KR20030091087A - Method for making environmental ceramic block - Google Patents

Method for making environmental ceramic block Download PDF

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KR20030091087A
KR20030091087A KR1020030078153A KR20030078153A KR20030091087A KR 20030091087 A KR20030091087 A KR 20030091087A KR 1020030078153 A KR1020030078153 A KR 1020030078153A KR 20030078153 A KR20030078153 A KR 20030078153A KR 20030091087 A KR20030091087 A KR 20030091087A
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ceramic block
manufacturing
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kiln
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KR1020030078153A
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KR100588458B1 (en
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노영호
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주식회사 대성아이디
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/24—Manufacture of porcelain or white ware
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/131—Inorganic additives
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Finishing Walls (AREA)
  • Road Paving Structures (AREA)

Abstract

PURPOSE: Provided is a method for making an environmental ceramic block which has excellent impact resistance, rigidity, elasticity, chemical resistance and decoration effect and is based on natural materials favorable to human bodies. CONSTITUTION: The method comprises the steps of: mixing clay, feldspar, silica, alumina and germanium, and further mixing the clay mixture with bentonite in the weight ratio of 1:5 to form foundation earth; forming the foundation earth into a desired shape by a press under the pressure greater than 500 tons; naturally drying the formed product on a drying plate in a shaded ground for about 5-10 days; baking the dried product in a kiln at 800-850 deg.C for 6-9 hours; optionally applying glaze to the baked product; and further baking the glazed product in a kiln at a high temperature of 1300-1450 deg.C for 10-12 hours.

Description

환경도자블록의 제조방법{omitted}Manufacturing method of environmental ceramic block

본 발명은 환경도자블록의 제조방법에 관한 것으로서, 더욱 상세히는 도자기로 이루어져 질감이 매우 우수하면서도 내충격성, 내강성, 탄력성 등이 우수하고, 건축물의 내외장재, 공원, 광장, 보도 등의 바닥재로 포장공사에 적용할 수 있는 등 그 사용범위가 광범위한 환경도자블록의 제조방법을 제공코자 하는 것이다.The present invention relates to a method of manufacturing an environmental ceramic block, and more particularly, made of ceramics, the texture is very excellent, but also excellent in impact resistance, strength resistance, elasticity, etc., paved with flooring materials such as interior and exterior materials of buildings, parks, plazas, sidewalks, etc. It is intended to provide a method of manufacturing environmental ceramic blocks with a wide range of applications, such as applicable to construction.

현대 건축물에 쓰이는 수많은 건축재료는 산업사회의 발전과 함께 오염된 공해속에서 벗어나려는 인간의 욕구 충족을 위해 보다 자연적인 소재의 연구가 시급한 시점이다.Numerous building materials used in modern buildings are urgently needed to study more natural materials to meet the human desire to escape from polluted pollution with the development of industrial society.

그로 인하여 환경친화적인 건축물 내외장재가 요구되고 있으며, 정부에서도 이를 적극 권장하고 있다.As a result, environmentally friendly interior and exterior materials are required, and the government strongly recommends this.

자연의 질감(느낌)을 줄 수 있는 재료 중 목재는 자원의 고갈로 인하여 양질의 자재를 대량으로 구입하기 어려운 실정이며, 그로 인하여 목재 공급의 한계를 합성수지재 제품으로 제작하여 인위적인 분위기를 연출 하고 있는 실정이다.Among the materials that can give a natural texture (wood), it is difficult to purchase high quality materials in large quantities due to the depletion of resources. Therefore, the limit of wood supply is made of synthetic resin products to create an artificial atmosphere. It is true.

한편, 석재는 자연 파괴의 한계로 개발을 제한하여 수요 충족을 만족시키지 못해 수입에 의존하고 있는 실정이다.On the other hand, the stone is relying on imports because it does not satisfy the demand by limiting the development to the limit of natural destruction.

그리고 건축용 내외장재 중에는 바닥장식용 타일, 벽면장식용 타일 등에 도자기로 이루어진 제품이 다수 안출, 사용되고 있으나, 기존 도자기로 이루어진 건축용 내외장재의 경우 충격에 매우 약하여 쉽게 파손되는 문제점이 있었고, 이러한 도자기 제품의 경우 바닥장식재로 사용하기에는 부적합하고, 그 표면 질감이 미끄러워 보행자가 보행 시 슬립 등으로 인하여 상해를 입는 경우도 많은 등 다수의 문제점이 있었던 것이다.Among the interior and exterior materials for building, many products made of ceramics are used for floor decoration tiles, wall decoration tiles, etc.However, the interior and exterior materials for existing ceramics are very weak to shock and are easily damaged. Inadequate to use, and the surface texture is slippery, there are a number of problems, such as a lot of pedestrians are injured due to slip during walking.

이에 본 발명에서는 기존 알려진 도자기로 이루어진 환경도자블록의 제조방법이 갖는 제반 문제점을 일소할 수 있는 신규한 구성의 환경도자블록의 제조방법을 제공코자 하는 것으로서,Accordingly, the present invention is to provide a method of manufacturing an environmental ceramic block of a novel configuration that can eliminate all the problems of the conventional manufacturing method of environmental ceramic blocks made of ceramics,

본 발명은 특히 그 질감이 매우 우수하고, 내충격성, 내강성이 뛰어난 환경도자블록의 제조방법을 제공함에 발명의 기술적 과제를 두고 본 발명을 완성한 것이다.The present invention has been completed in view of the technical problem of the present invention in order to provide a method for producing an environmental ceramic block having excellent texture and excellent impact resistance and rigidity.

본 발명에서는 질감이 다양, 양호하며, 내충격성, 내강성이 우수한 환경도자블록의 제조방법을 제공하기 위하여 다음과 같은 제조방법을 제공한다.In the present invention provides a manufacturing method as follows to provide a manufacturing method of the environmental ceramic block is a variety of texture, good, excellent impact resistance, and strong resistance.

즉, 우선 본 발명은 주재인 소지의 선택 및 구입을 하고, 제품 성형, 건조, 초벌구이, 유약 칠하기, 재벌구이 순서로 이루어지는 통상의 도자기 제조방법에 본 발명만이 갖는 특유의 첨가물과 제조방법을 통하여 본 발명이 득하고자 하는 특성을 갖는 환경도자블록을 제조하게 된다. 이를 이하의 실시예와 함께 상세히 설명키로 한다.In other words, the present invention first selects and purchases the main body, and the additives and manufacturing method peculiar to the present invention in the conventional ceramics manufacturing method consisting of product molding, drying, roasting, glazing, and chaebol. Through the manufacture of the environmental ceramic block having the characteristics to be obtained by the present invention. This will be described in detail with the following embodiments.

(실시예)(Example)

1. 소지(素地) 선택1. Choose your land

본 발명에서 제공하는 환경도자블록(이하 '제품'이라 통칭한다)의 제조방법은 사용코자 하는 내외장재에 맞게 재료(흙)의 선택이 가장 중요하다.In the method of manufacturing the environmental ceramic block (hereinafter referred to as "product") provided by the present invention, the selection of materials (soil) is most important for the interior and exterior materials to be used.

소지를 선택할 시는 가소성과 내열성, 그리고 연소성을 두루 갖는 흙을 선택토록 한다.When choosing a base, choose soil with plasticity, heat resistance and combustibility.

소지는 점토에 흙 성분인 장석, 규석, 알루미나, 게르마늄을 합성한 소지를 사용하여 제품을 만들도록 한다.Soji is made from clay, which is composed of earth, feldspar, silica, alumina and germanium.

한편, 본 발명은 상기와 같은 일반적으로 알려진 도자기 제작방법으로 내외장재를 제작 시 도자기의 특성상 물을 흡수하여 냉파의 원인이 되며, 강도가 약하여 깨지기 쉬운 문제점을 해결하기 위하여 상기한 소지에 벤토나이트(bentonite)를 적량 첨가한다.On the other hand, the present invention absorbs water due to the characteristics of the ceramics when manufacturing the interior and exterior materials by the generally known ceramics manufacturing method as described above causes cold waves, the strength is weak to solve the problem of fragile bentonite (bentonite) Appropriately add.

