JPS6243923B2 - - Google Patents
Info
- Publication number
- JPS6243923B2 JPS6243923B2 JP57047502A JP4750282A JPS6243923B2 JP S6243923 B2 JPS6243923 B2 JP S6243923B2 JP 57047502 A JP57047502 A JP 57047502A JP 4750282 A JP4750282 A JP 4750282A JP S6243923 B2 JPS6243923 B2 JP S6243923B2
- Authority
- JP
- Japan
- Prior art keywords
- polyphosphonate
- alkali metal
- metal salt
- composition according
- nacl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 86
- 239000000203 mixture Substances 0.000 claims description 54
- 239000011780 sodium chloride Substances 0.000 claims description 43
- -1 alkali metal salt Chemical class 0.000 claims description 36
- 239000003599 detergent Substances 0.000 claims description 25
- 238000004061 bleaching Methods 0.000 claims description 24
- 229910052783 alkali metal Inorganic materials 0.000 claims description 20
- 125000002947 alkylene group Chemical group 0.000 claims description 13
- 238000009472 formulation Methods 0.000 claims description 13
- 239000007844 bleaching agent Substances 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 9
- 239000013078 crystal Substances 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 238000003860 storage Methods 0.000 claims description 7
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 125000004437 phosphorous atom Chemical group 0.000 claims description 4
- 230000000087 stabilizing effect Effects 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 3
- 125000000524 functional group Chemical group 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 claims description 3
- 239000012459 cleaning agent Substances 0.000 claims description 2
- 159000000011 group IA salts Chemical class 0.000 claims description 2
- 239000012736 aqueous medium Substances 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 description 16
- 150000003839 salts Chemical class 0.000 description 13
- 239000000243 solution Substances 0.000 description 13
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical class OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 12
- 125000000217 alkyl group Chemical group 0.000 description 11
- 239000011734 sodium Substances 0.000 description 10
- 239000002253 acid Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 7
- 150000007513 acids Chemical class 0.000 description 6
- 239000000872 buffer Substances 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
- 239000012190 activator Substances 0.000 description 5
- 125000000129 anionic group Chemical group 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000007859 condensation product Substances 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 229910052700 potassium Inorganic materials 0.000 description 5
- 239000011591 potassium Substances 0.000 description 5
- 230000003381 solubilizing effect Effects 0.000 description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 125000002091 cationic group Chemical group 0.000 description 4
- 125000001165 hydrophobic group Chemical group 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 description 4
- 235000011152 sodium sulphate Nutrition 0.000 description 4
- 125000001424 substituent group Chemical group 0.000 description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 4
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 3
- 125000002252 acyl group Chemical group 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 3
- 150000007942 carboxylates Chemical class 0.000 description 3
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 229920005646 polycarboxylate Polymers 0.000 description 3
- 150000004760 silicates Chemical class 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 229910052911 sodium silicate Inorganic materials 0.000 description 3
