KR100709064B1 - Ceramic block and its process - Google Patents

Ceramic block and its process Download PDF

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KR100709064B1
KR100709064B1 KR1020060031756A KR20060031756A KR100709064B1 KR 100709064 B1 KR100709064 B1 KR 100709064B1 KR 1020060031756 A KR1020060031756 A KR 1020060031756A KR 20060031756 A KR20060031756 A KR 20060031756A KR 100709064 B1 KR100709064 B1 KR 100709064B1
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weight
clay
ceramic block
glaze
wood
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KR1020060031756A
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Korean (ko)
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노주호
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주식회사 대성아이디
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/04Clay; Kaolin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/04Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers
    • B28B11/044Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers with glaze or engobe or enamel or varnish
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/28Slip casting
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/32Burning methods
    • C04B33/34Burning methods combined with glazing

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Road Paving Structures (AREA)

Abstract

본 발명은 도자 블록 및 그 제조 방법에 관한 것으로, 산청점토, 산청백토, 핑크카오린, 황토, 안강옹기점토, 태백도석, 규조토를 혼합한 조합토를 사용하여 고온에서 소성하여 제조하는 것을 특징으로 한다. 본 발명에 따른 도자 블록은 한국 전통 도자기와 같은 미려한 외관을 지니며 다양한 문양이나 색상으로 제조가 가능할 뿐 아니라, 강도가 높고 불연성, 내마모성, 내약품성도 우수하여 아파트, 호텔, 백화점 등 일반 건축물의 실내 인테리어 마감재 및 외장 마감재로 사용할 수 있으며, 테마공원, 광장, 보도 등의 바닥재로도 활용이 가능하다.The present invention relates to a ceramic block and a method of manufacturing the same, characterized in that it is produced by firing at a high temperature using a mixed clay mixed with acid blue clay, acid blue clay, pink kaolin, ocher, oggong clay, taebaek stone, and diatomaceous earth. . Ceramic block according to the present invention has the same beautiful appearance as traditional Korean ceramics and can be manufactured in various patterns or colors, and has high strength and excellent non-flammability, wear resistance, and chemical resistance, so that the interior of general buildings such as apartments, hotels, department stores, etc. It can be used as interior finishing materials and exterior finishing materials, and can also be used as flooring materials for theme parks, plazas, and sidewalks.

도자 블록, 타일, 규조토, 산청점토, 산청백토. Ceramic blocks, tiles, diatomaceous earth, sancheong clay, sancheong clay.

Description

도자 블록 및 그 제조 방법 {Ceramic block and its process}Ceramic block and its manufacturing method {Ceramic block and its process}

본 발명은 도자 블록 및 그 제조 방법에 관한 것이다.The present invention relates to a ceramic block and a method of manufacturing the same.

일반적으로 점토 블록의 제조 방법은 크게 건식 제조 방법과 습식 제조 방법으로 나눌 수 있다. 이 중에서 건식 제조 방법은 고령토, 장석, 도석, 점토, 납석 등으로 이루어진 분말형태의 원료 혼합물을 프레스 금형에 넣고 가압하여 성형하며, 건조 단계를 거친 후 필요에 따라 시유 단계를 거칠 수 있으며, 1100-1200℃의 온도에서 소성이 이루어진다. 습식 제조 방법은 약 20%의 수분을 함유하며 점도를 지닌 원료 혼합물을 진공 토련 성형기를 이용하여 연속 압출시키면서 성형을 하는 방식에서 건식 제조 방법과 차이가 있다.In general, the clay block manufacturing method can be roughly divided into a dry manufacturing method and a wet manufacturing method. Among them, the dry manufacturing method is a powder raw material mixture consisting of kaolin, feldspar, pottery stone, clay, feldspar, etc. is put into a press mold and molded by pressing, and after the drying step may be subjected to a see-through step if necessary. Firing takes place at a temperature of 1200 ° C. The wet manufacturing method differs from the dry manufacturing method in that the raw material mixture containing about 20% of moisture and having a viscosity is continuously extruded using a vacuum grinder.

그러나, 이러한 방법들은 무늬가 없거나, 단순하고 규칙적인 무늬를 지닌 블록을 생산하는데 적합한 방식으로, 미세하고 섬세한 무늬를 지닌 블록을 생산하기엔 어려움이 있을 뿐 아니라, 강도에 있어서도 만족스럽지 못하다.However, these methods are not only difficult to produce blocks with fine and fine patterns, but also unsatisfactory in strength, in a manner suitable for producing blocks without patterns or simple and regular patterns.

