KR100885310B1 - 피셔-트롭쉬 합성용 코발트／인―알루미나 촉매와 이의제조방법 - Google Patents

피셔-트롭쉬 합성용 코발트／인―알루미나 촉매와 이의제조방법 Download PDF

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KR100885310B1
KR100885310B1 KR1020070075065A KR20070075065A KR100885310B1 KR 100885310 B1 KR100885310 B1 KR 100885310B1 KR 1020070075065 A KR1020070075065 A KR 1020070075065A KR 20070075065 A KR20070075065 A KR 20070075065A KR 100885310 B1 KR100885310 B1 KR 100885310B1
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phosphorus
alumina
cobalt
catalyst
reaction
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Korean (ko)
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KR20090011457A (ko
Inventor
전기원
배종욱
이윤조
김승문
Original Assignee
한국화학연구원
대림산업 주식회사
두산메카텍 주식회사
한국석유공사
현대엔지니어링 주식회사
에스케이에너지 주식회사
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Application filed by 한국화학연구원, 대림산업 주식회사, 두산메카텍 주식회사, 한국석유공사, 현대엔지니어링 주식회사, 에스케이에너지 주식회사 filed Critical 한국화학연구원
Priority to JP2010506028A priority patent/JP5174890B2/ja
Priority to US12/594,617 priority patent/US8084387B2/en
Priority to CN2008800122143A priority patent/CN101842156B/zh
Priority to PCT/KR2008/000549 priority patent/WO2009014292A2/en
Priority to EP08705005.0A priority patent/EP2173481B1/en
Publication of KR20090011457A publication Critical patent/KR20090011457A/ko
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Publication of KR100885310B1 publication Critical patent/KR100885310B1/ko
Assigned to 한국가스공사 reassignment 한국가스공사 출원인변경신고 및 권리지분의 일부이전등록 Assignors: 대림산업 주식회사, 한국석유공사, 현대엔지니어링 주식회사
Assigned to 디엘이앤씨 주식회사 reassignment 디엘이앤씨 주식회사 권리지분의 전부이전등록 Assignors: 디엘 주식회사
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B01J37/033—Using Hydrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B01J27/1853—Phosphorus; Compounds thereof with iron group metals or platinum group metals with iron, cobalt or nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
KR1020070075065A 2007-07-26 2007-07-26 피셔-트롭쉬 합성용 코발트／인―알루미나 촉매와 이의제조방법 Active KR100885310B1 (ko)

Priority Applications (6)

Application Number Priority Date Filing Date Title
KR1020070075065A KR100885310B1 (ko) 2007-07-26 2007-07-26 피셔-트롭쉬 합성용 코발트／인―알루미나 촉매와 이의제조방법
US12/594,617 US8084387B2 (en) 2007-07-26 2008-01-30 Catalysts for fischer-tropsch synthesis on cobalt/phosphorus-aluminum oxide and preparation methods thereof
CN2008800122143A CN101842156B (zh) 2007-07-26 2008-01-30 用于在钴/磷-氧化铝上费-托合成的催化剂及其制备方法
PCT/KR2008/000549 WO2009014292A2 (en) 2007-07-26 2008-01-30 Catalysts for fischer-tropsch synthesis on cobalt/phosphorus-aluminum oxide and preparation methods thereof
JP2010506028A JP5174890B2 (ja) 2007-07-26 2008-01-30 フィッシャー・トロプシュ合成用コバルト／リン−アルミナ触媒及びその製造方法
EP08705005.0A EP2173481B1 (en) 2007-07-26 2008-01-30 Cobalt/phosphorus-aluminum oxide catalysts, preparation methods thereof and use in fischer-tropsch synthesis

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020070075065A KR100885310B1 (ko) 2007-07-26 2007-07-26 피셔-트롭쉬 합성용 코발트／인―알루미나 촉매와 이의제조방법

Publications (2)

Publication Number Publication Date
KR20090011457A KR20090011457A (ko) 2009-02-02
KR100885310B1 true KR100885310B1 (ko) 2009-02-24

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Country Status (6)

