KR100626258B1 - 4-, 5-, 6- 또는 7-위치에서 실록시 또는 게르밀옥시 기로치환된 인데닐 잔기를 함유하는 메탈로센 촉매 - Google Patents

4-, 5-, 6- 또는 7-위치에서 실록시 또는 게르밀옥시 기로치환된 인데닐 잔기를 함유하는 메탈로센 촉매 Download PDF

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Publication number
KR100626258B1
KR100626258B1 KR1020037016745A KR20037016745A KR100626258B1 KR 100626258 B1 KR100626258 B1 KR 100626258B1 KR 1020037016745 A KR1020037016745 A KR 1020037016745A KR 20037016745 A KR20037016745 A KR 20037016745A KR 100626258 B1 KR100626258 B1 KR 100626258B1
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South Korea
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catalyst
group
formula
hydrocarbyl
ligand
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Expired - Fee Related
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KR1020037016745A
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English (en)
Korean (ko)
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KR20040007747A (ko
Inventor
페터 에콜름
헨드리크 루티케데
안네 마라넨
안티 펜닌칸가스
카를-에릭 빌렌
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보레알리스 테크놀로지 오와이
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Priority claimed from GB0115370A external-priority patent/GB0115370D0/en
Priority claimed from GB0117629A external-priority patent/GB0117629D0/en
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Publication of KR20040007747A publication Critical patent/KR20040007747A/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
KR1020037016745A 2001-06-22 2002-06-21 4-, 5-, 6- 또는 7-위치에서 실록시 또는 게르밀옥시 기로치환된 인데닐 잔기를 함유하는 메탈로센 촉매 Expired - Fee Related KR100626258B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
GB0115370.9 2001-06-22
GB0115370A GB0115370D0 (en) 2001-06-22 2001-06-22 Catalysts
GB0117629A GB0117629D0 (en) 2001-07-19 2001-07-19 Catalysts
GB0117629.6 2001-07-19
PCT/GB2002/002853 WO2003000744A1 (en) 2001-06-22 2002-06-21 Metallocene catalysts containing an idenyl moiety substituted at the 4-, 5-, 6- or 7-position by a siloxy or germyloxy group

Publications (2)

Publication Number Publication Date
KR20040007747A KR20040007747A (ko) 2004-01-24
KR100626258B1 true KR100626258B1 (ko) 2006-09-21

Family

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Application Number Title Priority Date Filing Date
KR1020037016745A Expired - Fee Related KR100626258B1 (ko) 2001-06-22 2002-06-21 4-, 5-, 6- 또는 7-위치에서 실록시 또는 게르밀옥시 기로치환된 인데닐 잔기를 함유하는 메탈로센 촉매

Country Status (9)

Country Link
US (1) US7074863B2 (enExample)
EP (1) EP1401880B1 (enExample)
JP (1) JP2004532346A (enExample)
KR (1) KR100626258B1 (enExample)
CN (1) CN1269855C (enExample)
AT (1) ATE487744T1 (enExample)
BR (1) BR0210607B1 (enExample)
DE (1) DE60238256D1 (enExample)
WO (1) WO2003000744A1 (enExample)

