KR100501775B1 - 엔유-88제올라이트,이의제조방법및이의촉매로서의용도 - Google Patents

엔유-88제올라이트,이의제조방법및이의촉매로서의용도 Download PDF

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KR100501775B1
KR100501775B1 KR1019970039773A KR19970039773A KR100501775B1 KR 100501775 B1 KR100501775 B1 KR 100501775B1 KR 1019970039773 A KR1019970039773 A KR 1019970039773A KR 19970039773 A KR19970039773 A KR 19970039773A KR 100501775 B1 KR100501775 B1 KR 100501775B1
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zeolite
catalyst
formula
bis
reaction
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KR19980018830A (ko
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리어넬로 캐쉬 존
베나지 에릭
룰로 로익
매벌리 시나
패트릭 그레이엄 헨니 롤랜드
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앵스띠뛰 프랑세 뒤 뻬뜨롤
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8621—Removing nitrogen compounds
    • B01D53/8625—Nitrogen oxides
    • B01D53/8628—Processes characterised by a specific catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
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    • C01—INORGANIC CHEMISTRY
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    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
    • C01B39/082—Gallosilicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/2206—Catalytic processes not covered by C07C5/23 - C07C5/31
    • C07C5/222—Catalytic processes not covered by C07C5/23 - C07C5/31 with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/2708—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767—Changing the number of side-chains
    • C07C5/277—Catalytic processes
    • C07C5/2775—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/321—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/123—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
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    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
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    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
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    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1019970039773A 1996-08-23 1997-08-21 엔유-88제올라이트,이의제조방법및이의촉매로서의용도 Expired - Fee Related KR100501775B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR96/10507 1996-08-23
FR9610507A FR2752567B1 (fr) 1996-08-23 1996-08-23 Zeolithe nu-88, son procede de preparation et ses applications catalytiques

Publications (2)

Publication Number Publication Date
KR19980018830A KR19980018830A (ko) 1998-06-05
KR100501775B1 true KR100501775B1 (ko) 2005-11-08

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KR1019970039773A Expired - Fee Related KR100501775B1 (ko) 1996-08-23 1997-08-21 엔유-88제올라이트,이의제조방법및이의촉매로서의용도

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US (1) US6027707A (cg-RX-API-DMAC10.html)
EP (1) EP0825152B1 (cg-RX-API-DMAC10.html)
JP (1) JP4135121B2 (cg-RX-API-DMAC10.html)
KR (1) KR100501775B1 (cg-RX-API-DMAC10.html)
CN (1) CN1094792C (cg-RX-API-DMAC10.html)
CA (1) CA2212579C (cg-RX-API-DMAC10.html)
DE (1) DE69710006T2 (cg-RX-API-DMAC10.html)
FR (1) FR2752567B1 (cg-RX-API-DMAC10.html)
MY (1) MY114585A (cg-RX-API-DMAC10.html)

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FR2758810B1 (fr) * 1997-01-24 1999-02-19 Inst Francais Du Petrole Zeolithe im-5 desaluminee
FR2758817B1 (fr) * 1997-01-24 1999-09-03 Inst Francais Du Petrole Procede de craquage de charges hydrocarbonees a l'aide d'un catalyseur comprenant une zeolithe im-5 eventuellement desaluminee
FR2775200B1 (fr) * 1998-02-20 2000-04-28 Inst Francais Du Petrole Catalyseur comprenant une zeolithe nu-88, un element du groupe vb et son utilisation en hydroconversion de charges petrolieres hydrocarbonees
FR2775201B1 (fr) * 1998-02-20 2000-03-24 Inst Francais Du Petrole Catalyseur comprenant une zeolithe nu-88 et son utilisation en hydroconversion de charges petrolieres hydrocarbonees
ES2155761B1 (es) * 1998-12-22 2001-12-01 Univ Valencia Politecnica Zeolita itq-7.
ES2155797B1 (es) * 1999-07-29 2001-12-01 Univ Valencia Politecnica Zeolita itq-10
US6419895B1 (en) * 2000-11-03 2002-07-16 Uop Llc Crystalline aluminosilicate zeolitic composition: UZM-4
AU2002212580A1 (en) * 2000-11-03 2002-05-15 Uop Llc Uzm-5, uzm-5p and uzm-6; crystalline aluminosilicate zeolites and processes using the same
RU2273602C2 (ru) * 2000-11-03 2006-04-10 Юоп Ллк Uzm-5, uzm-5p и uzm-6: кристаллические алюмосиликатные цеолиты и процессы, использующие их
SG115433A1 (en) * 2001-12-06 2005-10-28 Uop Llc Uzm-5, uzm-5p and uzm-6: crystalline aluminosilicate zeolites and process using the same
US7455718B2 (en) * 2005-06-30 2008-11-25 Praxair Technology, Inc. Silver-exchanged zeolites and methods of manufacture therefor
ES2303787B2 (es) * 2007-02-01 2009-06-12 Universidad Politecnica De Valencia "material cristalino microporoso de naturaleza zeolitica, zeolita itq-39, procedimiento de preparacion y usos".
FR2914635B1 (fr) * 2007-04-05 2009-11-20 Inst Francais Du Petrole Procede de preparation d'une zeolithe de type structural mel
KR100979580B1 (ko) * 2008-02-05 2010-09-01 에스케이에너지 주식회사 경질올레핀 생산용 탄화수소 접촉 분해 촉매 및 그제조방법
JP5111309B2 (ja) 2008-09-09 2013-01-09 京セラドキュメントソリューションズ株式会社 用紙供給装置及びこれを搭載した画像形成装置
US7651677B1 (en) * 2008-09-12 2010-01-26 Exxonmobil Research And Engineering Co. Method of preparing SSZ-74
US8075871B2 (en) * 2008-11-25 2011-12-13 Chevron U.S.A. Inc. Method for making molecular sieve SSZ-83
US7998457B2 (en) * 2008-11-25 2011-08-16 Chevron U.S.A. Inc. Molecular sieve SSZ-83
CA2693582A1 (en) * 2009-02-27 2010-08-27 Chevron U.S.A. Inc. Synthesis of molecular sieve ssz-74 using a hydroxide-mediated gel
FR2968010B1 (fr) * 2010-11-25 2014-03-14 Ifp Energies Now Procede de conversion d'une charge lourde en distillat moyen
CA2844120C (en) * 2011-08-04 2019-07-02 Exxonmobil Chemical Patents Inc. Emm-23 molecular sieve material, its synthesis and use
US8900548B2 (en) 2011-10-12 2014-12-02 Exxonmobil Research And Engineering Company Synthesis of MSE-framework type molecular sieves
JP5906320B2 (ja) 2011-10-12 2016-04-20 エクソンモービル リサーチ アンド エンジニアリング カンパニーExxon Research And Engineering Company Mseフレームワーク型モレキュラーシーブの合成
WO2013096072A2 (en) * 2011-12-22 2013-06-27 Uop Llc Layered conversion synthesis of zeolites
JP6134335B2 (ja) * 2011-12-22 2017-05-24 ユーオーピー エルエルシー Uzm−39アルミケイ酸塩ゼオライト
EP2935101B1 (en) 2012-12-21 2016-12-21 ExxonMobil Chemical Patents Inc. Synthesis of zsm-5
US9108856B2 (en) * 2013-09-18 2015-08-18 Chevron U.S.A. Inc. Method for preparing CHA-type molecular sieves using colloidal aluminosilicate and novel structure directing agents
JP6661615B2 (ja) * 2014-09-03 2020-03-11 エクソンモービル リサーチ アンド エンジニアリング カンパニーExxon Research And Engineering Company 新規合成結晶材料のemm−26、その調製、およびその使用
CN106276950B (zh) * 2015-06-02 2018-11-30 中国石油化工股份有限公司 一种制备nu-88分子筛的方法
CN106276951B (zh) * 2015-06-09 2018-11-02 中国石油化工股份有限公司 一种合成nu-88分子筛的方法
CN107285330B (zh) * 2016-03-30 2019-04-16 中国石油化工股份有限公司 一种nu-88分子筛的制备方法
CN115140747B (zh) * 2021-03-30 2023-11-10 中国石油化工股份有限公司 一种颗粒状nu-88分子筛及其制备方法
CN116002701B (zh) * 2021-10-22 2025-11-14 中国石油化工股份有限公司 Nu-88分子筛及其制备方法和应用
FR3135265B1 (fr) 2022-05-06 2026-01-09 Totalenergies Onetech Procédé d’obtention d’hydrocarbures, et installation associée
FR3135263B1 (fr) 2022-05-06 2026-01-09 Totalenergies Onetech Procédé de fabrication d’un carburéacteur comprenant une étape de conversion d’un flux d’alcool dans un lit fluidisé, carburéacteur et installation associés
FR3135264B1 (fr) 2022-05-06 2026-01-09 Totalenergies Onetech Procédé de fabrication d’un carburéacteur, carburéacteur et installation associés

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KR19980018830A (ko) 1998-06-05
DE69710006T2 (de) 2002-11-14
US6027707A (en) 2000-02-22
CA2212579C (fr) 2006-10-17
FR2752567A1 (fr) 1998-02-27
EP0825152B1 (fr) 2002-01-23
CA2212579A1 (fr) 1998-02-23
DE69710006D1 (de) 2002-03-14
JPH10101327A (ja) 1998-04-21
CN1192944A (zh) 1998-09-16
EP0825152A1 (fr) 1998-02-25
CN1094792C (zh) 2002-11-27
JP4135121B2 (ja) 2008-08-20
MY114585A (en) 2002-11-30
FR2752567B1 (fr) 1998-10-16

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