알려진 바와 같이 벤토나이트는 극히 미세한 입자로 된 점토로 주광물은 몬모릴로나이트(montmorillonite)인데, 화산의 유리성분이 분해되어 생성된 매우 점력이 강한 성분이다. 또한 벤토나이트는 가소성과 강도의 부여제로 쓰이고, 건조 강도를 증진시키는데 사용된다. 단, 도자기의 원료로 사용할 때는 2∼5% 이상 첨가하지 않는다.As is known, bentonite is a very fine particle clay whose main mineral is montmorillonite, a highly viscous component produced by the decomposition of the volcanic glass. Bentonite is also used to impart plasticity and strength and to enhance dry strength. However, when used as a raw material of ceramics, do not add more than 2 to 5%.

건축용 점토제품에서 벤토나이트를 첨가하면 강도, 건조강도, 소성강도가 크게 증가하기 때문에 일반 점토를 구운 도자블록과는 현격한 차이점을 나타낸다. 이러한 벤토나이트와 점토는 중량비 1:5로 혼합하여 사용한다.The addition of bentonite in building clay products greatly increases the strength, dry strength, and plastic strength, which is a significant difference from ceramic blocks baked in ordinary clay. Such bentonite and clay may be mixed in a weight ratio of 1: 5.

게르마늄 성분을 15% 정도 합성하면 탄력성과 강도에서 현격한 차이가 있으며 특히 건강에 이로운 음이온이 발생된다.Synthesizing about 15% of germanium has a noticeable difference in elasticity and strength, and particularly generates anions that are beneficial to health.

2. 제품의 성형2. Molding of the product

소지를 선택한 후 프레스를 이용하여 500ton 이상의 압력으로 습식 제작방법을 통하여 원하는 형상으로 조각 및 문양이 새겨지도록 제품을 성형한다. 프레스 성형 시에는 점토의 수축율을 고려하여 성형토록 한다.After selecting the base, the product is molded so that pieces and patterns are carved into a desired shape through a wet manufacturing method using a press at a pressure of 500 tons or more. When press molding, the shrinkage of the clay is considered in consideration of the shrinkage.

보통 산청토는 12%, 분청토는 13.5% 정도 수축한다는 데이터를 기반으로 제작한다.Normally, it is produced based on the data that 12% of fresh soil is contracted and 13.5% of fresh soil.

3. 건조3. Drying

상기와 같이 제품이 성형완료되면, 건조판에 프레스 성형된 제품을 나열하여 실내 음지에서 5∼10일 정도 자연건조시킨다.When the product is molded as described above, the press-formed product on the drying plate to enumerate in the indoor shade for 5 to 10 days to dry naturally.

건조작업을 서두르면 제품이 갈라지기도 하고 구울 때 균열이 일어나 터지는 등 애써 만든 제품이 파손될 수 있으므로 음지에서 천천히 자연건조 시켜야 한다.If you rush to dry, the product may crack or burst when you burn it.

필요에 따라서는 건조실을 제작하여 건조를 시킬 수 있으며, 이때는 약 2시간 정도면 건조가 이루어진다.If necessary, a drying chamber may be manufactured and dried. In this case, drying is performed in about 2 hours.

4. 초벌구이4. Grilled Beef

음지에서 건조된 제품을 가마에 넣어서 800∼850℃의 온도로 6∼9시간 걸려 소성한다.The dried product in the shade is put in a kiln and baked for 6 to 9 hours at a temperature of 800 to 850 ° C.

5. 유약 칠하기5. Glaze

유약칠하기는 '시유'라고 하며, 초벌구이 후에 제품 표면에 유약을 바르는 공정이다. 유약칠하기를 행하면 제품의 방수성이 좋고 광택이 나며 잘 더러워지지 않는 특성이 주어진다.Glazing is called 'seeding' and is the process of applying glaze on the surface of the product after roasting. Glazing gives the product good waterproofness, luster and dirt.

단, 유약이 매끄러우므로 제품의 성격에 맞추어서 유약을 바르지 않고 문양으로 표현하고 압력으로 강도를 맞출 수도 있다. 특히 바닥재는 미끄러울 경우 보행시 슬립되어 상해를 입을 수도 있으므로 유약 칠하기를 하지 않는 것이 바람직하다.However, because the glaze is smooth, it can be expressed as a pattern without applying glaze according to the characteristics of the product and the strength can be adjusted by pressure. In particular, the flooring is slippery when walking and may cause injury, so it is preferable not to apply glazing.

6. 재벌구이6. Grilled chaebol

유약 칠하기가 끝난 제품은 1,300∼1,450℃의 고온으로 10∼12시간 이상 가마에 넣어서 재벌구이를 행하여 최종적으로 본 발명이 얻고자 한 완성된 제품을 제조하는 것이다.The glazed product is baked in a kiln at a high temperature of 1,300 to 1,450 ° C for 10 to 12 hours or more to finally manufacture the finished product intended to be obtained by the present invention.

7. 검사 및 선별 및 출하7. Inspection, screening and shipment

완성된 제품의 사이즈 및 색상, 갈라짐 등을 선별검사 후 제품의 운송, 취급 및 보관 시 손상되지 않도록 한 보호조치한 상태에서 박스포장하여 출고하게 된다.After screening, the size, color and crack of the finished product will be packed and shipped in a protective condition to prevent damage during transportation, handling and storage.

이러한 실시예와 같은 본 발명의 제조방법에 의해 제조되는 제품 시공방법에 대하여 살펴 본다.It looks at the product construction method manufactured by the manufacturing method of the present invention such as this embodiment.

(1) 바닥재의 경우 블록시공에 가장 많이 사용되고 있는 일반화된 시공방법으로 바탕면에 평탄하게 레미콘 몰탈(바탕몰탈)을 조성한 후 붙임몰탈(시멘트:모래=1:1.5)을 2∼3mm 두께로 바르고, 블록두께의 1/3 이상이 묻히도록 충분하게 두들김을 주어 시공하는 방법 또는 보도블록설치와 동일한 방법으로도 모래로 수평을 맞추고 그 위에 문양에 맞게 시공한다.(1) In the case of flooring, after preparing the ready-mixed concrete mortar (base mortar) evenly on the base surface by the generalized construction method that is most commonly used for block construction, apply paste mortar (cement: sand = 1: 1.5) to 2 ~ 3mm thickness In the same way as installing the sidewalk block or the method of installing the sidewalk block, level it with sand and apply it to the pattern on it.

(2) 벽체의 경우 콘크리트 및 시멘트 벽면을 18∼20mm의 두께로 한번 더 수평으로 미장한 후 블록의 규격에 맞추어 줄눈을 먹줄로 표시한다.(줄눈의 간격은 6mm를 기준으로 한다)(2) In case of wall, concrete and cement wall is plastered horizontally once more with the thickness of 18 ~ 20mm, and the joints are marked with black lines according to the block size. (The spacing of joints is based on 6mm)

(3) 도판 뒷면에 경화제나 접착제가 잘 배합 되어진 에폭시본드 접착제를 1.5cm 정도 되는 공 모양으로 5곳 이상 부착하고 그어진 줄눈에 맞추어 부착한다.(에폭시 본드와 Hot melt 볼트를 이용하면 신속하게 부착할 수 있다.)(3) Attach more than 5 epoxy bond adhesives, which are well-mixed with a hardener or adhesive, on the back of the plate in the shape of a ball about 1.5cm, and fit them in line with the drawn joints. (Epoxy bonds and hot melt bolts can be attached quickly. Can be.)

(4) 벽체설치 시 흘러내림을 방지하는 합판을 6mm 두께로 작게 잘라 끼워 고정 시킨다.(4) When installing the wall, cut the plywood to prevent it from falling down into 6mm thickness and fix it.

