KR100648051B1 - 열팽창성 마이크로캡슐의 제조 방법 - Google Patents
열팽창성 마이크로캡슐의 제조 방법 Download PDFInfo
- Publication number
- KR100648051B1 KR100648051B1 KR1020027001527A KR20027001527A KR100648051B1 KR 100648051 B1 KR100648051 B1 KR 100648051B1 KR 1020027001527 A KR1020027001527 A KR 1020027001527A KR 20027001527 A KR20027001527 A KR 20027001527A KR 100648051 B1 KR100648051 B1 KR 100648051B1
- Authority
- KR
- South Korea
- Prior art keywords
- thermally expandable
- zirconium
- expandable microcapsules
- polymer
- producing
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/18—Suspension polymerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Manufacturing Of Micro-Capsules (AREA)
Abstract
Description
Claims (2)
- 에틸렌성 불포화 단량체를 중합하여 얻어진 중합체로서, 이 중합체의 연화 점 이하의 온도에서 가스상으로 되는 휘발성 팽창제를 마이크로캡슐화 하여 열팽창성 마이크로캡슐을 제조하는 방법에 있어서, 상기 중합체로서, 지르코늄 화합물, 염화티탄 및 황산티탄으로 되는 군으로부터 선택한 적어도 1종의 금속 화합물의 존재 하, 에틸렌성 불포화 단량체를 현탁중합하여 얻어진 중합체를 사용함을 특징으로 하는 열팽창성 마이크로캡슐의 제조 방법.
- 제1항에 있어서,상기 지르코늄 화합물이 황산지르코늄, 아세트산지르코늄, 염화지르코늄, 산화지르코늄 또는 질산지르코늄인 열팽창성 마이크로캡슐의 제조 방법.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP31419899 | 1999-09-29 | ||
JPJP-P-1999-00314198 | 1999-09-29 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20020026362A KR20020026362A (ko) | 2002-04-09 |
KR100648051B1 true KR100648051B1 (ko) | 2006-11-23 |
Family
ID=18050460
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020027001527A KR100648051B1 (ko) | 1999-09-29 | 2000-09-27 | 열팽창성 마이크로캡슐의 제조 방법 |
Country Status (6)
Country | Link |
---|---|
US (1) | US6365641B1 (ko) |
EP (1) | EP1230975B1 (ko) |
JP (1) | JP4633987B2 (ko) |
KR (1) | KR100648051B1 (ko) |
DE (1) | DE60029989T2 (ko) |
WO (1) | WO2001023081A1 (ko) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004155999A (ja) | 2002-11-08 | 2004-06-03 | Sekisui Chem Co Ltd | 熱膨張性マイクロカプセル |
KR101117521B1 (ko) * | 2003-11-19 | 2012-03-15 | 마쓰모토유시세이야쿠 가부시키가이샤 | 열팽창한 미소구, 그 제조방법, 열팽창성 미소구 및 용도 |
US7368167B2 (en) * | 2004-06-17 | 2008-05-06 | Henkel Corporation | Ultra low density thermally clad microspheres and method of making same |
WO2007046273A1 (ja) | 2005-10-20 | 2007-04-26 | Matsumoto Yushi-Seiyaku Co., Ltd. | 熱膨張性微小球およびその製造方法 |
EP1952881B1 (en) * | 2005-11-21 | 2017-01-18 | Matsumoto Yushi-Seiyaku Co., Ltd. | Process for producing heat-expandable microspheres |
US20070155859A1 (en) * | 2006-01-04 | 2007-07-05 | Zhengzhe Song | Reactive polyurethane hot melt adhesive |
US20070224395A1 (en) * | 2006-03-24 | 2007-09-27 | Rowitsch Robert W | Sprayable water-based adhesive |
EP2334721A4 (en) * | 2008-09-30 | 2013-09-25 | Henkel Corp | SHEAR AND / OR PRESSURE-RELATED MICROBALLS |
EP2367618A1 (en) | 2008-12-22 | 2011-09-28 | Akzo Nobel N.V. | Microspheres |
JP5839789B2 (ja) * | 2010-08-31 | 2016-01-06 | 積水化学工業株式会社 | 熱膨張性マイクロカプセルの製造方法 |
US9902829B2 (en) | 2012-05-30 | 2018-02-27 | Akzo Nobel Chemicals International B.V. | Microspheres |
EP2671716A1 (en) | 2012-06-08 | 2013-12-11 | Hexcel Composites SASU | Low density composite materials, their production and use |
US8679296B2 (en) | 2012-07-31 | 2014-03-25 | Kimberly-Clark Worldwide, Inc. | High bulk tissue comprising expandable microspheres |
KR20150052845A (ko) | 2012-09-07 | 2015-05-14 | 아크조 노벨 케미칼즈 인터내셔널 비.브이. | 팽창된 열가소성 미소구체의 제조 방법 및 제조 장치 |
WO2015098586A1 (ja) * | 2013-12-26 | 2015-07-02 | 松本油脂製薬株式会社 | 熱膨張性微小球の製造方法およびその利用 |
