JPS6375039A - 繊維強化フェノ−ル樹脂成形物の製造方法 - Google Patents
繊維強化フェノ−ル樹脂成形物の製造方法Info
- Publication number
- JPS6375039A JPS6375039A JP21808786A JP21808786A JPS6375039A JP S6375039 A JPS6375039 A JP S6375039A JP 21808786 A JP21808786 A JP 21808786A JP 21808786 A JP21808786 A JP 21808786A JP S6375039 A JPS6375039 A JP S6375039A
- Authority
- JP
- Japan
- Prior art keywords
- phenolic resin
- curing
- fiber
- molded article
- curing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000005011 phenolic resin Substances 0.000 title claims abstract description 11
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 title claims abstract description 10
- 229920001568 phenolic resin Polymers 0.000 title claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 239000007788 liquid Substances 0.000 claims abstract description 14
- 230000002378 acidificating effect Effects 0.000 claims abstract description 11
- 239000000835 fiber Substances 0.000 claims abstract description 11
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 17
- 239000011134 resol-type phenolic resin Substances 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 239000002253 acid Substances 0.000 abstract description 11
- 238000005260 corrosion Methods 0.000 abstract description 7
- 230000007797 corrosion Effects 0.000 abstract description 7
- 229910019142 PO4 Inorganic materials 0.000 abstract description 5
- 150000002989 phenols Chemical class 0.000 abstract description 5
- 239000000203 mixture Substances 0.000 abstract description 4
- 229920005989 resin Polymers 0.000 abstract description 4
- 239000011347 resin Substances 0.000 abstract description 4
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 abstract description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract description 3
- 239000010452 phosphate Substances 0.000 abstract description 3
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
- 239000011521 glass Substances 0.000 description 8
- 238000000465 moulding Methods 0.000 description 7
- 238000004945 emulsification Methods 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 5
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 4
- 150000007522 mineralic acids Chemical class 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 230000008719 thickening Effects 0.000 description 4
- 230000020169 heat generation Effects 0.000 description 3
- 229920006337 unsaturated polyester resin Polymers 0.000 description 3
- WHOZNOZYMBRCBL-OUKQBFOZSA-N (2E)-2-Tetradecenal Chemical compound CCCCCCCCCCC\C=C\C=O WHOZNOZYMBRCBL-OUKQBFOZSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 239000004760 aramid Substances 0.000 description 2
- 229920006231 aramid fiber Polymers 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 229940044654 phenolsulfonic acid Drugs 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 229940061610 sulfonated phenol Drugs 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- JIRHAGAOHOYLNO-UHFFFAOYSA-N (3-cyclopentyloxy-4-methoxyphenyl)methanol Chemical compound COC1=CC=C(CO)C=C1OC1CCCC1 JIRHAGAOHOYLNO-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- 235000002566 Capsicum Nutrition 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 239000005041 Mylar™ Substances 0.000 description 1
- 239000006002 Pepper Substances 0.000 description 1
- 235000016761 Piper aduncum Nutrition 0.000 description 1
- 235000017804 Piper guineense Nutrition 0.000 description 1
- 244000203593 Piper nigrum Species 0.000 description 1
- 235000008184 Piper nigrum Nutrition 0.000 description 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000009730 filament winding Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000010137 moulding (plastic) Methods 0.000 description 1
- -1 phosphoric acid Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000011417 postcuring Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000002256 xylenyl group Chemical class C1(C(C=CC=C1)C)(C)* 0.000 description 1
Landscapes
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP21808786A JPS6375039A (ja) | 1986-09-18 | 1986-09-18 | 繊維強化フェノ−ル樹脂成形物の製造方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP21808786A JPS6375039A (ja) | 1986-09-18 | 1986-09-18 | 繊維強化フェノ−ル樹脂成形物の製造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6375039A true JPS6375039A (ja) | 1988-04-05 |
JPH0349300B2 JPH0349300B2 (da) | 1991-07-29 |
Family
ID=16714434
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP21808786A Granted JPS6375039A (ja) | 1986-09-18 | 1986-09-18 | 繊維強化フェノ−ル樹脂成形物の製造方法 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6375039A (da) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0359060A (ja) * | 1989-07-27 | 1991-03-14 | Asahi Organic Chem Ind Co Ltd | フェノール系樹脂成形材料 |
JP2008507620A (ja) * | 2004-07-26 | 2008-03-13 | ジョージア − パシフィック ケミカルズ エルエルシー | エーテル化硬化剤を含有するフェノール樹脂組成物 |
JP2015048395A (ja) * | 2013-08-30 | 2015-03-16 | 群栄化学工業株式会社 | 熱硬化性樹脂組成物及びレゾール型フェノール樹脂 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2272668A (en) * | 1939-02-10 | 1942-02-10 | Reichhold Chemicals Inc | Partial phosphoric esters and process for preparing same |
US2330286A (en) * | 1939-02-10 | 1943-09-28 | Reichhold Chemicals Inc | Process for accelerating the hardening of hardenable resins and new composition of matter |
JPS61136527A (ja) * | 1984-12-07 | 1986-06-24 | Showa Highpolymer Co Ltd | 繊維強化フエノ−ル樹脂成型物の製造方法 |
-
1986
- 1986-09-18 JP JP21808786A patent/JPS6375039A/ja active Granted
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2272668A (en) * | 1939-02-10 | 1942-02-10 | Reichhold Chemicals Inc | Partial phosphoric esters and process for preparing same |
US2330286A (en) * | 1939-02-10 | 1943-09-28 | Reichhold Chemicals Inc | Process for accelerating the hardening of hardenable resins and new composition of matter |
JPS61136527A (ja) * | 1984-12-07 | 1986-06-24 | Showa Highpolymer Co Ltd | 繊維強化フエノ−ル樹脂成型物の製造方法 |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0359060A (ja) * | 1989-07-27 | 1991-03-14 | Asahi Organic Chem Ind Co Ltd | フェノール系樹脂成形材料 |
JP2008507620A (ja) * | 2004-07-26 | 2008-03-13 | ジョージア − パシフィック ケミカルズ エルエルシー | エーテル化硬化剤を含有するフェノール樹脂組成物 |
JP2015048395A (ja) * | 2013-08-30 | 2015-03-16 | 群栄化学工業株式会社 | 熱硬化性樹脂組成物及びレゾール型フェノール樹脂 |
Also Published As
Publication number | Publication date |
---|---|
JPH0349300B2 (da) | 1991-07-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3487043A (en) | Furane resins with silane coupling agents | |
JPH02300222A (ja) | 熱硬化性樹脂組成物 | |
FI82066B (fi) | Nya fenolhartsblandningar. | |
US5004789A (en) | Resin compositions based on phenolic resins | |
JPS6375039A (ja) | 繊維強化フェノ−ル樹脂成形物の製造方法 | |
JPS62211131A (ja) | 繊維強化フエノ−ル樹脂成形物の製造方法 | |
US3956227A (en) | Moulding compounds | |
US5141992A (en) | Phenolic resin composition with excellent impact strength | |
EP1100674B1 (en) | Resin transfer moulding | |
JPS61136527A (ja) | 繊維強化フエノ−ル樹脂成型物の製造方法 | |
JP3754166B2 (ja) | 繊維強化フェノール系樹脂成形品の製造方法 | |
JPS6139901B2 (da) | ||
JP2000502738A (ja) | 酸硬化可能なフェノール樹脂組成物のための反応性希釈剤 | |
JPS5935926B2 (ja) | 樹脂組成物 | |
US5559197A (en) | Modified phenolic resin toughened by phenoxy resin | |
CN115087688A (zh) | 由块状模塑料制备模塑复合材料的方法 | |
JPS6346099B2 (da) | ||
RU2339662C1 (ru) | Эпоксидное связующее для стеклопластиков | |
JP2004269812A (ja) | 繊維強化複合材料用フェノール樹脂組成物および繊維強化複合材料 | |
JPH051157A (ja) | 硬化性プリプレグ及びそれを硬化した成形品 | |
US20040164451A1 (en) | Resin transfer moulding | |
JP3529944B2 (ja) | 繊維強化フェノール樹脂成形品の製法および硬化剤 | |
CA1048676A (en) | Resin composition comprising aralkylene phenol resin and formaldehyde condensate | |
JPH0320349A (ja) | 新規の熱硬化性成形材料 | |
JP2002012736A (ja) | 常温硬化型フェノール樹脂組成物 |