KR101057864B1 - 에폭시화 방법의 개시방법 및 올레핀 에폭시화 방법 - Google Patents
에폭시화 방법의 개시방법 및 올레핀 에폭시화 방법 Download PDFInfo
- Publication number
- KR101057864B1 KR101057864B1 KR1020047021329A KR20047021329A KR101057864B1 KR 101057864 B1 KR101057864 B1 KR 101057864B1 KR 1020047021329 A KR1020047021329 A KR 1020047021329A KR 20047021329 A KR20047021329 A KR 20047021329A KR 101057864 B1 KR101057864 B1 KR 101057864B1
- Authority
- KR
- South Korea
- Prior art keywords
- catalyst
- feed
- oxygen
- epoxidation
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Epoxy Compounds (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US39267902P | 2002-06-28 | 2002-06-28 | |
| US60/392,679 | 2002-06-28 | ||
| PCT/US2003/020095 WO2004002972A2 (en) | 2002-06-28 | 2003-06-24 | A method for the start-up of an epoxidation process and a process for the epoxidation of an olefin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20050087726A KR20050087726A (ko) | 2005-08-31 |
| KR101057864B1 true KR101057864B1 (ko) | 2011-08-19 |
Family
ID=30000918
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020047021329A Expired - Lifetime KR101057864B1 (ko) | 2002-06-28 | 2003-06-24 | 에폭시화 방법의 개시방법 및 올레핀 에폭시화 방법 |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US7102022B2 (https=) |
| EP (1) | EP1517901B1 (https=) |
| JP (1) | JP4578967B2 (https=) |
| KR (1) | KR101057864B1 (https=) |
| CN (1) | CN1665797B (https=) |
| AU (1) | AU2003247652A1 (https=) |
| BR (2) | BR0312010A (https=) |
| CA (1) | CA2494767C (https=) |
| DE (1) | DE60333292D1 (https=) |
| IN (1) | IN2004DE03899A (https=) |
| MX (1) | MX245604B (https=) |
| MY (1) | MY135031A (https=) |
| RU (1) | RU2005102097A (https=) |
| TW (1) | TWI283242B (https=) |
| WO (1) | WO2004002972A2 (https=) |
Families Citing this family (58)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2003243757A1 (en) * | 2002-06-28 | 2004-01-19 | Shell Oil Company | A method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
| DE60333292D1 (de) | 2002-06-28 | 2010-08-19 | Shell Int Research | Verfahren für den start eines epoxierungsprozesses und epoxidierungsverfahren für olefine |
| TWI346574B (en) | 2003-03-31 | 2011-08-11 | Shell Int Research | A catalyst composition, a process for preparing the catalyst composition and a use of the catalyst composition |
| US7348444B2 (en) | 2003-04-07 | 2008-03-25 | Shell Oil Company | Process for the production of an olefin oxide |
| US8148555B2 (en) | 2003-06-26 | 2012-04-03 | Shell Oil Company | Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
| WO2006028940A2 (en) * | 2004-09-01 | 2006-03-16 | Shell Internationale Research Maatschappij B.V. | An olefin epoxidation process, a catalyst for use in the process, a carrier for use in preparing the catalyst, and a process for preparing the carrier |
| US20070154377A1 (en) * | 2005-12-22 | 2007-07-05 | Rekers Dominicus M | Process for the removal of combustible volatile contaminant materials from a process stream |
| GB2433705A (en) * | 2005-12-22 | 2007-07-04 | Shell Int Research | A method of installing an epoxidation catalyst |
| US7459589B2 (en) * | 2005-12-22 | 2008-12-02 | Shell Oil Company | Process for the preparation of an alkylene glycol |
| US20070203350A1 (en) * | 2005-12-22 | 2007-08-30 | Bolk Jeroen W | Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process |
| US20070203348A1 (en) * | 2005-12-22 | 2007-08-30 | Bolk Jeroen W | Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process |
| US20070203349A1 (en) * | 2005-12-22 | 2007-08-30 | Bolk Jeroen W | Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process |
| US20070213545A1 (en) * | 2005-12-22 | 2007-09-13 | Bolk Jeroen W | Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process |
| US20070203352A1 (en) * | 2005-12-22 | 2007-08-30 | Bolk Jeroen W | Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process |
