KR100691328B1 - Aluminum alloys for a form - Google Patents
Aluminum alloys for a form Download PDFInfo
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- KR100691328B1 KR100691328B1 KR1020060011592A KR20060011592A KR100691328B1 KR 100691328 B1 KR100691328 B1 KR 100691328B1 KR 1020060011592 A KR1020060011592 A KR 1020060011592A KR 20060011592 A KR20060011592 A KR 20060011592A KR 100691328 B1 KR100691328 B1 KR 100691328B1
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
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Description
도 1은 본 발명의 실시예 1에 따른 조직사진,1 is a tissue photograph according to Example 1 of the present invention,
도 2는 본 발명의 실시예 2에 따른 조직사진,2 is a tissue photograph according to Example 2 of the present invention,
도 3은 본 발명의 실시예 3에 따른 조직사진,3 is a tissue photograph according to a third embodiment of the present invention,
본 발명은 거푸집용 알루미늄 합금에 관한 것으로, 더욱 상세하게는, 압출성을 향상시켜 생산성을 높임과 동시에, 경량화를 기할 수 있도록 하고 Be의 사용으로 인하여 인장강도, 항복강도, 연신율, 경도(이하 "기계적 성질"이라 함)를 높일 수 있도록 한 거푸집용 알루미늄 합금을 제공하고자 하는 것이다.The present invention relates to an aluminum alloy for formwork, and more particularly, to improve the extrudability to increase the productivity, at the same time to reduce the weight, and due to the use of Be tensile strength, yield strength, elongation, hardness (hereinafter " It is intended to provide a die-cast aluminum alloy to increase the mechanical properties.
종래의 Al 합금은 적당한 압출성을 가지고, 시효 열처리 후, 미세한 석출물이 형성되어 강도가 높아지는 효과가 있다. 이에 대표적인 것으로는 Al-Mg-Si계 합금으로 A6061과 A6063 등이 알려져 있다.Conventional Al alloys have a moderate extrudability, and after aging heat treatment, fine precipitates are formed to have an effect of increasing strength. Representative examples of this are Al-Mg-Si-based alloys, such as A6061 and A6063.
상기 A6061 합금의 조성은 Si 0.4∼0.8 중량, Cu 0.15∼0.4 중량, Mg 0.8∼1.2중량, Cr 0.04∼0.35중량,나머지는 Al으로 이루어져 있고, A6063 합금의 조성은 Si 0.2∼0.6 중량, Cu 0.1 중량, Mg 0.45∼0.9 중량, Cr 0.1 중량, 나머지는 Al으 로 이루어져 있다. The composition of the A6061 alloy is 0.4 to 0.8 weight of Si, 0.15 to 0.4 weight of Cu, 0.8 to 1.2 weight of Mg, 0.04 to 0.35 weight of Cr, and the rest of Al. The composition of the A6063 alloy is 0.2 to 0.6 weight of Si and 0.1 to Cu. Weight, Mg 0.45 to 0.9 weight, Cr 0.1 weight, and the rest is Al.
그러나 상기 종래의 A6061 합금은 미세한 석출물을 이루는 Mg과 Si의 함유량이 A6063 합금보다 상대적으로 많아서 A6063 합금보다는 강도가 높은 합금을 얻을 수 있으나, 압출성이 A6063 합금보다는 떨어지는 문제점이 있고, 반대로 A6063 합금은 압출성이 우수하나, 강도가 높지 않아서 거푸집용으로 사용하는 데에는 한계가 있었다.However, the conventional A6061 alloy has a higher content of Mg and Si forming a fine precipitate than the A6063 alloy, so that an alloy having a higher strength than that of the A6063 alloy can be obtained. Although excellent extrudability, there was a limit to use for formwork because the strength is not high.
또한, 현재까지 여러 종류의 합금 알루미늄이 압출재(일본공개특허 평 7-70688, 평 6-287671, 평 7-41897 등)로 개발되었는데, 이들 모두도 압출성이 좋지 못하여 생산성 향상에 기여하지 못하는 문제점 있음은 물론, 기계적 성질 또는 기대치에 미치지 못하여 거푸집용으로 사용이 부적합한 문제점이 있었다.In addition, until now, various kinds of alloy aluminum have been developed as an extruded material (Japanese Patent Laid-Open No. 7-70688, Hei 6-287671, Hei 7-41897, etc.). Of course, there was a problem that the use is not suitable for the formwork did not meet the mechanical properties or expectations.
따라서, 근래에는 상기와 같은 문제점을 해소하고자 발명한 국내 특허공개공보 제2001-17742호(압출성이 우수한 고강도 알루미늄합금)가 있으며, 그의 구성을 살펴보면, Si : 0.64∼0.73 중량%, Mg : 0.27∼0.55 중량%, Mn : 0.27∼0.33 중량%, Cu : 0.4∼0.6 중량%, Zn : 0.13∼0.2 중량%, 불순물 Fe의 함유량은 0.5 중량%이하이고, 나머지는 Al으로 이루어진다.Therefore, in recent years there is a Korean Patent Publication No. 2001-17742 (high-strength aluminum alloy with excellent extrudability) invented to solve the above problems, looking at its configuration, Si: 0.64 ~ 0.73 wt%, Mg: 0.27 -0.55 weight%, Mn: 0.27-0.33 weight%, Cu: 0.4-0.6 weight%, Zn: 0.13-0.2 weight%, content of impurity Fe is 0.5 weight% or less, and remainder consists of Al.
상기와 같은 구성을 갖는 종래 국내 특허공개공보 제2001-17742호(압출성이 우수한 고강도 알루미늄합금) 역시 거푸집용으로 사용하기에는 기계적 성질이 기대치에 미치지 못하는 문제점이 있다. Conventional Korean Patent Publication No. 2001-17742 (high strength aluminum alloy with excellent extrudability) having the above configuration also has a problem that mechanical properties do not meet expectations for use in formwork.
본 발명은 상기와 같은 문제점을 감안하여 이를 해소하고자 발명한 것으로 서, 그 목적은 압출성을 향상시켜 생산성을 높임은 물론, 그 강도를 높임과 동시에, 경량화를 기하고 변형을 방지하여 거푸집용으로 사용하도록 한 거푸집용 알루미늄 합금을 제공함에 있다. The present invention has been invented to solve this problem in view of the above problems, the object of the present invention is to increase the productivity by increasing the extrudability, as well as to increase the strength, to reduce the weight and to prevent deformation to formwork It is to provide a die-cast aluminum alloy to be used.
상기 목적을 달성하기 위한 본 발명의 거푸집용 알루미늄 합금은, 주원료인 Al에 기계적 성질을 향상시키기 위한 소정 량의 Mg, Si, Mn, Fe, Cu, Be을 첨가하여 된 통상의 알루미늄 합금에 있어서,
상기 Mg : 0.65-0.80중량%, Si : 0.40-0.55중량%, Mn : 0.02-0.03중량%, Fe : 0.15-0.25중량%, Cu : 0.003-0.02, Be : 0.001-0.007중량%과, Cr : 0.01-0.007중량%, 나머지는 Al으로 이루어진다.In the aluminum alloy for formwork of the present invention for achieving the above object in a conventional aluminum alloy by adding a predetermined amount of Mg, Si, Mn, Fe, Cu, Be to improve the mechanical properties to Al, which is the main raw material,
Mg: 0.65-0.80% by weight, Si: 0.40-0.55% by weight, Mn: 0.02-0.03% by weight, Fe: 0.15-0.25% by weight, Cu: 0.003-0.02, Be: 0.001-0.007% by weight, and Cr: 0.01-0.007% by weight, the remainder being Al.
상기와 같은 특징을 갖는 본 발명의 거푸집용 알루미늄 합금을 형성하는 각 성분의 역할 및 사용범위 한정 이유에 대하여 상세하게 설명하면 다음과 같다.The role of each component forming the aluminum alloy for formwork of the present invention having the above characteristics and the reason for limiting the use range will be described in detail as follows.