- 239000003760 tallow Substances 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical group 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 235000011180 diphosphates Nutrition 0.000 description 2
- HUPXVBJTMJUPEX-UHFFFAOYSA-L disodium hydrogen peroxide hydrogen sulfate chloride Chemical class [Cl-].[Na+].OO.S(=O)(=O)([O-])O.[Na+] HUPXVBJTMJUPEX-UHFFFAOYSA-L 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- ATJCASULPHYKHT-UHFFFAOYSA-N hexadecane-1,16-diamine Chemical compound NCCCCCCCCCCCCCCCCN ATJCASULPHYKHT-UHFFFAOYSA-N 0.000 description 2
- POIZGMCHYSVWDU-UHFFFAOYSA-N icosane-1,20-diamine Chemical compound NCCCCCCCCCCCCCCCCCCCCN POIZGMCHYSVWDU-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000003871 sulfonates Chemical class 0.000 description 2
- 150000008053 sultones Chemical class 0.000 description 2
- 239000000271 synthetic detergent Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 2
- 239000001124 (E)-prop-1-ene-1,2,3-tricarboxylic acid Substances 0.000 description 1
- CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical compound OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 description 1
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 1
- CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 1
- VBDFPNJHQVMOPA-UHFFFAOYSA-N 2-acetyloxybenzenesulfonic acid Chemical compound CC(=O)OC1=CC=CC=C1S(O)(=O)=O VBDFPNJHQVMOPA-UHFFFAOYSA-N 0.000 description 1
- OQUFOZNPBIIJTN-UHFFFAOYSA-N 2-hydroxypropane-1,2,3-tricarboxylic acid;sodium Chemical compound [Na].OC(=O)CC(O)(C(O)=O)CC(O)=O OQUFOZNPBIIJTN-UHFFFAOYSA-N 0.000 description 1
- PSZAEHPBBUYICS-UHFFFAOYSA-N 2-methylidenepropanedioic acid Chemical compound OC(=O)C(=C)C(O)=O PSZAEHPBBUYICS-UHFFFAOYSA-N 0.000 description 1
- TXPKUUXHNFRBPS-UHFFFAOYSA-N 3-(2-carboxyethylamino)propanoic acid Chemical class OC(=O)CCNCCC(O)=O TXPKUUXHNFRBPS-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Chemical class C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- QNAYBMKLOCPYGJ-UHFFFAOYSA-N Alanine Chemical class CC([NH3+])C([O-])=O QNAYBMKLOCPYGJ-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- FFDGPVCHZBVARC-UHFFFAOYSA-N N,N-dimethylglycine Chemical group CN(C)CC(O)=O FFDGPVCHZBVARC-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical group OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Chemical class O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 239000001083 [(2R,3R,4S,5R)-1,2,4,5-tetraacetyloxy-6-oxohexan-3-yl] acetate Substances 0.000 description 1
- UAOKXEHOENRFMP-ZJIFWQFVSA-N [(2r,3r,4s,5r)-2,3,4,5-tetraacetyloxy-6-oxohexyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O UAOKXEHOENRFMP-ZJIFWQFVSA-N 0.000 description 1
- WERKSKAQRVDLDW-ANOHMWSOSA-N [(2s,3r,4r,5r)-2,3,4,5,6-pentahydroxyhexyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO WERKSKAQRVDLDW-ANOHMWSOSA-N 0.000 description 1
- XEKWJQURPPJYTC-UHFFFAOYSA-N [Cl-].CC(CCCCCCCCCCC[NH+](CCCCCCCCCCCC)CC)C Chemical compound [Cl-].CC(CCCCCCCCCCC[NH+](CCCCCCCCCCCC)CC)C XEKWJQURPPJYTC-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 229940091181 aconitic acid Drugs 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 125000005277 alkyl imino group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000012914 anti-clumping agent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- ZTRXAIIXCCGSMH-UHFFFAOYSA-N azanium;2,3-dipentylnaphthalene-1-sulfonate Chemical compound [NH4+].C1=CC=C2C(S([O-])(=O)=O)=C(CCCCC)C(CCCCC)=CC2=C1 ZTRXAIIXCCGSMH-UHFFFAOYSA-N 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N beta-monoglyceryl stearate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- GTZCVFVGUGFEME-IWQZZHSRSA-N cis-aconitic acid Chemical compound OC(=O)C\C(C(O)=O)=C\C(O)=O GTZCVFVGUGFEME-IWQZZHSRSA-N 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000001687 destabilization Effects 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- GFLLOMRSVVPUNQ-UHFFFAOYSA-M dimethyl-propyl-tetradecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)CCC GFLLOMRSVVPUNQ-UHFFFAOYSA-M 0.000 description 1