또한, 일반적인 도자기를 생산하는 방식을 블록에 그대로 적용하여 섬세한 무늬를 지닌 제품을 생산할 수도 있으나, 이러한 경우 배나옴 현상이 발생하여 균 일한 제품을 생산하기가 힘들 뿐 아니라 바닥재 등의 다양한 용도로 사용하기엔 강도나 질감이 적합하지 못하므로 소지의 선택을 달리할 필요가 있다.In addition, it is possible to produce a product with a delicate pattern by applying the general ceramic production method to the block as it is, but in this case, it is difficult to produce a uniform product due to doubling phenomenon, and also to be used for various purposes such as flooring. The strength and texture are not suitable, so you need to choose different materials.

따라서, 본 발명은 도자기 제조 방식을 블록에 적용하면서 용도에 맞는 소지를 선택함으로써, 균일하고 강도가 높아 벽체뿐 아니라 바닥재로도 사용할 수 있는 블록 및 그 제조 방법을 제공하는 것을 목적으로 한다. 또한, 외관에 있어서는 한국 전통 도자기와 같이 미려하면서도 배나옴과 같은 문제가 발생하지 않고, 재료에 있어서는 천연소재들을 사용하여 인체에 무해하며 친환경적인 블록 및 그 제조 방법을 제공하고자 한다.Accordingly, an object of the present invention is to provide a block and a method for producing the same, which can be used not only as a wall but also as a flooring material by selecting a base material suitable for a purpose while applying a ceramic production method to a block. In addition, the appearance is as beautiful as traditional Korean ceramics, but does not cause problems such as hungry, the material is to use natural materials harmless to the human body and to provide an eco-friendly block and its manufacturing method.

본 발명은 도자 블록 및 그 제조 방법에 관한 것으로, 조합토의 제조 및 가공, 성형 및 건조, 초벌구이, 유약의 제조 및 시유, 재벌구이의 공정을 거쳐 제조하며 상세한 방법은 아래와 같다.The present invention relates to a ceramic block and a method for manufacturing the same, which are manufactured through a process of manufacturing and processing a combination clay, forming and drying, roasting a glaze, preparing and glazing glaze, and chaebol, and the detailed method is as follows.

[제조공정 1] 조합토의 제조 및 가공[Manufacturing Process 1] Preparation and Processing of Composite Soil

소지는 가소성, 내열성, 연소성을 갖춘 재료를 도자 블록의 사용 목적에 맞도록 선택하며, 본 발명에서는 산청점토 34중량%, 산청백토 24중량%, 핑크카오린 14중량%, 황토 10중량%, 안강옹기점토 7중량%, 태백도석 8중량%, 규조토 3중량%를 혼합한 조합토를 사용한다. 이와 같이 조합토에 규조토를 첨가함으로써 블록의 휨을 최소화하고 항균, 탈취 효과를 얻을 수 있으며, 습도조절 및 원적외선 방출 효과를 강화할 수 있다.The material is selected from plastic materials, heat resistance, and combustible materials to suit the purpose of the ceramic block. In the present invention, 34% by weight of acid blue clay, 24% by weight of white clay, 14% by weight of pink kaolin, 10% by weight of ocher, A combination soil of 7% by weight of clay, 8% by weight of Taebaek Doseok and 3% by weight of diatomaceous earth is used. As such, by adding diatomaceous earth to the combination soil, the warpage of the block can be minimized, antibacterial and deodorizing effects can be obtained, and humidity control and far infrared ray emission effects can be enhanced.

상기의 조합토는 혼합 후에 미분쇄, 정제, 탈철, 숙성 과정을 거친 다음, 여과 압착, 진공 토련의 가공을 하여 사용한다.The above-mentioned combination soil is used after pulverizing, refining, degassing, and aging after mixing, followed by filtration, compression and vacuum processing.

[제조공정 2] 성형 및 건조[Manufacturing Process 2] Molding and Drying

원하는 문양이 새겨진 프레스 금형에 상기 조합토를 넣고 압력을 가하여 성형한다. 이때, 조합토의 수축률을 고려하여 금형의 크기를 결정하여야 하며, 상기의 소지는 10% 정도 수축한다.The combination soil is put into a press mold engraved with a desired pattern and is molded by applying pressure. At this time, the size of the mold should be determined in consideration of the shrinkage rate of the combination soil, the body is about 10% shrinkage.