Mg은 Al에 충분한 강도를 부여하는데 필요한 원소로서, 시효처리시 Si와 결합하여 석출상인 Mg2Si(마그네 실리케이트)금속간 화합물을 형성하여 강도를 향상시키는 것으로, 그 사용량이 0.65-0.80중량%인데, 0.65중량% 미만을 사용하게 되면 Si와 결합하여 강도 향상에 필요한 금속간화합물인 Mg2Si를 충분히 형성시키지 못하므로 효과가 낮고, 0.80중량%를 초과하게 되면 압출성이 떨어져 생산성을 저하시키는 문제점이 있다. 따라서, Mg은 0.65-0.80중량% 사용함이 바람직하다.Mg is an element necessary to give sufficient strength to Al. It combines with Si during aging treatment to form Mg 2 Si (magnesium silicate) intermetallic compound, which is a precipitated phase, and improves its strength. The amount of Mg is 0.65-0.80 wt%, which is 0.65. If less than% by weight is combined with Si, it is not effective enough to form Mg2Si, an intermetallic compound for strength improvement, and when the amount exceeds 0.80% by weight, there is a problem of lowering productivity due to low extrudability. Therefore, Mg is preferably used 0.65-0.80% by weight.
또한, Al-Mg계 합금에서는 Mg 함량이 증가함에 따라 적층 결함에너지 값이 낮아져서 부분 전위간의 거리가 넓어지고, 따라서 적층결함 영역이 넓어진다. 이러한 상태에서 재료에 변형을 가하면 전위의 교차슬립이 곤란하여 가공경화가 증대되며, 이 결과 변형이 균일하게 진행되어 결과적으로 연신율도 향상되게 된다.In addition, in the Al-Mg-based alloy, as the Mg content increases, the stacking defect energy value is lowered, so that the distance between the partial potentials is widened, and thus the stacking defect area is widened. In this state, if the material is deformed, cross-slip of dislocations is difficult and work hardening is increased. As a result, deformation proceeds uniformly, resulting in an improvement in elongation.
따라서, Mg은 0.65-0.80중량% 사용함이 바람직하다.Therefore, Mg is preferably used 0.65-0.80% by weight.
Si는 Mg와 함께 Al합금계를 구성하는 기본 원소로 시효처리시 Mg와 결합하여 Mg2Si를 형성하여 강도를 향상시키는 것으로, 그 사용량이 0.40-0.55중량%인데, 0.40중량% 미만을 사용하게 되면 Mg와 결합하여 강도 향상에 필요한 금속간 화합물인 Mg2Si를 충분히 형성시키지 못하므로 효과가 낮음은 물론, 합금재 표면에 나쁜 영향을 끼치게 되고, 0.55중량%를 초과하게 되면 압출성이 떨어져 생산성을 저하시키는 문제점이 있다. 따라서, Si는 0.45-0.55중량% 사용함이 바람직하다.Si is the basic element of Al alloy system with Mg, and it combines with Mg to form Mg2Si to improve strength during aging treatment. The amount of Si is 0.40-0.55% by weight. It does not form Mg2Si, which is an intermetallic compound necessary for strength improvement, in combination with, and it has a low effect and adversely affects the surface of the alloy material. There is this. Therefore, it is preferable to use 0.45-0.55 weight% of Si.
Mn은 Al과 결합하여 Al6Mn, Al12Mn등과 같은 분산상을 만들며, Al, Fe, Si 등과 결합하여 Al Fe Mn Si의 4원계 화합물을 형성한다. 이러한 분산상들은 시효처리전 기지(Matrix)안에 0.05~0.5㎛크기의 미세한 상으로 균일하게 분산되어 중강도 성형제품에 요구되는 기계적 특성을 나타내게 된다.Mn combines with Al to form a dispersed phase such as Al6Mn, Al12Mn, and the like, and combines with Al, Fe, Si, and the like to form a quaternary compound of Al Fe Mn Si. These dispersed phases are uniformly dispersed into a fine phase of 0.05-0.5 μm in matrix before aging treatment to exhibit the mechanical properties required for medium strength molded products.
또한, 시효처리를 실시하면 Mn계 분산상들은 합금 조직내에 미세하고 균일한 Mg2Si를 안정상인(αAl Fe Mn)Si 화합물의 위치에 석출 분산시켜 고속 성형시 3원 공정 융해에 의한 Pickup(성형재의 파단현상)을 억제시키고, 불안정상태의 βAl Fe Si상을 안정상인 α상으로의 변태를 촉진시켜 crack tip에 집중되는 응력을 완화시켜 주는 역할을 한다.In addition, aging treatment results in Mn-based dispersed phases precipitating and dispersing fine and uniform Mg 2 Si in the position of a stable phase (αAl Fe Mn) Si compound in the alloy structure. ), And promotes the transformation of the unstable βAl Fe Si phase to the stable α phase to relieve stress concentrated at the crack tip.
이와 같은 역할을 하는 Mn의 사용량은 0.02-0.03중량%인데, 0.02중량% 미만을 사용하게 되면 합금조직의 미세화효과가 낮아 강도향상의 효과가 낮고, 0.03중량%를 초과하게 되면 강도는 더 이상 향상되지 않고 오히려 강도를 저하시키는 작용을 하므로, Mn원소의 바람직한 첨가량은 0.02~0.03중량%로 제한한다.The amount of Mn that plays such a role is 0.02-0.03% by weight. When the amount of Mn used is less than 0.02% by weight, the effect of improving the strength is low due to the miniaturization effect of the alloy structure, and the strength is further improved when it exceeds 0.03% by weight. Rather than reducing the strength, the Mn element is preferably added in an amount of 0.02 to 0.03% by weight.
Fe는 Al 합금의 불순물로 함유되어 있으며, Al, Mn, Si 등과 결합하여 4원계 화합물을 형성하여 강도 향상시키는 것으로, 그 사용량은 0.15-0.25중량%인데, 0.25중량%를 초과하게 되면 압출성과 연성을 저하시키는 문제점이 있어 0.15-0.25중량%로 제한하였다.Fe is contained as an impurity of Al alloy, and combines with Al, Mn, Si, etc. to form quaternary compounds to improve strength. The amount used is 0.15-0.25% by weight. There is a problem to lower the limit to 0.15-0.25% by weight.
Cr은 재결정립을 미세화하고 조직을 균일하게 할 뿐만 아니라, 강도 향상에 필요한 원소로서, 그 사용량은 0.01-0.007중량%인데, 0.01중량% 초과하면 조대한 금속간 화합물을 형성시키므로, 연신율 저하와 아울러 강도가 떨어지는 문제점이 있고, 0.007중량% 미만을 사용하게 되면 효과가 거의 없다. 따라서, Cr의 조성범위는 0.007∼0.01중량%로 제한한다.Cr is an element necessary for miniaturizing the recrystallized grains and making the structure uniform, as well as an element used for improving the strength. The amount of Cr used is 0.01-0.007% by weight, and if it exceeds 0.01% by weight, Cr forms coarse intermetallic compounds. There is a problem that the strength falls, if less than 0.007% by weight is used, there is little effect. Therefore, the composition range of Cr is limited to 0.007 to 0.01 wt%.
Cu는 고용강화 및 인성을 증대시키기 위하여 사용되는 것으로, 그 사용량은 0.003-0.02중량%인데, 0.003중량% 미만을 사용하게 되면 고용간화 및 인성 증대가 일어나지 않고, 0.02중량%를 사용하게 되면 상기 고용강화 및 인성을 증대될 수 있으나, 압출 후 냉각과정에서 변형이 발생하는 문제점이 발생한다. 따라서, Cu는 0.003-0.02중량%를 사용함이 바람직하다.Cu is used to enhance solid solution and increase toughness. The amount of Cu used is 0.003-0.02% by weight. If less than 0.003% by weight of Cu is used, there is no increase in employment and toughness, and when 0.02% by weight of Cu is used, Although reinforcement and toughness may be increased, deformation occurs during cooling after extrusion. Therefore, it is preferable to use 0.003-0.02 weight% of Cu.
Be는 결정립의 조대화로 인한 강도증가 및 합금재의 변형을 방지하는 역할을 하는 것으로, 그 사용량은 0.001-0.007중량%인데, 0.001중량% 미만으로 사용하게 되면 결정립의 조대화가 정상적으로 일어나지 못해 목적하는 강도가 유지되지 못함은 물론, 변형이 발생하고, 0.007중량% 초과하게 되면 결정립의 조대화로 인한 강도의 증가는 기대할 수 있으나, 변형이 일어나지 않아 압출에 어려움이 따른다. 따라서, Be는 0.001-0.007중량% 사용함이 바람직하다.Be plays a role of preventing the increase in strength and deformation of the alloying material due to coarsening of grains. The amount of Be used is 0.001-0.007 wt%, but when used below 0.001 wt%, coarsening of grains does not occur normally. Of course, the strength is not maintained, the deformation occurs, if the amount exceeds 0.007% by weight can be expected to increase the strength due to the coarsening of the crystal grains, but the deformation does not occur, which leads to difficulty in extrusion. Therefore, Be is preferably used 0.001-0.007% by weight.
이하 본 발명을 실시예를 들어 상세하게 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail with reference to Examples.
[실시예 1]Example 1
실시예 1은 본 발명의 Al합금 원소의 조성비에 따른 기계적 성질을 알아보기 위하여 Mg : 0.72중량%, Si : 0.48중량%, Mn : 0.02중량%, Fe : 0.21중량%, Cr : 0.007중량%, Cu : 0.01중량%, Be : 0.0013중량%, 나머지는 Al으로 조성하고, 그를 통상의 방법에 의해 빌레트화 한 다음, 그 빌레트를 빌레트온도 490-530℃, 컨테이너온도 430-450℃, 금형온도 430-450℃, 출구온도 520-550℃, 냉각수온도 20-40℃, 압출속도 5.5-7m/분으로 하여 시편을 제조하였다.Example 1 is Mg: 0.72% by weight, Si: 0.48% by weight, Mn: 0.02% by weight, Fe: 0.21% by weight, Cr: 0.007% by weight, to determine the mechanical properties according to the composition ratio of the Al alloy element of the present invention, Cu: 0.01% by weight, Be: 0.0013% by weight, the remainder is made of Al, and billetized by the usual method, the billet is billet temperature 490-530 ℃, container temperature 430-450 ℃, mold temperature 430 Specimens were prepared at −450 ° C., outlet temperature 520-550 ° C., cooling water temperature 20-40 ° C., and extrusion rate 5.5-7 m / min.
상기 제조된 시편을 이용하여 기계적 성질을 측정해본 결과, 상기 실시예 1의 기계적 성질은 인장강도 296MPa, 항복강도 265MPa, 연신율 12%, 경도 99.1HV로 나타났다. 그리고, 상기 실시예 1의 조직사진은 도 1과 같이 나타났다.As a result of measuring the mechanical properties using the prepared specimens, the mechanical properties of Example 1 were found to be tensile strength 296MPa, yield strength 265MPa, elongation 12%, hardness 99.1HV. In addition, the tissue photograph of Example 1 is shown in FIG.
[실시예 2]Example 2
실시예 2는 본 발명의 Al합금 원소의 조성비에 따른 기계적 성질을 알아보기 위하여 Mg : 0.69중량%, Si : 0.47중량%, Mn : 0.02중량%, Fe : 0.23중량%, Cr : 0.001중량%, Cu : 0.003중량%, Be : 0.003중량%, 나머지는 Al으로 조성하고, 그를 통상의 방법에 의해 빌레트화 한 다음, 그 빌레트를 빌레트온도 490-530℃, 컨테이너온도 430-450℃, 금형온도 430-450℃, 출구온도 520-550℃, 냉각수온도 20-40℃, 압출속도 5.5-7m/분으로 하여 시편을 제조하였다.Example 2 Mg: 0.69% by weight, Si: 0.47% by weight, Mn: 0.02% by weight, Fe: 0.23% by weight, Cr: 0.001% by weight, to determine the mechanical properties according to the composition ratio of the Al alloy element of the present invention, Cu: 0.003% by weight, Be: 0.003% by weight, and the remainder is made of Al, and billetized by the usual method, the billet is billet temperature 490-530 ℃, container temperature 430-450 ℃, mold temperature 430 Specimens were prepared at −450 ° C., outlet temperature 520-550 ° C., cooling water temperature 20-40 ° C., and extrusion rate 5.5-7 m / min.