| US20070197801A1 (en) * | 2005-12-22 | 2007-08-23 | Bolk Jeroen W | Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitables for such a process |
| US7704908B2 (en) * | 2005-12-22 | 2010-04-27 | Shell Oil Company | Method for reusing rhenium from a donor spent epoxidation catalyst |
| US20070151451A1 (en) * | 2005-12-22 | 2007-07-05 | Rekers Dominicus M | Process for the cooling, concentration or purification of ethylene oxide |
| US20070197808A1 (en) * | 2005-12-22 | 2007-08-23 | Bolk Jeroen W | Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process |
| US8357812B2 (en) * | 2005-12-22 | 2013-01-22 | Shell Oil Company | Process for preparing a rejuvenated epoxidation catalyst |
| CA2641225A1 (en) * | 2006-02-03 | 2007-08-16 | Shell Internationale Research Maatschappij B.V. | A process for treating a catalyst, the catalyst, and use of the catalyst |
| US7553795B2 (en) | 2006-03-21 | 2009-06-30 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Activation of high selectivity ethylene oxide catalyst |
| US7977274B2 (en) * | 2006-09-29 | 2011-07-12 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Catalyst with bimodal pore size distribution and the use thereof |
| US20080154051A1 (en) * | 2006-12-20 | 2008-06-26 | Jeroen Willem Bolk | Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process |
| US20080154052A1 (en) * | 2006-12-20 | 2008-06-26 | Jeroen Willem Bolk | Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process |
| US20080254218A1 (en) * | 2007-04-16 | 2008-10-16 | Air Products And Chemicals, Inc. | Metal Precursor Solutions For Chemical Vapor Deposition |
| AR066469A1 (es) | 2007-05-09 | 2009-08-19 | Shell Int Research | Un proceso de produccion de oxido de olefina , 1,2- diol, 1,2- diol eter, 1,2- carbonato o alcanolamina |
| JP5542659B2 (ja) | 2007-05-09 | 2014-07-09 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | エポキシ化触媒、触媒を調製する方法、および酸化オレフィン、1,2−ジオール、1,2−ジオールエーテル、1,2−カーボネートまたはアルカノールアミンの製造方法 |
| RU2452564C2 (ru) * | 2007-05-11 | 2012-06-10 | Барри Дж. БИЛЛИГ | Активация высокоселективных катализаторов в установках синтеза оксидов олефинов |
| US7553980B2 (en) * | 2007-09-26 | 2009-06-30 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Process for initiating a highly selective ethylene oxide catalyst |
| KR101629037B1 (ko) | 2008-05-07 | 2016-06-09 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 에폭시화 방법의 스타트업 방법, 산화에틸렌, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산방법 |
| CA2723592C (en) | 2008-05-07 | 2016-08-16 | Shell Internationale Research Maatschappij B.V. | A process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
| CA2759397C (en) | 2009-04-21 | 2019-01-29 | Dow Technology Investments Llc | Improved method of achieving and maintaining a specified alkylene oxide production parameter with a high efficiency catalyst |
| CN102421766B (zh) | 2009-04-21 | 2015-03-25 | 陶氏技术投资有限公司 | 提高铼助催化的环氧化催化剂的效率的方法以及使用它们的环氧化方法 |
| JP2012524785A (ja) | 2009-04-21 | 2012-10-18 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | 高効率触媒を用いたアルキレンオキシド簡易製造方法 |
| EP2513077B1 (en) * | 2009-12-17 | 2014-06-11 | Scientific Design Company Inc. | Process for epoxidation start-up |
| CN102666515B (zh) * | 2009-12-23 | 2015-05-20 | 科学设计公司 | 高选择性氧化乙烯催化剂启动的方法 |
| US8845975B2 (en) | 2009-12-28 | 2014-09-30 | Dow Technology Investments Llc | Method of controlling the production of silver chloride on a silver catalyst in the production of alkylene oxides |
| TW201213013A (en) | 2010-05-17 | 2012-04-01 | Scient Design Co | Method for preparing an epoxidation catalyst |
| TW201208763A (en) | 2010-05-17 | 2012-03-01 | Scient Design Co | Method for making a highly selective ethylene oxide catalyst |
| US8546592B2 (en) | 2010-09-29 | 2013-10-01 | Shell Oil Company | Olefin epoxidation process |
| US8742147B2 (en) | 2010-12-08 | 2014-06-03 | Shell Oil Company | Process for improving the selectivity of an EO catalyst |