성형이 끝나면 건조 과정을 거치게 되며, 그늘진 곳에서 자연건조를 시킬 경우 30일 정도 소요되고, 건조실을 이용할 경우에는 4일 정도 소요된다.After molding, the drying process is carried out, and if the natural drying in a shaded place takes about 30 days, when using a drying room takes about 4 days.

[제조공정 3] 초벌구이[Manufacturing Process 3] Grilling

상기의 건조된 제품을 가마에 넣어 900℃의 온도로 8시간 동안 소성시킨다.The dried product is put into a kiln and fired at a temperature of 900 ° C. for 8 hours.

[제조공정 4] 유약의 제조 및 시유[Manufacturing Process 4] Preparation and Milking of Glaze

유약은 문경약토, 묵보래, 느룹나무재, 참나무재, 사과나무재, 소나무재로 이루어진 천연재료와 물을 1 : 2-4 중량비가 되도록 혼합하여 제조한다. 상기 천연재료에 대한 혼합비의 예로서, 묵보래 14중량%, 느릅나무재 4중량%, 문경약토 2중량%와 물 80중량%를 혼합하면 투명한 갈색, 참나무재 12중량%, 문경약토 4중량%, 묵보래 4중량%와 물 80중량%를 혼합하면 진한 갈색, 문경약토 18중량%, 사과나무재 1중량%, 소나무재 1중량%와 물 80중량%를 혼합하면 연한 고동색, 문경약토 16중량%, 사과나무재 2중량%, 소나무재 2중량%와 물 80중량%를 혼합하면 유광 검정색의 유약을 제조할 수 있다.Glaze is manufactured by mixing natural materials consisting of Mungyeong yakto, mukborae, nerb wood, oak wood, apple wood, pine wood and water to a weight ratio of 1: 2-4. As an example of the mixing ratio for the natural material, 14% by weight of mugwort, 4% by weight of elm wood, 2% by weight of Mungyeong Yakto and 80% by weight of water, transparent brown, 12% by weight of oak wood, 4% by weight of Mungyeong yakto , 4% by weight of mussels and 80% by weight of water are dark brown, 18% by weight of Mungyeong clay, 1% by weight of apple tree material, 1% by weight of pine material and 80% by weight of light brown, 16% by weight of Mungyeong clay %, Apple wood material 2% by weight, pine wood material 2% by weight and 80% by weight of water can produce a glossy black glaze.

시공시 접착에 방해되지 않도록 상부에만 유약을 도포하며, 옆면은 하부에서 일정 거리가 떨어진 부분까지만 시유한다. 유약을 도포한 후 닦아내기를 하여 2중 색의 효과를 나타낼 수 있으며, 재벌구이시 소성온도를 조절하여 색상의 변화를 줄 수도 있다.Glaze is applied only on the upper part so as not to interfere with the adhesion during construction, and the side surface should be oiled only to a part away from the lower part. After applying glaze, it can be wiped off to show the effect of double color, and it can also change the color by adjusting the firing temperature when grilling.

[제조공정 5] 재벌구이[Manufacturing Process 5] Grilling chaebol

시유가 끝난 제품을 가마에 넣어 1200-1300℃ 온도에서 24시간 동안 소성하여 도자 블록을 제조한다.The finished product is put into a kiln and calcined at 1200-1300 ° C. for 24 hours to prepare a ceramic block.

상기의 제조공정에 따라 제조한 도자 블록은 품질 검사 및 선별의 과정을 거친 후 제품으로 출하시킨다.The ceramic block manufactured according to the above manufacturing process is shipped to the product after the quality inspection and screening process.

[실시예]EXAMPLE

아래의 실시공정 1 내지 5에 따라 본 발명의 도자 블록을 제조하였다.The ceramic block of the present invention was prepared according to the following execution steps 1 to 5.

