JPS6270562A - 鉄合金材料の表面処理方法 - Google Patents
鉄合金材料の表面処理方法Info
- Publication number
- JPS6270562A JPS6270562A JP21049685A JP21049685A JPS6270562A JP S6270562 A JPS6270562 A JP S6270562A JP 21049685 A JP21049685 A JP 21049685A JP 21049685 A JP21049685 A JP 21049685A JP S6270562 A JPS6270562 A JP S6270562A
- Authority
- JP
- Japan
- Prior art keywords
- iron alloy
- zirconium
- alloy material
- treatment
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims description 73
- 239000000956 alloy Substances 0.000 title claims description 72
- 229910000640 Fe alloy Inorganic materials 0.000 title claims description 68
- 238000004381 surface treatment Methods 0.000 title claims description 10
- 229910052726 zirconium Inorganic materials 0.000 claims description 94
- 239000010410 layer Substances 0.000 claims description 84
- 239000002344 surface layer Substances 0.000 claims description 79
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 73
- 239000000463 material Substances 0.000 claims description 48
- 238000010438 heat treatment Methods 0.000 claims description 34
- 239000003795 chemical substances by application Substances 0.000 claims description 30
- 239000011812 mixed powder Substances 0.000 claims description 30
- 238000005121 nitriding Methods 0.000 claims description 29
- -1 iron-carbon-nitrogen nitride Chemical class 0.000 claims description 15
- ZVWKZXLXHLZXLS-UHFFFAOYSA-N zirconium nitride Chemical compound [Zr]#N ZVWKZXLXHLZXLS-UHFFFAOYSA-N 0.000 claims description 14
- 229910001507 metal halide Inorganic materials 0.000 claims description 8
- 150000005309 metal halides Chemical class 0.000 claims description 8
- 150000001340 alkali metals Chemical class 0.000 claims description 7
- 229910052783 alkali metal Inorganic materials 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 6
- 230000008018 melting Effects 0.000 claims description 6
- 150000001805 chlorine compounds Chemical class 0.000 claims description 5
- 150000002222 fluorine compounds Chemical class 0.000 claims description 5
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 4
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 4
- FBMGKRKUOZTARV-UHFFFAOYSA-N F.OB(O)O Chemical class F.OB(O)O FBMGKRKUOZTARV-UHFFFAOYSA-N 0.000 claims description 3
- 150000001642 boronic acid derivatives Chemical class 0.000 claims description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 3
- 150000002823 nitrates Chemical class 0.000 claims description 3
- 150000003755 zirconium compounds Chemical class 0.000 claims description 3
- YYXHRUSBEPGBCD-UHFFFAOYSA-N azanylidyneiron Chemical compound [N].[Fe] YYXHRUSBEPGBCD-UHFFFAOYSA-N 0.000 claims description 2
- 150000001649 bromium compounds Chemical class 0.000 claims description 2
- 150000004694 iodide salts Chemical class 0.000 claims description 2
- 229910001093 Zr alloy Inorganic materials 0.000 claims 1
- 238000003672 processing method Methods 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 57
- 150000003839 salts Chemical class 0.000 description 36
- 229910052757 nitrogen Inorganic materials 0.000 description 34
- 229910052742 iron Inorganic materials 0.000 description 30
- 150000004767 nitrides Chemical class 0.000 description 28
- 239000000843 powder Substances 0.000 description 27
- 229910052799 carbon Inorganic materials 0.000 description 26
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 19
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 17
- 239000007789 gas Substances 0.000 description 16
- 238000007654 immersion Methods 0.000 description 15
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 12
- 238000004458 analytical method Methods 0.000 description 12
- 239000002585 base Substances 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 229910017076 Fe Zr Inorganic materials 0.000 description 7
- 229910000831 Steel Inorganic materials 0.000 description 7
- 238000009792 diffusion process Methods 0.000 description 7
- 239000010959 steel Substances 0.000 description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
- 238000005868 electrolysis reaction Methods 0.000 description 6
- 239000011780 sodium chloride Substances 0.000 description 6
- 238000002441 X-ray diffraction Methods 0.000 description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- 239000012298 atmosphere Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229910002804 graphite Inorganic materials 0.000 description 5
- 239000010439 graphite Substances 0.000 description 5
- 230000007246 mechanism Effects 0.000 description 5
- 238000001000 micrograph Methods 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 229910052786 argon Inorganic materials 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical compound [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 2
- 239000004375 Dextrin Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 229910026551 ZrC Inorganic materials 0.000 description 2
- 229910007932 ZrCl4 Inorganic materials 0.000 description 2
- OTCHGXYCWNXDOA-UHFFFAOYSA-N [C].[Zr] Chemical compound [C].[Zr] OTCHGXYCWNXDOA-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 150000001341 alkaline earth metal compounds Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical class FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 235000019425 dextrin Nutrition 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 2
