JPWO2020136622A5 - - Google Patents
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- JPWO2020136622A5 JPWO2020136622A5 JP2021538091A JP2021538091A JPWO2020136622A5 JP WO2020136622 A5 JPWO2020136622 A5 JP WO2020136622A5 JP 2021538091 A JP2021538091 A JP 2021538091A JP 2021538091 A JP2021538091 A JP 2021538091A JP WO2020136622 A5 JPWO2020136622 A5 JP WO2020136622A5
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Claims (30)
前記第1の表面下レーザ・ダメージ・パターンの形成後に、第2の複数の実質的に平行な線を備える第2の表面下レーザ・ダメージ・パターンを有する表面下レーザ・ダメージを形成するために、前記結晶材料の前記内部に集束されるレーザ放射を供給し、前記レーザと前記基板との間の横方向相対移動を実行させることと、を含み、
前記第1の表面下レーザ・ダメージ・パターンは、前記結晶材料の前記内部に、前記第1の複数の実質的に平行な線の線から横方向外向きに伝播する第1の複数のクラックを形成し、
前記第2の表面下レーザ・ダメージ・パターンは、前記結晶材料の前記内部に、前記第2の複数の実質的に平行な線の線から横方向外向きに伝播する第2の複数のクラックを形成し、
前記第2の複数の実質的に平行な線の線は、前記第1の複数の実質的に平行な線の線同士の間に分散され、
前記第2の複数の実質的に平行な線の少なくともいくつかの線は、前記第1の複数の実質的に平行な線のうちのどの線とも交差しない、
結晶材料加工方法。 laser radiation focused within the crystalline material of the substrate to form subsurface laser damage having a first subsurface laser damage pattern comprising a first plurality of substantially parallel lines; providing and effecting lateral relative movement between the laser and the substrate;
to form subsurface laser damage having a second subsurface laser damage pattern comprising a second plurality of substantially parallel lines after forming the first subsurface laser damage pattern; , providing laser radiation focused into the interior of the crystalline material to effect lateral relative movement between the laser and the substrate;
The first subsurface laser damage pattern causes a first plurality of cracks in the interior of the crystalline material propagating laterally outwardly from a line of the first plurality of substantially parallel lines. form,
The second subsurface laser damage pattern causes a second plurality of cracks in the interior of the crystalline material propagating laterally outward from a line of the second plurality of substantially parallel lines. form,
the lines of the second plurality of substantially parallel lines are dispersed between the lines of the first plurality of substantially parallel lines;
at least some of the second plurality of substantially parallel lines do not intersect any of the first plurality of substantially parallel lines;
Crystal material processing method.
前記第1の複数の実質的に平行な線の各線および前記第2の複数の実質的に平行な線の各線は、前記六方晶構造の<11-20>方向に対する垂直方向から±5度以内にあり、かつ前記基板の表面と実質的に平行である、
請求項1に記載の結晶材料加工方法。 said crystalline material having a hexagonal crystal structure;
Each line of the first plurality of substantially parallel lines and each line of the second plurality of substantially parallel lines is within ±5 degrees from a direction perpendicular to the <11-20> direction of the hexagonal crystal structure and substantially parallel to the surface of the substrate;
The method of processing a crystalline material according to claim 1 .
前記第3の複数の実質的に平行な線のうちの少なくともいくつかの線は、前記第1の複数の実質的に平行な線および前記第2の複数の実質的に平行な線の線同士の間に分散される、
請求項1に記載の結晶材料加工方法。 a third subsurface laser damage pattern comprising a third plurality of substantially parallel lines after formation of said first subsurface laser damage pattern and said second subsurface laser damage pattern; providing laser radiation focused into the interior of the crystalline material and effecting lateral relative movement between the laser and the substrate to form a subsurface laser damage having
At least some of the third plurality of substantially parallel lines are aligned between the first plurality of substantially parallel lines and the second plurality of substantially parallel lines. distributed between
The method of processing a crystalline material according to claim 1 .
前記第3の表面下レーザ・ダメージ・パターンは、前記結晶材料の前記内部に、前記第3の複数の実質的に平行な線の線から横方向外向きに伝播する第3の複数のクラックを形成し、前記第3の複数のクラックのうちの少なくともいくつかのクラックは、前記第1の複数のクラックのうちの少なくともいくつかのクラックとおよび前記第2の複数のクラックのうちの少なくともいくつかのクラックと接続する、
請求項6に記載の結晶材料加工方法。 said second plurality of cracks not connecting with said first plurality of cracks;
The third subsurface laser damage pattern causes a third plurality of cracks in the interior of the crystalline material propagating laterally outwardly from a line of the third plurality of substantially parallel lines. forming at least some of the cracks of the third plurality of cracks, at least some of the cracks of the first plurality of cracks and at least some of the cracks of the second plurality of cracks connect with the crack of
The crystalline material processing method according to claim 6 .
前記複数の3線グループのうちの1つまたは複数の3線グループについて、前記3線グループは、少なくとも1つの隣り合う3線グループから、前記1つまたは複数の3線グループ中の任意の2つの隣り合う線の間の間隔を上回るグループ間間隔によって隔離される、請求項6に記載の結晶材料加工方法。 each line of said third plurality of substantially parallel lines corresponds to a corresponding line of said first plurality of substantially parallel lines and a corresponding line of said second plurality of substantially parallel lines; and the lines forming a three-line group, wherein said first, second, and third subsurface laser damage patterns combine to form a plurality of three-line groups;
For one or more 3-wire groups of the plurality of 3-wire groups, the 3-wire group is selected from at least one adjacent 3-wire group to any two of the one or more 3-wire groups. 7. The method of processing a crystalline material of claim 6 , separated by an inter-group spacing that exceeds the spacing between adjacent lines.
前記第1の複数の実質的に平行な線の各線、前記第2の複数の実質的に平行な線の各線、前記第3の複数の実質的に平行な線の各線は、前記六方晶構造の<11-20>方向に対する垂直方向から約1度から約5度までの範囲内の角度だけ偏向している、
請求項6に記載の結晶材料加工方法。 said crystalline material having a hexagonal crystal structure;
Each line of said first plurality of substantially parallel lines, each line of said second plurality of substantially parallel lines, each line of said third plurality of substantially parallel lines each having said hexagonal crystal structure is deflected by an angle within the range of about 1 degree to about 5 degrees from normal to the <11-20> direction of
The crystalline material processing method according to claim 6 .
請求項6に記載の結晶材料加工方法。The crystalline material processing method according to claim 6 .
前記結晶材料の不均一なドーピングを示す前記条件の検出に応答して、前記第1の表面下レーザ・ダメージ・パターンおよび前記第2の表面下レーザ・ダメージ・パターンの形成中、第1のドーピング領域内に表面下レーザ・ダメージを形成するときに第1の平均出力のレーザ放射を提供するように、および、第2のドーピング領域内に表面下レーザ・ダメージを形成するときに第2の平均出力のレーザ放射を提供するように、レーザ出力を変更することと、
を更に含む、請求項1に記載の結晶材料加工方法。 detecting the presence of a condition indicative of non-uniform doping of the crystalline material over at least a portion of the surface of the substrate, the non-uniform doping comprising at least one first doping region and at least one second doping region; detecting, including a doping region of
a first doping during formation of the first subsurface laser damage pattern and the second subsurface laser damage pattern in response to detecting the condition indicative of non-uniform doping of the crystalline material; to provide a first average power of laser radiation when forming subsurface laser damage in the region and a second average when forming subsurface laser damage in the second doped region; modifying the laser power to provide output laser radiation;
2. The method of processing a crystalline material of claim 1 , further comprising:
請求項1に記載の結晶材料加工方法。The method of processing a crystalline material according to claim 1.
請求項1に記載の方法。 Laser radiation focused into the interior of the crystalline material to form a repeating subsurface laser damage pattern aligned with at least one of the first or second subsurface laser damage patterns. , wherein the repeating step of at least one of the first or second subsurface laser damage patterns comprises applying a centered at a depth to the surface of the crystalline material different from at least one of the second subsurface laser damage patterns;
The method of claim 1 .
次の複数の実質的に平行な線を備える次の表面下レーザ・ダメージ・パターンを有する表面下レーザ・ダメージを形成するために、前記基板の前記内部に集束される前記レーザの放射を供給し、前記レーザと前記基板との間の横方向相対移動を実行させることと、を含み、
前記最初の複数の実質的に平行な線の線は、前記次の複数の実質的に平行な線の線と非平行であり、
前記次の複数の実質的に平行な線における線の角度方向と前記最初の複数の実質的に平行な線における線の角度方向との差は10度以下であり、
前記次の複数の実質的に平行な線のうちの少なくともいくつかの線は、前記最初の複数の実質的に平行な線のうちのどの線とも交差しない、
結晶材料加工方法。 providing focused laser radiation within a substrate of crystalline material to form a subsurface laser damage having an initial subsurface laser damage pattern comprising an initial plurality of substantially parallel lines; , effecting a lateral relative movement between the laser and the substrate;
providing said laser radiation focused into said interior of said substrate to form a subsurface laser damage having a next subsurface laser damage pattern comprising a plurality of substantially parallel lines; , effecting lateral relative movement between the laser and the substrate;
the lines of the first plurality of substantially parallel lines are non-parallel to the lines of the next plurality of substantially parallel lines;
the difference between the angular orientation of the lines in the next plurality of substantially parallel lines and the angular orientation of the lines in the first plurality of substantially parallel lines is no more than 10 degrees;
at least some of the next plurality of substantially parallel lines do not intersect any of the first plurality of substantially parallel lines;
Crystal material processing method.
前記次のレーザ・ダメージ・パターンは、第3の複数の実質的に平行な線を含む第3の表面下レーザ・ダメージ・パターンを備え、
前記第3の複数の実質的に平行な線の線は、前記第1の複数の実質的に平行な線および前記第2の複数の実質的に平行な線の線同士の間に分散され、前記第3の複数の実質的に平行な線の各線は、前記第1の複数の実質的に平行な線のうちの1つの線と前記第2の複数の実質的に平行な線のうちの1つの線との間に配置される、
請求項17に記載の結晶材料加工方法。 The first subsurface laser damage pattern includes a first subsurface laser damage pattern including a first plurality of substantially parallel lines and a second plurality of substantially parallel lines. a second subsurface laser damage pattern;
said next laser damage pattern comprising a third subsurface laser damage pattern comprising a third plurality of substantially parallel lines;
lines of said third plurality of substantially parallel lines are dispersed between lines of said first plurality of substantially parallel lines and said second plurality of substantially parallel lines; Each line of said third plurality of substantially parallel lines comprises one line of said first plurality of substantially parallel lines and one line of said second plurality of substantially parallel lines. placed between a line and
18. The method of processing a crystalline material according to claim 17.
前記第2の表面下レーザ・ダメージ・パターンは、前記結晶材料の前記内部に、前記第2の複数の実質的に平行な線の線から横方向外向きに伝播する第2の複数のクラックを備え、前記第2の複数のクラックは前記第1の複数のクラックと接続せず、
前記第3の表面下レーザ・ダメージ・パターンは、前記結晶材料の前記内部に、前記第3の複数の実質的に平行な線の線から横方向外向きに伝播する第3の複数のクラックを備え、前記第3の複数のクラックのうちの少なくともいくつかのクラックは、前記第1の複数のクラックのうちの少なくともいくつかのクラックとおよび前記第2の複数のクラックのうちの少なくともいくつかのクラックと接続する、
請求項20に記載の結晶材料加工方法。 The first subsurface laser damage pattern causes a first plurality of cracks in the interior of the crystalline material propagating laterally outwardly from a line of the first plurality of substantially parallel lines. prepared,
The second subsurface laser damage pattern causes a second plurality of cracks in the interior of the crystalline material propagating laterally outward from a line of the second plurality of substantially parallel lines. wherein the second plurality of cracks are not connected with the first plurality of cracks;
The third subsurface laser damage pattern causes a third plurality of cracks in the interior of the crystalline material propagating laterally outwardly from a line of the third plurality of substantially parallel lines. wherein at least some cracks of the third plurality of cracks comprise at least some cracks of the first plurality of cracks and at least some cracks of the second plurality of cracks connect with crack,
21. The method of processing a crystalline material according to claim 20 .
前記結晶材料の前記複数のエリアの各エリア内に第1の複数の表面下レーザ・ダメージ領域を形成することと、
前記結晶材料の前記複数のエリアの各エリア内に第2の複数の表面下レーザ・ダメージ領域を形成することとであって、前記第1の複数の表面下レーザ・ダメージ領域のうちの少なくともいくつかの表面下レーザ・ダメージ領域は、前記第2の複数の表面下レーザ・ダメージ領域の表面下レーザ・ダメージ領域と交差せず、前記第1の複数の表面下レーザ・ダメージ領域は第1の複数の実質的に平行な線を備え、前記第2の複数の表面下レーザ・ダメージ領域は第2の複数の実質的に平行な線を備える、形成することと、
前記第1の複数のまたは第2の複数の表面下レーザ・ダメージ領域のうちの少なくとも一方と位置合わせされる反復表面下レーザ・ダメージ領域を形成するために、前記結晶材料の前記内部に集束されるレーザ放射を供給することを含む、前記結晶材料の前記複数のエリアの各エリア内に前記第1の複数のまたは第2の複数の表面下レーザ・ダメージ領域のうちの少なくとも一方を形成する反復行程を実行することであって、前記反復表面下ダメージ領域は、前記第1の複数のまたは第2の複数のレーザ・ダメージ領域のうちの少なくとも一方とは異なる、前記結晶材料の表面に対する深さを中心とする、実行することと、を含む、方法。 A method for processing a crystalline material comprising a plurality of non-overlapping areas, comprising:
forming a first plurality of subsurface laser damage regions within each of the plurality of areas of the crystalline material;
forming a second plurality of subsurface laser damage regions within each of said plurality of areas of said crystalline material, wherein at least some of said first plurality of subsurface laser damage regions. The subsurface laser damage regions do not intersect the subsurface laser damage regions of the second plurality of subsurface laser damage regions, and the first plurality of subsurface laser damage regions are in the first subsurface laser damage region. forming a plurality of substantially parallel lines, the second plurality of subsurface laser damage regions comprising a second plurality of substantially parallel lines;
focused into the interior of the crystalline material to form repetitive subsurface laser damage regions aligned with at least one of the first or second plurality of subsurface laser damage regions; forming at least one of the first plurality or the second plurality of subsurface laser damage regions in each of the plurality of areas of the crystalline material, comprising: performing a process, wherein the repetitive subsurface damage regions are at a different depth to the surface of the crystalline material than at least one of the first plurality or the second plurality of laser damage regions; A method that revolves around and includes performing.