[실시공정 1] 조합토의 제조 및 가공[Process 1] Preparation and Processing of Composite Soil

산청점토 34kg, 산청백토 24kg, 핑크카오린 14kg, 황토 10kg, 안강옹기점토 7kg, 태백도석 8kg, 규조토 3kg을 혼합하여 조합토를 제조한 다음, 볼 밀에서 6시간 동안 미분쇄하고 불순물을 제거하였다. 상기 조합토를 탈철기를 이용하여 3회의 탈철작업을 하고 24시간 동안 저장탱크에서 숙성시킨 후, 필터프레스로 여과 압착 시키고 진공 토련 작업을 하였다.Sancheong clay 34kg, sancheol clay 24kg, pink kaolin 14kg, ocher 10kg, mixed clay clay clay 7kg, Taebaek doseok 8kg, diatomaceous earth was mixed to prepare a mixed clay, and then ground in a ball mill for 6 hours to remove impurities. The combination soil was degassed three times using a decarburizer and aged in a storage tank for 24 hours, followed by filtration and compression with a filter press and vacuum refining work.

[실시공정 2] 성형 및 건조[Process 2] Molding and Drying

원하는 문양이 새겨진 328×328×28(㎣)의 금형에 조합토를 넣고 200톤 압력의 프레스를 이용하여 성형한 다음 그늘진 곳에서 30일 동안 자연건조시켰다. Into a mold of 328 × 328 × 28 (금형) engraved with the desired pattern was put into a combination clay and molded using a press of 200 tons pressure and then dried in the shade for 30 days.

[실시공정 3] 초벌구이[Process 3] First Grill

건조된 제품들을 가마에 넣어 900℃의 온도로 8시간 동안 소성하였다.The dried products were put into a kiln and fired at a temperature of 900 ° C. for 8 hours.

[실시공정 4] 유약의 제조 및 시유Execution Step 4 Preparation and Application of Glaze

묵보래 14g, 느릅나무재 4g, 문경약토 2g과 물 80g을 혼합한 유약 1, 참나무재 12g, 문경약토 4g, 묵보래 4g과 물 80g을 혼합한 유약 2, 문경약토 18g, 사과나무재 1g, 소나무재 1g과 물 80g을 혼합한 유약 3, 문경약토 16g, 사과나무재 2g, 소나무재 2g과 물 80g을 혼합한 유약 4를 각각 제조하였다.Mugwort 14g, Elm wood 4g, 1 glaze mixed with 2g of Mungyeong clay and 80g of water, 12g oak wood, 4g of Mungyeong clay, 2g glaze mixed with 4g of mute and 80g of water, 18g of Mungyeong clay, 1g of apple wood, Glaze 3 containing 1g pine wood and 80g water, 16g of Mungyeong Yakto, 2g apple wood, 2g pine wood 2g and 80g water were prepared, respectively.

상기의 유약을 각각 제품의 상부에 도포하고 옆면은 바닥에서 8mm 떨어진 부분까지를 남기고 도포한 후, 도포한 유약을 닦아냄으로써 2중 색의 효과를 내도록 하였다. Each of the glazes were applied to the upper part of the product, and the side was applied to the left side up to 8 mm away from the bottom, and then the applied glaze was wiped out to have a double color effect.

[실시공정 5] 재벌구이[Process 5] Grilling chaebol

시유가 끝난 제품을 가마에서 1250℃의 온도로 24시간 동안 소성하여, 295×295×25(㎣)크기의 도자 블록을 제조하였다.The finished product was calcined for 24 hours at a temperature of 1250 ° C. in a kiln to prepare a ceramic block having a size of 295 × 295 × 25 (mm).

상기 실시공정에 따라 제조된 도자 블록은 인체에 무해한 천연 소재들로 이 루어져 있으며, 전통 도자기와 같은 미려한 외관을 지니면서도 배나옴이 발생하지 않았다.The ceramic block manufactured according to the above embodiment is made of natural materials that are harmless to the human body, and have no bleeding while having a beautiful appearance such as traditional ceramics.

[품질 시험][Quality test]

본 발명에 따른 도자 블록의 품질을 확인하기 위하여 보도, 차도, 광장, 주차장 용도의 포장에 관한 품질인증 기준인 KS F 4419(보차도용 콘크리트 인터로킹 블록)에 따라 흡수율, 휨강도에 관한 시험을 하였으며, 결과는 [표 1]에 기재하였다.In order to confirm the quality of the ceramic block according to the present invention was tested for absorption rate and bending strength according to KS F 4419 (concrete interlocking block for sidewalks), which is a quality certification standard for paving for sidewalks, driveways, plazas, and parking lots. The results are shown in [Table 1].

