JPS6352044B2 - - Google Patents
Info
- Publication number
- JPS6352044B2 JPS6352044B2 JP59142196A JP14219684A JPS6352044B2 JP S6352044 B2 JPS6352044 B2 JP S6352044B2 JP 59142196 A JP59142196 A JP 59142196A JP 14219684 A JP14219684 A JP 14219684A JP S6352044 B2 JPS6352044 B2 JP S6352044B2
- Authority
- JP
- Japan
- Prior art keywords
- fluorine
- tetrafluoroethylene
- vinylidene fluoride
- copolymer
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052731 fluorine Inorganic materials 0.000 claims description 36
- 239000011737 fluorine Substances 0.000 claims description 36
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 33
- 239000011347 resin Substances 0.000 claims description 16
- 229920005989 resin Polymers 0.000 claims description 16
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims description 10
- 230000005865 ionizing radiation Effects 0.000 claims description 10
- 229920001577 copolymer Polymers 0.000 claims description 9
- 239000000178 monomer Substances 0.000 claims description 9
- 150000002978 peroxides Chemical class 0.000 claims description 9
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- 229920000642 polymer Polymers 0.000 claims description 7
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 238000002844 melting Methods 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims description 4
- 125000001153 fluoro group Chemical group F* 0.000 claims description 3
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical compound FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 claims description 3
- 229920001897 terpolymer Polymers 0.000 claims description 3
- RRZIJNVZMJUGTK-UHFFFAOYSA-N 1,1,2-trifluoro-2-(1,2,2-trifluoroethenoxy)ethene Chemical compound FC(F)=C(F)OC(F)=C(F)F RRZIJNVZMJUGTK-UHFFFAOYSA-N 0.000 claims description 2
- XHGMOUXCWNPJHF-UHFFFAOYSA-N 1,1-difluoroethene;1,1,2,3,3,3-hexafluoroprop-1-ene;1,1,2,2-tetrafluoroethene Chemical group FC(F)=C.FC(F)=C(F)F.FC(F)=C(F)C(F)(F)F XHGMOUXCWNPJHF-UHFFFAOYSA-N 0.000 claims description 2
- COVXBJIKNGVTNV-UHFFFAOYSA-N 1-chloro-1,2,2-trifluoroethene;1,1-difluoroethene Chemical group FC(F)=C.FC(F)=C(F)Cl COVXBJIKNGVTNV-UHFFFAOYSA-N 0.000 claims description 2
- -1 ethylene, tetrafluoroethylene Chemical group 0.000 claims description 2
- 229920006027 ternary co-polymer Polymers 0.000 claims 2
- NSGXIBWMJZWTPY-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropane Chemical compound FC(F)(F)CC(F)(F)F NSGXIBWMJZWTPY-UHFFFAOYSA-N 0.000 claims 1
- 239000011521 glass Substances 0.000 claims 1
- 230000007704 transition Effects 0.000 claims 1
- 229920000578 graft copolymer Polymers 0.000 description 20
- 238000004132 cross linking Methods 0.000 description 12
- 230000006835 compression Effects 0.000 description 9
- 238000007906 compression Methods 0.000 description 9
- 229920001971 elastomer Polymers 0.000 description 7
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 6
- 229910001220 stainless steel Inorganic materials 0.000 description 6
- 239000010935 stainless steel Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000005855 radiation Effects 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 description 3
- 230000001678 irradiating effect Effects 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- BOSAWIQFTJIYIS-UHFFFAOYSA-N 1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Cl)Cl BOSAWIQFTJIYIS-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- 229920006172 Tetrafluoroethylene propylene Polymers 0.000 description 2
