JPWO2009028399A1 - Semiconductor wafer and manufacturing method thereof - Google Patents

Abstract

A large-diameter wafer having a diameter of 450 mm or more is manufactured at a high yield and at a low cost. A plurality of rectangular small silicon wafers are attached to a circular quartz glass plate having a diameter of 450 mm or more as a base material substrate by annealing or the like. After bonding, polysilicon is deposited by CVD to fill gaps between the small silicon wafers, and the surface of these small silicon wafers is polished to form a device forming surface. Alternatively, an epitaxial layer is formed on the surface of these small silicon wafers to form a device surface.

Description

  The present invention relates to a semiconductor wafer produced by attaching a plurality of small wafers to one large support plate having a diameter of 450 mm or more, and a method for producing the same.

The silicon wafer is manufactured by pulling up a single crystal ingot by the CZ (Czochralski) method, and manufacturing a mirror-polished wafer from this ingot through various processes such as slicing, chamfering, lapping, etching, mirror polishing, and cleaning. Is common.
However, when a large-diameter ingot with a diameter of 450 mm is pulled by the CZ method, parameters such as the thermal history of the pulled single crystal, the convection of the melt, and the temperature distribution are completely different from those of conventional products with a diameter of 300 mm or less. . Therefore, at present, it is extremely difficult to pull up a single crystal ingot having a large diameter of 450 mm and no dislocation by the CZ method.

Further, when pulling up a single crystal silicon ingot having a diameter of 450 mm by the CZ method, the weight of the top portion and the tail portion of the ingot is larger than that of a conventional single crystal silicon ingot having a diameter of 300 mm or less. Therefore, the loss of the ingot due to the cutting and removing of the top portion and the tail portion is also large. As a result, the product yield also decreases.
As shown in Patent Document 1, a target unit in which an erosion member is constituted by a plurality of types of members is known. However, a semiconductor wafer in which a plurality of small wafers are bonded to one support plate is not known.
Japanese Patent No. 2635362

  As described above, in a semiconductor wafer having an increased diameter, it is difficult to produce a defect-free single crystal ingot as a raw material by the CZ method.

  Therefore, the present invention improves the manufacturing yield of a semiconductor wafer having a large diameter of 450 mm or more and almost no crystal defects, and as a result, provides a method for manufacturing such a large diameter wafer at low cost. For the purpose.

  According to the first aspect of the present invention, a plurality of small wafers made of semiconductor wafers are arranged side by side on one surface of a single support plate having a diameter of 450 mm or more, and then the support plate on which the small wafers are arranged is heated. This is a method for manufacturing a semiconductor wafer, in which a plurality of small piece wafers are bonded to one surface of the support plate member, and a semiconductor wafer is produced using the surface of the small piece wafer as a device forming surface.

In addition to a semiconductor wafer such as a silicon wafer, a glass substrate or the like can be employed as the support plate material.
The small piece wafer means a small piece of a semiconductor wafer such as a silicon wafer, and is a wafer having a smaller area than the supporting plate material. The small wafer is produced using a silicon wafer produced from a single crystal silicon ingot pulled up by a known CZ method. That is, each small wafer has a predetermined thickness and a predetermined shape, and the surface thereof can be a polished mirror finish.
Further, the small wafer can be attached to the support plate by a known bonding method or the like. Further, a small wafer is placed on one surface of the support plate and annealed to join them. When a semiconductor wafer is used as the support plate material, the bonding surfaces of the support plate material and the small piece wafer can be mirror-finished, and can be firmly bonded by performing a bonding heat treatment after bonding at room temperature.
As the diameter of the support plate material, for example, 450 mm, 675 mm, or the like can be employed.
One surface of the support plate material means the front surface or the back surface of the support plate material.

According to a second aspect of the present invention, the supporting plate material is made of quartz glass, the small piece wafer is made a small piece of a silicon wafer, and these are superposed and then heated to form a plurality of small piece wafers via a silicon oxide film. It is a manufacturing method of the semiconductor wafer of Claim 1 joined to one surface of the support plate material.
As the quartz glass, fused quartz glass or synthetic quartz glass can be used. A silicon oxide film is grown between the surface of the support plate made of quartz glass and a small piece of the silicon wafer by heating, and the two are bonded via the silicon oxide film.

In the invention according to claim 3, after filling the gap provided between the small piece wafers with polycrystalline silicon, the surface of the small piece wafers is polished, and the surface of the polished small piece wafers is polished. 3. The method for producing a semiconductor wafer according to claim 1, wherein an epitaxial film is grown.
The filling of the polycrystalline silicon is performed by, for example, a CVD method performed by masking the surface of the small wafer.
The surface of the small wafer is polished using a known single-side polishing apparatus of a single wafer type or a batch type.
By growing the epitaxial film over the entire surface of the semiconductor wafer including the small wafer, the entire surface of the support plate can be used as the epitaxial layer. Further, a portion of the surface of the semiconductor wafer excluding the small piece wafer may be masked, and the epitaxial film may be grown only on the surface of the small piece wafer.

In the invention according to claim 4, a plurality of small wafers composed of small pieces of semiconductor wafers are arranged side by side on one surface of a single support plate having a diameter of 450 mm or more, and the surfaces of these small wafers are defined as device forming surfaces. This is a semiconductor wafer.
As the support plate material, a glass substrate or the like can be used in addition to a semiconductor wafer. A silicon wafer, a compound semiconductor wafer, or the like is used as the small wafer. Each small wafer has a surface area smaller than that of the support plate.

According to a fifth aspect of the present invention, the support plate material is quartz glass, the small piece wafer is a small piece of a silicon wafer, and a plurality of small piece wafers are bonded to one surface of the support plate material via a silicon oxide film. It is a semiconductor wafer of description.
Quartz glass is used as the glass substrate. In this case, a small piece of a silicon wafer can be bonded to the quartz glass substrate by annealing, for example.

According to a sixth aspect of the present invention, after the gap provided between the small wafers is filled with polycrystalline silicon, the surfaces of the small wafers are polished, and the surfaces of the polished small wafers are polished. 6. The semiconductor wafer according to claim 4, wherein an epitaxial film is grown.
By filling the gap between the small wafers with polycrystalline silicon, this polycrystalline silicon portion can be used as a gettering site for metal impurities.
The polycrystalline silicon deposited on the surface of the small wafer when the gap is filled with the polycrystalline silicon is removed by polishing, so that the surface of the small wafer is held as a mirror surface.
An epitaxial film is formed on the surface of the small wafer after polishing. Thereby, a large-diameter epitaxial wafer can be easily manufactured.

The invention according to claim 7 is the semiconductor wafer according to claim 4, wherein the support plate material is circular in plan view, and the small wafer is rectangular.
If a circular support plate is used, devices can be formed using the same manufacturing and processing equipment as conventional silicon wafers.

According to the present invention, even if a semiconductor wafer has a diameter of 450 mm or more, if a silicon wafer having few crystal defects is used as a small piece wafer, a large-diameter wafer having almost no crystal defects can be manufactured. Moreover, the manufacturing yield of a large-diameter semiconductor wafer is improved, and as a result, it can be manufactured at low cost.
In the present invention, a large-diameter wafer having a diameter of 450 mm or more is manufactured using a plurality of small wafers with high flatness. Therefore, there are few crystal defects compared with the case where one large-diameter wafer is produced from a large-diameter ingot, and a wafer with higher flatness can be produced. This is because it is very difficult to increase the flatness of one large-diameter wafer produced from a large-diameter ingot due to warpage or the like.
Further, when a small wafer is bonded, the polycrystalline silicon filled in the gap between the small wafers effectively acts as a gettering site in a device process or the like.
Furthermore, a device chip can be easily manufactured from a silicon wafer by making a small piece wafer into a rectangle.

1 is a plan view showing a schematic configuration of a semiconductor wafer according to a first embodiment of the present invention. It is sectional drawing which shows a part of semiconductor wafer which concerns on 1st Embodiment. It is a flow sheet which shows the manufacturing method of the semiconductor wafer which concerns on the 2nd Embodiment of this invention.

