KR101094676B1 - 3 개 이상의 가교된 비스인데닐 메탈로센 성분들을포함하는 촉매 성분 - Google Patents

3 개 이상의 가교된 비스인데닐 메탈로센 성분들을포함하는 촉매 성분 Download PDF

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KR101094676B1
KR101094676B1 KR1020077007662A KR20077007662A KR101094676B1 KR 101094676 B1 KR101094676 B1 KR 101094676B1 KR 1020077007662 A KR1020077007662 A KR 1020077007662A KR 20077007662 A KR20077007662 A KR 20077007662A KR 101094676 B1 KR101094676 B1 KR 101094676B1
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South Korea
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indenyl
thi
molecular weight
tetrahydro
catalyst
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KR1020077007662A
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English (en)
Korean (ko)
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KR20070110249A (ko
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아바스 라자비
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토탈 페트로케미칼스 리서치 펠루이
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642Component covered by group C08F4/64 with an organo-aluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
KR1020077007662A 2004-10-25 2005-10-24 3 개 이상의 가교된 비스인데닐 메탈로센 성분들을포함하는 촉매 성분 KR101094676B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP04105287A EP1650233A1 (en) 2004-10-25 2004-10-25 Catalyst component comprising three or more bridged bisindenyl metallocene components
EP04105287.9 2004-10-25
PCT/EP2005/055474 WO2006045762A1 (en) 2004-10-25 2005-10-24 Catalyst component comprising three or more bridged bisindenyl metallocene components

Publications (2)

Publication Number Publication Date
KR20070110249A KR20070110249A (ko) 2007-11-16
KR101094676B1 true KR101094676B1 (ko) 2011-12-20

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Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020077007662A KR101094676B1 (ko) 2004-10-25 2005-10-24 3 개 이상의 가교된 비스인데닐 메탈로센 성분들을포함하는 촉매 성분

Country Status (10)

Country Link
US (1) US20120316298A1 (ja)
EP (2) EP1650233A1 (ja)
JP (1) JP2008518070A (ja)
KR (1) KR101094676B1 (ja)
CN (1) CN101044168A (ja)
AT (1) ATE498635T1 (ja)
DE (1) DE602005026420D1 (ja)
EA (1) EA017729B9 (ja)
ES (1) ES2358270T3 (ja)
WO (1) WO2006045762A1 (ja)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2539129B1 (en) * 2011-01-11 2014-03-19 Total Research & Technology Feluy Injection stretch blow moulded articles
KR101549206B1 (ko) 2012-05-08 2015-09-02 주식회사 엘지화학 안사-메탈로센 화합물 및 이를 이용한 담지 촉매의 제조방법
US9540465B2 (en) 2013-11-19 2017-01-10 Chevron Phillips Chemical Company Lp Boron-bridged metallocene catalyst systems and polymers produced therefrom
WO2015077100A2 (en) 2013-11-19 2015-05-28 Chevron Phillips Chemical Company Lp Boron-bridged bis-indenyl metallocene catalyst systems and polymers produced therefrom
US9217049B2 (en) * 2013-11-19 2015-12-22 Chevron Phillips Chemical Company Lp Dual catalyst systems for producing polymers with a broad molecular weight distribution and a uniform short chain branch distribution
CN105849138A (zh) 2013-11-19 2016-08-10 切弗朗菲利浦化学公司 含有具有烯基取代基的硼桥接的环戊二烯基-芴基茂金属化合物的催化剂系统
BR112018011411B1 (pt) 2015-12-21 2022-02-22 Dow Quimica Mexicana S.A. De C.V. Formulação de polietileno, artigo e método para fazer a formulação de polietileno

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0516018B1 (de) * 1991-05-27 1996-03-27 Hoechst Aktiengesellschaft Verfahren zur Herstellung von Polyolefinen mit breiter Molmassenverteilung
DE59204800D1 (de) * 1991-05-27 1996-02-08 Hoechst Ag Verfahren zur Herstellung von syndiotaktischen Polyolefinen mit breiter Molmassenverteilung
DE4333128A1 (de) * 1993-09-29 1995-03-30 Hoechst Ag Verfahren zur Herstellung von Polyolefinen
JP3537236B2 (ja) * 1994-10-13 2004-06-14 昭和電工株式会社 ポリオレフィン製造用触媒成分、該成分を含むポリオレフィン製造用触媒及びポリオレフィンの製造方法
US6265512B1 (en) * 1997-10-23 2001-07-24 3M Innovative Company Elastic polypropylenes and catalysts for their manufacture
EP0989141A1 (en) * 1998-09-25 2000-03-29 Fina Research S.A. Production of multimodal polyethelene
JP2001064314A (ja) * 1999-08-26 2001-03-13 Idemitsu Petrochem Co Ltd オレフィン重合触媒及びオレフィン重合体の製造方法

Also Published As

Publication number Publication date
EA200700680A1 (ru) 2007-10-26
ES2358270T3 (es) 2011-05-09
JP2008518070A (ja) 2008-05-29
US20120316298A1 (en) 2012-12-13
DE602005026420D1 (de) 2011-03-31
EA017729B9 (ru) 2013-05-30
EP1805224B1 (en) 2011-02-16
EP1805224A1 (en) 2007-07-11
EP1650233A1 (en) 2006-04-26
ATE498635T1 (de) 2011-03-15
KR20070110249A (ko) 2007-11-16
CN101044168A (zh) 2007-09-26
EA017729B1 (ru) 2013-02-28
WO2006045762A1 (en) 2006-05-04

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