- YOALFLHFSFEMLP-UHFFFAOYSA-N azane;2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctanoic acid Chemical compound [NH4+].[O-]C(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YOALFLHFSFEMLP-UHFFFAOYSA-N 0.000 description 2
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000013016 damping Methods 0.000 description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 150000001451 organic peroxides Chemical class 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- CFJYNSNXFXLKNS-UHFFFAOYSA-N p-menthane Chemical compound CC(C)C1CCC(C)CC1 CFJYNSNXFXLKNS-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 229920002725 thermoplastic elastomer Polymers 0.000 description 2
- VTNMILOTNNHIPP-GQCTYLIASA-N CCCCOOC(=O)\C=C\C Chemical compound CCCCOOC(=O)\C=C\C VTNMILOTNNHIPP-GQCTYLIASA-N 0.000 description 1
- GUTLYIVDDKVIGB-OUBTZVSYSA-N Cobalt-60 Chemical compound [60Co] GUTLYIVDDKVIGB-OUBTZVSYSA-N 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- NACXPGJRIJFGLA-BQYQJAHWSA-N bis[(2-methylpropan-2-yl)oxy] (e)-but-2-enediperoxoate Chemical compound CC(C)(C)OOOC(=O)\C=C\C(=O)OOOC(C)(C)C NACXPGJRIJFGLA-BQYQJAHWSA-N 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- TVFDJXOCXUVLDH-RNFDNDRNSA-N cesium-137 Chemical compound [137Cs] TVFDJXOCXUVLDH-RNFDNDRNSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 229920003020 cross-linked polyethylene Polymers 0.000 description 1
- 239000004703 cross-linked polyethylene Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000005251 gamma ray Effects 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- DNNSSWSSYDEUBZ-OUBTZVSYSA-N krypton-85 Chemical compound [85Kr] DNNSSWSSYDEUBZ-OUBTZVSYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229930004008 p-menthane Natural products 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 239000012966 redox initiator Substances 0.000 description 1
- 238000001175 rotational moulding Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- ZUHAKVLHBJLXGV-UHFFFAOYSA-N tert-butyl 2-methylprop-2-eneperoxoate Chemical compound CC(=C)C(=O)OOC(C)(C)C ZUHAKVLHBJLXGV-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 238000001721 transfer moulding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
- C08F259/08—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14219684A JPS6123638A (ja) | 1984-07-11 | 1984-07-11 | 含ふつ素樹脂架橋体の製造法 |
| IT8521351A IT1206737B (it) | 1984-07-11 | 1985-06-28 | Procedimento per produrre un corpo sagomato di copolimero ad innesto contenente fluoro con legame a reticolazione usando radiazione. |
| GB08517035A GB2161816B (en) | 1984-07-11 | 1985-07-05 | Method of producing shaped body of cross-linked fluorine-containing graft copolymer by using radiation |
| DE19853524370 DE3524370A1 (de) | 1984-07-11 | 1985-07-08 | Verfahren zur herstellung eines formkoerpers aus vernetztem, fluorhaltigem pfropfcopolymerem unter anwendung von strahlung |
| FR858510586A FR2567528B1 (fr) | 1984-07-11 | 1985-07-10 | Procede de production d'un corps en forme en un copolymere greffe contenant du fluor et reticule en utilisant un rayonnement |
| US06/753,983 US4652592A (en) | 1984-07-11 | 1985-07-11 | Method of producing shaped body of cross-linked fluorine-containing graft copolymer by using radiation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14219684A JPS6123638A (ja) | 1984-07-11 | 1984-07-11 | 含ふつ素樹脂架橋体の製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6123638A JPS6123638A (ja) | 1986-02-01 |
| JPS6352044B2 true JPS6352044B2 (en, 2012) | 1988-10-17 |
Family
ID=15309621
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14219684A Granted JPS6123638A (ja) | 1984-07-11 | 1984-07-11 | 含ふつ素樹脂架橋体の製造法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4652592A (en, 2012) |
| JP (1) | JPS6123638A (en, 2012) |
| DE (1) | DE3524370A1 (en, 2012) |
| FR (1) | FR2567528B1 (en, 2012) |
| GB (1) | GB2161816B (en, 2012) |
| IT (1) | IT1206737B (en, 2012) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0788414B2 (ja) * | 1987-08-10 | 1995-09-27 | セントラル硝子株式会社 | 軟質ふっ素樹脂の製造方法 |
| JPH01255522A (ja) * | 1988-04-06 | 1989-10-12 | Sumitomo Electric Ind Ltd | 耐熱耐油熱収縮チューブおよび絶縁電線 |
| DE3816327A1 (de) * | 1988-05-13 | 1989-11-23 | Hoechst Ag | Formkoerper aus einem vinylidenfluorid-copolymeren und verfahren zu seiner herstellung |
| US5282854A (en) * | 1989-10-11 | 1994-02-01 | Daikin Industries Ltd. | Fluorine-containing block copolymer and artificial lens comprising the same |
| US5206298A (en) * | 1989-12-19 | 1993-04-27 | Tomei Sangyo Kabushiki Kaisha | Graft copolymer, solution containing the graft copolymer for treating contact lens, and method of treating contact lens with the solution and making hydrophilic lens surface |
| US5441782A (en) * | 1991-07-16 | 1995-08-15 | Central Glass Company, Limited | Plastic laminate having polyamide resin surface layer and fluororesin surface layer |
| DE4224768A1 (de) * | 1992-07-27 | 1994-02-03 | Bayer Ag | Durch Pfropfcopolymerisation hergestellte thermoplastische Fluorelastomere |
| DE4302552A1 (de) * | 1993-01-29 | 1994-08-04 | Wacker Chemie Gmbh | Pfropf- und Core-Shell-Copolymerisate mit verbesserter Phasenanbindung zwischen Pfropfgrundlage und aufgepfropfter Polymerphase |
| DE4440201A1 (de) * | 1994-11-10 | 1996-05-15 | Bayer Ag | Reaktive und verarbeitbare Fluorpolymere, ein Verfahren zu deren Herstellung, ein Verfahren zur Herstellung von vernetzten, bepfropften oder modifizierten Fluorpolymeren unter Einsatz der reaktiven und verarbeitbaren Fluorpolymere und deren Verwendung |
| DE19611311A1 (de) * | 1996-03-22 | 1997-09-25 | Dyneon Gmbh | Schichtstoff |
| IT1292391B1 (it) * | 1997-06-20 | 1999-02-08 | Ausimont Spa | Elastomeri termoplastici |
| JPH11236511A (ja) * | 1997-11-17 | 1999-08-31 | Samsung Electronics Co Ltd | 光学高分子組成物 |
| JP2002524626A (ja) * | 1998-09-15 | 2002-08-06 | インターナショナル・パワー・ピーエルシー | 水性ベースのグラフト化 |
| GB2371262B (en) | 2001-01-17 | 2005-02-16 | Megaprint Group Ltd | Folding card |
| DE10351814A1 (de) * | 2003-10-30 | 2005-06-16 | Institut Für Polymerforschung Dresden E.V. | Radikalisch gekoppelte PTFE-Polymer-Compounds und Verfahren zu ihrer Herstellung |
| DE10351812B4 (de) * | 2003-10-30 | 2006-04-20 | Leibniz-Institut Für Polymerforschung Dresden E.V. | Modifizierte Perfluor-Kunststoffe und Verfahren zu ihrer Herstellung |
| DE10351813B4 (de) * | 2003-10-30 | 2006-04-13 | Leibniz-Institut Für Polymerforschung Dresden E.V. | Radikalisch gekoppelte PTFE-Polymer-Pulver und Verfahren zu ihrer Herstellung |
| JP5573162B2 (ja) * | 2008-02-01 | 2014-08-20 | 旭硝子株式会社 | 熱可塑性フッ素樹脂及びその製造方法 |
| US9234062B2 (en) | 2011-12-14 | 2016-01-12 | Honeywell International Inc. | Process, properties, and applications of graft copolymers |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3539488A (en) * | 1968-03-07 | 1970-11-10 | Ethyl Corp | Radiation curable polyvinyl chloride composition containing triallyl isocyanurate |
