KR20030082673A - Noctilucence ornament tile - Google Patents
Noctilucence ornament tile Download PDFInfo
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- KR20030082673A KR20030082673A KR1020020021099A KR20020021099A KR20030082673A KR 20030082673 A KR20030082673 A KR 20030082673A KR 1020020021099 A KR1020020021099 A KR 1020020021099A KR 20020021099 A KR20020021099 A KR 20020021099A KR 20030082673 A KR20030082673 A KR 20030082673A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/32—Burning methods
- C04B33/34—Burning methods combined with glazing
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/131—Inorganic additives
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
- E04C2/02—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
- E04C2/04—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of concrete or other stone-like material; of asbestos cement; of cement and other mineral fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C3/00—Processes, not specifically provided for elsewhere, for producing ornamental structures
- B44C3/12—Uniting ornamental elements to structures, e.g. mosaic plates
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/54—Pigments; Dyes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Architecture (AREA)
- Inorganic Chemistry (AREA)
- Civil Engineering (AREA)
- Finishing Walls (AREA)
Abstract
Description
본 발명은 야광 장식 타일에 관한 것으로, 보다 상세히는 타일의 표면에 장식요홈을 형성하고, 상기 장식요홈에 야광 및 형광 특성을 갖는 에폭시를 삽입하여장식함으로써 취급이 용이하고 시공이 간편한 건축물의 내장재 및 인테리어 소재 등으로 이용할 수 있도록 구성된 야광 장식 타일에 관한 것이다.The present invention relates to a luminous decorative tile, and more particularly, to form a decorative groove on the surface of the tile, and to insert the decoration having a luminous and fluorescent properties in the decorative groove to decorate the building material and easy construction and easy construction The present invention relates to a luminous decorative tile configured to be used as an interior material.
일반적으로 타일은 현대 건축에 있어 외관상 미려하고 깨끗함을 지니며 또한 타일이 가지는 우수한 물성인 강도 및 내마모 내약품성 등으로 인하여 우수한 건축재료로 각광 받고 있다.In general, tiles are beautiful and clean in appearance in modern architecture, and due to the strength and wear resistance of the excellent properties of the tile has been spotlighted as an excellent building material.
이러한 타일은 그 이용되는 분야 즉 건축물의 내장재나 인테리어 소재로 이용되는 분야에 따라 주변과의 미감을 높이기 위하여 요즘에는 도 1a 및 도 1b에 도시한 바와 같이 타일(1)의 표면에 다양한 문양이나 꽃 그림 등을 인쇄하거나 또는 접착재가 포함된 안료 등으로 직접 그려 넣은 장식부(2)를 형성한 다양한 종류의 장식타일(10)이 제공되고 있다.These tiles have various patterns or flowers on the surface of the tiles 1 as shown in FIGS. 1A and 1B in order to increase aesthetics with the surroundings according to the fields used for the interior materials or the interior materials of buildings. There are provided various kinds of decorative tiles 10 in which a decorative portion 2 formed by printing a picture or the like or directly drawn with a pigment containing an adhesive material is provided.
그러나, 이와 같은 종래의 장식타일(10)은 타일(1)의 표면에 장식부(2)가 돌출되게 형성되어 있음으로 운반이나 시공시 자칫 부주위하게 되면, 상기 타일(1) 표면을 장식한 장식부(2)가 파손되거나 또는 타일(1)의 표면에서 이탈되어 이용이 불가능해지는 문제점이 있었다.However, since the decorative part 2 is formed to protrude on the surface of the tile 1, such a conventional decorative tile 10 is decorated around the surface of the tile 1 when it is uneven around during transportation or construction. There was a problem in that the decorative part 2 is broken or is separated from the surface of the tile 1 so that it cannot be used.
또한, 종래의 장식타일(10)은 내장재나 인테리어 소재로 시공된 경우 빛이 있는 장소에서는 외관상의 미려함 깨끗함을 잘 표현할 수 있으나 조명 빛이 어둡거나 빛이 없는 어두운 장소에서는 그미려함과 깨끗함을 연출할 수 없음으로 기능성 및 인테리어성의 한계를 극복하지 못하는 문제점이 있었다.In addition, the conventional decorative tile 10 can express the beauty of appearance in the place where the light is well when the interior or interior material is constructed, but in the dark place where the illumination light is dark or no light can produce a shine and clean There was a problem that does not overcome the limitations of functionality and interior as none.