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GB0118010D0 (en) * 2001-07-24 2001-09-19 Borealis Tech Oy Catalysts
EP1527176B2 (en) 2002-08-05 2017-03-22 Silence Therapeutics GmbH Further novel forms of interfering rna molecules
US8008412B2 (en) 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
GB0419851D0 (en) * 2004-09-07 2004-10-13 Borealis Tech Oy Catalysts
KR20060056712A (ko) * 2004-11-22 2006-05-25 삼성전자주식회사 포토리소그래피에 사용되는 바텀 레지스트용 폴리머 및 그제조 방법
US7446216B2 (en) 2004-12-16 2008-11-04 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
EP1739103A1 (en) 2005-06-30 2007-01-03 Borealis Technology Oy Catalyst
DE602005013376D1 (de) 2005-08-09 2009-04-30 Borealis Tech Oy Siloxy substituierte Metallocenkatalysatoren
US7538168B2 (en) 2005-12-14 2009-05-26 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
US7667064B2 (en) * 2005-12-14 2010-02-23 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
US7868197B2 (en) 2005-12-14 2011-01-11 Exxonmobil Chemical Patents Inc. Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization
US7763562B2 (en) 2005-12-14 2010-07-27 Exxonmobil Chemical Patents Inc. Heteroatom bridged metallocene compounds for olefin polymerization
US7550544B2 (en) 2005-12-14 2009-06-23 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
EP1803747A1 (en) 2005-12-30 2007-07-04 Borealis Technology Oy Surface-modified polymerization catalysts for the preparation of low-gel polyolefin films
US8242237B2 (en) 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
EP2160419B1 (en) 2007-06-04 2013-11-13 ExxonMobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization
EP2215129A2 (en) 2007-08-27 2010-08-11 Borealis Technology OY Catalysts
US7812104B2 (en) 2008-01-18 2010-10-12 Exxonmobil Chemical Patents Inc. Production of propylene-based polymers
US8318875B2 (en) 2008-01-18 2012-11-27 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
US7544825B1 (en) 2008-06-12 2009-06-09 Basell Polyolefine Gmbh Preparation of siloxy-bridged metallocenes
EP2330135B1 (en) 2009-12-02 2012-11-07 Borealis AG Process for producing polyolefins
US8058461B2 (en) 2010-03-01 2011-11-15 Exxonmobil Chemical Patents Inc. Mono-indenyl transition metal compounds and polymerization therewith
EP3184554B1 (en) * 2014-08-20 2019-09-04 Bridgestone Corporation Method for manufacturing conjugated diene polymer with modified end, conjugated diene polymer with modified end, rubber composition, and tire

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EP0537686B1 (de) * 1991-10-15 2005-01-12 Basell Polyolefine GmbH Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden
WO1993011258A1 (fr) 1991-11-29 1993-06-10 Bioxytech Procede de dosage de l'activite sod utilisant un compose autoxydable, necessaire pour sa mise en ×uvre, composes autoxydables et leur preparation
EP0582195B1 (de) * 1992-08-03 2000-12-20 TARGOR GmbH Verfahren zur Herstellung eines Olefinpolymers unter Verwendung spezieller Metallocene
ATE177436T1 (de) * 1992-08-15 1999-03-15 Targor Gmbh Verfahren zur herstellung von polyolefinen
WO1994028034A1 (en) 1993-05-25 1994-12-08 Exxon Chemical Patents Inc. Supported metallocene catalyst systems for the polymerization of olefins, preparation and use thereof
DE4330661A1 (de) * 1993-09-10 1995-03-16 Basf Ag Kälteschlagzähe Propylenpolymerisate
BR9508119A (pt) 1994-06-24 1997-08-12 Exxon Chemical Patents Inc Sistemas de catalisador de polimerização produção e uso dos mesmos
FI104975B (fi) 1995-04-12 2000-05-15 Borealis As Menetelmä katalyyttikomponenttien valmistamiseksi
IT1275408B (it) 1995-05-30 1997-08-05 Spherilene Spa Composti metallocenici bis-indenilici pontanti procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
FI104826B (fi) 1996-01-30 2000-04-14 Borealis As Heteroatomilla substituoituja metalloseeniyhdisteitä olefiinipolymerointikatalyytti-systeemejä varten ja menetelmä niiden valmistamiseksi
US5723632A (en) * 1996-08-08 1998-03-03 Mgi Pharma, Inc. Total synthesis of antitumor acylfulvenes
FI971565A7 (fi) 1997-04-14 1998-10-15 Borealis As Olefiinien polymerointiin tarkoitettujen katalysaattorisysteemien substituoituja metalloseeniyhdisteitä, niiden välituotteet ja valmistusmenetelmä

Also Published As

Publication number Publication date
DE60238256D1 (de) 2010-12-23
BR0210607B1 (pt) 2011-06-28
JP2004532346A (ja) 2004-10-21
KR20040007747A (ko) 2004-01-24
EP1401880B1 (en) 2010-11-10
BR0210607A (pt) 2004-09-28
US20040152882A1 (en) 2004-08-05
CN1269855C (zh) 2006-08-16
WO2003000744A1 (en) 2003-01-03
ATE487744T1 (de) 2010-11-15
CN1538975A (zh) 2004-10-20
US7074863B2 (en) 2006-07-11
EP1401880A1 (en) 2004-03-31

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