Explanation of symbols

10 Semiconductor wafer,
11 quartz glass substrate,
12-15 small wafers,
17 Polycrystalline silicon part.

  Hereinafter, an embodiment of a semiconductor wafer according to the present invention will be described in detail with reference to the drawings. The semiconductor wafer according to this embodiment is manufactured by attaching four square silicon wafers in a plan view on quartz glass. Here, the dimensions (vertical, horizontal, and thickness) and the number of silicon wafers to be bonded onto the quartz glass are appropriately selected according to the size of the device chip to be manufactured.

Hereinafter, the semiconductor wafer according to the present embodiment will be described with reference to FIGS.
1 and 2, a silicon wafer 10 has a circular quartz glass substrate 11 as a support plate material, and four square small wafers 12, 13, 14, and 15 are attached to the surface of the quartz glass substrate 11. . The four silicon wafers 12 to 15 are attached to the quartz glass substrate 11 so as to be point-symmetric about the center C of the quartz glass substrate 11 in plan view.
The small wafers 12 to 15 are separated by a cross-shaped polysilicon portion 16 in plan view. Further, the outer sides of the outer peripheral edges of the small wafers 12 to 15 are surrounded by a substantially half-moon shaped polysilicon portion 17.
The surfaces of these small wafers 12 to 15 are formed in the same plane as the surfaces of the polysilicon portions 16 and 17. A silicon oxide film 18 having a thickness of 10 μm is interposed between the quartz glass substrate 11 and the small wafers 12 to 15.
The small wafers 12 to 15 are wafers having the same size (side length and thickness). In addition, the small wafers 12 to 15 can have the same impurity concentration, for example, but the small wafers 12 to 15 can be changed in conductivity type or can be changed in impurity concentration. You can also paste.

Next, a manufacturing process of the semiconductor wafer 10 in this embodiment will be described. First, a quartz glass substrate 11 is produced as a support plate material. That is, the base material of the quartz glass substrate 11 is cut to produce a circular substrate having a diameter of 450 mm, for example. Specifically, a base material of a quartz glass substrate that is a square with a side length of at least 450 mm and sliced to a thickness of 1 mm is pasted on a processing table of a laser processing machine, and a carbon dioxide laser beam is applied to the surface of the base material. A circular substrate having a diameter of 450 mm is manufactured by cutting out the base material by irradiating the substrate. In this case, the thickness of the quartz glass substrate 11 is 1 mm.
Next, a silicon CZ wafer having a diameter of 300 mm is processed, and square wafers 12 to 15 (single-sided or double-sided mirror polished wafers) each having a 150 mm square are cut out. Specifically, the surface of a silicon wafer having a diameter of 300 mm is irradiated with a laser beam such as a carbon dioxide laser beam or a YAG laser beam. Next, the surface of the silicon wafer is scanned with a laser beam so as to draw a 150 mm square on the surface of the silicon wafer. Thereby, the square wafers 12-15 are obtained. The thickness of each wafer 12-15 is 775 micrometers. Alternatively, after a 150 mm square is scribed on the surface of a 300 mm diameter silicon wafer, the silicon wafer is cleaved along the scribed line, and the four sides of the cleaved silicon wafer are flattened by grinding or polishing. However, square wafers 12 to 15 are obtained.

Then, the square wafers 12 to 15 are superimposed on the quartz glass substrate 11 in a point-symmetric manner with the center C of the surface of the quartz glass substrate 11 as the center. As a specific overlaying method, at the center C of the quartz glass substrate 11, lines D1 and D2 indicating diameters perpendicular to each other are scratched on the surface of the quartz glass substrate 11, and any of the diagonal lines of the square wafers 12 to 15 is marked. These are arranged so that one of them coincides with the line D1 or the line D2 and the width w of the cross-shaped gap (groove) formed between the small wafers 12 to 15 is 8 mm. Thereby, the square wafers 12 to 15 each having a side length of 150 mm and a thickness of 775 μm are arranged at a point-symmetrical position on the surface of the quartz glass substrate 11 with a uniform gap.
Thereafter, the four small wafers 12 to 15 placed on the quartz glass substrate 11 are heated using a predetermined heat treatment furnace. Specifically, the small wafers 12 to 15 are heat-treated at 1100 to 1300 ° C. in an inert gas atmosphere such as argon. As a result, the four rectangular small silicon wafers 12 to 15 are bonded to the quartz glass substrate 11 through the silicon oxide film 18. At that time, a cross-shaped gap (groove) having a width w of 8 mm over the entire length is formed between the small wafers 12 to 15.

Next, the quartz glass substrate 11 having a small wafer bonded to the surface is inserted into a CVD furnace, and polysilicon is deposited on the surface. Specifically, a polysilicon layer having a thickness of about 1 mm is obtained using a normal pressure or reduced pressure CVD furnace at a growth temperature of 600 to 700 ° C.
The polysilicon is deposited on the surface of the quartz glass substrate 11 until the cross-shaped groove is filled. As a result, the polysilicon layer 17 is also deposited on the upper surfaces of the small wafers 12 to 15 and the upper surface (oxide film) of the quartz glass substrate 11. Next, the surface (mirror surface) of the small wafers 12 to 15 is exposed by polishing the surface of the quartz glass substrate 11 including the small wafers 12 to 15 and the polysilicon portions 16 and 17. Specifically, in a state where the back surface of the quartz glass substrate 11 where the polysilicon portions 16 and 17 are not present is vacuum-adsorbed and held on the polishing head, an abrasive is supplied to the polishing cloth, and the quartz glass held on the polishing head. The surface of the substrate 11 is brought into sliding contact with the polishing cloth. As a result, the surfaces of the small wafers 12 to 15 and the surfaces of the polysilicon portions 16 and 17 are mirror-finished. As a result, a semiconductor wafer 10 composed of four rectangular silicon mirror surfaces and a polysilicon surface surrounding them is obtained.
In the semiconductor wafer 10, the rectangular silicon surface portions 12 to 15 serve as device forming surfaces. A desired device is fabricated on the semiconductor wafer 10 through subsequent device processes.

Thus, in the semiconductor wafer 10, the quartz glass substrate 11 was made into a disk in plan view, and the four small wafers 12 to 15 were made into a square shape having a total size of 4 and the same size in plan view. Moreover, the gaps between the small wafers 12 to 15 are made uniform, and each gap is filled with the cross-shaped polysilicon portion 16. Therefore, the four small wafers 12 to 15 can be accurately and easily positioned on the surface of the circular quartz glass substrate 11 having a diameter of 450 mm.
That is, at the center C of the surface of the quartz glass substrate 11, either one of the diagonal lines of the small wafers 12 to 15 is aligned with either the line D1 or the line D2 indicating the diameters orthogonal to each other. Moreover, the corner portions of the small wafers 12 to 15 existing on the line D1 or the line D2 overlap with each other on a concentric circle with the center C of the quartz glass substrate 11 as the center. Thereby, the four small wafers 12 to 15 can be easily positioned at equal spaced positions on the surface of the quartz glass substrate 11.

  Further, the adjacent gaps of the small wafers 12 to 15 are filled with the polysilicon portion 16. Therefore, the polysilicon portion 16 can be used as a gettering site that captures metal impurities and the like of the small wafers 12 to 15. Further, since the small wafer 12 is square in plan view, the wafer can be easily chipped. And since it was set as the circular support plate material, device formation can be performed using the manufacturing and processing equipment equivalent to the conventional silicon wafer.

In FIG. 3, the manufacturing process of the semiconductor wafer in another embodiment is shown. In this embodiment, a substrate as a large-diameter support plate formed by slicing a polysilicon ingot is produced (S21 to S23). The surface of the polysilicon substrate is mirror-polished to be mirror-finished.
Then, a 300 mm diameter silicon single crystal ingot (cross section is circular) pulled up by a normal CZ method is subjected to side grinding or cutting from four directions of the side surface of the cylindrical part after block cutting, and a single crystal having a square cross section Ingot blocks are produced (S01, S02). The cross section of the ingot block is a square with a side of 205 mm.
Thereafter, the ingot block is sliced to a thickness of 775 μm using a wire saw or the like (S03), and processing such as lapping, grinding, and etching is sequentially performed (S04, S05, S06). Both are performed by known methods in wafer processing.