본 발명은 상기한 바와 같은 문제점에 착안하여 제안된 것으로, 그 목적은 타일의 표면에 장식요홈을 형성하고, 상기 장식요홈에 야광 및 형광 특성을 갖는 에폭시를 삽입하여 장식함으로써 건축물의 내장재 및 인테리어 소재 등으로 이용할 수 있도록 구성된 야광 장식 타일을 제공하고자 하는 것이다.The present invention has been proposed in view of the problems described above, the object of which is to form a groove on the surface of the tile, the interior of the building material and interior materials by decorating by inserting the epoxy having luminous and fluorescent properties to the decoration groove It is to provide a luminous decorative tile configured to be used as such.
이와 같은 목적을 달성하기 위한 본 발명의 특징에 따르면, 점토 10 내지 30중량%, 도석 25 내지 45중량%, 장석 25 내지 45중량%, 납석 5 내지 15중량%가 혼합되어 조성되고 함수율이 10%이하인 성형재를 압축성형기로 성형하여 상면에 장식요홈을 갖는 장방형의 타일을 형성하는 타일성형단계와; 상기 성형된 타일을 건조로 넣고 약 100 내지 130℃의 온도에서 약 45분 내지 80분 정도 건조시켜 상기 타일의 함수율이 0%가 되도록 하는 타일건조단계와; 상기 건조된 타일을 장석 10 내지 35중량%, 카오린 1 내지 20중량%, 수산화알루미나 1 내지 13중량%, 아연화 1 내지 8중량%, 휠트 8 내지 20중량%, 규화석 15 내지 30중량%, 활석 8 내지 18중량%가 혼합된 유약재에 물이 중량비 0.5:1 내지 1:1 비율로 혼합되어 조성된 유약시유에 넣어 상기 타일의 표면에 유약시유를 바른 다음 가마에 넣고 약 1100 내지 1200℃ 온도로 약 1 내지 2시간 정도 가열하여 상기 유약이 도포된 타일을 소성시키는 타일소성단계와; 상기 소성된 타일의 장식요홈에 에피클로로히드린 50 내지 70중량%, 비스페놀에이 20 내지 40중량%, 폴리에틸렌걸리컬 1 내지 20중량%가 혼합된 주재료와, 제파민 20 내지 40중량%, 야광안료 40 내지 60중량%, 노페놀 5 내지 25중량%, 첨가제 1 내지 10중량%가 혼합된 경화제가 중량비 1:0.5 내지 1:1비율로 혼합되어조성된 야광에폭시수지를 삽입 경화시켜 장식부를 형성하는 장식부성형단계를 거쳐 제작된 것을 특징으로 하는 야광 장식 타일이 제공된다.According to the features of the present invention for achieving the above object, 10 to 30% by weight of clay, 25 to 45% by weight of pottery stone, 25 to 45% by weight of feldspar, 5 to 15% by weight of feldspar are mixed and the water content is 10% A molding step of forming a rectangular tile having a recess on the upper surface by molding the molding material having the following shape with a compression molding machine; A tile drying step of putting the molded tile in a drying state and drying it for about 45 to 80 minutes at a temperature of about 100 to 130 ° C. such that the water content of the tile becomes 0%; The dried tile is 10 to 35% by weight of feldspar, 1 to 20% by weight kaolin, 1 to 13% by weight of alumina hydroxide, 1 to 8% by weight of zinc, 8 to 20% by weight, 15 to 30% by weight of silicate, talc Into the glaze mixed with 8 to 18% by weight of water in the glaze oil composition, which is mixed in a weight ratio of 0.5: 1 to 1: 1 ratio, apply the glaze oil to the surface of the tile, and then put it in a kiln, about 1100 to 1200 ° C. A tile firing step of firing the glaze-coated tiles by heating for about 1 to 2 hours; 50 to 70% by weight of epichlorohydrin, 20 to 40% by weight of bisphenol A, and 1 to 20% by weight of polyethylene gallic, and 20 to 40% by weight of Jeffamine, luminous pigment in the decorative recess of the calcined tile A curing agent mixed with 40 to 60% by weight, 5 to 25% by weight of nophenol and 1 to 10% by weight of an additive is mixed in a weight ratio of 1: 0.5 to 1: 1 ratio to insert and cure the prepared luminous epoxy resin to form a decorative part. There is provided a luminous decorative tile, characterized in that made through a decorative molding step.
도 1a와 도 1b는 종래에 통상적인 장식타일을 나타낸 사시도 및 단면도.1A and 1B are a perspective view and a cross-sectional view showing a conventional decorative tile.
도 2는 본 발명의 실시예에 의한 야광 장식 타일을 나타낸 사시도 및 단면도.Figure 2 is a perspective view and a sectional view showing a luminous decorative tile according to an embodiment of the present invention.
