KR100895777B1 - 중합체 전해질 막 - Google Patents

중합체 전해질 막 Download PDF

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Publication number
KR100895777B1
KR100895777B1 KR1020037013786A KR20037013786A KR100895777B1 KR 100895777 B1 KR100895777 B1 KR 100895777B1 KR 1020037013786 A KR1020037013786 A KR 1020037013786A KR 20037013786 A KR20037013786 A KR 20037013786A KR 100895777 B1 KR100895777 B1 KR 100895777B1
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South Korea
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block
functional group
polymer electrolyte
hydrophobic
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Expired - Fee Related
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KR1020037013786A
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English (en)
Korean (ko)
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KR20030090779A (ko
Inventor
피셔앨리슨엠.
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모토로라 인코포레이티드
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B01D67/0093—Chemical modification
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/28—Polymers of vinyl aromatic compounds
    • B01D71/281—Polystyrene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/30—Polyalkenyl halides
    • B01D71/32—Polyalkenyl halides containing fluorine atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
    • B01D71/80—Block polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
    • B01D71/82—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74 characterised by the presence of specified groups, e.g. introduced by chemical after-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2243—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/411—Organic material
    • H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
    • H01M50/42—Acrylic resins
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/411—Organic material
    • H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
    • H01M50/423—Polyamide resins
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1072—Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. in situ polymerisation or in situ crosslinking
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1081—Polymeric electrolyte materials characterised by the manufacturing processes starting from solutions, dispersions or slurries exclusively of polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1086—After-treatment of the membrane other than by polymerisation
    • H01M8/109—After-treatment of the membrane other than by polymerisation thermal other than drying, e.g. sintering
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/30—Cross-linking
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Nanotechnology (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Composite Materials (AREA)
  • Physics & Mathematics (AREA)
  • Dispersion Chemistry (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Conductive Materials (AREA)
  • Fuel Cell (AREA)
KR1020037013786A 2001-04-23 2002-03-20 중합체 전해질 막 Expired - Fee Related KR100895777B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/797,557 US6503378B1 (en) 2001-04-23 2001-04-23 Polymer electrolyte membrane and method of fabrication
US09/797,557 2001-04-23
PCT/US2002/008879 WO2002087001A2 (en) 2001-04-23 2002-03-20 Polymer electrolyte membrane

Publications (2)

Publication Number Publication Date
KR20030090779A KR20030090779A (ko) 2003-11-28
KR100895777B1 true KR100895777B1 (ko) 2009-05-08

Family

ID=25171173

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KR1020037013786A Expired - Fee Related KR100895777B1 (ko) 2001-04-23 2002-03-20 중합체 전해질 막

Country Status (8)

Country Link
US (2) US6503378B1 (enExample)
EP (1) EP1389352A2 (enExample)
JP (1) JP2005509243A (enExample)
KR (1) KR100895777B1 (enExample)
CN (1) CN1579032A (enExample)
AU (1) AU2002255885A1 (enExample)
TW (1) TWI239358B (enExample)
WO (1) WO2002087001A2 (enExample)