- 229910001337 iron nitride Inorganic materials 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 239000006104 solid solution Substances 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000005211 surface analysis Methods 0.000 description 2
- 238000005496 tempering Methods 0.000 description 2
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 229910015900 BF3 Inorganic materials 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- 101100348017 Drosophila melanogaster Nazo gene Proteins 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 229910020261 KBF4 Inorganic materials 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910000746 Structural steel Inorganic materials 0.000 description 1
- 229910010342 TiF4 Inorganic materials 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 229910001514 alkali metal chloride Inorganic materials 0.000 description 1
- 229910001617 alkaline earth metal chloride Inorganic materials 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- LDDQLRUQCUTJBB-UHFFFAOYSA-N ammonium fluoride Chemical compound [NH4+].[F-] LDDQLRUQCUTJBB-UHFFFAOYSA-N 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 239000013040 bath agent Substances 0.000 description 1
- ZDVYABSQRRRIOJ-UHFFFAOYSA-N boron;iron Chemical compound [Fe]#B ZDVYABSQRRRIOJ-UHFFFAOYSA-N 0.000 description 1
- 238000009933 burial Methods 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 238000005255 carburizing Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005243 fluidization Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- MNWBNISUBARLIT-UHFFFAOYSA-N sodium cyanide Chemical compound [Na+].N#[C-] MNWBNISUBARLIT-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- XROWMBWRMNHXMF-UHFFFAOYSA-J titanium tetrafluoride Chemical compound [F-].[F-].[F-].[F-].[Ti+4] XROWMBWRMNHXMF-UHFFFAOYSA-J 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
Landscapes
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21049685A JPS6270562A (ja) | 1985-09-24 | 1985-09-24 | 鉄合金材料の表面処理方法 |
| AU59620/86A AU582000B2 (en) | 1985-06-17 | 1986-06-09 | Treating the surface of iron alloy materials |
| PCT/JP1986/000287 WO1986007614A1 (en) | 1985-06-17 | 1986-06-09 | Method of treating the surface of iron alloy materials |
| US07/023,862 US4765847A (en) | 1985-06-17 | 1986-06-09 | Method of treating the surface of iron alloy materials |
| EP86903588A EP0264448B1 (en) | 1985-06-17 | 1986-06-09 | Method of treating the surface of iron alloy materials |
| DE8686903588T DE3668913D1 (de) | 1985-06-17 | 1986-06-09 | Verfahren zur behandlung der oberflaeche von eisenlegierungsmaterialien. |
| CA000511632A CA1247468A (en) | 1985-06-17 | 1986-06-16 | Method of treating the surface of iron alloy materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21049685A JPS6270562A (ja) | 1985-09-24 | 1985-09-24 | 鉄合金材料の表面処理方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6270562A true JPS6270562A (ja) | 1987-04-01 |
| JPH0447028B2 JPH0447028B2 (enrdf_load_stackoverflow) | 1992-07-31 |
Family
ID=16590315
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21049685A Granted JPS6270562A (ja) | 1985-06-17 | 1985-09-24 | 鉄合金材料の表面処理方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6270562A (enrdf_load_stackoverflow) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013244534A (ja) * | 2012-05-29 | 2013-12-09 | Toyota Motor Corp | 表面処理方法および塗型剤 |
-
1985
- 1985-09-24 JP JP21049685A patent/JPS6270562A/ja active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013244534A (ja) * | 2012-05-29 | 2013-12-09 | Toyota Motor Corp | 表面処理方法および塗型剤 |
| US9605157B2 (en) | 2012-05-29 | 2017-03-28 | Toyota Jidosha Kabushiki Kaisha | Surface treatment method and coating agent |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0447028B2 (enrdf_load_stackoverflow) | 1992-07-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Dearnley et al. | Engineering the surface with boron based materials | |
| US4765847A (en) | Method of treating the surface of iron alloy materials | |
| US10689745B2 (en) | System and method for surface hardening of refractory metals | |
| US4818351A (en) | Method for the surface treatment of an iron or iron alloy article | |
| JPS61291962A (ja) | 鉄合金材料の表面処理方法 | |
| JPH0249271B2 (enrdf_load_stackoverflow) | ||
| JPS6270561A (ja) | 鉄合金材料の表面処理方法 | |
| CA1036976A (en) | Anodically dissolving group v-a element into molten borate bath | |
| CN115992338B (zh) | 过渡金属表面盐浴碳化制备碳化物涂层的方法 | |
| JPH05140725A (ja) | チタン材料の表面処理法 | |
| JPS6270562A (ja) | 鉄合金材料の表面処理方法 | |
| JPS63153259A (ja) | 鉄または鉄合金材料の表面処理方法 | |
| JPH0424422B2 (enrdf_load_stackoverflow) | ||
| JPS6335764A (ja) | 鉄または鉄合金材料の表面処理方法 | |
| JP2518710B2 (ja) | 鉄合金材料の表面処理方法および処理剤 | |
| JPS62156264A (ja) | 鉄合金材料の表面処理方法 | |
| JPS6141984B2 (enrdf_load_stackoverflow) | ||
| JPS62107055A (ja) | 鉄合金材料の表面処理方法 | |
| US3959092A (en) | Method for a surface treatment of cemented carbide article | |
| JPS622628B2 (enrdf_load_stackoverflow) | ||
| JP2616814B2 (ja) | 鉄合金材料の表面処理方法および処理剤 | |
| JPS63125654A (ja) | 鉄または鉄合金材料の表面処理方法 | |
| Stern | Metalliding | |
| JP2000160319A (ja) | アルミニウムの表面窒化方法 | |
| JPS6227577A (ja) | 金属化合物層を備えた表面処理物品およびその製法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |