KR100227004B1 - 고속방사 폴리에테르 계스판 덱스 - Google Patents
고속방사 폴리에테르 계스판 덱스 Download PDFInfo
- Publication number
- KR100227004B1 KR100227004B1 KR1019950704250A KR19950704250A KR100227004B1 KR 100227004 B1 KR100227004 B1 KR 100227004B1 KR 1019950704250 A KR1019950704250 A KR 1019950704250A KR 19950704250 A KR19950704250 A KR 19950704250A KR 100227004 B1 KR100227004 B1 KR 100227004B1
- Authority
- KR
- South Korea
- Prior art keywords
- spandex
- mixture
- glycol
- diamine
- sample
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000009987 spinning Methods 0.000 title claims description 15
- 229920000570 polyether Polymers 0.000 title claims description 13
- 239000004721 Polyphenylene oxide Substances 0.000 title claims description 12
- SPBDXSGPUHCETR-JFUDTMANSA-N 8883yp2r6d Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O[C@@H]([C@@H](C)CC4)C(C)C)O3)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1C[C@H](C)[C@@H]([C@@H](C)CC)O[C@@]21O[C@H](C\C=C(C)\[C@@H](O[C@@H]1O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C1)[C@@H](C)\C=C\C=C/1[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\1)O)C[C@H]4C2 SPBDXSGPUHCETR-JFUDTMANSA-N 0.000 title 1
- 229920002334 Spandex Polymers 0.000 claims abstract description 90
- 239000004759 spandex Substances 0.000 claims abstract description 90
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims abstract description 44
- 239000000203 mixture Substances 0.000 claims abstract description 40
- 150000004985 diamines Chemical class 0.000 claims abstract description 26
- 238000000034 method Methods 0.000 claims abstract description 25
- 229920003226 polyurethane urea Polymers 0.000 claims abstract description 17
- 238000000578 dry spinning Methods 0.000 claims abstract description 12
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 claims abstract description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 50
- 229920000642 polymer Polymers 0.000 claims description 30
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 25
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 21
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 20
- 238000004804 winding Methods 0.000 claims description 11
- 229920001577 copolymer Polymers 0.000 claims description 10
- 239000012948 isocyanate Substances 0.000 claims description 10
- 150000002513 isocyanates Chemical class 0.000 claims description 10
- 125000005442 diisocyanate group Chemical group 0.000 claims description 8
- 239000004970 Chain extender Substances 0.000 claims description 7
- 125000004427 diamine group Chemical group 0.000 claims description 7
- LJPCNSSTRWGCMZ-UHFFFAOYSA-N 3-methyloxolane Chemical compound CC1CCOC1 LJPCNSSTRWGCMZ-UHFFFAOYSA-N 0.000 claims description 5
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 5
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 5
- 150000002334 glycols Chemical class 0.000 claims description 4
- 239000004753 textile Substances 0.000 claims description 4
- 125000003827 glycol group Chemical group 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- JZUHIOJYCPIVLQ-UHFFFAOYSA-N 2-methylpentane-1,5-diamine Chemical compound NCC(C)CCCN JZUHIOJYCPIVLQ-UHFFFAOYSA-N 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 7
- 239000004677 Nylon Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- 229920001778 nylon Polymers 0.000 description 5
- 210000000988 bone and bone Anatomy 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 150000002009 diols Chemical class 0.000 description 3
- 238000009998 heat setting Methods 0.000 description 3
- 238000009940 knitting Methods 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000011120 plywood Substances 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- SQHUBVCIVAIUAB-UHFFFAOYSA-N 2-hydroxy-2-methylpropanedial Chemical compound O=CC(O)(C)C=O SQHUBVCIVAIUAB-UHFFFAOYSA-N 0.000 description 2
- KZMGYPLQYOPHEL-UHFFFAOYSA-N Boron trifluoride etherate Chemical compound FB(F)F.CCOCC KZMGYPLQYOPHEL-UHFFFAOYSA-N 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 238000007429 general method Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- SBPIDKODQVLBGV-UHFFFAOYSA-N 1h-imidazole;pyridine Chemical compound C1=CNC=N1.C1=CC=NC=C1 SBPIDKODQVLBGV-UHFFFAOYSA-N 0.000 description 1
- XHJGXOOOMKCJPP-UHFFFAOYSA-N 2-[tert-butyl(2-hydroxyethyl)amino]ethanol Chemical compound OCCN(C(C)(C)C)CCO XHJGXOOOMKCJPP-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- IAZDPXIOMUYVGZ-WFGJKAKNSA-N Dimethyl sulfoxide Chemical class [2H]C([2H])([2H])S(=O)C([2H])([2H])[2H] IAZDPXIOMUYVGZ-WFGJKAKNSA-N 0.000 description 1
- -1 MPMD diamine Chemical class 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 210000001072 colon Anatomy 0.000 description 1
- 238000004590 computer program Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- SSJXIUAHEKJCMH-UHFFFAOYSA-N cyclohexane-1,2-diamine Chemical compound NC1CCCCC1N SSJXIUAHEKJCMH-UHFFFAOYSA-N 0.000 description 1
- GEQHKFFSPGPGLN-UHFFFAOYSA-N cyclohexane-1,3-diamine Chemical compound NC1CCCC(N)C1 GEQHKFFSPGPGLN-UHFFFAOYSA-N 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical compound C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 125000001664 diethylamino group Chemical group [H]C([H])([H])C([H])([H])N(*)C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000010191 image analysis Methods 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 150000004988 m-phenylenediamines Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
- 150000004987 o-phenylenediamines Chemical class 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001447 polyvinyl benzene Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- WHRNULOCNSKMGB-UHFFFAOYSA-N tetrahydrofuran thf Chemical compound C1CCOC1.C1CCOC1 WHRNULOCNSKMGB-UHFFFAOYSA-N 0.000 description 1
- 238000001029 thermal curing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/70—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4858—Polyethers containing oxyalkylene groups having more than four carbon atoms in the alkylene group
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
- Polyethers (AREA)
- Polyurethanes Or Polyureas (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/042,342 | 1993-04-02 | ||
| US08/042,342 US5362432A (en) | 1993-04-02 | 1993-04-02 | Process for dry spinning spandex |
| US8/042342 | 1993-04-02 | ||
| PCT/US1994/003670 WO1994023100A1 (en) | 1993-04-02 | 1994-04-04 | High-speed spun polyether-based spandex |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR960702021A KR960702021A (ko) | 1996-03-28 |
| KR100227004B1 true KR100227004B1 (ko) | 1999-10-15 |
Family
ID=21921359
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019950704250A Expired - Lifetime KR100227004B1 (ko) | 1993-04-02 | 1994-04-04 | 고속방사 폴리에테르 계스판 덱스 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5362432A (enExample) |
| EP (1) | EP0692039B1 (enExample) |
| JP (1) | JP3565853B2 (enExample) |
| KR (1) | KR100227004B1 (enExample) |
| BR (1) | BR9405849A (enExample) |
| DE (1) | DE69401749T2 (enExample) |
| TW (1) | TW272999B (enExample) |
| WO (1) | WO1994023100A1 (enExample) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011081447A3 (ko) * | 2009-12-31 | 2011-12-01 | 주식회사 효성 | 고속방사용 폴리우레탄우레아 탄성사의 제조방법 |
| KR101262775B1 (ko) | 2006-12-29 | 2013-05-09 | 주식회사 효성 | 무기물 안정화가 우수한 폴리우레탄우레아 탄성사 |
| KR101578156B1 (ko) * | 2015-07-31 | 2015-12-28 | 주식회사 효성 | 파워 및 균제도가 우수한 폴리우레탄우레아 탄성사 및 이의 제조방법 |
| KR101638164B1 (ko) * | 2015-07-31 | 2016-07-11 | 주식회사 효성 | 질소 방사를 이용한 폴리우레탄우레아 탄성사 및 이의 제조방법 |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4973647A (en) * | 1989-05-31 | 1990-11-27 | E. I. Du Pont De Nemours And Company | Fiber from polyether-based spandex |
| JPH08113824A (ja) * | 1994-10-19 | 1996-05-07 | Toyobo Co Ltd | 熱セット性の改善されたポリウレタン弾性糸 |
| KR0134656B1 (ko) * | 1994-10-22 | 1998-04-20 | 박홍기 | 점도 안정성이 우수한 폴리우레탄계 탄성중합체의 제조방법 |
| JP3717186B2 (ja) * | 1995-06-23 | 2005-11-16 | 旭化成せんい株式会社 | ポリウレタン弾性繊維及びその製造方法 |
| US6214145B1 (en) * | 1996-07-24 | 2001-04-10 | Dupont Toray Co., Ltd. | Coalesced multifilament spandex and method for its preparation |
| US5644015A (en) * | 1996-07-24 | 1997-07-01 | Hyosung T & C Co., Ltd. | Process of manufacturing improved polyurethane fiber polymer |
| CN1065294C (zh) * | 1996-09-24 | 2001-05-02 | 烟台氨纶股份有限公司 | 一种聚醚型易染氨纶丝的制造方法 |
