 1978-06-29 Basf Ag, 6700 Ludwigshafen Katalysator für die Oxadation von (Methacrolein zu (Meth)Acrylsäure
JPS57165040A (en) 1981-04-03 1982-10-09 Sumitomo Chem Co Ltd Preparation of catalyst for preparing methacrylic acid
JP2574948B2 (ja) 1990-02-08 1997-01-22 株式会社日本触媒 メタクリル酸の製造方法
JP3146486B2 (ja) 1990-06-28 2001-03-19 住友化学工業株式会社 メタクリル酸製造用触媒の製造方法
US5198579A (en) * 1990-11-14 1993-03-30 Mitsui Toatsu Chemicals, Inc. Catalyst for oxidizing methacrolein and method for preparing methacrylic acid
JP3186243B2 (ja) 1992-09-14 2001-07-11 三菱レイヨン株式会社 メタクリル酸製造用触媒の調製法
US5716895A (en) * 1993-04-01 1998-02-10 Nippon Kayaku Kabushiki Kaisha Process for regeneration of catalysts
JPH08157414A (ja) 1994-12-01 1996-06-18 Mitsui Toatsu Chem Inc メタクリル酸製造用触媒及びメタクリル酸の製造方法
JP3482476B2 (ja) * 1995-07-12 2003-12-22 住友化学工業株式会社 メタクリル酸製造用触媒の製造方法およびメタクリル酸の製造方法
JPH0924277A (ja) 1995-07-14 1997-01-28 Sumitomo Chem Co Ltd メタクリル酸製造用触媒及びメタクリル酸の製造方法
JPH09290162A (ja) 1996-04-26 1997-11-11 Mitsubishi Chem Corp 酸化触媒の製造方法及びメタクリル酸の製造方法
JP3799660B2 (ja) * 1996-05-16 2006-07-19 三菱化学株式会社 酸化触媒及びその製造方法並びにメタクリル酸の製造方法
US6339037B1 (en) 1999-04-27 2002-01-15 Nippon Shokubai Co. Ltd Catalysts for methacrylic acid production and process for producing methacrylic acid
DE19922156A1 (de) 1999-05-12 2000-08-10 Basf Ag Multimetalloxidmassen, Verfahren zu ihrer Herstellung, sowie Vorrichtungen zur Durchführung des Verfahrens
EP1325780A4 (en) 2000-09-21 2006-05-03 Nippon Kayaku Kk CATALYST FOR METHACRYLIC ACID PRODUCTION, COATED CATALYST AND METHOD FOR THE PRODUCTION THEREOF
JP3797148B2 (ja) * 2001-06-29 2006-07-12 住友化学株式会社 メタクリル酸製造用触媒の製造方法およびメタクリル酸の製造方法
JP4200744B2 (ja) * 2002-10-15 2008-12-24 住友化学株式会社 メタクリル酸製造用触媒の製造方法およびメタクリル酸の製造方法
TWI341219B (en) 2003-02-20 2011-05-01 Nippon Kayaku Kk Catalyst for producing methacrylic acid and preparation method thereof
BRPI0410816A (pt) 2003-05-30 2006-06-27 Nippon Kayaku Kk método de preparação de catalisador para produção de ácido metacrìlico
JP2005021727A (ja) * 2003-06-30 2005-01-27 Sumitomo Chem Co Ltd メタクリル酸製造用触媒の製造方法及びメタクリル酸の製造方法
JP2005058909A (ja) 2003-08-12 2005-03-10 Mitsubishi Rayon Co Ltd メタクリル酸合成用触媒の製造方法
JP4352856B2 (ja) 2003-10-31 2009-10-28 住友化学株式会社 メタクリル酸製造用触媒の製造方法、これにより得られるメタクリル酸製造用触媒、及びメタクリル酸の製造方法。
JP4745653B2 (ja) 2003-12-05 2011-08-10 三菱レイヨン株式会社 メタクリル酸の製造方法
JP4093194B2 (ja) * 2004-03-23 2008-06-04 住友化学株式会社 メタクリル酸の製造方法
JP2006314923A (ja) 2005-05-12 2006-11-24 Nippon Kayaku Co Ltd メタクリル酸製造用触媒の製造方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4225466A (en) * 1973-12-29 1980-09-30 Nippon Shokubai Kagaku Kogyo Co. Ltd. Catalytic oxide composition for preparing methacrylic acid

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
JP特开2003-10691A 2003.01.14
JP特开2004-188231A 2004.07.08
JP特开2005-21727A 2005.01.27
JP特开平9-75740A 1997.03.25

Also Published As

Publication number Publication date
KR101208433B1 (ko) 2012-12-05
KR20070114362A (ko) 2007-12-03
CN101829589A (zh) 2010-09-15
WO2006104155A1 (ja) 2006-10-05
EP1867387A1 (en) 2007-12-19
EP1867387B1 (en) 2013-12-04
EP1867387A4 (en) 2009-09-02
CN101829589B (zh) 2013-08-21
JP4756890B2 (ja) 2011-08-24
CA2603005A1 (en) 2006-10-05
US8716523B2 (en) 2014-05-06
BRPI0608759A2 (pt) 2010-01-26
KR101223590B1 (ko) 2013-01-17
EP2204234A1 (en) 2010-07-07
KR20120043152A (ko) 2012-05-03
TW200642757A (en) 2006-12-16
CN101175568A (zh) 2008-05-07
US20090234158A1 (en) 2009-09-17
JP2006272151A (ja) 2006-10-12
TWI374056B (enExample) 2012-10-11
MY143359A (en) 2011-04-29

Similar Documents

Publication Publication Date Title
US8148291B2 (en) Method for manufacturing catalyst for use in production of methacrylic acid
CN100457264C (zh) 制备甲基丙烯酸用的催化剂及其制备方法
KR102422025B1 (ko) 불포화 알데히드 및/또는 불포화 카본산 제조용 촉매 및 그의 제조 방법 그리고 불포화 알데히드 및/또는 불포화 카본산의 제조 방법
CN103945938B (zh) 甲基丙烯酸制造用催化剂及使用该催化剂的甲基丙烯酸的制造方法
CN101175568B (zh) 用于制备甲基丙烯酸的催化剂及其制备方法
JP4421558B2 (ja) メタクリル酸製造用触媒の製造方法
JP6077533B2 (ja) メタクリル酸製造用触媒、その製造方法及び該触媒を用いるメタクリル酸の製造方法
CN105612141A (zh) 不饱和羧酸的制造方法和负载催化剂
CN107848920A (zh) 不饱和醛和/或不饱和羧酸的制造方法
KR102618400B1 (ko) 촉매 및 그의 제조 방법, 그리고 당해 촉매를 이용한 직결 2단 접촉 기상 산화 방법 및 그의 이용
JP2011152543A (ja) メタクリル酸製造用触媒の製造方法
CN104203883B (zh) 使用固定床多管式反应器的丙烯醛和丙烯酸的制备方法
JP2000024502A (ja) メタクリル酸製造用触媒およびその製造方法
JP5269046B2 (ja) メタクリル酸製造用触媒の製造方法
JP7468291B2 (ja) 不飽和アルデヒド及び不飽和カルボン酸合成用触媒の製造方法
KR20240116732A (ko) 촉매 및, 그것을 이용한 화합물의 제조 방법

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20110525

Termination date: 20170328