(5) 도판 시공 후 최소 24시간 경과한 다음, 줄눈 사이에 이물질을 제거한 후 줄눈시멘트(시멘트:모래=1:2) 로 충분히 물과 배합하여 빈틈이 생기지 않도록 한다.(디자인 벽체의 경우 줄눈 마감은 가급적 하지 않는다.)(5) After at least 24 hours have passed after coating, remove foreign substances between joints and mix them with water with joint cement (cement: sand = 1: 2) to prevent any gaps. Is not possible.)

(6) 모양에 따른 제품의 절단은 다이아몬드-소우(Diamond-saw)를 이용한 커팅기를 사용한다.(6) The cutting of the product according to the shape uses a cutter using a diamond-saw.

(7) 양생: 옥외 장소에서는 직사광선, 바람, 비 등에 의한 나쁜 영향이 예상될 때는 미리 시트(sheet) 등을 쳐서 양생을 하여야 한다.(7) Curing: In outdoor places, curing is to be done by sheeting in advance when adverse effects from direct sunlight, wind or rain are expected.

특히 동절기에는 기온이 2℃ 이하로 내려갈 우려가 있으면 시공을 피하는 것이 좋다. 또한 시공 중이나 경화되기 전 진동과 충격 등으로부터 보호해야 한다.In winter, especially if there is a possibility that the temperature will drop below 2 ℃, avoid construction. In addition, it must be protected from vibration and impact during construction and before hardening.

(8) 시공이 종료되면 발주처 및 감독관의 입회 하에 검수를 받고, 시방서에 기술되지 아니한 사항은 발주처 및 감독관의 지시에 따른다.(8) Upon completion of construction, inspections will be made in the presence of the client and the supervisor, and any matters not described in the specification will follow the instructions of the client and the supervisor.

(10) 제품의 설치 및 줄눈 그라우팅 작업이 끝난 다음, 타일 전체 표면을 청소하여 이물질을 제거토록 한다.(10) After installation and joint grouting of the product, clean the entire surface of the tile to remove foreign substances.

이상에서 상세히 살펴 본 바와 같이 본 발명에서 제공하는 환경도자블록의 제조방법은 기존 도자기로 만들어지는 도자블록이 가진 제반 문제점을 일소할 수 있는 것으로서,As described in detail above, the manufacturing method of the environmental ceramic block provided by the present invention can eliminate all the problems of the ceramic block made of existing ceramics.

특히 본 발명의 제조방법에 의해 제조된 환경도자블록은,In particular, the environmental ceramic block produced by the manufacturing method of the present invention,

(1) 그 질감이 매우 우수하고, 내충격성, 내강성, 탄력성, 장식성 등이 뛰어나다.(1) The texture is very excellent, and the impact resistance, the rigidity, the elasticity, the decoration is excellent.

(2) 인체에 전혀 해가없는 천연소재를 원료로 하여 인체에 이롭다.(2) It is beneficial to human body by using natural material which is harmless to human body.

(3) 전통도자기 제조공법 및 다양한 문양을 응용하여 독창적이고 창의성이 돋보이는 문화상품으로 사용범위가 큰 건축자재이다.(3) It is a building material with a wide range of use as a cultural product that shows original and creativity by applying traditional ceramic manufacturing methods and various patterns.

(4) 형태의 조형이 자유로우며 색상, 채색, 문양조각 등이 자유롭다.(4) Free form molding and free color, coloring, and sculpture.

(5) 시공, 설치가 간단하며, 각종 화학물질에도 변색, 변형이 없는 특징을 갖는 것이다.(5) It is easy to install and install, and it is characterized by no discoloration or deformation in various chemical substances.

그리고 이러한 본 발명의 환경도자블록은 일반 건축물, 아파트, 고급건축물(호텔, 백화점), 고건축물(기념관, 박물관, 종교시설)등의 내외장재, 그리고 테마공원, 광장, 보도블록의 바닥재, 건축물의 실내외 인테리어 디자인 작품 등으로 널리 활용될 수 있는 등 그 응용범위가 광범위한 것이다.And the environmental ceramic block of the present invention is an interior and exterior materials such as general buildings, apartments, high-grade buildings (hotels, department stores), old buildings (memorial halls, museums, religious facilities), and floors of theme parks, plazas, sidewalk blocks, interior and exterior of buildings It can be widely used for interior design works, etc., and its application range is wide.