After etching, the rectangular silicon wafer is divided into four by a laser (S07). As a specific method, the surface of the silicon wafer is irradiated with a laser beam such as a carbon dioxide laser beam or a YAG laser beam, and the surface of the silicon wafer is scanned with the laser beam to divide into four. Alternatively, after dividing the square on the surface of the silicon wafer, the silicon wafer is cleaved along the scribed line, and four sides of the cleaved silicon wafer are flattened by grinding or polishing, so that four divisions can be performed.
Thereafter, both surfaces are mirror-polished (S08). As a result, four rectangular small wafers can be obtained.
Next, the polishing surface of the small rectangular wafer is superposed on the polishing surface of the large-diameter polysilicon substrate at room temperature and bonded together (S09). This bonding is performed by a known bonding method, and then a bonding strengthening heat treatment between the polysilicon substrate and each small rectangular wafer is performed. The conditions for the bonding strengthening heat treatment are, for example, 1000 to 1200 ° C. and an inert gas atmosphere such as argon.

  Thereafter, the surface of the polysilicon substrate to which the small rectangular wafer is bonded is subjected to predetermined cleaning (S10), and polysilicon is deposited on the surface by CVD (S11). As a result, the gap between the small pieces is filled with polysilicon. Thereafter, predetermined polishing (CMP) is performed on the polysilicon deposition surface (S12), and further cleaning (S13) is performed to produce a semiconductor wafer whose surface becomes a silicon surface (divided four surfaces).

Thus, a silicon wafer having a larger diameter can be manufactured by arranging a plurality of small pieces of silicon wafers on the surface of the polysilicon substrate.
As a manufacturing method in this case, a plurality of pieces of silicon wafer can be attached to the silicon oxide film (for example, on quartz glass) by arranging and annealing on the surface of the polysilicon substrate.
Further, after bonding as described above, the gap between adjacent small wafers is filled with polycrystalline silicon. Polycrystalline silicon functions as a gettering site, for example.

Small wafers may be square or rectangular, or other shapes. The number of small wafers attached to the polysilicon substrate is not limited.
After each small wafer is attached to the polysilicon substrate, the gaps interposed between the small wafers are filled with polycrystalline silicon. Thereafter, the surface or front and back surfaces of the polysilicon substrate with small pieces are mirror-polished. When the front and back surfaces are mirror-polished, the flatness is further increased compared to the case where only the front surface is mirror-polished. Alternatively, an epitaxial film may be grown on the surface of each small wafer. In this case, the silicon epitaxial film is used as a device formation surface.

Claims (7)

  A plurality of small wafers composed of small pieces of semiconductor wafers are arranged side by side on one surface of a single support plate having a diameter of 450 mm or more, and then the support plate on which the small pieces of wafers are arranged is heated. A method for manufacturing a semiconductor wafer, wherein a small wafer is joined to one surface of the support plate, and a semiconductor wafer is produced using the surface of the small wafer as a device forming surface.   The support plate material is quartz glass, the small piece wafer is a small piece of a silicon wafer, and after superposing them, a plurality of small piece wafers are bonded to one surface of the support plate material through a silicon oxide film by heating. 2. A method for producing a semiconductor wafer according to 1.   2. The polycrystalline silicon is filled in a gap provided between the small wafer and the small wafer, the surfaces of the small wafers are polished, and an epitaxial film is grown on the surface of the polished small wafer. Or the manufacturing method of the semiconductor wafer of Claim 2.   A semiconductor wafer in which a plurality of small wafers made of small pieces of semiconductor wafers are arranged and pasted on one surface of a support plate having a diameter of 450 mm or more, and the surface of these small wafers is used as a device formation surface.   5. The semiconductor wafer according to claim 4, wherein the support plate material is quartz glass, the small piece wafer is a small piece of a silicon wafer, and a plurality of small piece wafers are bonded to one surface of the support plate material via a silicon oxide film.   5. The gap provided between the small wafers is filled with polycrystalline silicon, the surfaces of the small wafers are polished, and an epitaxial film is grown on the surface of the polished small wafers. Or the semiconductor wafer of Claim 5.   The semiconductor wafer according to claim 4, wherein the support plate is circular in plan view, and the small wafer is rectangular.

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