JPS6357501B2 - - Google Patents
Info
- Publication number
- JPS6357501B2 JPS6357501B2 JP21372286A JP21372286A JPS6357501B2 JP S6357501 B2 JPS6357501 B2 JP S6357501B2 JP 21372286 A JP21372286 A JP 21372286A JP 21372286 A JP21372286 A JP 21372286A JP S6357501 B2 JPS6357501 B2 JP S6357501B2
- Authority
- JP
- Japan
- Prior art keywords
- sulfide
- sulfur
- skin
- forming
- metal surface
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011593 sulfur Substances 0.000 claims description 45
- 229910052717 sulfur Inorganic materials 0.000 claims description 45
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 41
- 238000000034 method Methods 0.000 claims description 40
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 24
- 239000002184 metal Substances 0.000 claims description 21
- 229910052751 metal Inorganic materials 0.000 claims description 21
- 239000007787 solid Substances 0.000 claims description 21
- 238000006243 chemical reaction Methods 0.000 claims description 20
- 238000010438 heat treatment Methods 0.000 claims description 6
- -1 sulfur ions Chemical class 0.000 claims description 6
- 230000008016 vaporization Effects 0.000 claims description 5
- 238000009835 boiling Methods 0.000 claims description 4
- 230000005684 electric field Effects 0.000 claims description 4
- 239000007789 gas Substances 0.000 description 21
- 238000005987 sulfurization reaction Methods 0.000 description 20
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 12
- 229910000831 Steel Inorganic materials 0.000 description 12
- 239000010959 steel Substances 0.000 description 12
- 238000005486 sulfidation Methods 0.000 description 12
- 239000000203 mixture Substances 0.000 description 8
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 6
- 230000001105 regulatory effect Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000011261 inert gas Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000002309 gasification Methods 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 238000006396 nitration reaction Methods 0.000 description 3
- 150000004763 sulfides Chemical class 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- 238000009834 vaporization Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910000805 Pig iron Inorganic materials 0.000 description 2
- NFMAZVUSKIJEIH-UHFFFAOYSA-N bis(sulfanylidene)iron Chemical compound S=[Fe]=S NFMAZVUSKIJEIH-UHFFFAOYSA-N 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910000339 iron disulfide Inorganic materials 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 238000009958 sewing Methods 0.000 description 2
- 125000000101 thioether group Chemical group 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- 229910000906 Bronze Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000531 Co alloy Inorganic materials 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 229910000997 High-speed steel Inorganic materials 0.000 description 1
- 229910001182 Mo alloy Inorganic materials 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- GNVXPFBEZCSHQZ-UHFFFAOYSA-N iron(2+);sulfide Chemical compound [S-2].[Fe+2] GNVXPFBEZCSHQZ-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000005088 metallography Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000005491 wire drawing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/36—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases using ionised gases, e.g. ionitriding
- C23C8/38—Treatment of ferrous surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
- Chemical Vapour Deposition (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN85106828A CN85106828B (zh) | 1985-09-10 | 1985-09-10 | 金属零件表面形成硫化物层的方法及设备 |
| CN85106828 | 1985-09-10 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6289858A JPS6289858A (ja) | 1987-04-24 |
| JPS6357501B2 true JPS6357501B2 (zh) | 1988-11-11 |
Family
ID=4795305
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21372286A Granted JPS6289858A (ja) | 1985-09-10 | 1986-09-10 | 金属表面に硫化物外皮を形成する方法およびその装置 |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0218916B1 (zh) |
| JP (1) | JPS6289858A (zh) |
| CN (1) | CN85106828B (zh) |
| DE (1) | DE3683119D1 (zh) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH671407A5 (zh) * | 1986-06-13 | 1989-08-31 | Balzers Hochvakuum | |
| FR2688010B1 (fr) * | 1992-03-02 | 1995-02-24 | Innovatique Sa | Procede pour la formation, sur une piece d'acier ou d'alliage d'acier d'une couche superficielle en un compose sulfure presentant des proprietes antifriction. |
| CN1217438A (zh) | 1997-11-07 | 1999-05-26 | 张昕辉 | 金属基润滑耐磨功能梯度材料 |
| CN1296515C (zh) * | 2004-05-13 | 2007-01-24 | 上海交通大学 | 自辉光等离子体基离子注入或者注入且沉积装置 |
| EP2910624B1 (en) | 2007-10-31 | 2016-11-23 | China Petroleum & Chemical Corporation | Passivation process for a continuous reforming apparatus during the initial reaction |
| CN102505106A (zh) * | 2011-12-30 | 2012-06-20 | 瓦房店轴承集团有限责任公司 | 风力发电主轴轴承的表面处理工艺 |
| CN102776472A (zh) * | 2012-07-23 | 2012-11-14 | 宁波市鸿博机械制造有限公司 | 提高汽车转向泵定子的耐磨性能的方法 |
| CN103397305B (zh) * | 2013-08-06 | 2015-08-26 | 深圳先进技术研究院 | 硒化/硫化处理装置 |
| CN110408885B (zh) * | 2019-08-27 | 2021-06-11 | 南京工程学院 | 一种车用轻型齿轮及其制造工艺 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1273518A (fr) * | 1960-10-28 | 1961-10-13 | Ass Elect Ind | Perfectionnements aux appareils de vaporisation sous vide |
| GB1160895A (en) * | 1965-08-25 | 1969-08-06 | Rank Xerox Ltd | Coating Surfaces by Vapour Deposition |
| GB1133397A (en) * | 1966-09-08 | 1968-11-13 | Hughes Aircraft Co | Method for the rapid deposition of metallic films using a plasma of the material to be deposited |
| JPS5165039A (ja) * | 1974-12-03 | 1976-06-05 | Seiko Instr & Electronics | Metsukihoho |
| US4039416A (en) * | 1975-04-21 | 1977-08-02 | White Gerald W | Gasless ion plating |
| JPS5749219A (en) * | 1980-09-08 | 1982-03-23 | Ayao Wada | Forming method for ionized thin film without necessity of direct gas plasma |
-
1985
- 1985-09-10 CN CN85106828A patent/CN85106828B/zh not_active Expired
-
1986
- 1986-09-10 JP JP21372286A patent/JPS6289858A/ja active Granted
- 1986-09-10 DE DE8686112510T patent/DE3683119D1/de not_active Expired - Lifetime
- 1986-09-10 EP EP86112510A patent/EP0218916B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0218916A1 (en) | 1987-04-22 |
| EP0218916B1 (en) | 1991-12-27 |
| DE3683119D1 (de) | 1992-02-06 |
| CN85106828A (zh) | 1987-03-11 |
| JPS6289858A (ja) | 1987-04-24 |
| CN85106828B (zh) | 1987-09-09 |
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