- 108700003601 dimethylglycine Proteins 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- RXHDXDIEHWVFOC-UHFFFAOYSA-M ethyl-dimethyl-octadecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC RXHDXDIEHWVFOC-UHFFFAOYSA-M 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000002979 fabric softener Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000001087 glyceryl triacetate Substances 0.000 description 1
- 235000013773 glyceryl triacetate Nutrition 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- ZIJNHAPCKXQHDW-UHFFFAOYSA-N hexadecanoic acid oxirane Chemical compound C1CO1.CCCCCCCCCCCCCCCC(O)=O ZIJNHAPCKXQHDW-UHFFFAOYSA-N 0.000 description 1
- WZXYXXWJPMLRGG-UHFFFAOYSA-N hexadecyl benzenesulfonate Chemical compound CCCCCCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 WZXYXXWJPMLRGG-UHFFFAOYSA-N 0.000 description 1
- 229940005740 hexametaphosphate Drugs 0.000 description 1
- 229910052806 inorganic carbonate Inorganic materials 0.000 description 1
- 229910052816 inorganic phosphate Inorganic materials 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical class OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 230000002366 lipolytic effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000005341 metaphosphate group Chemical group 0.000 description 1
- 125000005528 methosulfate group Chemical group 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- 229940043348 myristyl alcohol Drugs 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229940044652 phenolsulfonate Drugs 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 230000002797 proteolythic effect Effects 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 108700004121 sarkosyl Proteins 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229940077386 sodium benzenesulfonate Drugs 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 1
- DHQIJSYTNIUZRY-UHFFFAOYSA-M sodium;2,3-di(nonyl)naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CCCCCCCCC)C(CCCCCCCCC)=CC2=C1 DHQIJSYTNIUZRY-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000012430 stability testing Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- XGMYMWYPSYIPQB-UHFFFAOYSA-J tetrasodium;2-(1,2-dicarboxylatoethoxy)butanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC(C([O-])=O)OC(C([O-])=O)CC([O-])=O XGMYMWYPSYIPQB-UHFFFAOYSA-J 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Chemical class OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- 229940087291 tridecyl alcohol Drugs 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229940071104 xylenesulfonate Drugs 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3937—Stabilising agents
- C11D3/394—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/055—Peroxyhydrates; Peroxyacids or salts thereof
- C01B15/06—Peroxyhydrates; Peroxyacids or salts thereof containing sulfur
- C01B15/08—Peroxysulfates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Detergent Compositions (AREA)
Description
æ¬çºæã¯éé
žåæ°ŽçŽ ä»å ç©ãç¹ã«ã¢ã«ã«ãªæ§æŒ
çœåªè³ªäžã«ãããŠæ¹è¯ãããå®å®æ§ããã€ç¡«é žã
ããªãŠã âéé žåæ°ŽçŽ âå¡©åãããªãŠã ä»å ç©ã«
é¢ããã åŒïŒ4Na2SO4ã»2H2O2ã»NaCl ããã€ç¡«é žãããªãŠã âéé žåæ°ŽçŽ âå¡©åãããª
ãŠã ä»å ç©ã¯éé žçŽ æŒçœå€ãšããŠç¥ãããŠããã
ãã®ä»å ç©ã¯æ°Žæº¶æ¶²äžã§ç¡«é žãããªãŠã ãå¡©åã
ããªãŠã ããã³éé žåæ°ŽçŽ ãåå¿ãããŠå®¹æã«ã
ããããããã¯æº¶è§£é床ãéããå·æ°Žãžã®æº¶è§£åºŠ
ã倧ãããšããããããæ§è³ªããã¡ãŸãå®äŸ¡ç¡æ¯
ã®åºçºç©è³ªãã補é ã§ããããã®è£œåã®è£œæ³ãšæŒ
çœçšéçã®è©³çŽ°ã«ã€ããŠã¯ç±³åœç¹èš±ç¬¬3979312
å·ã3979313å·ããã³4005182å·ã«èšèŒãããŠã
ãã 4Na2SO4ã»2H2O2ã»NaClã¯äžè¬ã«ããããæŒçœ
äœçšã瀺ããã匷åæŒçœå€ã«å«ãŸããåã®èæ§å¡©
é¡ã®ååšã«ãããŠã¯äžå®å®ã§ãããšãã奜ãŸãã
ãªãæ§è³ªããã€ãŠããããã®ã¢ã«ã«ãªæææ§ã¯å°
ãªããšãååãšããŠã¯æŒçœã«ããã4Na2SO4ã»
2H2O2ã»NaClã®å©çšã倧ããå¶éããŠããã