<도면의 주요 부분에 대한 부호의 설명><Explanation of symbols for the main parts of the drawings>
100 : 야광 장식 타일100: luminous decorative tiles
110 : 타일110: tiles
111 : 장식요홈111: Decorative groove
120 : 장식부120: decoration
이하 본 발명인 야광 장식 타일을 첨부된 도면을 참조하여 상세히 설명하면 다음과 같다.Hereinafter, described in detail with reference to the accompanying drawings, the present invention luminous decorative tiles as follows.
도 2는 본 발명의 실시예에 의한 야광 장식 타일을 나타낸 사시도 및 단면도이다.2 is a perspective view and a cross-sectional view showing a luminous decorative tile according to an embodiment of the present invention.
도시한 바와 같이 본 발명의 실시예에 의한 야광 장식 타일(100)은 표1에 나타낸 바와 같이 점토 10 내지 30중량%, 도석 25 내지 45중량%, 장석 25 내지 45중량%, 납석 5 내지 15중량%가 혼합되어 조성되고 함수율이 10%이하인 성형재를 압축성형기로 성형하여 상면에 장식요홈(111)을 갖는 장방형의 타일(110)을 형성하는 타일성형단계와; 상기 성형된 타일(110)을 건조로 넣고 약 100 내지 130℃의 온도에서 약 45분 내지 80분 정도 건조시켜 상기 타일(110)의 함수율이 0%가 되도록 하는 타일건조단계와; 상기 건조된 타일(110)을 표2에 나타낸 바와 같이 장석 10 내지 35중량%, 카오린 1 내지 20중량%, 수산화알루미나 1 내지 13중량%, 아연화 1 내지 8중량%, 휠트(Frit) 8 내지 20중량%, 규화석 15 내지 30중량%, 활석 8 내지 18중량%가 혼합된 유약재에 물이 중량비 0.5:1 내지 1:1 비율로 혼합된 유약시유에 넣어 상기 타일(110)의 표면에 유약시유를 바른 다음 가마에 넣고 약 1100 내지 1200℃의 온도로 약 1 내지 2시간 정도 가열하여 상기 유약이 도포된 타일(110)을소성시키는 타일소성단계와; 상기 소성된 타일(110)의 장식요홈(111)에 표3에 나타낸 바와 같이 에피클로로히드린(Epichlorohydrin) 50 내지 70중량%, 비스페놀에이 20 내지 40중량%, 폴리에틸렌걸리컬 1 내지 20중량%가 혼합된 주재료와, 제파민(Zeffamine) 20 내지 40중량%, 야광안료 40 내지 60중량%, 노페놀(Nonphenol) 5 내지 25중량%, 첨가제 1 내지 10중량%가 혼합된 경화제가 중량비 1:0.5 내지 1:1비율로 혼합되어 조성된 야광에폭시수지를 삽입 경화시켜 장식부(120)를 형성하는 장식부성형단계를 거쳐 상기 장식부(120)에 조사된 빛이 축광되어 빛이 없는 어두운 환경속에서 장시간 발광하도록 제작된다.As shown in the luminous decorative tile 100 according to an embodiment of the present invention, as shown in Table 1 10 to 30% by weight, 25 to 45% by weight pottery stone, 25 to 45% by weight feldspar, 5 to 15 weight of feldspar A molding step of forming a rectangular tile (110) having a groove (111) on the upper surface by molding a molding material having a mixture of% and having a water content of 10% or less by a compression molding machine; A tile drying step of putting the molded tile 110 in a drying state and drying it for about 45 minutes to 80 minutes at a temperature of about 100 to 130 ° C. such that the water content of the tile 110 becomes 0%; As shown in Table 2, the dried tile 110 is 10 to 35% by weight of feldspar, 1 to 20% by weight of kaolin, 1 to 13% by weight of alumina hydroxide, 1 to 8% by weight of zinc, and 8 to 20 of Frit. Glaze on the surface of the tile 110 is put into the glaze oil mixed with water by weight ratio of 0.5: 1 to 1: 1 in the glaze material, which is mixed by weight, 15 to 30% by weight of siliceous, 8 to 18% by weight of talc. Applying the oil to the kiln and then heating it at a temperature of about 1100 to 1200 ° C. for about 1 to 2 hours to bake the glaze-coated tile 110; 50 to 70% by weight of epichlorohydrin, 20 to 40% by weight of bisphenol A, and 1 to 20% by weight of polyethylene gallium as shown in Table 3 in the decorative groove 111 of the calcined tile 110 The mixed main material, the curing agent mixed with 20 to 40% by weight of Zeffamine, 40 to 60% by weight of luminous pigment, 5 to 25% by weight of nonphenol, and 1 to 10% by weight of additives are 1: 0.5. To a luminous epoxy resin mixed and mixed at a ratio of 1: 1 to form a decorative part 120 to form a decorative part 120, and the light irradiated to the decorative part 120 is photoluminescent, so that no light exists in the dark environment. It is produced to emit light for a long time.
