KR100934127B1 - Manufacturing method of fertilizer using oystershells - Google Patents

Manufacturing method of fertilizer using oystershells Download PDF

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KR100934127B1
KR100934127B1 KR1020090071493A KR20090071493A KR100934127B1 KR 100934127 B1 KR100934127 B1 KR 100934127B1 KR 1020090071493 A KR1020090071493 A KR 1020090071493A KR 20090071493 A KR20090071493 A KR 20090071493A KR 100934127 B1 KR100934127 B1 KR 100934127B1
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oyster shell
fertilizer
fermentation
oyster
organic
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KR1020090071493A
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Korean (ko)
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김봉규
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김봉규
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D3/00Calcareous fertilisers
    • C05D3/02Calcareous fertilisers from limestone, calcium carbonate, calcium hydrate, slaked lime, calcium oxide, waste calcium products
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F11/00Other organic fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G1/00Mixtures of fertilisers belonging individually to different subclasses of C05

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Processing Of Solid Wastes (AREA)
  • Fertilizers (AREA)

Abstract

PURPOSE: A method for manufacturing a fertilizer by using an oyster shell, and the fertilizer prepared by the method are provided to obtain a fertilizer useful as a soil conditioner neutralizing the acidified soil. CONSTITUTION: A method for manufacturing a fertilizer by using an oyster shell comprises the steps of washing an oyster shell, heating it at a drying furnace to remove salt, and pulverizing it to prepare an oyster shell powder; pulverizing an organic material comprising sawdust, rice hulls, and the plant and tree pulverized material, adjusting the water content to be 50~60% at a fermentation tank, injecting a fermentation facilitating agent, and fermenting it with stirring; mixing the oyster shell powder and the organic fermented product; kneading the mixture; granulating the kneaded one; and drying it with hot wind until the final water content becomes 5~10%.

Description

굴 패각을 이용한 비료 및 그 제조방법 {Manufacturing method of fertilizer using oystershells}Fertilizer using oyster shell and manufacturing method {Manufacturing method of fertilizer using oystershells}

본 발명은 굴 패각을 주원료로 하고 여기에 유기 발효물을 혼합하여 비료를 제조함으로써 식물생장 및 토지개량제로서 양질의 비료가 될 수 있도록 한 굴 패각을 이용한 비료 및 그 제조방법에 관한 것이다.The present invention relates to a fertilizer using a oyster shell and a method for producing the same as oyster shell as a main raw material and by mixing the organic fermented product to produce a fertilizer to be a good fertilizer as a plant growth and land improver.

일반적으로 우리나라의 남해안 등지에서 많이 생산되어 폐기되는 막대한 량의 굴 패각(껍질)은 일부 극소량만 재활용되고 나머지 대부분은 해양에 투기하거나 육지에 매립을 하였으므로 침출수가 주위를 오염시켜 환경공해를 유발하는 등의 문제점이 있다.In general, the vast amount of oyster shells (shells) produced and disposed of in the south coast of Korea is recycled only a small amount, and most of them are dumped in the ocean or landfilled, causing leachate to pollute the environment. There is a problem.

즉, 굴을 생산하면서 부산물인 굴 패각의 처리에 대한 대책에 어려움이 있는바, 이는 굴 패각은 연간 수십만 톤에 이르고 있으나 폐자재 활용은 극히 저조한 실정이므로 수십만 톤의 굴 패각은 폐기물로 전락하여 각종 환경 오염과 바다를 황폐화시키고 있을 뿐만 아니라 굴 패각이 각처에 적재 방치되어 악취만 풍기며 파리, 모기가 서식하는 장소로 제공되어 위생적으로 좋지 않은 영향을 미치고 있는바, 이를 감안하여 굴 패각을 활용하는 방안으로 굴 패각을 건조하고 이를 분쇄하여 분말화시킨 것을 비료로 사용할 수 있도록 하고 있으나, 염분이 포함되어 있을 뿐만 아니라 경작지에 비료 시비시의 비산이나 빗물에 의한 비료의 유실 등이 발생하였고 이를 감안하여 과립형으로 성형하더라도 굴 패각으로만 만들어진 과립형 굴 패각은 분해효율이 좋지 않아서 식물생장이나 토지개량의 효과가 크게 떨어지므로 굴 패각을 이용한 비료가 활성화되지 못하였다.In other words, while producing oysters, there are difficulties in dealing with the treatment of oyster shells, which are by-products. The oyster shells reach hundreds of thousands of tons per year, but the use of waste materials is extremely low. In addition to devastating environmental pollution and the sea, oyster shells are placed in various places, leaving only odors and serving as places where flies and mosquitoes live. The oyster shells were dried and pulverized to be used as fertilizers, but not only salts were contained, but fertilizer fertilizers were scattered on the arable land or fertilizers were lost due to rainwater. Granular oyster shells made only of oyster shells have good decomposition efficiency even when molded into molds. Since the effects of plant growth and land improvement were greatly reduced, fertilizers using oyster shells were not activated.

