KR101094676B1 - 3 개 이상의 가교된 비스인데닐 메탈로센 성분들을포함하는 촉매 성분 - Google Patents
3 개 이상의 가교된 비스인데닐 메탈로센 성분들을포함하는 촉매 성분 Download PDFInfo
- Publication number
- KR101094676B1 KR101094676B1 KR1020077007662A KR20077007662A KR101094676B1 KR 101094676 B1 KR101094676 B1 KR 101094676B1 KR 1020077007662 A KR1020077007662 A KR 1020077007662A KR 20077007662 A KR20077007662 A KR 20077007662A KR 101094676 B1 KR101094676 B1 KR 101094676B1
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- South Korea
- Prior art keywords
- indenyl
- thi
- molecular weight
- tetrahydro
- catalyst
- Prior art date
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP04105287A EP1650233A1 (en) | 2004-10-25 | 2004-10-25 | Catalyst component comprising three or more bridged bisindenyl metallocene components |
EP04105287.9 | 2004-10-25 | ||
PCT/EP2005/055474 WO2006045762A1 (en) | 2004-10-25 | 2005-10-24 | Catalyst component comprising three or more bridged bisindenyl metallocene components |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20070110249A KR20070110249A (ko) | 2007-11-16 |
KR101094676B1 true KR101094676B1 (ko) | 2011-12-20 |
Family
ID=34929763
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020077007662A KR101094676B1 (ko) | 2004-10-25 | 2005-10-24 | 3 개 이상의 가교된 비스인데닐 메탈로센 성분들을포함하는 촉매 성분 |
Country Status (10)
Country | Link |
---|---|
US (1) | US20120316298A1 (ja) |
EP (2) | EP1650233A1 (ja) |
JP (1) | JP2008518070A (ja) |
KR (1) | KR101094676B1 (ja) |
CN (1) | CN101044168A (ja) |
AT (1) | ATE498635T1 (ja) |
DE (1) | DE602005026420D1 (ja) |
EA (1) | EA017729B9 (ja) |
ES (1) | ES2358270T3 (ja) |
WO (1) | WO2006045762A1 (ja) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2539129B1 (en) * | 2011-01-11 | 2014-03-19 | Total Research & Technology Feluy | Injection stretch blow moulded articles |
KR101549206B1 (ko) | 2012-05-08 | 2015-09-02 | 주식회사 엘지화학 | 안사-메탈로센 화합물 및 이를 이용한 담지 촉매의 제조방법 |
US9540465B2 (en) | 2013-11-19 | 2017-01-10 | Chevron Phillips Chemical Company Lp | Boron-bridged metallocene catalyst systems and polymers produced therefrom |
WO2015077100A2 (en) | 2013-11-19 | 2015-05-28 | Chevron Phillips Chemical Company Lp | Boron-bridged bis-indenyl metallocene catalyst systems and polymers produced therefrom |
US9217049B2 (en) * | 2013-11-19 | 2015-12-22 | Chevron Phillips Chemical Company Lp | Dual catalyst systems for producing polymers with a broad molecular weight distribution and a uniform short chain branch distribution |
CN105849138A (zh) | 2013-11-19 | 2016-08-10 | 切弗朗菲利浦化学公司 | 含有具有烯基取代基的硼桥接的环戊二烯基-芴基茂金属化合物的催化剂系统 |
BR112018011411B1 (pt) | 2015-12-21 | 2022-02-22 | Dow Quimica Mexicana S.A. De C.V. | Formulação de polietileno, artigo e método para fazer a formulação de polietileno |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0516018B1 (de) * | 1991-05-27 | 1996-03-27 | Hoechst Aktiengesellschaft | Verfahren zur Herstellung von Polyolefinen mit breiter Molmassenverteilung |
DE59204800D1 (de) * | 1991-05-27 | 1996-02-08 | Hoechst Ag | Verfahren zur Herstellung von syndiotaktischen Polyolefinen mit breiter Molmassenverteilung |
DE4333128A1 (de) * | 1993-09-29 | 1995-03-30 | Hoechst Ag | Verfahren zur Herstellung von Polyolefinen |
JP3537236B2 (ja) * | 1994-10-13 | 2004-06-14 | 昭和電工株式会社 | ポリオレフィン製造用触媒成分、該成分を含むポリオレフィン製造用触媒及びポリオレフィンの製造方法 |
US6265512B1 (en) * | 1997-10-23 | 2001-07-24 | 3M Innovative Company | Elastic polypropylenes and catalysts for their manufacture |
EP0989141A1 (en) * | 1998-09-25 | 2000-03-29 | Fina Research S.A. | Production of multimodal polyethelene |
JP2001064314A (ja) * | 1999-08-26 | 2001-03-13 | Idemitsu Petrochem Co Ltd | オレフィン重合触媒及びオレフィン重合体の製造方法 |
-
2004
- 2004-10-25 EP EP04105287A patent/EP1650233A1/en not_active Withdrawn
-
2005
- 2005-10-24 CN CNA2005800356301A patent/CN101044168A/zh active Pending
- 2005-10-24 JP JP2007538394A patent/JP2008518070A/ja active Pending
- 2005-10-24 WO PCT/EP2005/055474 patent/WO2006045762A1/en active Application Filing
- 2005-10-24 AT AT05801739T patent/ATE498635T1/de active
- 2005-10-24 ES ES05801739T patent/ES2358270T3/es active Active
- 2005-10-24 DE DE602005026420T patent/DE602005026420D1/de active Active
- 2005-10-24 KR KR1020077007662A patent/KR101094676B1/ko not_active IP Right Cessation
- 2005-10-24 EA EA200700680A patent/EA017729B9/ru not_active IP Right Cessation
- 2005-10-24 EP EP05801739A patent/EP1805224B1/en not_active Not-in-force
-
2012
- 2012-05-21 US US13/476,648 patent/US20120316298A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
EA200700680A1 (ru) | 2007-10-26 |
ES2358270T3 (es) | 2011-05-09 |
JP2008518070A (ja) | 2008-05-29 |
US20120316298A1 (en) | 2012-12-13 |
DE602005026420D1 (de) | 2011-03-31 |
EA017729B9 (ru) | 2013-05-30 |
EP1805224B1 (en) | 2011-02-16 |
EP1805224A1 (en) | 2007-07-11 |
EP1650233A1 (en) | 2006-04-26 |
ATE498635T1 (de) | 2011-03-15 |
KR20070110249A (ko) | 2007-11-16 |
CN101044168A (zh) | 2007-09-26 |
EA017729B1 (ru) | 2013-02-28 |
WO2006045762A1 (en) | 2006-05-04 |
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