[표 1] 품질 시험[Table 1] Quality Test

보차도 인터로킹 블록 기준 (KS F 4419 기준)Based on sidewalk interlocking blocks (based on KS F 4419) 점토블록 포장재Clay Block Packaging 도자 블록Ceramic block 흡수율 (%)Absorption rate (%) 개개Individual 10.0 이하10.0 or less 1종Type 1 10.0 이하10.0 or less 7.0 이하  7.0 or less 평균Average 7.0 이하 7.0 or less 2종2 types 13.0 이하13.0 or less 휨강도 MPa(N/㎟)Flexural Strength MPa (N / ㎡) 5.0 이상 5.0 or more 1종Type 1 20.6 이상20.6 or more 21.0 이상 21.0 or more 2종2 types 15.7 이상15.7 or more

상기 [표 1]에 기재된 바와 같이 본 발명에 따른 도자 블록은 일반적인 점토블록 포장재에 비하여 흡수율이 낮고 휨강도가 높은 우수한 품질을 나타내었으며, 보도, 차도, 광장, 주차장 용도의 포장에도 적합한 품질임을 확인할 수 있었다.As shown in Table 1, the ceramic block according to the present invention exhibited excellent quality with low absorption rate and high bending strength, compared to general clay block pavement, and can be confirmed to be suitable for pavement for sidewalks, driveways, plazas, and parking lots. there was.

본 발명에 따른 도자 블록은 천연 소재로 제조하여 인체에 무해한 친환경적인 건축 내, 외장 마감재로서, 한국 전통 도자기와 같은 미려한 외관을 지녀 장식 성이 뛰어나다. 또한, 배나옴이 발생하지 않는 균일한 제품을 생산할 수 있고 다양한 색상과 문양이 가능할 뿐 아니라, 고온에서 소성하여 강도가 높고, 불연성, 내마모성, 내약품성이 우수한 특성이 있다. 따라서, 아파트, 호텔, 백화점 등의 일반 건축물의 실내 인테리어 마감재 및 외장 마감재로 사용할 수 있으며, 테마공원, 광장, 보도 등의 바닥재로도 활용할 수 있다.Ceramic block according to the present invention is made of a natural material, harmless to the human body as an environmentally friendly building, exterior finishing material, having a beautiful appearance such as Korean traditional ceramics, excellent decoration. In addition, it is possible to produce a uniform product that does not generate bleeding, various colors and patterns are possible, as well as high strength by firing at a high temperature, non-flammability, wear resistance, chemical resistance is excellent. Therefore, it can be used as interior finishing materials and exterior finishing materials of general buildings such as apartments, hotels, department stores, and can also be used as flooring materials for theme parks, plazas, and sidewalks.

Claims (3)

산청점토 34중량%, 산청백토 24중량%, 핑크카오린 14중량%, 황토 10중량%, 안강옹기점토 7중량%, 태백도석 8중량%, 규조토 3중량%를 혼합한 조합토를 사용하여 제조한 것을 특징으로 하는 도자 블록.Prepared by using a combination of a mixture of 34% by weight of clay, 24% by weight of white clay, 14% by weight of pink kaolin, 10% by weight of ocher, 7% by weight of oggong clay, 8% by weight of Taebaek Doseok, and 3% by weight of diatomaceous earth. Ceramic block, characterized in that. 산청점토 34중량%, 산청백토 24중량%, 핑크카오린 14중량%, 황토 10중량%, 안강옹기점토 7중량%, 태백도석 8중량%, 규조토 3중량%를 혼합하여 미분쇄, 정제, 탈철, 숙성, 여과 압착, 진공 토련 가공을 하여 조합토를 만들고,34% by weight of acidic clay, 24% by weight of white clay, 14% by weight of pink kaolin, 10% by weight of ocher, 7% by weight of oggong clay, 8% by weight of Taebaek Doseok, 3% by weight of diatomaceous earth Aging, filtration, compression, and vacuum refining make the clay 문양이 새겨진 금형에 조합토를 넣고 200톤 압력의 프레스를 이용하여 성형하고 그늘진 곳에서 30일 동안 자연건조시킨 다음,Put the combination clay into the mold engraved and mold it using a press of 200 tons pressure and dry it in the shade for 30 days. 가마에 넣어 900℃의 온도로 8시간 동안 소성시키고 유약을 도포한 후,Put it in a kiln and bake at 900 ℃ for 8 hours, apply glaze, 1250℃의 온도로 24시간 동안 소성하는 것을 특징으로 하는 도자블록의 제조 방법.Method of producing a ceramic block, characterized in that baked for 24 hours at a temperature of 1250 ℃. 제 2항에 있어서, 묵보래 14중량%, 느릅나무재 4중량%, 문경약토 2중량%와 물 80중량%를 혼합하여 만든 유약 1, 참나무재 12중량%, 문경약토 4중량%, 묵보래 4중량%와 물 80중량%를 혼합하여 만든 유약 2, 문경약토 18중량%, 사과나무재 1중량%, 소나무재 1중량%와 물 80중량%를 혼합하여 만든 유약 3, 문경약토 16중량%, 사과나무재 2중량%, 소나무재 2중량%와 물 80중량%를 혼합하여 만든 유약 4 ; 중에서 선택되는 어느 하나의 유약으로 도포한 것을 특징으로 하는 도자 블록의 제조 방법.According to claim 2, 14% by weight of mussels, 4% by weight of elm wood, glaze 1, 12% by weight of oak wood, 4% by weight of mumpyeong clay Glaze 2 made by mixing 4% by weight and 80% by weight of water, 18% by weight of Mungyeong clay, 1% by weight of apple wood, 1% by weight of pine wood and 80% by weight of water , Glaze 4 made by mixing 2% by weight of apple tree material, 2% by weight pine material and 80% by weight of water; A method for producing a ceramic block, characterized in that the coating with any one of the glazes selected from.
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KR100925800B1 (en) 2008-06-04 2009-11-11 신규식 The natural glaze composition for the pine nuts
KR100944035B1 (en) 2009-08-26 2010-02-24 주식회사 상산쎄라믹 A clay brick using natural glaze and manufacturing method of it
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KR101466965B1 (en) * 2014-05-19 2014-12-10 장기덕 Method of Manufacturing Porcelain Body having Sintering Flower
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KR20160075449A (en) * 2016-06-15 2016-06-29 장기덕 Method of Manufacturing Porcelain Body having Sintering Flower
KR20160075448A (en) * 2016-06-15 2016-06-29 장기덕 Method of Manufacturing Porcelain Body having Sintering Flower
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* Cited by examiner, † Cited by third party
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KR100919954B1 (en) * 2008-02-15 2009-10-01 주식회사 동양이앤피 Interior materials composition of natural material and method of preparing interior materials using the same
KR100925800B1 (en) 2008-06-04 2009-11-11 신규식 The natural glaze composition for the pine nuts
KR101055907B1 (en) * 2009-03-05 2011-08-09 김영식 Method for manufacturing brown glaze and method for manufacturing brown glaze using same
KR100944035B1 (en) 2009-08-26 2010-02-24 주식회사 상산쎄라믹 A clay brick using natural glaze and manufacturing method of it
KR101525023B1 (en) * 2013-12-24 2015-06-10 한상용 A pottery manufacture method
KR101466965B1 (en) * 2014-05-19 2014-12-10 장기덕 Method of Manufacturing Porcelain Body having Sintering Flower
KR101634383B1 (en) 2014-12-03 2016-06-28 장기덕 Method of Manufacturing Porcelain Body having Sintering Flower
KR20160066801A (en) * 2014-12-03 2016-06-13 장기덕 Method of Manufacturing Porcelain Body having Sintering Flower
KR20160073367A (en) * 2016-06-15 2016-06-24 장기덕 Method of Manufacturing Porcelain Body having Sintering Flower
KR20160075449A (en) * 2016-06-15 2016-06-29 장기덕 Method of Manufacturing Porcelain Body having Sintering Flower
KR20160075448A (en) * 2016-06-15 2016-06-29 장기덕 Method of Manufacturing Porcelain Body having Sintering Flower
KR101639272B1 (en) 2016-06-15 2016-07-13 장기덕 Method of Manufacturing Porcelain Body having Sintering Flower
KR101639274B1 (en) 2016-06-15 2016-07-13 장기덕 Method of Manufacturing Porcelain Body having Sintering Flower
KR101639270B1 (en) 2016-06-15 2016-07-13 장기덕 Method of Manufacturing Porcelain Body having Sintering Flower
KR20220042524A (en) * 2020-09-28 2022-04-05 이희복 Brick shaped pottery and manufacturing method thereof
KR20220093055A (en) * 2020-09-28 2022-07-05 이희복 Brick shaped pottery and manufacturing method thereof
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