前記第3の複数の表面下レーザ・ダメージ領域は第3の複数の実質的に平行な線を備え、
前記第3の複数の実質的に平行な線のうちの少なくともいくつかの線は、前記第1の複数の実質的に平行な線および前記第2の複数の実質的に平行な線の線同士の間に分散される、
請求項23に記載の方法。 forming a third plurality of subsurface laser damage regions in each of the plurality of areas of the crystalline material after forming the first plurality of subsurface laser damage regions and the second subsurface laser damage regions; further comprising forming a region;
said third plurality of subsurface laser damage regions comprising a third plurality of substantially parallel lines;
At least some of the third plurality of substantially parallel lines are aligned between the first plurality of substantially parallel lines and the second plurality of substantially parallel lines. distributed between
24. The method of claim 23 .
前記第2の複数の表面下レーザ・ダメージ領域は、前記結晶材料の前記内部に、前記第2の複数の実質的に平行な線の線から横方向外向きに伝播する第2の複数のクラックを備える、
請求項23に記載の方法。 The first plurality of subsurface laser damage regions comprises a first plurality of cracks propagating laterally outwardly from the first plurality of substantially parallel lines in the interior of the crystalline material. with
The second plurality of subsurface laser damage regions comprises a second plurality of cracks propagating laterally outwardly from the second plurality of substantially parallel lines in the interior of the crystalline material. comprising
24. The method of claim 23 .
前記結晶材料の前記複数のエリアの各エリア内に前記第1の複数および前記第2の複数の表面下レーザ・ダメージ領域を形成する反復行程を実行することを含む、請求項23に記載の方法。 said performing a repetitive step of forming at least one of said first plurality or said second plurality of subsurface laser damage regions in each of said plurality of areas of said crystalline material;
24. The method of claim 23 , comprising performing iterative steps of forming said first plurality and said second plurality of subsurface laser damage regions in each of said plurality of areas of said crystalline material. .
分散された表面下レーザ・ダメージ領域を形成するために、前記複数のエリアの各エリアにわたって第1および第2の複数の表面下レーザ・ダメージ領域を連続的に形成することであって、前記第1の複数の表面下レーザ・ダメージ領域のうちの少なくともいくつかの表面下レーザ・ダメージ領域は、前記第2の複数の表面下レーザ・ダメージ領域の表面下レーザ・ダメージ領域と交差せず、前記第1の複数の表面下レーザ・ダメージ領域は第1の複数の実質的に平行な線を備え、前記第2の複数の表面下レーザ・ダメージ領域は第2の複数の実質的に平行な線を備える、形成することと、
前記第1の複数の表面下レーザ・ダメージ領域および前記第2の表面下レーザ・ダメージ領域の形成後に、前記結晶材料の前記複数のエリアの各エリア内に第3の複数の表面下レーザ・ダメージ領域を形成することと、を含み、
前記第3の複数の表面下レーザ・ダメージ領域は第3の複数の実質的に平行な線を備え、
前記第3の複数の実質的に平行な線のうちの少なくともいくつかの線は、前記第1の複数の実質的に平行な線および前記第2の複数の実質的に平行な線の線同士の間に分散される、方法。 A method for processing a crystalline material comprising a plurality of non-overlapping areas, comprising:
continuously forming a first and a second plurality of subsurface laser damage regions across each of the plurality of areas to form distributed subsurface laser damage regions; at least some subsurface laser damage regions of the one plurality of subsurface laser damage regions do not intersect subsurface laser damage regions of the second plurality of subsurface laser damage regions ; a first plurality of subsurface laser damage regions comprising a first plurality of substantially parallel lines and said second plurality of subsurface laser damage regions comprising a second plurality of substantially parallel lines; comprising, forming
forming a third plurality of subsurface laser damage regions in each of the plurality of areas of the crystalline material after forming the first plurality of subsurface laser damage regions and the second subsurface laser damage regions; forming a region;
said third plurality of subsurface laser damage regions comprising a third plurality of substantially parallel lines;
At least some of the third plurality of substantially parallel lines are aligned between the first plurality of substantially parallel lines and the second plurality of substantially parallel lines. A method that is distributed between
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