| US8742146B2 (en) * | 2010-12-08 | 2014-06-03 | Shell Oil Company | Process for improving the selectivity of an EO catalyst |
| SG190901A1 (en) | 2010-12-15 | 2013-07-31 | Dow Technology Investments Llc | Method of starting-up a process of producing an alkylene oxide using a high-efficiency catalyst |
| WO2012141942A1 (en) * | 2011-04-11 | 2012-10-18 | Dow Technology Investments Llc | Process for conditioning a high efficiency ethylene oxide catalyst |
| BR112013027585B1 (pt) * | 2011-04-29 | 2020-09-29 | Shell Internationale Research Maatschappij B.V | Método para melhorar a seletividade de um catalisador de alta seletividade suportado usado na epoxidação de etileno e método para preparar um 1,2-diol, um 1,2-diol éter, um 1,2-carbonato ou uma alcanolamina |
| IN2014DN03028A (https=) * | 2011-10-18 | 2015-05-08 | AHMADI Hassan Eisa AL | |
| CA2858551C (en) | 2011-12-09 | 2021-10-26 | Dow Technology Investments Llc | Method of maintaining the value of an alkylene oxide production parameter in a process of making an alkylene oxide using a high efficiency catalyst |
| CN104884167B (zh) * | 2012-12-31 | 2017-07-07 | 科学设计公司 | 用于生产改善的环氧乙烷催化剂的煅烧方法 |
| KR102155068B1 (ko) * | 2012-12-31 | 2020-09-11 | 사이언티픽 디자인 컴파니 인코포레이티드 | 고 선택성 산화에틸렌 촉매를 위한 스타트-업 공정 |
| KR102155073B1 (ko) | 2013-01-11 | 2020-09-11 | 사이언티픽 디자인 컴파니 인코포레이티드 | 후-컨디셔닝 단계를 이용하는 에폭시화 공정 |
| EP3087061B1 (en) | 2013-12-23 | 2018-04-11 | Scientific Design Company Inc. | Epoxidation process |
| CN105618036B (zh) * | 2014-11-03 | 2018-10-16 | 中国石油化工股份有限公司 | 银催化剂的制备方法、银催化剂以及生产环氧乙烷的方法 |
| CN105618046B (zh) * | 2014-11-03 | 2018-10-16 | 中国石油化工股份有限公司 | 银催化剂的制备方法、银催化剂以及生产环氧乙烷的方法 |
| EP3302794A4 (en) | 2015-06-02 | 2019-06-26 | Scientific Design Company, Inc. | epoxidation |
| US11801493B2 (en) | 2016-12-02 | 2023-10-31 | Shell Usa, Inc. | Methods for conditioning an ethylene epoxidation catalyst and associated methods for the production of ethylene oxide |
| US10449520B2 (en) | 2017-05-15 | 2019-10-22 | Scientific Design Company, Inc. | Porous bodies with enhanced crush strength |
| US11439986B2 (en) | 2017-12-13 | 2022-09-13 | Scientific Design Company, Inc. | Silver impregnation solution containing high-boiling oxygenated additive and its use in ethylene oxide catalyst preparation |
| US11931725B2 (en) | 2022-07-19 | 2024-03-19 | Scientific Design Company, Inc. | Ethylene oxide high selectivity catalyst conditioning process |
Family Cites Families (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2219575A (en) | 1939-06-16 | 1940-10-29 | Carbide & Carbon Chem Corp | Catalyst and process for making olefin oxides |
| GB1170663A (en) * | 1967-03-22 | 1969-11-12 | Shell Int Research | Process for preparing Silver Catalysts |
| GB1191983A (en) | 1968-04-11 | 1970-05-13 | Sir Soc Italiana Resine Spa | Preparation of Ethylene Oxide |
| GB1491447A (en) | 1973-12-05 | 1977-11-09 | Ici Ltd | Alkylene oxide production and catalysts therefor |
| GB1489335A (en) | 1973-10-26 | 1977-10-19 | Shell Int Research | Catalyst for the production of ethylene oxide |
| EP0003642B1 (en) | 1978-02-10 | 1984-07-18 | Imperial Chemical Industries Plc | Production of olefine oxides |
| JPS57107240A (en) | 1980-12-26 | 1982-07-03 | Nippon Shokubai Kagaku Kogyo Co Ltd | Production of silver catalyst for producing ethylene oxide |
| US4845296A (en) | 1983-12-13 | 1989-07-04 | Union Carbide Corporation | Process for preparing alkanolamines |
| GB8423044D0 (en) | 1984-09-12 | 1984-10-17 | Ici Plc | Production of ethylene oxide |
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| AU656537B2 (en) | 1990-10-12 | 1995-02-09 | Union Carbide Chemicals & Plastics Technology Corporation | Alkylene oxide catalysts having enhanced activity and/or stability |
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| CA2089510C (en) | 1992-02-27 | 1998-09-01 | Shinichi Nagase | Silver catalyst for production of ethylene oxide and method for production of the catalyst |
| CA2078480A1 (en) | 1992-04-20 | 1993-10-21 | Bennie Albert Horrell Jr. | Improved process for ethylene epoxidation |
| US5407888A (en) | 1992-05-12 | 1995-04-18 | Basf Aktiengesellschaft | Silver catalyst |
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| EP0716884B2 (en) | 1994-12-15 | 2009-09-23 | Shell Internationale Researchmaatschappij B.V. | Process for preparing ethylene oxide catalysts |
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| US5780656A (en) | 1997-04-14 | 1998-07-14 | Scientific Design Company, Inc. | Ethylene oxide catalyst and process |
| US5770746A (en) * | 1997-06-23 | 1998-06-23 | Arco Chemical Technology, L.P. | Epoxidation process using supported silver catalysts pretreated with organic chloride |
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| DE19803890A1 (de) | 1998-01-31 | 1999-08-05 | Erdoelchemie Gmbh | Silberhaltige Trägerkatalysatoren und Katalysator-Zwischenprodukte, Verfahren zu ihrer Herstellung und ihre Verwendung |
| US6455713B1 (en) | 1998-09-14 | 2002-09-24 | Eastman Chemical Company | Reactivation of Cs-promoted, Ag catalysts for the selective epoxidation of butadiene to 3,4-epoxy-1-butene |
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| RU2278730C2 (ru) | 2000-05-01 | 2006-06-27 | Сайентифик Дизайн Компани, Инк. | Катализатор для окисления этилена и способ получения оксида этилена |
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| DE60333292D1 (de) | 2002-06-28 | 2010-08-19 | Shell Int Research | Verfahren für den start eines epoxierungsprozesses und epoxidierungsverfahren für olefine |
| US7348444B2 (en) | 2003-04-07 | 2008-03-25 | Shell Oil Company | Process for the production of an olefin oxide |
-
2003
- 2003-06-24 DE DE60333292T patent/DE60333292D1/de not_active Expired - Lifetime
- 2003-06-24 BR BR0312010-4A patent/BR0312010A/pt active IP Right Grant
- 2003-06-24 EP EP03762055A patent/EP1517901B1/en not_active Revoked
- 2003-06-24 CA CA2494767A patent/CA2494767C/en not_active Expired - Lifetime
- 2003-06-24 KR KR1020047021329A patent/KR101057864B1/ko not_active Expired - Lifetime
- 2003-06-24 CN CN038153157A patent/CN1665797B/zh not_active Expired - Lifetime
- 2003-06-24 MX MXPA04012743 patent/MX245604B/es active IP Right Grant
- 2003-06-24 WO PCT/US2003/020095 patent/WO2004002972A2/en not_active Ceased
- 2003-06-24 RU RU2005102097/04A patent/RU2005102097A/ru not_active Application Discontinuation
- 2003-06-24 AU AU2003247652A patent/AU2003247652A1/en not_active Abandoned
- 2003-06-24 BR BRPI0312010-4A patent/BRPI0312010B1/pt not_active IP Right Cessation
- 2003-06-24 JP JP2004517843A patent/JP4578967B2/ja not_active Expired - Lifetime
- 2003-06-26 TW TW092117442A patent/TWI283242B/zh not_active IP Right Cessation
- 2003-06-26 MY MYPI20032404A patent/MY135031A/en unknown
- 2003-06-26 US US10/607,346 patent/US7102022B2/en not_active Expired - Lifetime
-
2004
- 2004-12-08 IN IN3899DE2004 patent/IN2004DE03899A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN1665797A (zh) | 2005-09-07 |
| TWI283242B (en) | 2007-07-01 |
| BR0312010A (pt) | 2005-03-22 |
| CA2494767A1 (en) | 2004-01-08 |
| MY135031A (en) | 2008-01-31 |
| MXPA04012743A (es) | 2005-08-15 |
| KR20050087726A (ko) | 2005-08-31 |
| US7102022B2 (en) | 2006-09-05 |
| WO2004002972A3 (en) | 2004-06-10 |
| BRPI0312010B1 (pt) | 2017-11-28 |
| DE60333292D1 (de) | 2010-08-19 |
| MX245604B (es) | 2007-05-04 |
| IN2004DE03899A (en) | 2009-11-20 |
| CN1665797B (zh) | 2011-09-14 |
| EP1517901B1 (en) | 2010-07-07 |
| JP4578967B2 (ja) | 2010-11-10 |
| US20040110971A1 (en) | 2004-06-10 |
| EP1517901A2 (en) | 2005-03-30 |
| JP2006504642A (ja) | 2006-02-09 |
| WO2004002972A2 (en) | 2004-01-08 |
| AU2003247652A1 (en) | 2004-01-19 |
| RU2005102097A (ru) | 2005-08-27 |
| CA2494767C (en) | 2012-07-17 |
| TW200415144A (en) | 2004-08-16 |
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