JPS6362546A - 複合型リチウム吸着剤及びその製造方法 - Google Patents
複合型リチウム吸着剤及びその製造方法Info
- Publication number
- JPS6362546A JPS6362546A JP61208720A JP20872086A JPS6362546A JP S6362546 A JPS6362546 A JP S6362546A JP 61208720 A JP61208720 A JP 61208720A JP 20872086 A JP20872086 A JP 20872086A JP S6362546 A JPS6362546 A JP S6362546A
- Authority
- JP
- Japan
- Prior art keywords
- lithium
- adsorbent
- adsorption
- contg
- magnesium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003463 adsorbent Substances 0.000 title claims abstract description 34
- 239000002131 composite material Substances 0.000 title claims abstract description 12
- 229910052744 lithium Inorganic materials 0.000 title claims description 59
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims description 57
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 239000002253 acid Substances 0.000 claims abstract description 9
- 238000010438 heat treatment Methods 0.000 claims abstract description 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 16
- 229910052749 magnesium Inorganic materials 0.000 claims description 15
- 239000011777 magnesium Substances 0.000 claims description 15
- -1 manganese-aluminum Chemical compound 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 13
- 239000013535 sea water Substances 0.000 abstract description 6
- 238000002156 mixing Methods 0.000 abstract description 5
- 229910001425 magnesium ion Inorganic materials 0.000 abstract description 4
- 229910018657 Mn—Al Inorganic materials 0.000 abstract 3
- 229910018131 Al-Mn Inorganic materials 0.000 abstract 1
- 229910018461 Al—Mn Inorganic materials 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 description 33
- 239000000243 solution Substances 0.000 description 16
- 238000000034 method Methods 0.000 description 15
- 229940091250 magnesium supplement Drugs 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 8
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical class Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 4
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 4
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
- 238000005065 mining Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 239000012267 brine Substances 0.000 description 2
- 238000000975 co-precipitation Methods 0.000 description 2
- 238000010828 elution Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 239000000347 magnesium hydroxide Substances 0.000 description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- 229960000869 magnesium oxide Drugs 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 235000012245 magnesium oxide Nutrition 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- ZIGCAHUFDDOFRE-UHFFFAOYSA-L manganese(2+);oxygen(2-);dihydroxide Chemical compound [OH-].[OH-].[O-2].[O-2].[Mn+2].[Mn+2].[Mn+2] ZIGCAHUFDDOFRE-UHFFFAOYSA-L 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 2
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- DJHGAFSJWGLOIV-UHFFFAOYSA-K Arsenate3- Chemical compound [O-][As]([O-])([O-])=O DJHGAFSJWGLOIV-UHFFFAOYSA-K 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229940000489 arsenate Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 229910001437 manganese ion Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011707 mineral Chemical class 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 230000001373 regressive effect Effects 0.000 description 1
- 230000003716 rejuvenation Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Manufacture And Refinement Of Metals (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61208720A JPS6362546A (ja) | 1986-09-03 | 1986-09-03 | 複合型リチウム吸着剤及びその製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61208720A JPS6362546A (ja) | 1986-09-03 | 1986-09-03 | 複合型リチウム吸着剤及びその製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6362546A true JPS6362546A (ja) | 1988-03-18 |
| JPH0423577B2 JPH0423577B2 (cs) | 1992-04-22 |
Family
ID=16560965
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61208720A Granted JPS6362546A (ja) | 1986-09-03 | 1986-09-03 | 複合型リチウム吸着剤及びその製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6362546A (cs) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03160063A (ja) * | 1989-11-16 | 1991-07-10 | Kubota Corp | 防食被覆用ポリエチレン粉体とその製造方法 |
| WO1996017682A1 (en) * | 1994-12-07 | 1996-06-13 | M And K Patent Company, Inc. | Acid contacted enhanced adsorbent particle and method of making and using therefor |
| US5948726A (en) * | 1994-12-07 | 1999-09-07 | Project Earth Industries, Inc. | Adsorbent and/or catalyst and binder system and method of making therefor |
| US5955393A (en) * | 1995-04-21 | 1999-09-21 | Project Earth Industries, Inc. | Enhanced adsorbent and room temperature catalyst particle and method of making therefor |
| US5985790A (en) * | 1994-12-07 | 1999-11-16 | Project Earth Industries, Inc. | Method of making acid contacted enhanced aluminum oxide adsorbent particle |
| US6342191B1 (en) | 1994-12-07 | 2002-01-29 | Apyron Technologies, Inc. | Anchored catalyst system and method of making and using thereof |
| CN106824304A (zh) * | 2017-01-04 | 2017-06-13 | 潍坊学院 | 一种钛基锂离子提取材料的制备方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5334116A (en) * | 1976-09-11 | 1978-03-30 | Toyo Tire & Rubber Co Ltd | Flexible joint for hume pipes |
-
1986
- 1986-09-03 JP JP61208720A patent/JPS6362546A/ja active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5334116A (en) * | 1976-09-11 | 1978-03-30 | Toyo Tire & Rubber Co Ltd | Flexible joint for hume pipes |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03160063A (ja) * | 1989-11-16 | 1991-07-10 | Kubota Corp | 防食被覆用ポリエチレン粉体とその製造方法 |
| WO1996017682A1 (en) * | 1994-12-07 | 1996-06-13 | M And K Patent Company, Inc. | Acid contacted enhanced adsorbent particle and method of making and using therefor |
| US5948726A (en) * | 1994-12-07 | 1999-09-07 | Project Earth Industries, Inc. | Adsorbent and/or catalyst and binder system and method of making therefor |
| US5985790A (en) * | 1994-12-07 | 1999-11-16 | Project Earth Industries, Inc. | Method of making acid contacted enhanced aluminum oxide adsorbent particle |
| US6338830B1 (en) | 1994-12-07 | 2002-01-15 | Apyron Technologies, Inc. | Absorbent and/or catalyst and binder system and method of making and using therefor |
| US6342191B1 (en) | 1994-12-07 | 2002-01-29 | Apyron Technologies, Inc. | Anchored catalyst system and method of making and using thereof |
| US5955393A (en) * | 1995-04-21 | 1999-09-21 | Project Earth Industries, Inc. | Enhanced adsorbent and room temperature catalyst particle and method of making therefor |
| CN106824304A (zh) * | 2017-01-04 | 2017-06-13 | 潍坊学院 | 一种钛基锂离子提取材料的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0423577B2 (cs) | 1992-04-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |