JPH04159316A - Composition for shaping - Google Patents

Composition for shaping

Info

Publication number
JPH04159316A
JPH04159316A JP28340490A JP28340490A JPH04159316A JP H04159316 A JPH04159316 A JP H04159316A JP 28340490 A JP28340490 A JP 28340490A JP 28340490 A JP28340490 A JP 28340490A JP H04159316 A JPH04159316 A JP H04159316A
Authority
JP
Japan
Prior art keywords
parts
weight
composition
polyester resin
marble powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP28340490A
Other languages
Japanese (ja)
Inventor
Junko Okada
岡田 純子
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
UUDEN DE-LE KK
Original Assignee
UUDEN DE-LE KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by UUDEN DE-LE KK filed Critical UUDEN DE-LE KK
Priority to JP28340490A priority Critical patent/JPH04159316A/en
Publication of JPH04159316A publication Critical patent/JPH04159316A/en
Pending legal-status Critical Current

Links

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  • Macromonomer-Based Addition Polymer (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

PURPOSE:To obtain a composition which can give a satisfactory shape which can be easily seen even in dark with an economical lighting unit by mixing a marble powder with a phosphorescent pigment, an unsaturated polyester resin and a thickener in a specified ratio. CONSTITUTION:The title composition is obtained by mixing 40-55 pts.wt. marble powder with 5-25 pts.wt. phosphorescent pigment, 35-55 pts.wt. unsaturated polyester resin, a thickener and optionally a pigment, an antioxidant, an ultraviolet absorber, etc.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は、彫塑、彫刻、レリーフ、その他の美術工芸品
等の造形物、或いは建築物の内装や外装に用いる各種の
造形部材、また、看板や標識等に利用される造形物など
を製造するに用いられる造形用組成物に関する。
[Detailed Description of the Invention] [Industrial Field of Application] The present invention is applicable to sculptures, sculptures, reliefs, other arts and crafts, and various shaped members used for the interior and exterior of buildings. The present invention relates to a modeling composition that is used for producing shaped objects such as signboards and signs.

[従来の技術〕 従来、彫刻などの美術品を作成するための素材として大
理石などの石材、木材、硬質プラスチックス、ブロンズ
等が用いられているが、美麗で寸法の大きなものは極め
て高価である。
[Conventional technology] Traditionally, stones such as marble, wood, hard plastics, bronze, etc. have been used as materials for creating works of art such as sculptures, but beautiful and large-sized items are extremely expensive. .

また、建築物の内装や外装に大理石の板を用いることも
行われているが、これまた産出量が限られていて高価で
ある。
Marble plates are also used for the interior and exterior of buildings, but they are also expensive and produced in limited quantities.

そのため、この様な天然大理石に代わるものとして、大
理石粉を白色セメントで結合した人造大理石や、各種の
石粉や顔料などを不飽和ポリエステル樹脂で結合した模
造大理石などが提案され、用いられている。
Therefore, as alternatives to such natural marble, artificial marble, which is made by bonding marble powder with white cement, and imitation marble, which is made by bonding various stone powders and pigments with unsaturated polyester resin, have been proposed and used.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

これら従来の造形用素材を用いて作成した彫刻などの造
形物は、明るい環境下では鑑貰することができるが、暗
(なると照明をする必要がある。
Sculptures and other objects created using these conventional modeling materials can be viewed in bright environments, but in the dark (when it is dark), they must be illuminated.

しかし、野外等では通常用いられている点光源による照
明は、造形物の微妙な凹凸を鑑賞することができず、ま
た、多数の面光源を用いた散光照明は設備費が嵩んで不
経済である。
However, the point light source lighting that is commonly used outdoors does not allow you to appreciate the subtle unevenness of objects, and the diffused lighting that uses multiple surface light sources is uneconomical due to high equipment costs. be.

そこで本発明は、夜間などの暗い環境下でも容易に鑑賞
することができ、しかも極めて経済的な照明設備で足り
るような特殊な造形物を得ることを目的としたものであ
り、かかる造形物を作成するに通した新規な造形用組成
物を提供しようとするものである。
Therefore, the purpose of the present invention is to obtain a special shaped object that can be easily viewed even in a dark environment such as at night, and that requires extremely economical lighting equipment. The present invention aims to provide a novel modeling composition that is easy to create.