그 결과 상기 실시예 2의 기계적 성질은 인장강도 300MPa, 항복강도 274MPa, 연신율 11%, 강도 101HV로 나타났다. 그리고, 상기 실시예 2의 조직사진은 도 2와 같이 나타났다.As a result, the mechanical properties of Example 2 were shown to be 300MPa tensile strength, 274MPa yield strength, 11% elongation, 101HV strength. And, the organizational picture of Example 2 was shown as FIG.
[실시예 3]Example 3
실시예 3은 본 발명의 Al합금 원소의 조성비에 따른 기계적 성질을 알아보기 위하여 Mg : 0.73중량%, Si : 0.42중량%, Mn : 0.03중량%, Fe : 0.18중량%, Cr : 0.01중량%, Cu : 0.02중량%, Be : 0.007중량%, 나머지는 Al으로 조성하고, 그를 통상의 방법에 의해 빌레트화 한 다음, 그 빌레트를 빌레트온도 490-530℃, 컨테이너온도 430-450℃, 금형온도 430-450℃, 출구온도 520-550℃, 냉각수온도 20-40℃, 압출속도 5.5-7m/분으로 하여 시편을 제조하였다.Example 3 is Mg: 0.73% by weight, Si: 0.42% by weight, Mn: 0.03% by weight, Fe: 0.18% by weight, Cr: 0.01% by weight to determine the mechanical properties according to the composition ratio of the Al alloy element of the present invention, Cu: 0.02% by weight, Be: 0.007% by weight, the remainder is made of Al, and billetized by the usual method, and then the billet is billet temperature 490-530 ° C, container temperature 430-450 ° C, mold temperature 430 Specimens were prepared at −450 ° C., outlet temperature 520-550 ° C., cooling water temperature 20-40 ° C., and extrusion rate 5.5-7 m / min.
그 결과 상기 실시예 3의 기계적 성질은 인장강도 303MPa, 항복강도 279MPa, 연신율 10%, 강도 102.5HV로 나타났다. 그리고, 상기 실시예 3의 조직사진은 도 3과 같이 나타났다.As a result, the mechanical properties of Example 3 were found to be tensile strength 303MPa, yield strength 279MPa, elongation 10%, strength 102.5HV. And, the organizational picture of Example 3 is shown as FIG.
상기 실시예 1 내지 실시예 3에 나타낸 바와 같이, Be와 Mn 및 Cr의 함량이 많아질수록 인장강도, 내력, 강도는 좋아지고, 연신율은 저하됨을 알 수 있다.As shown in Examples 1 to 3, it can be seen that as the content of Be, Mn, and Cr increases, tensile strength, yield strength, and strength are improved, and elongation is decreased.
상술한 바와 같은 본 발명의 합금은 압출성의 향상으로 생산성을 높임은 물론, 그 강도 특성이 일반 스틸재와 비교할 만한 특성을 갖는 고강도이고, 변형이 낮기 때문에 거푸집으로 사용하기에 적합한 효과가 있다.As described above, the alloy of the present invention has an effect of being suitable for use as a formwork because of its high strength and low deformation, as well as its productivity due to the improvement of extrudability and its strength characteristics comparable to those of ordinary steel materials.
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US6607616B2 (en) * | 2000-06-27 | 2003-08-19 | Corus Aluminium Voerde Gmbh | Aluminum casting alloy |
US20040140022A1 (en) | 2003-01-22 | 2004-07-22 | Yasuo Inohana | Copper base alloy and method for producing same |
US20050173032A1 (en) | 2004-02-11 | 2005-08-11 | Hubert Koch | Casting of an aluminium alloy |
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US20040140022A1 (en) | 2003-01-22 | 2004-07-22 | Yasuo Inohana | Copper base alloy and method for producing same |
US20050173032A1 (en) | 2004-02-11 | 2005-08-11 | Hubert Koch | Casting of an aluminium alloy |
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