상기 경화제에 혼합되는 첨가제는 표 4에 나타낸 바와 같이 기포발생억제제 20 내지 80중량%와, 경화촉진제 20 내지 80중량%가 혼합되어 이루어진다.As shown in Table 4, the additive to be mixed with the curing agent is made by mixing 20 to 80% by weight of the bubble generating inhibitor and 20 to 80% by weight of the curing accelerator.
상기 타일(110)의 표면과 장식부(120)의 표면은 단차가 없이 같도록 하는 것이 바람직하며, 경우에 따라서는 장식부(120)의 표면이 타일(110)의 표면보다 약간 낮아 함몰되거나 또는 높아 돌출되도록 형성될 수 있다.It is preferable that the surface of the tile 110 and the surface of the decoration unit 120 is the same without a step, in some cases, the surface of the decoration unit 120 is recessed slightly lower than the surface of the tile 110 or It can be formed so as to protrude.
상기 타일성형단계에서 성형재는 점토와 도석과 장석과 납석이 혼합된 것에 물을 약 1:0.5 내지 1:1비율로 혼합하여 미분쇄 시킨 다음 분무 건조기에 넣고 건조시켜 일정매시를 갖는 함수율 약 8%정도의 분말형태가 되도록 하는 습식분쇄방식이 이용되며, 상기 압축성형기에 의해 가압되어 성형되는 타일(110)의 장식요홈(111)은 그림나 도형이나 글씨 등과 같이 다양한 형태의 문양이 선택적으로 형성된다.In the tile forming step, the molding material is pulverized by mixing water in a ratio of about 1: 0.5 to 1: 1 by mixing clay, pottery, feldspar, and feldspar, and then putting it in a spray dryer to dry. The wet grinding method is used to form a powder of degree, and the decorative groove 111 of the tile 110 pressed and formed by the compression molding machine is selectively formed in various shapes such as a picture, a figure, or a letter. .
상기 장식부성형단계에서 상기 주재료와 경화제가 혼합된 야광에폭수지를 경화시킬 경우에는 상온에서 약 24시간 정도 경화하거나 또는 건조기에서 약 60 내지 80℃의 온도로 4 내지 6시간 동안 가열하여 경화시킨다.When curing the luminous epoxy resin in which the main material and the curing agent are mixed in the decoration part molding step, it is cured at room temperature for about 24 hours or by heating at a temperature of about 60 to 80 ℃ for 4 to 6 hours in a drier. .
상기 경화제에 혼합되는 야광안료는 밝은 곳에서 빛을 축적하였다가 어두운 곳에서 빛을 발산하는 축광안료을 이용하는 것이 바람직 하며, 경우에 따라서는 빛을 반사하는 형광안료가 축광안료와 혼합되어 이용될 수 있다.The luminous pigment mixed with the curing agent preferably uses a photoluminescent pigment that accumulates light in a bright place and emits light in a dark place. In some cases, a fluorescent pigment reflecting light may be mixed with the photoluminescent pigment. .
한편, 본 발명인 야광 장식 타일의 제작 과정을 반복 실행하여 얻은 실시예의 성형재와 유약재와 야광에폭시수지의 최적 배합비는 표 5와 도 6과 표7에 나타낸 바와 같다.On the other hand, the optimum blending ratio of the molding material, glaze material and luminous epoxy resin of the embodiment obtained by repeatedly performing the manufacturing process of the luminous decorative tile of the present invention is shown in Table 5 and 6 and Table 7.
이와 같이 구성된 본 발명인 야광 장식 타일(100)은 장식부(120)가 타일(110)의 장식홈에 메워져 결합됨으로 상기 타일(110)과 장식부(120)의 결합이 보다 견고히 이루어짐은 물론 그로 인한 운반 및 취급이 용이함으로 타일 시공을보다 간편하게 행할 수 있게된다.The luminous decorative tile 100 of the present invention configured as described above is decorated with the decoration portion 120 is embedded in the decoration groove of the tile 110, the combination of the tile 110 and the decoration portion 120 is made more solid, of course, It is easy to carry and handle, making it easier to perform tile construction.
또한, 본 발명인 야광 장식 타일(100)은 빛에 의해 축광된 장식부(120)가 어두운 곳에서 빛을 발산하게됨으로 야간에도 미관을 고려한 장식용 타일이나 구조물, 벽면의 각종 광고물의 대용물 뿐만 아니라 수영장, 화장실, 공원 조경용 계단, 야간 표지판, 통로, 비상구 보도 등의 새로운 기능성 건축 자재로 이용될 수 있게 된다.In addition, the present invention luminous decorative tile 100 is a luminous decorative part 120 by the light is to emit light in a dark place, as well as substitutes for decorative tiles or structures, various advertisements of the wall surface in consideration of aesthetics at night as well as a swimming pool It can be used as a new functional building material such as toilets, toilets, park landscaping stairs, night signs, walkways and emergency exit walkways.
이상에서 설명한 바와 같은 본 발명인 야광 장식 타일은 타일의 표면에 형성된 장식요홈에 야광 기능을 갖는 장식부가 부분적으로 매입되어 결합됨으로 타일과 장식부의 결합이 보다 견고히 이루어져 취급 및 시공을 용이하게 할 수 있는 효과가 있다.The luminous decorative tile of the present invention as described above is a decorative part having a luminous function is partially embedded in the decorative groove formed on the surface of the tile is coupled to the effect of making the combination of the tile and the decorative portion more firmly to facilitate handling and construction There is.
또한, 본 발명인 야광 장식 타일은 장식부가 어둠속에서 발광하는 야광성을 가지므로 야간에도 실내외의 미적 감각을 살릴 수 있는 연출과 함께 도로의 주행선 표시나 표지병 등의 용도로 사용할 수 있는 등 그 활용 분야를 보다 넓게 확보할 수 있는 효과가 있다.In addition, the present invention luminous decorative tiles have luminous luminous that the decorative part emits light in the dark, so that it can be used for the purpose of displaying the driving line of the road and the cover bottle, etc., while utilizing the aesthetic sense of indoor and outdoor even at night. There is an effect that can be obtained more widely.
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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KR100754026B1 (en) * | 2006-07-03 | 2007-09-03 | 태영세라믹주식회사 | Composition for manufacturing tile that emits light in the dark using printing process and manufacturing method for tile that emits light in the dark using the composition |
US7297416B2 (en) * | 2003-04-28 | 2007-11-20 | Seoul Ceramics Co., Ltd. | Photoluminescent tile and method for fabricating the same |
KR100797870B1 (en) * | 2005-12-28 | 2008-01-24 | 유창현 | A Ceramics-Tile With A Phosphorescent function And Manufacturing Method Thereof |
KR101514382B1 (en) * | 2014-10-24 | 2015-04-22 | (주)켐씨텍 | Tile for water tank and manufacuring method thereof |
CN108558449A (en) * | 2018-02-08 | 2018-09-21 | 福建省南安市荣达建材有限公司 | A kind of production method of fluorescence ceramic tile |
Family Cites Families (5)
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JPH01157485A (en) * | 1987-12-15 | 1989-06-20 | Nippon Steel Corp | Production of fluorescent tile |
JPH03290380A (en) * | 1990-04-04 | 1991-12-20 | Inax Corp | Formation of fluorescent pattern on tile |
JPH09302904A (en) * | 1996-05-10 | 1997-11-25 | Takayoshi Tanabe | Floor tile (vinyl floor sheet) in which luminous fluorescent material is buried |
KR100268605B1 (en) * | 1997-12-30 | 2000-10-16 | 이용재 | Luminous tile and its manufacturing method |
KR200236200Y1 (en) * | 2001-02-05 | 2001-09-28 | 권오인 | Design In Stone Or Tile |
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2002
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7297416B2 (en) * | 2003-04-28 | 2007-11-20 | Seoul Ceramics Co., Ltd. | Photoluminescent tile and method for fabricating the same |
KR100797870B1 (en) * | 2005-12-28 | 2008-01-24 | 유창현 | A Ceramics-Tile With A Phosphorescent function And Manufacturing Method Thereof |
KR100754026B1 (en) * | 2006-07-03 | 2007-09-03 | 태영세라믹주식회사 | Composition for manufacturing tile that emits light in the dark using printing process and manufacturing method for tile that emits light in the dark using the composition |
KR101514382B1 (en) * | 2014-10-24 | 2015-04-22 | (주)켐씨텍 | Tile for water tank and manufacuring method thereof |
CN108558449A (en) * | 2018-02-08 | 2018-09-21 | 福建省南安市荣达建材有限公司 | A kind of production method of fluorescence ceramic tile |
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