| US3947525A (en) * | 1973-01-30 | 1976-03-30 | Allied Chemical Corporation | Melt-processable, radiation cross-linkable E-CTFE copolymer compositions |
| US4155823A (en) * | 1976-10-12 | 1979-05-22 | Raychem Corporation | Shaped article from crosslinked fluorocarbon polymer and process therefor |
| US4472557A (en) * | 1983-05-19 | 1984-09-18 | Central Glass Company, Limited | Elastic fluorohydrocarbon resin and method of producing same |
-
1984
- 1984-07-11 JP JP14219684A patent/JPS6123638A/ja active Granted
-
1985
- 1985-06-28 IT IT8521351A patent/IT1206737B/it active
- 1985-07-05 GB GB08517035A patent/GB2161816B/en not_active Expired
- 1985-07-08 DE DE19853524370 patent/DE3524370A1/de active Granted
- 1985-07-10 FR FR858510586A patent/FR2567528B1/fr not_active Expired
- 1985-07-11 US US06/753,983 patent/US4652592A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE3524370A1 (de) | 1986-01-16 |
| FR2567528A1 (fr) | 1986-01-17 |
| FR2567528B1 (fr) | 1989-05-26 |
| GB2161816B (en) | 1987-10-21 |
| JPS6123638A (ja) | 1986-02-01 |
| IT1206737B (it) | 1989-05-03 |
| US4652592A (en) | 1987-03-24 |
| GB2161816A (en) | 1986-01-22 |
| IT8521351A0 (it) | 1985-06-28 |
| DE3524370C2 (en, 2012) | 1988-10-20 |
| GB8517035D0 (en) | 1985-08-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS6352044B2 (en, 2012) | ||
| US4148982A (en) | Thermal modification method for fluoroelastomers | |
| JP2789349B2 (ja) | ビニリデンフルオライド共重合体より成る成形体およびその製造方法 | |
| JP5598579B2 (ja) | 改質フッ素樹脂混合物、フッ素樹脂成形品、及び、フッ素樹脂成形品の製造方法 | |
| EP1576020B1 (en) | Fluoroplastic polymers having nitrogen-containing cure sites | |
| US4472557A (en) | Elastic fluorohydrocarbon resin and method of producing same | |
| EP0197562A2 (en) | Fluorine-containing elastomeric copolymer and use of the same | |
| DK149170B (da) | Fluorholdig copolymer | |
| ITMI972764A1 (it) | Elastomeri termoplastici fluorurati | |
| JP5392433B1 (ja) | 改質含フッ素共重合体、フッ素樹脂成形品、及び、フッ素樹脂成形品の製造方法 | |
| US3817951A (en) | Low-modulus thermoplastic ethylene-tetrafluoroethylene-hexafluoropropene terpolymers | |
| US6645590B1 (en) | Articles of functional fluoropolymer | |
| US3846267A (en) | Method for cross-linking copolymer of tetrafluoroethylene and propylene by ionizing radiation | |
| US3539488A (en) | Radiation curable polyvinyl chloride composition containing triallyl isocyanurate | |
| ITMI971468A1 (it) | Elastomeri termoplastici | |
| US3718558A (en) | Process for producing a cross-linked copolymer of tetrafluoroethylene and propylene using high energy ionizing radiation | |
| US4322511A (en) | Process of hydrolyzing fluorine-containing multi-component copolymers | |
| JPS58206615A (ja) | 柔軟性を有するふつ素樹脂の製造方法 | |
| US20210277218A1 (en) | Cross-linked thermoplastic polyvinylidene fluoride compositions | |
| US4155953A (en) | Process for production of modified polychlorotrifluoroethylene | |
| JPS5930847A (ja) | ポリフツ化ビニリデン樹脂組成物 | |
| JPH06136218A (ja) | 硬化性含フッ素ポリマー組成物およびその硬化方法 | |
| US3330886A (en) | Graft copolymers of polyvinyl chloride with butadiene, acrylate ester and diethylenic compound | |
| US3350373A (en) | Copolymers from 1, 2, 3, 3, 3-pentafluoropropylene and tetrafluoroethylene and process for preparing same | |
| EP0987288B1 (en) | Composition for vulcanizing fluororubbers and fluororubber moldings |