KR100390121B1 - 디메틸 벤젠디카복실레이트를 상응하는 디메틸 사이클로헥산디카복실레이트로수소화시키기위한저압방법 - Google Patents

디메틸 벤젠디카복실레이트를 상응하는 디메틸 사이클로헥산디카복실레이트로수소화시키기위한저압방법 Download PDF

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Publication number
KR100390121B1
KR100390121B1 KR1019950705692A KR19950705692A KR100390121B1 KR 100390121 B1 KR100390121 B1 KR 100390121B1 KR 1019950705692 A KR1019950705692 A KR 1019950705692A KR 19950705692 A KR19950705692 A KR 19950705692A KR 100390121 B1 KR100390121 B1 KR 100390121B1
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South Korea
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dimethyl
palladium
catalyst
alumina
weight
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KR1019950705692A
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Korean (ko)
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KR960703099A (ko
Inventor
브루스 리로이 구스타프슨
브렌트 알란 테난트
엥 젠 쿠오
티모시 워렌 프라이스
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이스트만 케미칼 컴파니
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/303—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by hydrogenation of unsaturated carbon-to-carbon bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/892—Nickel and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/394—Metal dispersion value, e.g. percentage or fraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
KR1019950705692A 1993-06-15 1994-06-03 디메틸 벤젠디카복실레이트를 상응하는 디메틸 사이클로헥산디카복실레이트로수소화시키기위한저압방법 Expired - Lifetime KR100390121B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US076,575 1993-06-15
US08/076,675 US5286898A (en) 1993-06-15 1993-06-15 Low pressure process for the hydrogenation of dimethyl benzenedicarboxylates to the corresponding dimethyl cyclohexanedicarboxlates
US08/076675 1993-06-15

Publications (2)

Publication Number Publication Date
KR960703099A KR960703099A (ko) 1996-06-19
KR100390121B1 true KR100390121B1 (ko) 2003-11-13

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019950705692A Expired - Lifetime KR100390121B1 (ko) 1993-06-15 1994-06-03 디메틸 벤젠디카복실레이트를 상응하는 디메틸 사이클로헥산디카복실레이트로수소화시키기위한저압방법

Country Status (11)

Country Link
US (1) US5286898A (cg-RX-API-DMAC7.html)
EP (1) EP0703894B1 (cg-RX-API-DMAC7.html)
JP (1) JP3499557B2 (cg-RX-API-DMAC7.html)
KR (1) KR100390121B1 (cg-RX-API-DMAC7.html)
CN (1) CN1042327C (cg-RX-API-DMAC7.html)
CA (1) CA2165207C (cg-RX-API-DMAC7.html)
DE (1) DE69412827T2 (cg-RX-API-DMAC7.html)
ES (1) ES2120054T3 (cg-RX-API-DMAC7.html)
SG (1) SG47888A1 (cg-RX-API-DMAC7.html)
TW (1) TW265332B (cg-RX-API-DMAC7.html)
WO (1) WO1994029260A1 (cg-RX-API-DMAC7.html)

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KR101780405B1 (ko) * 2015-09-24 2017-09-20 롯데케미칼 주식회사 1,4-사이클로헥산디카르복실산의 제조 방법

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DE19927978A1 (de) * 1999-06-18 2000-12-21 Basf Ag Ausgewählte Cyclohexan-1,3- und 1,4-dicarbonsäureester
AU6369200A (en) * 1999-07-28 2001-02-19 Sud-Chemie, Inc. Hydrogenation catalysts
DE19939544C1 (de) 1999-08-20 2001-02-15 Haarmann & Reimer Gmbh Verfahren zur Herstellung von Methyl-cyclohexyl-propionat
DE10128242A1 (de) * 2001-06-11 2002-12-12 Basf Ag Verfahren zur Hydrierung organischer Verbindungen
DE10146869A1 (de) 2001-09-24 2003-04-24 Oxeno Olefinchemie Gmbh Alicyclische Polycarbonsäureestergemische mit hohem trans-Anteil und Verfahren zu deren Herstellung
CN102408646A (zh) 2001-09-25 2012-04-11 埃克森美孚化学专利公司 增塑聚氯乙烯
US6803341B2 (en) * 2002-01-18 2004-10-12 Chinese Petroleum Corporation Method of a high stability selectable hydrogenate catalyst producing and using for DMCHD manufacturing
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DE102004063673A1 (de) * 2004-12-31 2006-07-13 Oxeno Olefinchemie Gmbh Verfahren zur kontinuierlichen katalytischen Hydrierung von hydrierbaren Verbindungen an festen, im Festbett angeordneten Katalysatoren mit einem wasserstoffhaltigen Gas
DE102004063637A1 (de) 2004-12-31 2006-07-13 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von alicyclischen Carbonsäuren oder deren Derivaten
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CN102381976B (zh) * 2010-09-01 2013-09-04 中国石油天然气股份有限公司 一种制备1，4-环己烷二甲酸二甲酯的方法
CN102476052A (zh) * 2010-11-29 2012-05-30 中国石油化工股份有限公司 一种负载型钌催化剂及其制备方法
CN102796001A (zh) * 2011-05-25 2012-11-28 江苏恒祥化工有限责任公司 无溶剂制备1，4-环己烷二甲酸二甲酯
TWI421240B (zh) 2011-12-12 2014-01-01 Ind Tech Res Inst 苯多羧酸或其衍生物形成環己烷多元酸酯之氫化方法
CN102631925B (zh) * 2012-03-30 2015-03-25 中国科学院山西煤炭化学研究所 一种苯羧酸酯加氢催化剂及其制备方法和应用
ITMI20121641A1 (it) 2012-10-02 2014-04-03 Polynt S P A Procedimento per l'idrogenazione di esteri di acidi carbossilici aromatici a dare loro omologhi saturi, nuovi usi per detti omologhi, e nuove miscele polimeriche plastificate.
EP2716623A1 (de) 2012-10-05 2014-04-09 Basf Se Verfahren zur Herstellung von Cyclohexanpolycarbonsäure-Derivaten mit geringem Nebenproduktanteil
US9090553B2 (en) 2012-10-05 2015-07-28 Basf Se Process for preparing cyclohexanepolycarboxylic acid derivatives having a low proportion of by-products
CN102921409A (zh) * 2012-10-26 2013-02-13 中国海洋石油总公司 一种加氢生产1,2环己烷二羧酸酯的催化剂的制法
CN102935365B (zh) * 2012-11-12 2014-12-03 中国石油化工股份有限公司 一种制备1，4-环己烷二甲酸二甲酯的催化剂及方法
CN103157468A (zh) * 2013-03-14 2013-06-19 北京化工大学 一种低含量负载型钌-钯双金属加氢催化剂及其制备方法
CN104649864A (zh) * 2013-11-19 2015-05-27 中国石油天然气股份有限公司 一种对苯二甲酸二烷基酯加氢生产1,4-环己烷二甲醇的方法
US9340482B2 (en) 2013-12-30 2016-05-17 Eastman Chemical Company Processes for making cyclohexane compounds
US9346737B2 (en) 2013-12-30 2016-05-24 Eastman Chemical Company Processes for making cyclohexane compounds
US9328050B1 (en) 2014-12-23 2016-05-03 Eastman Chemical Company Processes for making hydroxymethylbenzoic acid compounds
KR101905165B1 (ko) * 2015-04-01 2018-10-05 한화케미칼 주식회사 프탈레이트 화합물의 수소화 촉매의 재생 방법
TWI577658B (zh) * 2015-05-06 2017-04-11 中國石油化學工業開發股份有限公司 １，４－環己烷二甲酸二甲酯及１，４－環己烷二甲醇之製法
CN106866415A (zh) * 2015-12-12 2017-06-20 中国科学院大连化学物理研究所 一种脂环族羧酸酯的制造方法
CN109562355A (zh) 2016-08-18 2019-04-02 芝加哥大学 用于高效有机转化的金属氧化物负载的地球丰富的金属催化剂
KR101883993B1 (ko) * 2016-09-29 2018-07-31 롯데케미칼 주식회사 1,3-사이클로헥산디카르복시산의 제조 방법
FR3059252B1 (fr) * 2016-11-29 2018-11-16 IFP Energies Nouvelles Catalyseur d’hydrogenation selective de coupes c3 de vapocraquage et/ou de craquage catalytique
FR3059253B1 (fr) * 2016-11-29 2020-01-17 IFP Energies Nouvelles Catalyseur d'hydrogenation selective d'une coupe d'hydrocarbures c3.
KR102506281B1 (ko) * 2017-11-29 2023-03-06 한화솔루션 주식회사 프탈레이트 화합물의 수소화 방법
TWI684585B (zh) * 2018-11-14 2020-02-11 中國石油化學工業開發股份有限公司 １,４-環己烷二甲酸二甲酯之製法
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KR101780405B1 (ko) * 2015-09-24 2017-09-20 롯데케미칼 주식회사 1,4-사이클로헥산디카르복실산의 제조 방법

Also Published As

Publication number Publication date
CN1099745A (zh) 1995-03-08
US5286898A (en) 1994-02-15
CA2165207C (en) 1998-08-18
JPH08511775A (ja) 1996-12-10
CA2165207A1 (en) 1994-12-22
EP0703894B1 (en) 1998-08-26
SG47888A1 (en) 1998-04-17
ES2120054T3 (es) 1998-10-16
KR960703099A (ko) 1996-06-19
JP3499557B2 (ja) 2004-02-23
DE69412827T2 (de) 1999-01-14
EP0703894A1 (en) 1996-04-03
CN1042327C (zh) 1999-03-03
WO1994029260A1 (en) 1994-12-22
TW265332B (cg-RX-API-DMAC7.html) 1995-12-11
DE69412827D1 (de) 1998-10-01

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