본 발명은 이러한 문제점을 해결하기 위하여 안출한 것으로, 굴 패각에서 염분을 제거하고 이를 분말화한 굴 패각 분말과, 톱밥, 왕겨, 초목분쇄물로 이루어진 유기 발효물과, 상기 굴 패각 분말과 유기 발효물을 혼합하여 과립상태로 성형하여서 된 굴 패각을 이용한 비료에 의해 식물생장 및 토지개량제로서 우수한 양질의 비료를 제공하면서 비료 시비시의 비산이나 빗물에 의한 유실을 방지하면서 비료의 분해효율성을 높일 수 있도록 한 것을 목적으로 한다.The present invention has been made to solve the above problems, the oyster shell powder and the oyster shell powder, which is removed from the oyster shell and powdered it, the organic fermentation consisting of sawdust, rice husk, vegetation grinding, the oyster shell powder and organic fermentation Fertilizers using oyster shells formed by mixing water and granulated to provide excellent quality fertilizers as plant growth and land improvers, while preventing fertilizer fertilization and loss due to rainwater, while improving fertilizer decomposition efficiency. The purpose is to make it.

본 발명은 수거된 굴 패각을 세척하는 세척단계와, 상기 세척된 굴 패각을 건조로에서 가열하여 염분을 수분증발시키는 수단으로 염분을 제거하는 단계와, 상기 염분이 제거된 상태에서 분쇄기를 통해 분말하는 분말화단계로 이루어진 굴 패각 분말 제조공정과; 톱밥, 왕겨, 초목분쇄물로 이루어진 유기물을 분쇄하는 단계와, 상기 유기물을 발효조에 투입하여 수분함량 50~60%의 조건으로 조성한 다음 발효촉진제를 주입하여 골고루 교반하고 발효시키는 단계로 이루어진 유기물의 발효공정과; 상기 공정의 굴 패각 분말에 유기 발효물을 혼합한 혼합물을 조성하는 혼합공정과; 상기 공정의 혼합물을 반죽물로 만드는 반죽공정과; 공정의 반죽물을 과립기에서 과립상태로 성형하는 공정과; 상기 공정의 과립형 성형물을 열풍으로 건조시켜 최종 수분함량 5~10%가 되도록 하는 열풍공정을 포함하여서 된 패각을 이용한 비료 및 그 제조방법을 특징으로 한다.The present invention provides a washing step of washing the collected oyster shells, removing the salts by means of heating the washed oyster shells in a drying furnace to evaporate the salts, and powdering through the grinder in the state where the salts are removed. Oyster shell powder manufacturing process consisting of a powdering step; Organic matter consisting of crushing the organic material consisting of sawdust, rice husk, vegetation grinding, and putting the organic material in the fermentation tank conditions of 50 to 60% of water content, and then stirring and fermenting evenly by injecting a fermentation accelerator. Process; A mixing step of forming a mixture of organic fermented products in the oyster shell powder of the step; A kneading step of making the mixture of the steps into kneaded water; Molding the dough of the step into a granular state in a granulator; It characterized in that the fertilizer using a shell and a method for producing the same, including a hot air step to dry the granular molded product of the process to hot air to the final moisture content of 5 to 10%.