Claims (1)

환경도자블록을 제조함에 있어서;In manufacturing environmental ceramic blocks; 점토에 흙 성분인 장석, 규석, 알루미나, 게르마늄을 합성하고, 상기 점토에 벤토나이트를 중량비 1:5로 혼합하여 소지를 조성하며,Synthesizing feldspar, silica, alumina, germanium, which are soil components in clay, and mixing bentonite in clay at a weight ratio of 1: 5 to form a base material, 상기 소지를 프레스에서 500ton 이상의 압력으로 습식 제작방법을 통하여 원하는 형상으로 조각 및 문양이 새겨지도록 제품을 성형하고,Molding the product to be carved into the desired shape and pattern through a wet manufacturing method at a pressure of 500ton or more in the press, 상기 성형된 제품을 건조판에 나열하여 실내 음지에서 5∼10일 정도 자연건조시키며,The molded products are listed on a dry plate and dried naturally in indoor shade for about 5 to 10 days, 상기 건조된 제품을 가마에 넣어서 800∼850℃의 온도로 6∼9시간 걸려 소성하며,The dried product is put into a kiln and baked for 6 to 9 hours at a temperature of 800 to 850 ° C. 상기 소성하여 초벌구이 된 제품 표면에 선택적으로 유약칠하기를 수행하고,Selectively calcining the surface of the fired product, 상기 유약 칠하기가 끝난 제품은 1,300∼1,450℃의 고온으로 10∼12시간 이상 가마에 넣어서 재벌구이를 행하여 환경도자블록을 제조하는 것을 특징으로 하는 환경도자블록의 제조방법.The glazed finished product is an environmental ceramic block manufacturing method characterized in that the environmental ceramic block is produced by baking in a kiln for 10 to 12 hours or more at a high temperature of 1,300 ~ 1,450 ℃.
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Cited By (3)

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Publication number Priority date Publication date Assignee Title
KR100678366B1 (en) * 2003-08-20 2007-02-05 우성세라믹스공업 주식회사 Eco-friendly ceramic clay pavers having permeability and method for producing thereof
KR100709064B1 (en) * 2006-04-07 2007-04-18 주식회사 대성아이디 Ceramic block and its process
KR101371295B1 (en) * 2012-09-21 2014-03-13 박용고 Gumganggyung celadon zhuanta

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KR101281302B1 (en) * 2011-08-03 2013-07-03 이동자 Manufacturing method and that geostatic appliance of massage geostatic appliance
KR101430128B1 (en) 2014-04-16 2014-08-18 채홍우 Manufacturing method for toy bricks treated firing of clay and using method of the toy bricks

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JPH09156997A (en) * 1995-12-05 1997-06-17 Mitsubishi Materials Corp Production of glazed ceramic plate
JPH11199307A (en) * 1998-01-19 1999-07-27 Akechi Ceramics Kk Production of clay roof tile
KR200191916Y1 (en) * 1998-03-26 2000-08-16 백옥순 Bulgogi pan
KR20030084414A (en) * 2002-04-26 2003-11-01 주식회사 화성세라믹 a far infrared rays emitting powder and manufacturing method thereof
KR20030058986A (en) * 2003-05-14 2003-07-07 송연배 Glaze composition for coating surface of ceramic panel and coating method of ceramic panel surface using thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100678366B1 (en) * 2003-08-20 2007-02-05 우성세라믹스공업 주식회사 Eco-friendly ceramic clay pavers having permeability and method for producing thereof
KR100709064B1 (en) * 2006-04-07 2007-04-18 주식회사 대성아이디 Ceramic block and its process
KR101371295B1 (en) * 2012-09-21 2014-03-13 박용고 Gumganggyung celadon zhuanta

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