4Na2SO4ã»2H2O2ã»NaClã®ã¢ã«ã«ãªæ§äžå®å®è§£æ¶
ã¯æããã«æŒçœæè¡ã«å¯äžããã§ãããã ãããã€ãŠæ¬çºæã®ç®çã¯ã¢ã«ã«ãªã«å®å®ãª
4Na2SO4ã»2H2O2ã»NaClããã³ãã®è£œæ³ãæäŸã
ãããšã«ãããæ¬çºæã®ç®çã¯ãŸãäžèšã¢ã«ã«ãª
å®å®æ§4Na2SO4ã»2H2Oã»NaClãå«ãå®å®ãªã¢ã«
ã«ãªæ§æŒçœçšçµæç©ããã³ãã®çšæ³ãæäŸããã
ãšã«ãããä»ã®ç®çã¯æ¬æ现æžããæããã«ãªã
ã§ãããã æ¬çºæã«ããã°äžèšç®çã¯4Na2SO4ã»2H2Oã»
NaClã®çµæ¶æ§é äžã«å¯æº¶æ§ææ©ããªãã¹ããã€
ããå«æãããã¢ã«ã«ãªå®å®æ§ä»å ç©ãã¢ã«ã«ãª
æ§æŒçœç³»ã«éé žçŽ æŒçœå€ãšããŠäœ¿çšããããšã«ã
ã€ãŠå®çŸããããããªãã¹ããã€ãã®ååšãé€å€
ããŠ4Na2SO4ã»2H2Oã»NaClã¯ç¥ãããæ¹æ³ã§è£œ
é ããçµæ¶åããããäžè¬ã«åå¿ã¯æ°Žæº¶æ¶²äž
NaClã®ååšã«ãããŠïŒä¹è³50âã®æž©åºŠã«ãããŠ
ç¡«é žãããªãŠã ãéé žåæ°ŽçŽ ãšçµåãããããšã«
ããè¡ããããåå¿ç³»äžã®éé žåæ°ŽçŽ æ¿åºŠã¯70ä¹
è³800ïœïŒãšããŸãå¡©åãããªãŠã æ¿åºŠã¯20ä¹
è³300ïœïŒãšãããã€åå¿ç³»ããçµæ¶æ§åºäœã
ååããã4Na2SO4ã»2H2O2ã»NaClã®æ¶åºäžããª
ãã¹ããã€ããååšããéããã®å°å ¥ã¯è£œé äžé©
å®ã®ææã«ã§ããã ã¢ã«ã«ãªã«å¯Ÿãå®å®ãšããããã«ã¯ããªãã¹ã
ãã€ãã¯4Na2SO4ã»2H2O2ã»NaClã®çµæ¶æ§é äžã«
å«ãŸããããå¿ èŠããããåã«çæãããä»å ç©
ã«ããªãã¹ããã€ããæ·»å ããŠãå¹æããªããã
ãªãã¹ããã€ãã¯4Na2SO4ã»2H2O2ã»NaClãã¢ã«
ã«ãªã«å¯Ÿãäžææ§ãšããæ§ãã®çµæ¶æ§è³ªãå€ãã
ãåã¯æ§è³ªã«äœãã圱é¿ãäžããããšã¯æããã§
ãããããã«ã€ããŠé¡åŸ®é¡æ€æ»ã¯ãã¹ããã€ãã§
åŠçãã4Na2SO4ã»2H2O2ã»NaClãšå¯Ÿç §è©Šæã®é
ã®çµæ¶åœ¢ã«å·®éã瀺ããããâç·åæãã¿ãŒã³
ã®å·®éã¯æããã§ãªãã€ããããã«åããŠ
4Na2SO4ã»2H2O2ã»NaClã®éå®å®åè©Šæã®å解枩
床ã180âåã¯ãã以äžã§ããã®ã«æ¯ã¹ãŠå®å®å
è©Šæã®ããã220âã§ãããããå®å®åãããä»
å ç©ãçšãã補åã¯ç±å®å®æ§ãæ¹è¯ãããŠããã 4Na2SO4ã»2H2O2ã»NaClã®å®å®åã«æå¹ãšãã
ã€ãŠããããªãã¹ããã€ãã¯ã¢ã«ãã¬ã³éãçªçŽ
ååã®ä»åšããŠããã¢ã«ãã¬ã³éããã³ãããã
ã·çœ®æåºããã€ã¢ã«ãã¬ã³éããæã矀ãããã
ã°ããïŒäŸ¡ã®éãä»ããŠããååã©ãããçµåã
ãŠããâPO3ïŒå®èœåºãïŒå以äžãã€ææ©ããªã
ã¹ããã€ãã§ããã æ¬æ现æžã«ãããŠããªãã¹ããã€ããšã¯éé¢é ž
ããã³ãã®å¡©é¡ãå å«ãããããªãã¹ããã€ãã®
äŸã«ã¯æ¬¡ã®ããªãã¹ãã³é žåã¯ãããã®ã¢ã«ã«ãª
éå±å¡©é¡ãããïŒ 4Na2SO4ã»2H2Oã»NaClãå®å®åããã«æå¹ãª
ããªãã¹ããã€ãéã¯ä»å ç©èªäœã«å¯Ÿã極ããŠå°
éã§ããããã¡ãããããªãã¹ããã€ãã®ååé
䞊ã³ã«ãã¹ããã€ãå®èœåºã®æ°ã¯ããããå®å®åºŠ
ã«åœ±é¿ãããã®çš®ã®ãããã®ã¯ä»ã®ãã®ãããæ
å¹ã§ãããäžè¬ã«çµæç©ééãåºæºãšããŠå¯æº¶æ§
ããªãã¹ããã€ã0.001ä¹è³2.0ééïŒ ãå«ã
4Na2SO4ã»2H2O2ã»NaClã¯ä»å ç©ã«ååãªå®å®æ§
ãäžããã®ã§ã匷åæŒçœå€ãšæž æµå€äžã®éé žçŽ æŒ
çœæ§æåãšããŠäœ¿çšã§ããã æ¬çºæã®å®å®å4Na2SO4ã»2H2O2ã»NaClãå«ã
ã¢ã«ã«ãªæ§æŒçœçµæç©ã¯ç¥ãããæ¹æ³ã§è£œé ãã
ã代衚çéé žçŽ æŒçœå€ã§ãããåºæ¬æåã¯éé žçŽ
æŒçœå€ãšïŒãè¶ ããŠå¥œãŸããã¯10.6ååŸã®PHãã
ã€æŒçœæ°Žæº¶æ¶²ãäžããã¢ã«ã«ãªæ§æåã§ãããå¿
èŠãªPHæ¡ä»¶ã«ä¿ã€ããç·©è¡å€ãå¿ èŠãªããšãã
ããããã§äœ¿ãç·©è¡å€ã«ã¯æº¶æ¶²PHãæãç¯å²å ã«
å€ãããã³ïŒåã¯ïŒä¿ã€é劚害æ§ååç©ãããã
ãã®æ§ãªç·©è¡å€ã¯åœæ¥è ã«ãã€ãŠå®¹æã«éžæã§ã
ããäŸãã°PHãïŒä¹è³12ã®ç¯å²å ã«ç·©è¡ãããã¹
ããšã€ããçé žå¡©åã¯éçé žå¡©é¡ã䟿å©ã§ããã
奜ãŸããç·©è¡å€ã®äŸã¯éçé žãããªãŠã ãçé žã
ããªãŠã ãããé žãããªãŠã ãããé žæ°ŽçŽ ïŒãã
ãªãŠã ãããé žïŒæ°ŽçŽ ãããªãŠã ã§ãããæŒçœæº¶
液ã¯æž æµå€ãå«ãã§ããŠãããããã®å Žåç¹åžã®
æŒçœãšæŽæ¿¯ãåæã«ã§ãããæž æµå€æ¿åºŠã¯æ®éæŽ
æµæ°Žã®0.05ä¹è³0.20ééïŒ ã§ããã æ¬çºæã®å®å®åããã4Na2SO4ã»2H2O2ã»NaCl
ã¯äžè¬ã«ã¢ã«ã«ãªæ§æŒçœã«äœ¿çšã§ããããä»å ç©
ã¯åŒ·åã¢ã«ã«ãªæ§æž æµçšçµæç©äžã«éé žçŽ æŒçœå€
ãšããŠå«ãŸãããäžè¬ã«100ééïŒ äžã(a)æ¬çºæ
ã®å®å®åããã4Na2SO4ã»2H2O2ã»NaCl3ä¹è³70
ééïŒ ïŒ(b)ã¢ã«ã«ãªæ§ç¡æ©å¡©ãã«ããŒ30ä¹è³80é
éïŒ ïŒ(c)è¡šé¢æŽ»æ§å€ïŒä¹è³20ééïŒ ïŒ(d)å å¡«å€ãš
ããŠäžæ§åã¯ã¢ã«ã«ãªæ§å¡©ïŒä¹è³50ééïŒ ãå«
ããçµæç©ã¯æ®éæŽæ¿¯åã¯æž æµçšçµæç©ã«æ·»å ã
ããçš®ã ã®ä»»æç©è³ªãïŒä¹è³çŽïŒééïŒ å«ãã§ã
ãŠããããéŠæãå åŠèŒå€ãå å¡«å€ãå¡åé²æ¢
å€ãåžæè»å€çã®æ§ãªè£å©å€ãæž æµå€çµæç©äžã«
䜿çšããŠããããããæ§è³ªãäžãããããããã
å ããŠããããé µçŽ ãç¹ã«ç±ã«å®å®ãªæž æµå€ã«äœ¿
ãããèçœè³ªå解ããã³èèªåè§£é µçŽ ãçµæç©äž
ã«ä¹ŸåŒæ··åã§ããã æ¬çºæã®äœ¿çšã«é©ããè¡šé¢æŽ»æ§å€ã¯æ¯èŒçåºç¯
å²ã®ç©è³ªãå å«ãé°ã€ãªã³æ§ãéã€ãªã³æ§ãè žã€
ãªã³æ§åã¯äž¡æ§åã®ãã®ã§ãããã é°ã€ãªã³æ§è¡šé¢æŽ»æ§å€ã«ã¯ææ©çæ°Žæ§åºãšé°ã€
ãªã³æ§æº¶è§£ååºããã€è¡šé¢æŽ»æ§åã¯æž æµæ§ååç©
é¡ããããé°ã€ãªã³æº¶è§£ååºã®ä»£è¡šäŸã«ã¯ã¹ã«ã
ãªãã€ãããµã«ããšã€ããã«ã«ããã·ã¬ã€ããã
ã¹ããã€ãããã³ãã¹ããšã€ããããã奜ãŸãã
é°ã€ãªã³æ§æž æµå€ã®äŸã«ã¯åç©ãæ€ç©åã¯æµ·ç£ç©
ã®èèªãæ²¹ããã³ã¯ãã¯ã¹ããçæã§ããæ§ãªé«
çŽèèªé žåã¯ããžã³é žã®æ°Žæº¶æ§å¡©ã®æ§ãªç³ããã
äŸãã°çèãã°ãªãŒã¹ãã³ã³ãããæ²¹ãããŒã«æ²¹
ããã³ãããã®æ··åç©ã®ãããªãŠã ç³ããïŒãã