본 발명의 굴 패각을 이용한 비료는 염분이 제거된 굴 패각 분말과 톱밥, 왕겨, 초목분쇄물로 이루어진 유기물을 발효시킨 유기 발효물을 혼합하여 과립형으로 성형하여서 된 비료에 의해 식물생장 및 산성화된 토양을 중화시키는 토지개량제로서 우수한 비료를 제공하면서 비료 시비시의 비산이나 빗물에 의한 유실을 방지하면서 다공질에 의해 비료의 분해효율성을 높일 수 있게 되어 식물이 영양공급이 충분히 이루어지도록 하는 양질의 비료를 얻을 수 있는 효과가 있다.Fertilizer using the oyster shell of the present invention is a plant-grown and acidified by the fertilizer obtained by mixing the salt-free oyster shell powder and the organic fermentation products fermented organic material consisting of sawdust, rice husk, vegetation grinds to form a granule As a land improver to neutralize the soil, it provides excellent fertilizer and prevents fertilizer fertilizer from scattering or rainwater loss, and improves the decomposition efficiency of fertilizer by the porous material. There is an effect that can be obtained.

이하 본 발명의 상세히 설명하면 다음과 같다. 그리고 본 발명을 설명함에 있어서 관련된 공지기능에 대한 구체적인 설명이 본 발명의 요지를 불필요하게 흐릴 수 있다고 판단되는 경우 그 상세한 설명을 생략한다.Hereinafter, the present invention will be described in detail. In the following description of the present invention, if it is determined that the detailed description of the related well-known function may unnecessarily obscure the gist of the present invention, the detailed description thereof will be omitted.

본 발명은 굴 패각 분말 80~90중량%에 유기 발효물 10~20중량%를 혼합한 혼합물로 이루어진 비료를 제공한다.
상기 굴 패각 분말을 80~90중량%로 하는 이유는, 상기 혼합물에 혼합되는 굴 패각 분말이 80중량% 이하가 되면 유기물이 과다하게 함유되면서 굴 패각에 의한 식물생장 및 토지개량제로서의 효과가 떨어지고, 굴 패각 분말이 90중량% 이상으로 혼합되는 경우에는 굴 패각 분말과 유기 발효물이 결합되어 과립형으로 성형되는 비료의 분해효율성이 떨어지기 때문이다.
The present invention provides a fertilizer consisting of a mixture of 80 to 90% by weight of oyster shell powder 10 to 20% by weight of organic fermentation.
The reason why the oyster shell powder is 80 to 90% by weight is that when the oyster shell powder mixed in the mixture is 80% by weight or less, the organic matter is excessively contained and the effect as plant growth and land improving agent due to the oyster shell is reduced. This is because when the oyster shell powder is mixed at 90 wt% or more, the decomposition efficiency of the fertilizer formed into granules by combining the oyster shell powder and the organic fermented product is inferior.

더욱 상세하게는 굴 패각을 세척 및 가열하여 염분을 제거하고 이를 분말화한 굴 패각 분말과, 톱밥, 왕겨, 초목분쇄물로 이루어진 유기물을 분쇄 및 발효시켜서 된 유기 발효물과, 상기 굴 패각 분말과 유기 발효물을 혼합 및 반죽하고 이를 과립상태로 성형 및 열풍건조시켜서 된 것이다.More specifically, the oyster shell powder is washed and heated to remove salt and powdered oyster shell powder, the organic fermentation product obtained by grinding and fermenting the organic material consisting of sawdust, rice husk, vegetation grinding, and the oyster shell powder and It is made by mixing and kneading the organic fermented product, forming it into granules and drying with hot air.

본 발명은 다음과 같은 공정에 의해 굴 패각을 이용한 비료가 제조된다.In the present invention, a fertilizer using an oyster shell is manufactured by the following process.

A) 수거된 굴 패각을 세척하는 세척단계와, 상기 세척된 굴 패각을 건조로에서 굴 패각에 잔류된 염분을 제거할 수 있는 500~600℃의 온도로 10~20분간 가열하여 염분을 수분증발시키는 수단으로 염분을 제거하는 단계와, 상기 염분이 제거된 상태에서 분쇄기를 통해 분말하는 분말화단계로 이루어진 굴 패각 분말 제조공정과; A) a washing step of washing the collected oyster shells and heating the washed oyster shells at a temperature of 500 to 600 ° C. to remove salts remaining on the oyster shells in a drying furnace for 10 to 20 minutes to evaporate the salts. Oyster shell powder manufacturing process comprising the steps of removing the salt by means and a powdering step of powdering through a grinder in the state where the salt is removed;

B) 톱밥, 왕겨, 초목분쇄물로 이루어진 유기물은 분해가 용이하도록 200메시 미만으로 분쇄하는 단계와, 상기 유기물을 발효조에 투입하여 발효를 활성화시킬 수 있는 수분함량 50~60%의 조건으로 조성한 다음 통상의 발효 미생물이 파종(播種)된 발효촉진제를 주입하여 골고루 교반하고 3~5일간 발효시키는 단계로 이루어진 유기물의 발효공정과;B) the organic material consisting of sawdust, rice hulls, vegetation pulverization is pulverized to less than 200 mesh to facilitate decomposition, and the organic material is put into a fermenter to form a condition of 50 to 60% moisture content to activate fermentation Fermentation process of the organic material consisting of the step of injecting a fermentation promoter seeded with conventional fermentation microorganisms, stirring evenly and fermentation for 3-5 days;

C) 상기 A) B)공정의 굴 패각 분말 80~90 중량%에 유기 발효물 10~20 중량%를 혼합한 혼합물로 조성하는 혼합공정과;C) a mixing step of forming a mixture of 10 to 20% by weight of the organic fermented product to 80 to 90% by weight of the oyster shell powder of step A) B);

D) 상기 C) 공정의 혼합물을 반죽물로 만드는 반죽공정과;D) a kneading step of making the mixture of the step C) into a dough;

E) 상기 D) 공정의 반죽물을 과립기에서 과립상태로 성형하는 공정과;E) the step of molding the dough of the step D) in a granulator state in a granulator;

F) 상기 E) 공정의 과립형 성형물을 열풍으로 건조시켜 최종 수분함량 5~10%가 되도록 하는 열풍공정을 포함하여서 된 것을 특징으로 한다.F) characterized in that it comprises a hot air step of drying the granular molded product of the step E) with hot air to have a final moisture content of 5 to 10%.

상기 굴 패각은 2~3회 세척하여 이물질을 제거한 다음 이를 건조로에서 500~600℃의 온도로 10~20분간 가열하여 염분을 수분증발시키는 수단으로 굴 패각에 잔류 된 염분을 완전 제거하여 토양작물이 염해로 인한 피해가 발생되지 않도록 한 다음 미세 입자로 된 굴 패각 분말을 만든다.The oyster shell is washed two or three times to remove foreign substances, and then heated in a drying furnace at a temperature of 500-600 ° C. for 10-20 minutes to completely evaporate salinity, thereby completely removing the salinity remaining in the oyster shell. Make sure that no salt damage is incurred, then make fine oyster shell powder.

상기 톱밥, 왕겨, 초목분쇄물로 이루어진 유기물은 토양에서 분해가 용이하도록 200메시 미만으로 분쇄함이 바람직하며 이러한 유기 분쇄물을 발효조에 투입하여 발효가 용이한 수분함량 50~60%의 조건으로 조성한 다음 통상의 발효 미생물이 파종된 발효촉진제를 주입하여 골고루 교반하고 3~5일간 발효시키는 단계로 유기물을 발효시킴으로써 토양의 유기물 함량을 높여 주고 토양에서 용이하게 분해되어 식물에 영양공급이 충분히 이루어지도록 한다.The organic material consisting of the sawdust, chaff, vegetation crushed powder is preferably pulverized to less than 200 mesh to facilitate decomposition in the soil, and put the organic pulverized powder in the fermentation tank conditions for easy moisture fermentation 50 ~ 60% Next, fermentation of organic fermentation promoter seeded with conventional fermentation microorganisms is evenly stirred and fermented organically in a step of fermentation for 3 to 5 days to increase organic matter content of soil and easily decompose in soil so that nutrients are supplied to plants. .

상기 과립형으로 성형 된 비료는 비료 시비시의 비산이나 빗물에 의한 유실을 방지하면서 혼합물에 포함된 유기 발효물에 의해 형성되는 다수의 공극에 의해 수분침투가 용이하여 분해효율성을 높여주게 된다.The fertilizer molded into the granular form is easy to penetrate the water by a plurality of pores formed by the organic fermentation product contained in the mixture while preventing the loss of fertilizer fertilizer scattering or rain water to improve the decomposition efficiency.

이하 본 발명의 굴 패각을 이용한 비료의 제조방법에 따른 바람직한 실시 예를 상세히 설명하면 다음과 같다.Hereinafter, a preferred embodiment according to the manufacturing method of the fertilizer using the oyster shell of the present invention will be described in detail.

가) 굴 A) oysters 패각Shell 분말 제조공정 Powder manufacturing process

수거된 상태의 굴 패각을 세척수에 의해 2~3회 세척한 다음 상기 세척된 굴 패각을 건조로에 투입하여 건조로에서 600℃의 온도로 20분간 가열하는 수단으로 굴 패각에 잔류 된 염분이 수분과 함께 증발하도록 하여 염분을 제거하고 이렇게 염분이 제거된 굴 패각을 분쇄기를 통해 미세한 분말상태로 만든다.The collected oyster shells are washed two to three times with washing water, and then the washed oyster shells are put into a drying furnace and heated in a drying furnace at a temperature of 600 ° C. for 20 minutes, and the salt remaining in the oyster shells together with the water. The salt is removed by evaporation, and the salted oyster shell is made into a fine powder through a grinder.

나) 유기물의 발효공정B) Fermentation process of organic matter

초목분쇄물로 된 유기 발효물을 150메시로 분쇄한 다음 이를 발효조에 투입하여 수분함량 60%의 조건으로 조성한 상태에서 통상의 발효 미생물이 파종된 발효촉진제를 주입하여 골고루 교반하고 5일간 발효시켜 초목분쇄물을 완전 분해시킨다. After grinding the organic fermentation product of the vegetation powder into 150 mesh and putting it into the fermenter, the composition is made under the condition of 60% water content. Completely break up the mill.

다) 혼합물 조성공정C) Mixture composition process

상기 공정의 주원료인 굴 패각 분말 80중량%에 상기 공정의 유기 발효물 20 중량%를 혼합한 혼합물질로 조성한다.80% by weight of the oyster shell powder, which is the main raw material of the process, is mixed in a mixture of 20% by weight of the organic fermented product of the process.

라) 반죽,성형,건조공정D) Dough, forming and drying process

상기 공정을 거쳐 이루어진 혼합물을 반죽한 반죽물을 과립기에 투입하여 과립성형하고 이를 열풍건조기에서 100℃의 열풍으로 건조시켜 최종 수분함량 10%가 되는 과립형 비료를 얻게 되었다.The dough kneaded the mixture made through the above process was put into a granulator to granulate and dried in a hot air dryer at 100 ° C. to obtain a granular fertilizer having a final moisture content of 10%.

이상에서 본 발명은 상기 실시 예를 참고하여 설명하였지만 본 발명의 기술 사상범위 내에서 다양한 변형실시가 가능함은 물론이다.Although the present invention has been described with reference to the above embodiment, various modifications are possible within the technical scope of the present invention.

Claims (3)