Country Link
US (1) US8084387B2 (https=)
EP (1) EP2173481B1 (https=)
JP (1) JP5174890B2 (https=)
KR (1) KR100885310B1 (https=)
CN (1) CN101842156B (https=)
WO (1) WO2009014292A2 (https=)

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KR101284161B1 (ko) 2011-05-26 2013-07-10 한국화학연구원 피셔-트롭쉬 반응용 촉매의 제조방법

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KR100885311B1 (ko) * 2007-09-04 2009-02-24 한국화학연구원 피셔-트롭쉬 합성용 코발트/인-알루미나 촉매와 이의 제조방법
CN103418388B (zh) * 2012-05-24 2015-09-23 中国石油化工股份有限公司 一种费托合成催化剂及其制备和应用
KR101412518B1 (ko) * 2012-08-29 2014-06-26 한국과학기술연구원 합성가스를 이용한 액체 탄화수소 제조용 촉매, 및 이의 제조 방법
KR101298783B1 (ko) 2012-12-14 2013-08-26 한국가스공사 피셔-트롭쉬 촉매의 제조방법
CN103073036B (zh) * 2012-12-25 2014-09-10 太原理工大学 超微孔高比表面积氧化铝材料及其制备方法
US9358526B2 (en) 2013-11-19 2016-06-07 Emerging Fuels Technology, Inc. Optimized fischer-tropsch catalyst
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FR3028770B1 (fr) * 2014-11-26 2016-12-02 Ifp Energies Now Procede de preparation d'un catalyseur fischer-tropsch avec traitement a la vapeur
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KR101982773B1 (ko) * 2017-05-18 2019-05-27 한국화학연구원 내열성이 개선된 메탄 개질 반응용 모노리스 촉매 및 이의 제조방법
KR101933014B1 (ko) * 2017-05-18 2018-12-27 한국화학연구원 이산화탄소를 이용한 메탄 개질 반응용 촉매 및 이의 제조방법
CN108187708B (zh) * 2018-02-01 2021-05-04 中科合成油内蒙古有限公司 一种含磷高稳定性重质烃费托合成催化剂及其制备方法和应用
CN110252358B (zh) * 2018-03-12 2022-03-22 国家能源投资集团有限责任公司 费托合成钴催化剂及其制备方法以及费托合成的方法
FR3093653B1 (fr) 2019-03-15 2021-12-24 Ifp Energies Now Procede de preparation d’un support de catalyseur
FR3102069B1 (fr) 2019-10-22 2021-12-31 Ifp Energies Now Procede de preparation d’un support de catalyseur
US12582935B2 (en) 2020-05-29 2026-03-24 Climeworks Ag Method for capture of carbon dioxide from ambient air and corresponding adsorber structures with a plurality of parallel surfaces
CN114950573B (zh) * 2021-02-24 2024-09-06 中国石油天然气股份有限公司 大孔氧化铝载体及其制备方法
EP4547371A1 (en) 2022-07-01 2025-05-07 W. L. Gore & Associates, Inc. Structure with external support for particle adsorbent bed for adsorption gas separation process
JP2025529036A (ja) 2022-08-15 2025-09-04 ダブリュ．エル．ゴア アンド アソシエイツ，インコーポレイティド 周囲空気からの二酸化炭素の回収を強化するための構造及び方法
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101284161B1 (ko) 2011-05-26 2013-07-10 한국화학연구원 피셔-트롭쉬 반응용 촉매의 제조방법

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Publication number Publication date
EP2173481A2 (en) 2010-04-14
JP5174890B2 (ja) 2013-04-03
US20100093523A1 (en) 2010-04-15
JP2010524681A (ja) 2010-07-22
EP2173481B1 (en) 2016-03-23
EP2173481A4 (en) 2011-06-29
CN101842156A (zh) 2010-09-22
US8084387B2 (en) 2011-12-27
WO2009014292A2 (en) 2009-01-29
KR20090011457A (ko) 2009-02-02
CN101842156B (zh) 2013-01-30
WO2009014292A3 (en) 2009-03-26

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