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US20020192537A1 (en) * 2001-06-15 2002-12-19 Xiaoming Ren Metallic layer component for use in a direct oxidation fuel cell
US7318972B2 (en) 2001-09-07 2008-01-15 Itm Power Ltd. Hydrophilic polymers and their use in electrochemical cells
EP1474839B1 (en) * 2002-02-06 2010-04-07 Battelle Memorial Institute Polymer electrolyte membranes for use in fuel cells
US7202001B2 (en) 2002-05-13 2007-04-10 Polyfuel, Inc. Sulfonated copolymer
WO2004042839A2 (en) * 2002-05-13 2004-05-21 Polyfuel, Inc. Ion conductive block copolymers
US7354679B2 (en) * 2002-05-13 2008-04-08 Polyfuel, Inc. Ion conductive random copolymers
US20040175598A1 (en) * 2002-12-02 2004-09-09 Bliven David C. Fuel cell power supply for portable computing device and method for fuel cell power control
DE10258175A1 (de) 2002-12-12 2004-07-08 General Motors Corp., Detroit Ein Blockcopolymer zur Verwendung als fester Polymerelektrolyt, eine ionenleitfähige Membran, die aus einem Blockcopolymer gemacht ist, und Verfahren zur Herstellung eines Blockcopolymers
KR100509298B1 (ko) * 2003-05-31 2005-08-22 한국과학기술연구원 무기질 박막이 코팅된 직접메탄올 연료전지용 복합고분자 전해질막의 제조 방법
EP1667263A1 (en) * 2003-09-12 2006-06-07 Rohm Co., Ltd. Proton conductive membrane, method for producing same, and fuel cell using same
US7071271B2 (en) * 2003-10-30 2006-07-04 3M Innovative Properties Company Aqueous emulsion polymerization of functionalized fluoromonomers
US7259208B2 (en) * 2003-11-13 2007-08-21 3M Innovative Properties Company Reinforced polymer electrolyte membrane
US7179847B2 (en) * 2003-11-13 2007-02-20 3M Innovative Properties Company Polymer electrolytes crosslinked by e-beam
US7074841B2 (en) 2003-11-13 2006-07-11 Yandrasits Michael A Polymer electrolyte membranes crosslinked by nitrile trimerization
US7265162B2 (en) * 2003-11-13 2007-09-04 3M Innovative Properties Company Bromine, chlorine or iodine functional polymer electrolytes crosslinked by e-beam
WO2005053060A2 (en) * 2003-11-20 2005-06-09 Virginia Tech Intellectual Properties, Inc. Multiblock copolymers containing hydrophilic-hydrophobic segments for proton exchange membrane
US7060756B2 (en) * 2003-11-24 2006-06-13 3M Innovative Properties Company Polymer electrolyte with aromatic sulfone crosslinking
US7329348B2 (en) * 2003-12-01 2008-02-12 Societe Bic Fuel cell system including an ion filter
US7112614B2 (en) * 2003-12-08 2006-09-26 3M Innovative Properties Company Crosslinked polymer
US7060738B2 (en) * 2003-12-11 2006-06-13 3M Innovative Properties Company Polymer electrolytes crosslinked by ultraviolet radiation
US7173067B2 (en) 2003-12-17 2007-02-06 3M Innovative Properties Company Polymer electrolyte membranes crosslinked by direct fluorination
JP4379130B2 (ja) * 2004-01-27 2009-12-09 Ｊｓｒ株式会社 直接メタノール型燃料電池用プロトン伝導膜およびその製造方法
US7842435B2 (en) * 2004-11-01 2010-11-30 Gm Global Technology Operations, Inc. Fuel cell water management enhancement method
US7459487B2 (en) * 2005-02-16 2008-12-02 The University Of Hong Kong Polymer composite membrane and method of making the same
US7977394B2 (en) 2005-05-03 2011-07-12 GM Global Technology Operations LLC Triblock copolymers with acidic groups
US7459505B2 (en) 2005-05-03 2008-12-02 General Motors Corporation Block copolymers with acidic groups
CN100407482C (zh) * 2005-06-22 2008-07-30 新源动力股份有限公司 抗一氧化碳复合阳极电极催化层结构及制备方法
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US20070026282A1 (en) * 2005-07-26 2007-02-01 Canon Kabushiki Kaisha Polymer Electrolyte Membrane, Process For Production Thereof, Polymer Electrolyte, Electrolyte Composition, Membrane-Electrode Assembly, And Fuel Cell
GB0515329D0 (en) * 2005-07-27 2005-08-31 Novel Polymer Solutions Ltd Methods of forming a barrier
US8222367B2 (en) 2005-09-30 2012-07-17 Battelle Memorial Institute Polymers for use in fuel cell components
DE102005051887A1 (de) * 2005-10-29 2007-05-03 Pemeas Gmbh Membran für Brennstoffzellen, enthaltend Polymere, die Phosphonsäure-und/oder Sulfonsäuregruppen umfassen, Membran-Elektroden-Einheit und deren Anwendung in Brennstoffzellen
WO2007094185A1 (ja) * 2006-02-13 2007-08-23 Kuraray Co., Ltd. 高分子電解質膜、膜－電極接合体及び固体高分子型燃料電池
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US7993792B2 (en) 2006-07-26 2011-08-09 GM Global Technology Operations LLC Polymer blocks for PEM applications
US8492460B2 (en) 2006-07-28 2013-07-23 GM Global Technology Operations LLC Fluorinated polymer blocks for PEM applications
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KR100813515B1 (ko) * 2006-09-11 2008-03-17 삼성에스디아이 주식회사 연료전지용 프로톤 전도체 및 이를 채용한 연료전지
KR100796990B1 (ko) * 2006-09-20 2008-01-22 연세대학교 산학협력단 친수성 및 술폰화 그룹이 도입된 가지형 불소계 공중합체전해질막
SE530389C2 (sv) * 2006-10-06 2008-05-20 Morphic Technologies Ab Publ Protonledande membran för en bränslecell eller en på bränslecellteknik baserad reaktor samt förfarande för framställning av membranet
US20100021788A1 (en) * 2007-05-17 2010-01-28 Canon Kabushiki Kaisha Polymer electrolyte composite film, membrane-electrode assembly and fuel cell
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US3577357A (en) 1968-11-29 1971-05-04 Shell Oil Co Selectively sulfonated block copolymers
US5264508A (en) 1992-06-25 1993-11-23 The Dow Chemical Company Polymers of haloperfluoro and perfluoro ethers
US5468574A (en) 1994-05-23 1995-11-21 Dais Corporation Fuel cell incorporating novel ion-conducting membrane
JP2000119420A (ja) * 1998-10-19 2000-04-25 Nissan Motor Co Ltd イオン交換膜およびその製造方法
WO2001088025A1 (en) 2000-05-16 2001-11-22 Biocure, Inc. Membranes formed from amphiphilic copolymers

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AU5320199A (en) * 1998-07-23 2000-02-14 Massachusetts Institute Of Technology Block copolymer electrolyte

Patent Citations (5)

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Publication number Priority date Publication date Assignee Title
US3577357A (en) 1968-11-29 1971-05-04 Shell Oil Co Selectively sulfonated block copolymers
US5264508A (en) 1992-06-25 1993-11-23 The Dow Chemical Company Polymers of haloperfluoro and perfluoro ethers
US5468574A (en) 1994-05-23 1995-11-21 Dais Corporation Fuel cell incorporating novel ion-conducting membrane
JP2000119420A (ja) * 1998-10-19 2000-04-25 Nissan Motor Co Ltd イオン交換膜およびその製造方法
WO2001088025A1 (en) 2000-05-16 2001-11-22 Biocure, Inc. Membranes formed from amphiphilic copolymers

Also Published As

Publication number Publication date
EP1389352A2 (en) 2004-02-18
US6670403B2 (en) 2003-12-30
CN1579032A (zh) 2005-02-09
KR20030090779A (ko) 2003-11-28
US20030060521A1 (en) 2003-03-27
TWI239358B (en) 2005-09-11
JP2005509243A (ja) 2005-04-07
US6503378B1 (en) 2003-01-07
WO2002087001A2 (en) 2002-10-31
AU2002255885A1 (en) 2002-11-05
WO2002087001A3 (en) 2003-09-04

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