〔課題を解決するための手段〕[Means to solve the problem]

本発明による造形用組成物は、大理石粉40〜55重量
部、蓄光性顔料5〜25重量部、および不飽和ポリエス
テル樹脂35〜55重量部ならびに有効量の増粘剤を含
有するもの、または、大理石粉45〜50重量部、蓄光
性顔料20〜40重量部、および白色セメント20〜4
0重量部ならびに有効量の照度調節剤と凝結用水を含有
するものである。
The modeling composition according to the present invention contains 40 to 55 parts by weight of marble powder, 5 to 25 parts by weight of luminescent pigment, and 35 to 55 parts by weight of unsaturated polyester resin and an effective amount of a thickener, or 45-50 parts by weight of marble powder, 20-40 parts by weight of luminescent pigment, and 20-4 parts by weight of white cement
It contains 0 parts by weight as well as effective amounts of an illuminance control agent and water for coagulation.

本発明の組成物は、骨材として大理石粉と蓄光性顔料と
を用い、結合剤として不飽和ポリエステル樹脂または白
色セメントを配合したことを基本とするものであり、こ
れに有効量の増粘剤または照度調節剤を配合してなるも
のである。
The composition of the present invention is based on marble powder and a luminescent pigment as aggregates, unsaturated polyester resin or white cement as a binder, and an effective amount of a thickener. Alternatively, it may contain an illuminance control agent.

これらの組成物のうち、白色セメントを結合剤とし7た
ものには当然にセメント凝結用の水が配合されるが、こ
の水は配合物の可塑性を調節するために理論量よりも多
めに配合されることが望ましい。
Of these compositions, water for cement setting is naturally added to those using white cement as a binder, but this water is added in a larger amount than the theoretical amount in order to adjust the plasticity of the mixture. It is desirable that

本発明の組成物中で用いられる大理石粉の配合量は、少
な過ぎると造形物の質感が失われ、また配合量が多すぎ
ると蓄光性顔料の効果を滅するので好ましくない。
If the amount of marble powder used in the composition of the present invention is too small, the texture of the object will be lost, and if it is too large, the effect of the luminescent pigment will be lost, so it is not preferable.

一方、蓄光性顔料の配合量は、不飽和ポリエステル樹脂
と共に用いる場合は最低5重量部以上で美しい発光が得
られるが、多過ぎては経済的でないから25重量部程度
までで充分である。
On the other hand, when using the luminous pigment in combination with an unsaturated polyester resin, beautiful luminescence can be obtained with a minimum of 5 parts by weight or more, but too much is not economical, so it is sufficient to use up to about 25 parts by weight.

これに対し、白色セメントと共に用いる場合は最低20
重量部以上40重量部程度が望ましい。
In contrast, when used with white cement, the minimum
The amount is desirably at least 40 parts by weight.

このような本発明の組成物は、上記のような基本配合成
分の他に、必要に応じて着色のための顔料や抗酸化側、
或いは、紫外線吸収剤などの配合剤を含有していてもよ
い。
In addition to the above-mentioned basic ingredients, the composition of the present invention may optionally contain pigments for coloring, antioxidants,
Alternatively, it may contain a compounding agent such as an ultraviolet absorber.

〔作 用〕[For production]

本発明の造形用組成物を用いて成形し、また、適宜に彫
刻等の加工をした造形物は、外部から、または、その内
部もしくはその裏側などから適宜の光線で照射した後消
灯すると、全体が透明感のある発光をするので、暗い環
境下においても造形物が浮かび上がって見え、極めて美
しい。
A model that has been molded using the modeling composition of the present invention and has been appropriately processed, such as engraving, is irradiated with an appropriate light beam from the outside, inside, or from the back side of the object, and then the light is turned off. Because it emits a transparent light, the objects stand out even in dark environments, making them extremely beautiful.

〔実施例1〕 白色大理石粉40重量部、硫化亜鉛系蓄光性顔料(シン
ロイヒ、LC−CIA)8重量部、増粘剤(ヱロジール
)2重量部、バリウム系安定剤0゜2重量部を、不飽和
ポリエステル樹脂40重量部と配合して流動性の組成物
を得た。
[Example 1] 40 parts by weight of white marble powder, 8 parts by weight of zinc sulfide luminous pigment (Shinroihi, LC-CIA), 2 parts by weight of thickener (Erosil), 0.2 parts by weight of barium stabilizer, A fluid composition was obtained by blending with 40 parts by weight of an unsaturated polyester resin.

次いで、筒状の型の中央に空洞形状の芯材を固定し、前
記の組成物を型と空洞形状の芯材の間に流し込んで硬化
させた。
Next, a hollow core material was fixed in the center of a cylindrical mold, and the composition was poured between the mold and the hollow core material and cured.

こうして成形した硬化物は、型から取り出した後外面に
彫刻を施すが、この造形物の壁の厚さは50〜80厘程
度であった。
After the cured product thus molded was taken out of the mold, the outer surface was engraved, and the wall thickness of this molded product was approximately 50 to 80 rin.

更に、この造形物の表面にシリコーン系防水塗料(例え
ば、東亜ペイント、トアハソスイシーラー)及び、弗素
樹脂塗料(例えば、東亜ペイント、ニューガーメッl−
#7000)を順次塗布した。
Furthermore, the surface of this model is coated with a silicone-based waterproof paint (e.g. Toa Paint, Toa Hasosui Sealer) and a fluororesin paint (e.g. Toa Paint, New Garmell).
#7000) were applied sequentially.

この様にして作成した造形物は、昼間の太陽光及び明る
い散光の下では大理石と殆ど同様の外観を有しており、
また、暗い環境下では外部に設けた紫外線ランプを所望
時間点灯して照射した後消灯することによって、全体が
深みのある青白い発光をし、空間に浮かんでいるように
見えた。
The objects created in this way have an appearance almost similar to marble under daytime sunlight and bright diffused light.
In addition, in a dark environment, by turning on an external ultraviolet lamp for a desired period of time, then turning off the light, the entire structure emitted a deep blue-white light, making it appear as if it was floating in space.

更に、この造形物を屋外におき、紫外線ランプによる間
欠的な繰り返し照明を行ったところ、息づくような周期
的な発光をし、幻想的な美しさが惑じられた。
Furthermore, when this sculpture was placed outdoors and illuminated intermittently and repeatedly with an ultraviolet lamp, it emitted periodic light that seemed to be alive, giving it a mystical beauty.

また、この様な発光は、1年間の屋外曝露の後でも全く
変化が見られなかった。
Moreover, no change was observed in such luminescence even after one year of outdoor exposure.

〔実施例2] 白色大理石粉50重量部、硫化亜鉛系蓄光性顔料35重
量部、白色セメント25重量部、減水剤0.1重量部と
水15重量部の混合液を配合して、流動性の組成物を得
た。
[Example 2] A mixture of 50 parts by weight of white marble powder, 35 parts by weight of zinc sulfide luminous pigment, 25 parts by weight of white cement, 0.1 part by weight of water reducing agent and 15 parts by weight of water was blended to improve fluidity. A composition was obtained.

この組成物を実施例1と同様の手順で成形し、同様に直
付けして造形物を作った。
This composition was molded in the same manner as in Example 1, and directly applied in the same manner to create a shaped article.

この造形物は重量感があり、高い強度を有するものであ
り、殆ど同様な発光性を示した。
This shaped object had a heavy feel and high strength, and exhibited almost the same luminescence.

〔発明の効果〕〔Effect of the invention〕

本発明の造形用組成物は、大理石粉と蓄光性顔料とを不
飽和ポリエステル樹脂又は白色セメントによって結合し
たものであるから、硬化造形して得た造形物は光エネル
ギーを吸収して柔らかな発光を継続するものであり、観
察者に幻想的な印象を与えるので芸術的な彫刻や工芸品
、或いは建築用その他構造物構築のだめの部材、その他
者板や標識など種々の用途に利用できる効果がある。
Since the modeling composition of the present invention combines marble powder and luminescent pigment with unsaturated polyester resin or white cement, the shaped object obtained by hardening and modeling absorbs light energy and emits soft light. Since it gives a fantastic impression to the observer, it can be used for various purposes such as artistic sculptures and crafts, construction materials for architecture and other structures, and other purposes such as boards and signs. be.

Claims (2)

【特許請求の範囲】[Claims] (1)大理石粉40〜55重量部、蓄光性顔料5〜25
重量部、および不飽和ポリエステル樹脂35〜55重量
部ならびに有効量の増粘剤を含有することを特徴とする
造形用組成物。
(1) Marble powder 40-55 parts by weight, luminous pigment 5-25 parts
and 35 to 55 parts by weight of an unsaturated polyester resin and an effective amount of a thickener.
(2)大理石粉45〜50重量部、蓄光性顔料20〜4
0重量部、および白色セメント20〜40重量部ならび
に有効量の貼度調節剤と凝結用水を含有することを特徴
とする造形用組成物。
(2) Marble powder 45-50 parts by weight, luminous pigment 20-4
1. A modeling composition comprising 0 parts by weight of white cement, 20 to 40 parts by weight of white cement, and effective amounts of a patchiness regulator and setting water.
JP28340490A 1990-10-23 1990-10-23 Composition for shaping Pending JPH04159316A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP28340490A JPH04159316A (en) 1990-10-23 1990-10-23 Composition for shaping