ã³ç¡«é žå¡©ååã¯ã¹ã«ããªã³é žå¡©åãããåææŽ
å€ãç¹ã«ååäžã«ççŽ ååçŽïŒä¹è³26ã奜ãŸãã
ã¯çŽ12ä¹è³22ããã€ãã®ãããã 奜ãŸããé°ã€ãªã³æ§åææŽå€ã®äŸãšããŠã¯é«çŽ
ã¢ã«ãã«åæ žè³éŠæã¹ã«ããªãã€ããç¹ã«ã¢ã«ã
ã«åºäžã«ççŽ åå10ä¹è³16ããã€é«çŽã¢ã«ãã«ã
ã³ãŒã³ã¹ã«ããªãã€ãã®æ§ãªLASåãäŸãã°ã
ã·ã«ããŠã³ãã·ã«ãããã·ã«ïŒã©ãŠãªã«ïŒãããª
ãã·ã«ãããã©ãã·ã«ããã³ã¿ãã·ã«åã¯ãããµ
ãã·ã«ãã³ãŒã³ã¹ã«ããªãã€ãããã³é«çŽã¢ã«ã
ã«ãã«ãšã³ããã·ã¬ã³ããã³ããšããŒã«ã¹ã«ããª
ãã€ãã®ãããªãŠã å¡©ïŒã¢ã«ãã«ããã¿ã¬ã³ã¹ã«
ããªãã€ããã¢ã³ã¢ããŠã ãžã¢ãã«ããã¿ã¬ã³ã¹
ã«ããªãã€ãããã³ãããªãŠã ãžããã«ããã¿ã¬
ã³ã¹ã«ããªãã€ãã奜ãŸããã ä»ã®é°ã€ãªã³æ§æŽå€ã«ã¯é·éã¢ã«ã±ã³ã¹ã«ããª
ãã€ããé·éããããã·ã¢ã«ã«ã³ã¹ã«ããªãã€ã
åã¯ã¢ã«ã±ã³ã¹ã«ããªãã€ããšããããã·ã¢ã«ã«
ã³ã¹ã«ããªãã€ãã®æ··åç©ãå«ããªã¬ãã€ã³ã¹ã«
ããªãã€ãé¡ãããããã®ãªã¬ãã€ã³ã¹ã«ããªã
ã€ãã¯SO3ãåŒRCHïŒCHR1ïŒäœãã¯ã¢ã«ãã«
ãè¡šãããã€R1ã¯ã¢ã«ãã«åã¯æ°ŽçŽ ãè¡šããïŒ
ããã€é·éãªã¬ãã€ã³ïŒççŽ ååïŒä¹è³25ã奜ãŸ
ããã¯12ä¹è³21ããã€ïŒãšåå¿ãããŠãµã«ãã³ãš
ã¢ã«ã±ã³ã¹ã«ããªã³é žã®æ··åç©ãšããåŸæ··åç©ã
åŠçããŠãµã«ãã³ãã¹ã«ããªãã€ãã«è»¢åããç¥
ãããæ¹æ³ã§è£œé ã§ãããä»ã®ãµã«ããšã€ãåã¯
ã¹ã«ããªãã€ãæŽå€ã®äŸã«ã¯ã¢ã«ãã¢ãªã¬ãã€ã³
ãšéäºç¡«é žå¡©ïŒäŸãã°éäºç¡«é žãããªãŠã ïŒã®å
å¿çæç©ã®æ§ãªãã©ãã€ã³ã¹ã«ããªãã€ããäŸã
ã°ççŽ ååçŽ10â20ã奜ãŸããã¯çŽ15â20ããã€
第ïŒçŽãã©ãã€ã³ã¹ã«ããªãã€ãïŒé«çŽã¢ã«ã³ãŒ
ã«ã®ãµã«ããšã€ããαâã¹ã«ããªèèªé žãšã¹ãã«
ã®å¡©é¡ïŒäŸãã°ã¡ãã«Î±âã¹ã«ããªããªã¹ãã€ã
åã¯Î±âã¹ã«ããªã¿ããŠãšã€ãã®æ§ãªççŽ ååæ°
10â20ããã€ãã®ïŒãããã é«çŽã¢ã«ã³ãŒã«ã®ãµã«ããšã€ãã®äŸã«ã¯ã©ãŠãª
ã«ç¡«é žãããªãŠã ãã¿ããŠã¢ã«ã³ãŒã«ç¡«é žãããª
ãŠã ãã¿ãŒããŒã¬ããæ²¹åã¯ä»ã®ç¡«é žåæ²¹ãåã¯
èèªé žã®ã¢ãâåã¯ãžâã°ãªã»ãªãã®ç¡«é žå¡©ïŒäŸ
ãã°ã¹ãã¢ãªã³é žã¢ãã°ãªã»ãªãã¢ããµã«ããšã€
ãïŒããšãã¬ã³ãªããµã€ããšã©ãŠãªã«ã¢ã«ã³ãŒã«
ã®çž®åçæç©ç¡«é žå¡©ã®æ§ãªã¢ã«ãã«ããªïŒãšãã
ãã·ïŒãšãŒãã«ãµã«ããšã€ãïŒæ®éåååœããšã
ããã·åºïŒä¹è³ïŒããã€ïŒïŒã©ãŠãªã«åã¯ä»ã®ã¢
ã«ãã«ã°ãªã»ãªã«ãšãŒãã«ãµã«ããšã€ãïŒãšãã¬
ã³ãªããµã€ããšããã«ããšããŒã«ã®çž®åçæç©ç¡«
é žå¡©ã®æ§ãªè³éŠæããªïŒãšãããã·ïŒãšãŒãã«ãµ
ã«ããšã€ãïŒæ®éåååœããªãã·ãšãã¬ã³åºïŒä¹
è³20ã奜ãŸããã¯ïŒâ12ããã€ïŒãããã 奜ãŸããé°ã€ãªã³æ§æŽå€ã«ã¯ãŸãã¢ã·ã«ãµã«ã³
ã·ãã€ãïŒäŸãã°ãããªãŠã ã©ãŠãã€ã«ãµã«ã³ã·
ãã€ãïŒãã€ã»ããªãã€ãã®ã¢ã·ã«ãšã¹ãã«ïŒäŸ
ãã°ãªã¬ã€ã³é žãšã¹ãã«ïŒããã³ã¢ã·ã«ïŒ®âã¡ã
ã«ã¿ãŠã©ã€ãïŒäŸãã°ã«ãªãŠã âã¡ãã«ã©ãŠã
ã€ã«åã¯ãªã¬ã€ã«ã¿ãŠã©ã€ãïŒãããã ä»ã®éåžžã«å¥œãŸãã氎溶æ§é°ã€ãªã³æ§æŽå€åå
ç©ã«ã¯é«çŽã¢ã«ãã«ãµã«ããšã€ãããã³é«çŽèèª
é žã¢ãã°ãªã»ãªããµã«ããšã€ãã®ã¢ã³ã¢ããŠã ã
眮æã¢ã³ã¢ããŠã ïŒã¢ãâããžâãããã³ããªâ
ãšã¿ããŒã«ã¢ãã³ã®æ§ãªïŒãã¢ã«ã«ãªéå±ãïŒãã
ãªãŠã ãšã«ãªãŠã ã®æ§ãªïŒãããã³ã¢ã«ã«ãªåé¡
éå±ïŒäŸãã°ã«ã«ã·ãŠã ãšãã°ãã·ãŠã ïŒãå¡©é¡
ããããç¹å®ã®èª¿åããã³å²åã«å¿ããŠç¹å®ã®å¡©
ãé©å®éžã°ããã§ãããã éã€ãªã³æ§è¡šé¢æŽ»æ§å€ã«ã¯ã«ã«ããã·ã¬ã€ãã
ããããã·ã«ãã¢ããåã¯ã¢ããã®æ§ãªæº¶è§£ååº
ãšãšãã¬ã³ãªããµã€ãåã¯ããªãšãã¬ã³ã°ãªã³ãŒ
ã«ã®åå¿çæç©ã§ããææ©çæ°Žæ§åºãšèŠªæ°Žæ§åºã
ãã€è¡šé¢æŽ»æ§åã¯æž æµæ§ååç©ãããã 䜿çšã§ããéã€ãªã³æ§è¡šé¢æŽ»æ§å€ã®äŸã«ã¯ã¢ã«
ãã«ããšããŒã«ãšãšãã¬ã³ãªããµã€ãã®çž®åçæ
ç©ãäŸãã°ãªã¯ãã«ããšããŒã«ãšçŽïŒä¹è³30ã®ãš
ãã¬ã³ãªããµã€ãåäœã®åå¿çæç©ïŒã¢ã«ãã«ã
ãªããšããŒã«ãš10ä¹è³15ã®ãšãã¬ã³ãªããµã€ãå
äœã®çž®åçæç©ïŒããªãã·ã«ã¢ã«ã³ãŒã«ã®æ§ãªé«
çŽèèªæã¢ã«ã³ãŒã«ãšãšãã¬ã³ãªããµã€ãã®çž®å
çæç©ïŒãœã«ãããŒã«ã¢ãã©ãŠã¬ã€ãããœã«ãã
ãŒã«ã¢ããªã¬ãšã€ãããã³ãã³ãããŒã«ã¢ããã«
ããã€ãã®æ§ãªïŒäŸ¡ã¢ã«ã³ãŒã«ããã³ãã®å éšãš
ãŒãã«ã®ã¢ãâãšã¹ãã«ã®ãšãã¬ã³ãªããµã€ãçž®
åç©ïŒããã³ããªãããã¬ã³ã°ãªã³ãŒã«ãšãšãã¬
ã³ãªããµã€ãã®çž®åçæç©ãããã éœã€ãªã³æ§è¡šé¢æŽ»æ§å€ã䜿çšã§ããããããã«
ã¯ææ©çæ°Žæ§åºãšéœã€ãªã³æ§æº¶è§£ååºããã€è¡šé¢
掻æ§æž æµæ§ååç©ãããã代衚çéœã€ãªã³æ§æº¶è§£
ååºã¯ã¢ãã³åºãšç¬¬ïŒçŽåºã§ããã 奜ãŸããåæéœã€ãªã³æ§æŽå€ã®äŸã«ã¯åŒ
RNHC2H4NH2ïŒäœãã¯ççŽ ååçŽ12ä¹è³22ã
ãã€ã¢ã«ãã«åºãè¡šããïŒããã€æ§ãªãžã¢ãã³ã
äŸãã°ïŒ®âïŒâã¢ãããšãã«ã¹ãã¢ãªã«ã¢ãã³ã
ãã³ïŒ®âïŒâã¢ãããšãã«ããªã¹ãã«ã¢ãã³ïŒåŒ
R1CONHC2H4NH2ïŒäœãã¯ççŽ ååçŽïŒä¹è³
20ããã€ã¢ã«ãã«åºãè¡šããïŒãããã€æ§ãªã¢ã
ãçµåã¢ãã³ãäŸãã°ïŒ®âïŒâã¢ãããšãã«ã¹ã
ã¢ãªã«ã¢ããããã³ïŒ®âã¢ãããšãã«ããªã¹ãã«
ã¢ããïŒçªçŽ ã«çµåããŠããåºã®ïŒãççŽ ååïŒ
ä¹è³ïŒããã€ã¢ã«ãã«åºã§ããæ§ãªç¬¬ïŒçŽã¢ã³ã¢
ããŠã ååç©ããã³äžèšã¢ã«ãã«åºãããšãã«åº
ã®æ§ãªäžæŽ»æ§çœ®æåºããã€ãã®ããã³ããã²ã³å
ç©ãã¢ã»ãã€ããã¡ããµã«ããšã€ãçã®æ§ãªé°ã€
ãªã³ããããã®ãããã代衚ç第ïŒçŽã¢ã³ã¢ããŠ
ã æŽå€ã«ã¯ãšãã«âãžã¡ãã«âã¹ãã¢ãªã«ã¢ã³ã¢
ããŠã ã¯ãã©ã€ãããã³ãžã«âãžã¡ãã«âã¹ãã¢