WO2016044013A1 (en) | 2014-09-16 | 2016-03-24 | Henkel IP & Holding GmbH | Use of hollow polymeric microspheres in composite materials requiring flame resistance |
US10214624B2 (en) | 2014-12-11 | 2019-02-26 | Akzo Nobel Chemicals International B.V. | Apparatus and method for expanding thermally expandable thermoplastic microspheres to expanded thermoplastic microspheres |
GB2558971A (en) | 2016-12-16 | 2018-07-25 | Formformform Ltd | Silicone elastomer composition |
CA3095670A1 (en) | 2018-04-05 | 2019-10-10 | Nouryon Chemicals International B.V. | Device for preparation of expanded microspheres |
EP3628710A1 (en) | 2018-09-26 | 2020-04-01 | Holland Novochem Technical Coatings B.V. | Coating composition |
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US3615972A (en) | 1967-04-28 | 1971-10-26 | Dow Chemical Co | Expansible thermoplastic polymer particles containing volatile fluid foaming agent and method of foaming the same |
JPS6019033A (ja) | 1983-07-12 | 1985-01-31 | Matsumoto Yushi Seiyaku Kk | 中空マイクロバル−ンおよびその製法 |
JPH06813B2 (ja) * | 1984-07-27 | 1994-01-05 | 三菱油化株式会社 | オレフイン重合体の製造法 |
JPS62172004A (ja) * | 1986-01-24 | 1987-07-29 | Mitsui Petrochem Ind Ltd | 重合方法 |
JPH04168200A (ja) * | 1990-10-30 | 1992-06-16 | Henkel Hakusui Kk | 革用柔軟充填剤 |
SE9003600L (sv) | 1990-11-12 | 1992-05-13 | Casco Nobel Ab | Expanderbara termoplastiska mikrosfaerer samt foerfarande foer framstaellning daerav |
JPH04239003A (ja) * | 1991-01-11 | 1992-08-26 | Kanegafuchi Chem Ind Co Ltd | 加工性に優れた塩化ビニル系樹脂の製造法 |
JP3659979B2 (ja) * | 1992-04-15 | 2005-06-15 | 松本油脂製薬株式会社 | 熱膨張性マイクロカプセルとその製法 |
JP3186835B2 (ja) * | 1992-05-28 | 2001-07-11 | 松本油脂製薬株式会社 | 熱膨張性マイクロカプセルおよびその製法と膨張方法 |
CA2092232C (en) * | 1992-09-10 | 2003-12-09 | Robert E. Miller | Latent image receiving sheet |
JPH06172407A (ja) * | 1992-12-07 | 1994-06-21 | Kanegafuchi Chem Ind Co Ltd | 塩化ビニル系樹脂の製造法 |
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JP3476223B2 (ja) | 1993-09-27 | 2003-12-10 | 松本油脂製薬株式会社 | マイクロカプセルの製法 |
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JP2761188B2 (ja) * | 1994-05-27 | 1998-06-04 | 株式会社日本触媒 | 乳化重合防止剤およびこれを用いた懸濁重合法 |
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JPH10101710A (ja) * | 1996-09-30 | 1998-04-21 | Sekisui Chem Co Ltd | 塩化ビニル系樹脂の懸濁重合方法 |
JP3392747B2 (ja) * | 1998-01-22 | 2003-03-31 | 三ツ星ベルト株式会社 | ゴム複合組成物 |
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-
2000
- 2000-09-27 DE DE60029989T patent/DE60029989T2/de not_active Expired - Lifetime
- 2000-09-27 KR KR1020027001527A patent/KR100648051B1/ko active IP Right Grant
- 2000-09-27 US US09/869,833 patent/US6365641B1/en not_active Expired - Lifetime
- 2000-09-27 JP JP2001526284A patent/JP4633987B2/ja not_active Expired - Lifetime
- 2000-09-27 WO PCT/JP2000/006660 patent/WO2001023081A1/ja active IP Right Grant
- 2000-09-27 EP EP00962884A patent/EP1230975B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US6365641B1 (en) | 2002-04-02 |
DE60029989T2 (de) | 2007-01-18 |
WO2001023081A1 (fr) | 2001-04-05 |
EP1230975A1 (en) | 2002-08-14 |
EP1230975B1 (en) | 2006-08-09 |
JP4633987B2 (ja) | 2011-02-16 |
DE60029989D1 (de) | 2006-09-21 |
EP1230975A4 (en) | 2003-07-16 |
KR20020026362A (ko) | 2002-04-09 |
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