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP28340490A JPH04159316A (en) 1990-10-23 1990-10-23 Composition for shaping

Publications (1)

Publication Number Publication Date
JPH04159316A true JPH04159316A (en) 1992-06-02

Family

ID=17665091

Family Applications (1)

Application Number Title Priority Date Filing Date
JP28340490A Pending JPH04159316A (en) 1990-10-23 1990-10-23 Composition for shaping

Country Status (1)

Country Link
JP (1) JPH04159316A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997024234A1 (en) * 1995-12-29 1997-07-10 Eduardo Huarte Erro Process for coating alabaster plates for ornamental purposes
EP1110996A1 (en) * 1999-12-24 2001-06-27 BUNDESDRUCKEREI GmbH Process and means for coding of thermoplastic plastic parts
JP2003523445A (en) * 2000-02-18 2003-08-05 オリオン 21 エイ.ディ.プロプライエタリイ リミテッド Luminescent gel coat and molding resin
CN104530674A (en) * 2014-12-18 2015-04-22 无锡伊诺永利文化创意有限公司 Formula for making sculpture

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS519121A (en) * 1974-07-12 1976-01-24 Tatsuo Ikeno JINZOOHATSUKOOSEKINO SEIZOOHOOHOO
JPS5230290A (en) * 1975-09-04 1977-03-07 Kawasaki Heavy Ind Ltd Apparatus for treatment of fused melt
JPS5843246A (en) * 1981-09-09 1983-03-12 Fuji Electric Co Ltd Overheat preventing device of sorter for non-magnetic metal
JPS6077158A (en) * 1983-09-30 1985-05-01 協和ガス化学工業株式会社 Luminescent resin concrete
JPS60137862A (en) * 1983-12-23 1985-07-22 協和ガス化学工業株式会社 Fluorescent tile
JPS6032341B2 (en) * 1978-11-30 1985-07-27 太陽誘電株式会社 Manufacturing method of cylindrical porcelain capacitor
JPS61120804A (en) * 1984-11-16 1986-06-07 Fukubi Kagaku Kogyo Kk Production of luminescent artificial stone molding
JPS61236645A (en) * 1985-04-11 1986-10-21 山本 恒太郎 Manufacture of refractory artificial rock
JPS6317783A (en) * 1986-07-07 1988-01-25 三菱電機株式会社 Winding device for elevator

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS519121A (en) * 1974-07-12 1976-01-24 Tatsuo Ikeno JINZOOHATSUKOOSEKINO SEIZOOHOOHOO
JPS5230290A (en) * 1975-09-04 1977-03-07 Kawasaki Heavy Ind Ltd Apparatus for treatment of fused melt
JPS6032341B2 (en) * 1978-11-30 1985-07-27 太陽誘電株式会社 Manufacturing method of cylindrical porcelain capacitor
JPS5843246A (en) * 1981-09-09 1983-03-12 Fuji Electric Co Ltd Overheat preventing device of sorter for non-magnetic metal
JPS6077158A (en) * 1983-09-30 1985-05-01 協和ガス化学工業株式会社 Luminescent resin concrete
JPS60137862A (en) * 1983-12-23 1985-07-22 協和ガス化学工業株式会社 Fluorescent tile
JPS61120804A (en) * 1984-11-16 1986-06-07 Fukubi Kagaku Kogyo Kk Production of luminescent artificial stone molding
JPS61236645A (en) * 1985-04-11 1986-10-21 山本 恒太郎 Manufacture of refractory artificial rock
JPS6317783A (en) * 1986-07-07 1988-01-25 三菱電機株式会社 Winding device for elevator

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997024234A1 (en) * 1995-12-29 1997-07-10 Eduardo Huarte Erro Process for coating alabaster plates for ornamental purposes
ES2102331A1 (en) * 1995-12-29 1997-07-16 Erro Eduardo Huarte Process for coating alabaster plates for ornamental purposes
EP1110996A1 (en) * 1999-12-24 2001-06-27 BUNDESDRUCKEREI GmbH Process and means for coding of thermoplastic plastic parts
JP2003523445A (en) * 2000-02-18 2003-08-05 オリオン 21 エイ.ディ.プロプライエタリイ リミテッド Luminescent gel coat and molding resin
CN104530674A (en) * 2014-12-18 2015-04-22 无锡伊诺永利文化创意有限公司 Formula for making sculpture

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