| DE69802521T2 (de) * | 1997-09-03 | 2002-06-27 | Du Pont-Toray Co. Ltd., Tokio/Tokyo | Herstellungsverfahren für spandex und das so hergestellte spandex |
| US6399003B1 (en) * | 1997-09-03 | 2002-06-04 | Dupont-Toray Co. Ltd. | Process for making melt-spun spandex |
| GB9721588D0 (en) | 1997-10-10 | 1997-12-10 | Du Pont | Textile treatment |
| US5981686A (en) * | 1998-03-26 | 1999-11-09 | E. I. Du Pont De Nemours And Company | Spandex made with 1,3-diaminopentane |
| US6063892A (en) * | 1999-10-05 | 2000-05-16 | E. I. Du Pont De Nemours And Company | Spandex prepared with hindered diisocyanates |
| TW589421B (en) * | 2000-04-26 | 2004-06-01 | Du Pont | Spandex with high heat-set efficiency |
| EP1356144A1 (en) * | 2000-12-20 | 2003-10-29 | DuPont-Toray Co. Ltd. | Elastomeric polyurethane fiber with high heat-set efficiency |
| JP2004526069A (ja) * | 2001-04-19 | 2004-08-26 | コーロン インダストリーズ インク | ポリウレタン系弾性繊維およびその製造方法 |
| RU2294335C2 (ru) | 2001-07-24 | 2007-02-27 | Рэдисиспандекс Корпорейшн | Усовершенствованный состав спандекса |
| US6984708B2 (en) * | 2002-10-04 | 2006-01-10 | Invista North America S.A.R.L. | Spandex of a particular composition and process for making same |
| KR100598870B1 (ko) * | 2003-11-25 | 2006-07-10 | 태광산업주식회사 | 내열성과 세트성이 우수한 폴리우레탄우레아 탄성섬유 및그의 제조방법 |
| DE102004029274A1 (de) * | 2004-06-17 | 2006-01-05 | Dorlastan Fibers & Monofil Gmbh | Gegen Farbänderung geschützte chlorbeständige Elastanfasern |
| US8138283B2 (en) * | 2007-01-19 | 2012-03-20 | Basf Se | Method for changing the predefined mean molecular weight Mn during the continuous production of polytetrahydrofuranes or THF copolymers |
| US20180305842A1 (en) * | 2015-06-30 | 2018-10-25 | Invista North America S.A R.L. | Polyurethane fiber including copolymer polyol |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03279415A (ja) * | 1990-03-27 | 1991-12-10 | Toyobo Co Ltd | ポリウレタン弾性繊維 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL288240A (enExample) * | 1963-11-08 | |||
| JPS58194915A (ja) * | 1982-05-10 | 1983-11-14 | Fuji Boseki Kk | ポリウレタン弾性体の製造方法 |
| US5000899A (en) * | 1988-05-26 | 1991-03-19 | E. I. Du Pont De Nemours And Company | Spandex fiber with copolymer soft segment |
| US4973647A (en) * | 1989-05-31 | 1990-11-27 | E. I. Du Pont De Nemours And Company | Fiber from polyether-based spandex |
-
1993
- 1993-04-02 US US08/042,342 patent/US5362432A/en not_active Expired - Lifetime
-
1994
- 1994-03-14 TW TW083102187A patent/TW272999B/zh not_active IP Right Cessation
- 1994-04-04 KR KR1019950704250A patent/KR100227004B1/ko not_active Expired - Lifetime
- 1994-04-04 EP EP94912946A patent/EP0692039B1/en not_active Expired - Lifetime
- 1994-04-04 DE DE69401749T patent/DE69401749T2/de not_active Expired - Lifetime
- 1994-04-04 JP JP52245094A patent/JP3565853B2/ja not_active Expired - Lifetime
- 1994-04-04 BR BR9405849A patent/BR9405849A/pt not_active IP Right Cessation
- 1994-04-04 WO PCT/US1994/003670 patent/WO1994023100A1/en not_active Ceased
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03279415A (ja) * | 1990-03-27 | 1991-12-10 | Toyobo Co Ltd | ポリウレタン弾性繊維 |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101262775B1 (ko) | 2006-12-29 | 2013-05-09 | 주식회사 효성 | 무기물 안정화가 우수한 폴리우레탄우레아 탄성사 |
| WO2011081447A3 (ko) * | 2009-12-31 | 2011-12-01 | 주식회사 효성 | 고속방사용 폴리우레탄우레아 탄성사의 제조방법 |
| KR101148302B1 (ko) | 2009-12-31 | 2012-05-25 | 주식회사 효성 | 고속방사용 폴리우레탄우레아 탄성사의 제조방법 |
| KR101578156B1 (ko) * | 2015-07-31 | 2015-12-28 | 주식회사 효성 | 파워 및 균제도가 우수한 폴리우레탄우레아 탄성사 및 이의 제조방법 |
| KR101638164B1 (ko) * | 2015-07-31 | 2016-07-11 | 주식회사 효성 | 질소 방사를 이용한 폴리우레탄우레아 탄성사 및 이의 제조방법 |
| WO2017022946A1 (ko) * | 2015-07-31 | 2017-02-09 | (주)효성 | 파워 및 균제도가 우수한 폴리우레탄우레아 탄성사 및 이의 제조방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| KR960702021A (ko) | 1996-03-28 |
| DE69401749T2 (de) | 1997-09-04 |
| WO1994023100A1 (en) | 1994-10-13 |
| EP0692039B1 (en) | 1997-02-12 |
| DE69401749D1 (de) | 1997-03-27 |
| TW272999B (enExample) | 1996-03-21 |
| EP0692039A1 (en) | 1996-01-17 |
| US5362432A (en) | 1994-11-08 |
| JPH08508552A (ja) | 1996-09-10 |
| BR9405849A (pt) | 1995-12-26 |
| JP3565853B2 (ja) | 2004-09-15 |
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