A) 수거된 굴 패각을 세척하는 세척단계와, 상기 세척된 굴 패각을 건조로에서 가열하여 염분을 수분증발시키는 수단으로 염분을 제거하는 단계와, 상기 염분이 제거된 상태에서 분쇄기를 통해 분말하는 분말화단계로 이루어진 굴 패각 분말 제조공정과; A) a washing step of washing the collected oyster shells, removing the salts by means of heating the washed oyster shells in a drying furnace to evaporate the salts, and the powder powdered through the grinder in the state where the salts are removed. Oyster shell powder manufacturing process consisting of a step; B) 톱밥, 왕겨, 초목분쇄물로 이루어진 유기물을 분쇄하는 단계와, 상기 유기물을 발효조에 투입하여 수분함량 50~60%의 조건으로 조성한 다음 발효 미생물이 파종된 발효촉진제를 주입하여 골고루 교반하고 발효시키는 단계로 이루어진 유기물의 발효공정과;B) pulverizing the organic material consisting of sawdust, rice husk, vegetation grinding, and putting the organic material in the fermentation tank to the composition of water content of 50 ~ 60% and injecting the fermentation promoter seeded with fermentation microorganisms and stir evenly and fermentation Fermentation process of the organic material consisting of; C) 상기 A) B)공정의 굴 패각 분말에 유기 발효물을 혼합한 혼합물을 조성하는 혼합공정과;C) a mixing step of forming a mixture of the organic fermented product in the oyster shell powder of step A) B); D) 상기 C) 공정의 혼합물을 반죽물로 만드는 반죽공정과;D) a kneading step of making the mixture of the step C) into a dough; E) 상기 D) 공정의 반죽물을 과립기에서 과립상태로 성형하는 공정과;E) the step of molding the dough of the step D) in a granulator state in a granulator; F) 상기 E) 공정의 과립형 성형물을 열풍으로 건조시켜 최종 수분함량 5~10%가 되도록 하는 열풍공정을 포함하여서 된 것을 특징으로 하는 굴 패각을 이용한 비료제조방법.F) Fertilizer manufacturing method using the oyster shell, characterized in that it comprises a hot air step of drying the granular molded product of the above step E) to hot water 5-10%. 제 1항에 있어서,The method of claim 1, 상기 C) 공정의 혼합물은 굴 패각 분말 80~90 중량%에 유기 발효물 10~20 중량%로 혼합된 것을 특징으로 하는 굴 패각을 이용한 비료제조방법.The mixture of the step C) is a fertilizer manufacturing method using the oyster shell, characterized in that the mixture of oyster shell powder 80 to 90% by weight of the organic fermentation 10 to 20% by weight. 상기 제 1항의 방법에 의하여 제조된 굴 패각을 이용한 비료.Fertilizer using an oyster shell prepared by the method of claim 1.
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KR102253152B1 (en) * 2021-03-10 2021-05-18 (주)씨엘지오텍 mortar composition using oyster shell and manufacturing of it, pile construction method using oyster shell
CN113174266A (en) * 2021-04-20 2021-07-27 集美大学 Oyster shell soil conditioner and low-carbon green production method and application thereof
CN113402328A (en) * 2021-07-28 2021-09-17 烟台凯多海洋生物研究院有限公司 Nutritional soil water-retaining composition, and preparation method and application thereof
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KR101011594B1 (en) 2010-08-24 2011-01-27 김형식 The casting production method using the r.d.f. and the earthworm breeding apparatus
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KR20200058991A (en) 2018-11-20 2020-05-28 한국신발피혁연구원 Eco-friendly foam composition with shell powder
KR20200119033A (en) * 2019-04-09 2020-10-19 이중근 manufacturing method of paint additive using natural pozzolan
KR102282501B1 (en) 2019-04-09 2021-07-28 이중근 manufacturing method of paint additive using natural pozzolan
KR102202243B1 (en) * 2020-09-02 2021-01-12 윤해용 Method for recycling of oyster-shells using effective microorganism
KR102253153B1 (en) * 2021-03-10 2021-05-18 (주)씨엘지오텍 mortar composition using oyster shell and manufacturing of it, compaction grouting method using oyster shell
KR102253152B1 (en) * 2021-03-10 2021-05-18 (주)씨엘지오텍 mortar composition using oyster shell and manufacturing of it, pile construction method using oyster shell
CN113174266A (en) * 2021-04-20 2021-07-27 集美大学 Oyster shell soil conditioner and low-carbon green production method and application thereof
CN113402328A (en) * 2021-07-28 2021-09-17 烟台凯多海洋生物研究院有限公司 Nutritional soil water-retaining composition, and preparation method and application thereof
KR20230075207A (en) 2021-11-22 2023-05-31 한국신발피혁연구원 Eco friendly bio epdm foam composition

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