ãªã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ããããªã¡ãã«ã¹ãã¢
ãªã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ããããªã¡ãã«ã»ãã«
ã¢ã³ã¢ããŠã ãããã€ãããžã¡ãã«ãšãã«ãžã©ãŠ
ãªã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãããžã¡ãã«âããã
ã«âããªã¹ãã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ããããã³
察å¿ããã¡ããµã«ããšã€ãé¡ããã³ã¢ã»ãã€ãé¡
ãããã 奜ãŸããäž¡æ§æŽå€ã®äŸã¯é°ã€ãªã³æ§ãšéœã€ãªã³
æ§åºäž¡æ¹ããã³å¥œãŸããã¯äŸãã°ççŽ åå10â20
ããã€é«çŽèèªæåºã§ããææ©çæ°Žæ§åºããã€ã
ã®ãããããããã«ã¯äŸãã°åŒïŒ ããã€ïŒ®âé·éã¢ã«ãã«ã¢ããã«ã«ãã³é žïŒäŸã
ã°åŒRNïŒRâ²COOHïŒ2ããã€ïŒ®âé·éã¢ã«ãã«ã€
ãããžâã«ã«ãã³é žïŒããã³äŸãã°åŒïŒ ããã€ïŒ®âé·éã¢ã«ãã«ãã¿ã€ã³ããããäžèšå
åŒã«ãããŠïŒ²ã¯äŸãã°ççŽ åå10ä¹è³20ããã€é·
éã¢ã«ãã«åºã§ãããRâ²ã¯ã¢ããé žã®ã¢ãããš
ã«ã«ããã·ã«éšåãçµåããïŒäŸ¡åºïŒäŸãã°ççŽ
ååïŒâïŒããã€ã¢ã«ãã¬ã³åºïŒã§ãããã¯æ°Ž
çŽ åã¯å¡©çææ§éå±ã§ãããR2ã¯æ°ŽçŽ åã¯ä»ã®
ïŒäŸ¡ã®çœ®æåºïŒäŸãã°ã¡ãã«åã¯ä»ã®äœçŽã¢ã«ã
ã«ïŒã§ãããã€R3ãšR4ã¯ççŽ âçªçŽ çµåã«ãã€
ãŠçªçŽ ã«çµåããŠããïŒäŸ¡ã®çœ®æåºãïŒäŸãã°ã¡
ãã«åã¯ä»ã®äœçŽã¢ã«ãã«çœ®æåºïŒã§ããã奜ãŸ
ããäž¡æ§æŽå€ã®äŸã«ã¯ïŒ®âã¢ã«ãã«âããŒã¿ãŒã¢
ããâããããªã³é žïŒïŒ®âã¢ã«ãã«âããŒã¿âã€
ãããžããããªã³é žããã³ïŒ®âã¢ã«ãã«ãã»ïŒ®
âãžã¡ãã«ã°ãªã·ã³ããããã¢ã«ãã«åºã¯äŸãã°
ã³ã³èèªæã¢ã«ã³ãŒã«ãã©ãŠãªã«ã¢ã«ã³ãŒã«ãã
ãªã¹ãã«ã¢ã«ã³ãŒã«ãïŒåã¯ã©ãŠãªã«âããªã¹ã
ã«æ··åç©ïŒãæ°Žæ·»ããã¿ããŠã¢ã«ã³ãŒã«ãã»ã
ã«ãã¹ãã¢ãªã«åã¯ãããã®ã¢ã«ã³ãŒã«æ··åç©ã
ãèªå°ãããã®ã§ãããã眮æãããã¢ãããã
ããªã³é žããã³ã€ãããžããããªã³é žã¯ãã°ãã°
ãããªãŠã å¡©åã¯ä»ã®å¡©åœ¢ã§äŸçµŠããããããã¯
æ¬çºæã«åæ§ã«äœ¿çšã§ãããä»ã®äž¡æ§æŽå€äŸã«ã¯
é·éèèªé žïŒäŸãã°ççŽ åå10â20ããã€ãã®ïŒ
ãšãžãšãã¬ã³ããªã¢ãã³ããã³ççŽ ååïŒâïŒã
ãã€ã¢ãããã«ã«ãã³é žãšã®åå¿ã«ããçæãã
ãèèªæã€ãããŸãªã³ãäŸãã°ïŒâã³ã³âïŒâã
ãããã·ãšãã«âïŒâã«ã«ããã·âã¡ãã«âã€ã
ããŸãªã³ïŒã«ã«ããã·ã«åºã®ä»£ãã«ã¹ã«ããªã³åº
ããã€ãã¿ã€ã³ïŒé·é眮æåºãçªçŽ ååã®ä»åšãª
ãã«ã«ã«ããã·ã«åºã«çµåããŠãããã¿ã€ã³ãäŸ
ãã°ïŒâããªã¡ãã«ã¢ããâã©ãŠãªã³é žã®æ§ãªïŒ
âããªã¡ãã«ã¢ããèèªé žã®å éšå¡©ããã³äžèšå
ã®ååç©ã§ãããçªçŽ ååãããã«ãã€ãŠçœ®æã
ããŠããååç©ãããã æ¬çºæçµæç©ã¯æ®éæž æµå€èª¿åã«å ããããå
ã®æž æµãã«ããŒãå«ã¿ããããã®å Žå䟿å©ãªãã«
ããŒã«ã¯æ®éã®ç¡æ©ããã³ææ©ã®æ°Žæº¶æ§å¡©ãã«ã
ãŒããããæçšãªç¡æ©æž æµãã«ããŒã«ã¯äŸãã°æ°Ž
溶æ§ããé žå¡©ãããããé žå¡©ããªã«ãããé žå¡©ã
ããªããé žå¡©ãã¡ã¿ããé žå¡©ãããé žå¡©ãçé ž
å¡©ããŒãªã©ã€ãããããã倩ç¶ç£ããã³åæãã
ãã®ããããç¡æ©ããé žå¡©ãã«ããŒã®ç¹å®äŸã«ã¯
ããªããªããé žãããããé žãªã«ãããé žããã³
ãããµã¡ã¿ããé žãããªãŠã ããã³ã«ãªãŠã ãã
ããããªããªããé žãããªãŠã ã¯ç¹ã«å¥œãŸããæ°Ž
溶液ç¡æ©ãã«ããŒã§ããã ãããå«ãŸãªãéé¢å€ãæž æµãã«ããŒãšããŠã®
䜿çšã«éžã°ãããç¡ããç¡æ©ãã«ããŒæåã®ç¹å®
äŸã«ã¯æ°Žæº¶æ§ç¡æ©çé žå¡©ãéçé žå¡©ããã³ããé ž
å¡©ããããã¢ã«ã«ãªéå±ãäŸãã°ãããªãŠã ãšã«
ãªãŠã ã®çé žãéçé žããã³ããé žå¡©ã¯ç¹ã«äŸ¿å©
ã§ããã 氎溶æ§ææ©ãã«ããŒãæ¬çºæã«ãããŠäŸ¿å©ã§ã
ããäŸãã°ã¢ã«ã«ãªéå±ãã¢ã³ã¢ããŠã ããã³çœ®
æã¢ã³ã¢ããŠã ã®ããªã¢ã»ãã€ããã«ã«ããã·ã¬
ã€ããããªã«ã«ããã·ã¬ã€ãããã³ããªãããã
ã·âã¹ã«ããªãã€ãã¯æ¬çºæã®çµæç©ãšæ¹æ³ã«äŸ¿
å©ãªãã«ããŒã§ãããããªã¢ã»ãã€ããšããªã«ã«
ããã·ã¬ã€ããã«ããŒã®å¥œãŸããäŸã«ã¯ãšãã¬ã³
ãžã¢ãã³ïŒé ¢é žããããªãïŒé ¢é žããªãã·ïŒãã¯
ãé žãã¡ãªããé žããã³ãŒã³ããªã«ã«ãã³é žïŒå³
ã¡ãã³ã¿âããã³ããã©âïŒãã«ã«ããã·ã¡ãã
ã·ãã¯ãé žããã³ãããé žã®ãããªãŠã ãã«ãªãŠ
ã ããªããŠã ãã¢ã³ã¢ããŠã ããã³çœ®æã¢ã³ã¢ã
ãŠã å¡©ãããã æ¬çºæã«ãããŠéåžžã«å¥œãŸããç¡ãããã«ããŒ
ïŒææ©ãšç¡æ©äž¡æ¹ã®ïŒã¯çé žãããªãŠã ãéçé ž
ãããªãŠã ãããé žãããªãŠã ããããé žãããª
ãŠã ããªãã·ïŒãã¯ãé žãããªãŠã ãã¡ãªããé ž
ãããªãŠã ããããªãïŒé ¢é žãããªãŠã ãããã³
ãšãã¬ã³ãžã¢ãã³ïŒé ¢é žãããªãŠã ããã³ããã
ã®æ··åç©ã§ããã æ¬çºæã«ãããä»ã®å¥œãŸããææ©ãã«ããŒã¯ç±³
åœç¹èš±ç¬¬3308067å·ã«èšèŒã®ããªã«ã«ããã·ã¬ã€
ããã«ããŒã§ãããäžèšç¹èš±ã¯åèãšãæ¬æ现æž
ã«å ããŠããããã®ç©è³ªã®äŸã¯ãã¬ã€ã³é žãã€ã¿
ã³ã³é žãã¡ãµã³ã³é žãããã«é žãã¢ã³ãããé žã
ã·ãã©ã³ã³é žãããã³ã¡ãã¬ã³ããã³é žã®æ§ãªè
èªæã«ã«ãã³é žã®ãã¢âããã³å ±éåäœã®æ°Žæº¶æ§
å¡©é¡ã§ããã äžèšãã«ããŒãç¹ã«ç¡æ©åã®ãã®ã¯ç·©è¡å€ãšã
ãŠäœçšãæŒçœæ¶²ã«å¿ èŠãªã¢ã«ã«ãªæ§ãäžãããã
ã«ããŒããã®ç·©è¡æŽ»æ§ã瀺ããªãå Žåã¯ã¢ã«ã«ãª
æ§ãšããŠåå¿ããå¡©ã調åã«å ããããšãã§ã
ãã æ¬çºæçµæç©äžã®äžæ§ç¡æ©å¡©ã¯é垞氎溶æ§ã¢ã«
ã«ãªéå±å¡©ãäŸãã°å¡©åãããªãŠã ããã³ç¡«é žã
ããªãŠã ã§ãããåŸè ãç¹ã«å¥œãŸãããã¢ã«ã«ãª
ç¡æ©å¡©ã¯äžè¬ã«ã¢ã«ã«ãªéå±çé žå¡©é¡ã§ãçé žã
ããªãŠã ã¯ç¹ã«å¥œãŸããã 掻æ§å€ãæ¬çºæçµæç©æåäžã«å«ãŸããããã«
ã€ããŠã¯æ°Žæº¶æ¶²äžã®éé žåæ°ŽçŽ ãšåå¿ãææ©éâ
é žãçæããã掻æ§å€ãäŸãã°ã°ã«ã³ãŒã¹ãã³ã¿
ã¢ã»ãã€ãããªã¯ã¿âã¢ã»ãã«åãããèç³ãã
ãªã¢ã»ãã³ãã¢ã»ããã·ãã³ãŒã³ã¹ã«ããªãã€ã
ããã³ããªã¢ã»ãã«ã·ã¢ãã¬ã€ãã®æ§ãªïœâã¢ã»
ãã«åçæç©ïŒããã©ã¢ã»ãã«ãšãã¬ã³ãžã¢ã
ã³ãããã³ããã©ã¢ã»ãã«ã°ãªã³ã«ãªã³ã®æ§ãªïŒ®
âã¢ã·ã«åçæç©ïŒããã³ç¡æ°Žãã¿ã«é žããã³ç¡
æ°Žãã¯ãé žã®æ§ãªé žç¡æ°Žç©ããã³ãããã®æ··åç©
ããããããã 掻æ§å€ã®åŒ(1)ã4Na2SO4ã»2H2O2ã»NaClããã€
éé žåæ°ŽçŽ ä»å ç©ã«å¯Ÿããæ··åå²åã¯æ¬çºæã«ã
ããŠã¯éèŠã§ã¯ãªãããäžè¬ã«æŽ»æ§å€ïŒä»å ç©ã®
æ··åæ¯ã¯ééæ¯ã§99ïŒïŒããïŒïŒ99ãŸã§ã奜ãŸã
ãã¯ïŒïŒïŒããïŒïŒ20ãŸã§ã§ããã 4Na2SO4ã»2H2Oã»NaClçšæŽ»æ§å€ã䜿çšããå Ž
åäžèšæŒçœçšçµæç©äžã®ãããã®åèšéã¯çŽ25ä¹
è³70ééïŒ ã§ããã 溶液äžæŽ»æ§é žçŽ çŽïŒä¹è³çŽ2000ppmïŒééåº
æºïŒä»¥äžåãïŒãšãªãã«ååã®4Na2SO4ã»
2H2Oã»NaClã䜿çšããã家åºæŒçœçšæŽæµæ°Žã®æŽ»
æ§é žçŽ æ¿åºŠã¯çŽïŒä¹è³100ppmã奜ãŸããã¯çŽ15
ä¹è³60ppmã§ãããäžããããæŒçœçšæº¶æ¶²ã«äœ¿
ãããå®éã®æ¿åºŠã¯æ¶²ã®çšæ³ã«ãã€ãŠåºç¯å²ã«å€
ãããã 次ã®å®æœäŸãåèãšããŠèšè¿°ããããæ¬çºæã
éå®ãããã®ã§ã¯ãªããå®æœäŸäžã®ïŒ ã¯ä»ã«ç¹å¥
ã®èšèŒã®ãªãéãééïŒ ã§ããã å®æœäŸ ïŒ Na2SO428ïŒ ãNaCl3ïŒ ããã³ãããªãããªã¹
ïŒã¡ãã¬ã³ïŒããªãã¹ãã³é žïŒãã¯ãšã¹ã
2000ïŒ0.03ïŒ ãå«ã20ïŒ H2O2溶液ã宀枩ã§æžå§
èžçºããŠçµæ¶æ§çæç©ã®ã¿ãšã4Na2SO4ã»
2H2O2ã»NaClã補é ããããã®çæç©ã宀枩ã§
也ç¥ããåŸåŽå°ä¹Ÿç¥ããã¢ã«ã«ãªæ§æž æµå€ãšä¹ŸåŒ
æ··åããŠæ¬¡ã®æåããã€æŒçœèª¿åç©ãããïŒ 4Na2SO4ã»2H2Oã»NaCl 20ïŒ çé žãããªãŠã 38ïŒ ç·ç¶ã¢ã«ãã«ïŒå¹³åC12ïŒãã³ãŒã³ã¹ã«ããªã³é žã
ããªãŠã ïŒLASïŒ 14ïŒ ããé žãããªãŠã 14ïŒ ç¡«é žãããªãŠã ïŒïŒ æ°Žå ïŒïŒ ã«ã«ããã·ã¡ãã«ã»ã«ããŒã¹ïŒCMCïŒ ïŒïŒ å®æœäŸ ïŒ ãããªãããªã¹ïŒã¡ãã¬ã³ïŒããªãã¹ãã³é ž
ïŒãã¯ãšã¹ã2000ïŒ0.045ïŒ ãå«ã31ïŒ H2O2液250
mläžã«NaCl9ïœãšNa2SO4190ïœãé 次å ããŠ
4Na2SO4ã»2H2O2ã»NaClã補é ããã溶液ã25â
ã§30åéæ¹æãéãä»å ç©ã倧æ°ç¶æ ã§ä¹Ÿç¥ã
ãåŸå®æœäŸïŒã®æŒçœèª¿åç©ã«ä¹ŸåŒæ··åããã å®æœäŸ ïŒ å®æœäŸïŒã®æ¹æ³ãå埩ãããäœãããªãã¹ãã³
é žã¯ããããã·ãšããªãã³âïŒã»ïŒâãžãã¹ãã³
é žïŒãã¯ãšã¹ã2010ïŒãåå¿æº¶æ¶²äž0.065ïŒ æ¿åºŠ
ã§çšããã å®æœäŸ ïŒ Na2SO4200ïœãNaCl20ïœããã³ãããªãããª
ã¹âïŒã¡ãã¬ã³ïŒããªãã¹ãã³é žïŒãã¯ãšã¹ã
2000ïŒ0.10ïŒ ãå«ã20ïŒ H2O2溶液400mlã倧æ°ç¶
æ ã«ãããŠèžçºããŠ4Na2SO4ã»2H2O2ã»NaClã補
é ãããçæç©ãååçµæ¶ããåŸæº¶æ¶²ãéãå
åçæç©ã倧æ°ç¶æ ã§ä¹Ÿç¥ãå®æœäŸïŒã®æŒçœèª¿å
ç©ã«ä¹ŸåŒæ··åããã å®æœäŸ ïŒ ãããªãããªã¹ïŒã¡ãã¬ã³ïŒããªãã¹ãã³é ž
ïŒãã¯ãšã¹ã2000ïŒ0.13ïŒ ãå«ã30ïŒ H2O2170ml
ã«NaCl5.9ïœãšNa2SO450ïœãå ã倧æ°æž©ã§èžçºã
ãŠ4Na2SO4ã»2H2O2ã»NaClã補é ãããçæçµæ¶
ãéã倧æ°ç¶æ ã§ä¹Ÿç¥ããåŸæ··åããŠå®æœäŸïŒ
ã®æŒçœèª¿åç©ãšããã 貯èµå®å®æ§ æ¬çºæã®ããªãã¹ããã€ãåŠçãã4Na2SO4ã»
2H2O2ã»NaClãå«ãäžèšå®æœäŸã®ã¢ã«ã«ãªæ§æŒ
çœèª¿åç©ã®è²¯èµå®å®æ§ã«ã€ããŠè©Šéšããã䜿çšæ³
ã¯å é貯èµå®å®æ§è©ŠéšãšããŠç¥ãããŠããããã®
è©Šéšæ³ã¯è©Šéšèª¿åç©ãåééæ§å²ãããã€ïŒãªã³
ã¹ãžã€ãŒäžã«å ¥ã容åšãçŽ40ä¹è³50âãçžå¯Ÿæ¹¿åºŠ
çŽ90ïŒ ã«ãããŠïŒæ¥éæŸçœ®ããã調åç©ãåæã
ãŠæŽ»æ§é žçŽ å«éã枬å®ããã ããªãã¹ããã€ããé€ãå®æœäŸãšåæ§ã«è£œé ã
ãäžé£ã®æ¯èŒå¯Ÿç §èª¿åç©ãåæ§ã«è²¯èµå®å®æ§ã«ã€
ããŠè©Šéšãããå®æœäŸãšå¯Ÿç §èª¿åç©ã®è©Šéšçµæã
è¡šã«ç€ºããŠããã容æã«ãããæ§ã«æ¬çºæã®ã
ãªãã¹ããã€ãã§å®å®åãã4Na2SO4ã»2H2O2ã»
NaClæŒçœå€ãå«ãæŒçœçšçµæç©ã¯ããªãã¹ãã
ã€ãã§åŠçããªã4Na2SO4ã»2H2O2ã»NaClãå«ã
çµæç©ã«æ¯ã¹ãŠåªç§ãªè²¯èµå®å®æ§ã瀺ãããå®æœ
äŸïŒãïŒããã³ïŒã¯ç¹ã«é«ã貯èµå®å®æ§ã瀺ãã
ã®ã§ãããããã¯ãããã®å®æœäŸã«ãããŠ
4Na2SO4ã»2H2O2ã»NaClã¯ä»ã®å®æœäŸã«ãããã
ããããªãã¹ããã€ãã®ååšã«ãããŠãããã€ã
ããšçµæ¶åãããããšä¿¡ããããã
çœåªè³ªäžã«ãããŠæ¹è¯ãããå®å®æ§ããã€ç¡«é žã
ããªãŠã âéé žåæ°ŽçŽ âå¡©åãããªãŠã ä»å ç©ã«
é¢ããã åŒïŒ4Na2SO4ã»2H2O2ã»NaCl ããã€ç¡«é žãããªãŠã âéé žåæ°ŽçŽ âå¡©åãããª
ãŠã ä»å ç©ã¯éé žçŽ æŒçœå€ãšããŠç¥ãããŠããã
ãã®ä»å ç©ã¯æ°Žæº¶æ¶²äžã§ç¡«é žãããªãŠã ãå¡©åã
ããªãŠã ããã³éé žåæ°ŽçŽ ãåå¿ãããŠå®¹æã«ã
ããããããã¯æº¶è§£é床ãéããå·æ°Žãžã®æº¶è§£åºŠ
ã倧ãããšããããããæ§è³ªããã¡ãŸãå®äŸ¡ç¡æ¯
ã®åºçºç©è³ªãã補é ã§ããããã®è£œåã®è£œæ³ãšæŒ
çœçšéçã®è©³çŽ°ã«ã€ããŠã¯ç±³åœç¹èš±ç¬¬3979312
å·ã3979313å·ããã³4005182å·ã«èšèŒãããŠã
ãã 4Na2SO4ã»2H2O2ã»NaClã¯äžè¬ã«ããããæŒçœ
äœçšã瀺ããã匷åæŒçœå€ã«å«ãŸããåã®èæ§å¡©
é¡ã®ååšã«ãããŠã¯äžå®å®ã§ãããšãã奜ãŸãã
ãªãæ§è³ªããã€ãŠããããã®ã¢ã«ã«ãªæææ§ã¯å°
ãªããšãååãšããŠã¯æŒçœã«ããã4Na2SO4ã»
2H2O2ã»NaClã®å©çšã倧ããå¶éããŠããã
4Na2SO4ã»2H2O2ã»NaClã®ã¢ã«ã«ãªæ§äžå®å®è§£æ¶
ã¯æããã«æŒçœæè¡ã«å¯äžããã§ãããã ãããã€ãŠæ¬çºæã®ç®çã¯ã¢ã«ã«ãªã«å®å®ãª
4Na2SO4ã»2H2O2ã»NaClããã³ãã®è£œæ³ãæäŸã
ãããšã«ãããæ¬çºæã®ç®çã¯ãŸãäžèšã¢ã«ã«ãª
å®å®æ§4Na2SO4ã»2H2Oã»NaClãå«ãå®å®ãªã¢ã«
ã«ãªæ§æŒçœçšçµæç©ããã³ãã®çšæ³ãæäŸããã
ãšã«ãããä»ã®ç®çã¯æ¬æ现æžããæããã«ãªã
ã§ãããã æ¬çºæã«ããã°äžèšç®çã¯4Na2SO4ã»2H2Oã»
NaClã®çµæ¶æ§é äžã«å¯æº¶æ§ææ©ããªãã¹ããã€
ããå«æãããã¢ã«ã«ãªå®å®æ§ä»å ç©ãã¢ã«ã«ãª
æ§æŒçœç³»ã«éé žçŽ æŒçœå€ãšããŠäœ¿çšããããšã«ã
ã€ãŠå®çŸããããããªãã¹ããã€ãã®ååšãé€å€
ããŠ4Na2SO4ã»2H2Oã»NaClã¯ç¥ãããæ¹æ³ã§è£œ
é ããçµæ¶åããããäžè¬ã«åå¿ã¯æ°Žæº¶æ¶²äž
NaClã®ååšã«ãããŠïŒä¹è³50âã®æž©åºŠã«ãããŠ
ç¡«é žãããªãŠã ãéé žåæ°ŽçŽ ãšçµåãããããšã«
ããè¡ããããåå¿ç³»äžã®éé žåæ°ŽçŽ æ¿åºŠã¯70ä¹
è³800ïœïŒãšããŸãå¡©åãããªãŠã æ¿åºŠã¯20ä¹
è³300ïœïŒãšãããã€åå¿ç³»ããçµæ¶æ§åºäœã
ååããã4Na2SO4ã»2H2O2ã»NaClã®æ¶åºäžããª
ãã¹ããã€ããååšããéããã®å°å ¥ã¯è£œé äžé©
å®ã®ææã«ã§ããã ã¢ã«ã«ãªã«å¯Ÿãå®å®ãšããããã«ã¯ããªãã¹ã
ãã€ãã¯4Na2SO4ã»2H2O2ã»NaClã®çµæ¶æ§é äžã«
å«ãŸããããå¿ èŠããããåã«çæãããä»å ç©
ã«ããªãã¹ããã€ããæ·»å ããŠãå¹æããªããã
ãªãã¹ããã€ãã¯4Na2SO4ã»2H2O2ã»NaClãã¢ã«
ã«ãªã«å¯Ÿãäžææ§ãšããæ§ãã®çµæ¶æ§è³ªãå€ãã
ãåã¯æ§è³ªã«äœãã圱é¿ãäžããããšã¯æããã§
ãããããã«ã€ããŠé¡åŸ®é¡æ€æ»ã¯ãã¹ããã€ãã§
åŠçãã4Na2SO4ã»2H2O2ã»NaClãšå¯Ÿç §è©Šæã®é
ã®çµæ¶åœ¢ã«å·®éã瀺ããããâç·åæãã¿ãŒã³
ã®å·®éã¯æããã§ãªãã€ããããã«åããŠ
4Na2SO4ã»2H2O2ã»NaClã®éå®å®åè©Šæã®å解枩
床ã180âåã¯ãã以äžã§ããã®ã«æ¯ã¹ãŠå®å®å
è©Šæã®ããã220âã§ãããããå®å®åãããä»
å ç©ãçšãã補åã¯ç±å®å®æ§ãæ¹è¯ãããŠããã 4Na2SO4ã»2H2O2ã»NaClã®å®å®åã«æå¹ãšãã
ã€ãŠããããªãã¹ããã€ãã¯ã¢ã«ãã¬ã³éãçªçŽ
ååã®ä»åšããŠããã¢ã«ãã¬ã³éããã³ãããã
ã·çœ®æåºããã€ã¢ã«ãã¬ã³éããæã矀ãããã
ã°ããïŒäŸ¡ã®éãä»ããŠããååã©ãããçµåã
ãŠããâPO3ïŒå®èœåºãïŒå以äžãã€ææ©ããªã
ã¹ããã€ãã§ããã æ¬æ现æžã«ãããŠããªãã¹ããã€ããšã¯éé¢é ž
ããã³ãã®å¡©é¡ãå å«ãããããªãã¹ããã€ãã®
äŸã«ã¯æ¬¡ã®ããªãã¹ãã³é žåã¯ãããã®ã¢ã«ã«ãª
éå±å¡©é¡ãããïŒ 4Na2SO4ã»2H2Oã»NaClãå®å®åããã«æå¹ãª
ããªãã¹ããã€ãéã¯ä»å ç©èªäœã«å¯Ÿã極ããŠå°
éã§ããããã¡ãããããªãã¹ããã€ãã®ååé
䞊ã³ã«ãã¹ããã€ãå®èœåºã®æ°ã¯ããããå®å®åºŠ
ã«åœ±é¿ãããã®çš®ã®ãããã®ã¯ä»ã®ãã®ãããæ
å¹ã§ãããäžè¬ã«çµæç©ééãåºæºãšããŠå¯æº¶æ§
ããªãã¹ããã€ã0.001ä¹è³2.0ééïŒ ãå«ã
4Na2SO4ã»2H2O2ã»NaClã¯ä»å ç©ã«ååãªå®å®æ§
ãäžããã®ã§ã匷åæŒçœå€ãšæž æµå€äžã®éé žçŽ æŒ
çœæ§æåãšããŠäœ¿çšã§ããã æ¬çºæã®å®å®å4Na2SO4ã»2H2O2ã»NaClãå«ã
ã¢ã«ã«ãªæ§æŒçœçµæç©ã¯ç¥ãããæ¹æ³ã§è£œé ãã
ã代衚çéé žçŽ æŒçœå€ã§ãããåºæ¬æåã¯éé žçŽ
æŒçœå€ãšïŒãè¶ ããŠå¥œãŸããã¯10.6ååŸã®PHãã
ã€æŒçœæ°Žæº¶æ¶²ãäžããã¢ã«ã«ãªæ§æåã§ãããå¿
èŠãªPHæ¡ä»¶ã«ä¿ã€ããç·©è¡å€ãå¿ èŠãªããšãã
ããããã§äœ¿ãç·©è¡å€ã«ã¯æº¶æ¶²PHãæãç¯å²å ã«
å€ãããã³ïŒåã¯ïŒä¿ã€é劚害æ§ååç©ãããã
ãã®æ§ãªç·©è¡å€ã¯åœæ¥è ã«ãã€ãŠå®¹æã«éžæã§ã
ããäŸãã°PHãïŒä¹è³12ã®ç¯å²å ã«ç·©è¡ãããã¹
ããšã€ããçé žå¡©åã¯éçé žå¡©é¡ã䟿å©ã§ããã
奜ãŸããç·©è¡å€ã®äŸã¯éçé žãããªãŠã ãçé žã
ããªãŠã ãããé žãããªãŠã ãããé žæ°ŽçŽ ïŒãã
ãªãŠã ãããé žïŒæ°ŽçŽ ãããªãŠã ã§ãããæŒçœæº¶
液ã¯æž æµå€ãå«ãã§ããŠãããããã®å Žåç¹åžã®
æŒçœãšæŽæ¿¯ãåæã«ã§ãããæž æµå€æ¿åºŠã¯æ®éæŽ
æµæ°Žã®0.05ä¹è³0.20ééïŒ ã§ããã æ¬çºæã®å®å®åããã4Na2SO4ã»2H2O2ã»NaCl
ã¯äžè¬ã«ã¢ã«ã«ãªæ§æŒçœã«äœ¿çšã§ããããä»å ç©
ã¯åŒ·åã¢ã«ã«ãªæ§æž æµçšçµæç©äžã«éé žçŽ æŒçœå€
ãšããŠå«ãŸãããäžè¬ã«100ééïŒ äžã(a)æ¬çºæ
ã®å®å®åããã4Na2SO4ã»2H2O2ã»NaCl3ä¹è³70
ééïŒ ïŒ(b)ã¢ã«ã«ãªæ§ç¡æ©å¡©ãã«ããŒ30ä¹è³80é
éïŒ ïŒ(c)è¡šé¢æŽ»æ§å€ïŒä¹è³20ééïŒ ïŒ(d)å å¡«å€ãš
ããŠäžæ§åã¯ã¢ã«ã«ãªæ§å¡©ïŒä¹è³50ééïŒ ãå«
ããçµæç©ã¯æ®éæŽæ¿¯åã¯æž æµçšçµæç©ã«æ·»å ã
ããçš®ã ã®ä»»æç©è³ªãïŒä¹è³çŽïŒééïŒ å«ãã§ã
ãŠããããéŠæãå åŠèŒå€ãå å¡«å€ãå¡åé²æ¢
å€ãåžæè»å€çã®æ§ãªè£å©å€ãæž æµå€çµæç©äžã«
䜿çšããŠããããããæ§è³ªãäžãããããããã
å ããŠããããé µçŽ ãç¹ã«ç±ã«å®å®ãªæž æµå€ã«äœ¿
ãããèçœè³ªå解ããã³èèªåè§£é µçŽ ãçµæç©äž
ã«ä¹ŸåŒæ··åã§ããã æ¬çºæã®äœ¿çšã«é©ããè¡šé¢æŽ»æ§å€ã¯æ¯èŒçåºç¯
å²ã®ç©è³ªãå å«ãé°ã€ãªã³æ§ãéã€ãªã³æ§ãè žã€
ãªã³æ§åã¯äž¡æ§åã®ãã®ã§ãããã é°ã€ãªã³æ§è¡šé¢æŽ»æ§å€ã«ã¯ææ©çæ°Žæ§åºãšé°ã€
ãªã³æ§æº¶è§£ååºããã€è¡šé¢æŽ»æ§åã¯æž æµæ§ååç©
é¡ããããé°ã€ãªã³æº¶è§£ååºã®ä»£è¡šäŸã«ã¯ã¹ã«ã
ãªãã€ãããµã«ããšã€ããã«ã«ããã·ã¬ã€ããã
ã¹ããã€ãããã³ãã¹ããšã€ããããã奜ãŸãã
é°ã€ãªã³æ§æž æµå€ã®äŸã«ã¯åç©ãæ€ç©åã¯æµ·ç£ç©
ã®èèªãæ²¹ããã³ã¯ãã¯ã¹ããçæã§ããæ§ãªé«
çŽèèªé žåã¯ããžã³é žã®æ°Žæº¶æ§å¡©ã®æ§ãªç³ããã
äŸãã°çèãã°ãªãŒã¹ãã³ã³ãããæ²¹ãããŒã«æ²¹
ããã³ãããã®æ··åç©ã®ãããªãŠã ç³ããïŒãã
ã³ç¡«é žå¡©ååã¯ã¹ã«ããªã³é žå¡©åãããåææŽ
å€ãç¹ã«ååäžã«ççŽ ååçŽïŒä¹è³26ã奜ãŸãã
ã¯çŽ12ä¹è³22ããã€ãã®ãããã 奜ãŸããé°ã€ãªã³æ§åææŽå€ã®äŸãšããŠã¯é«çŽ
ã¢ã«ãã«åæ žè³éŠæã¹ã«ããªãã€ããç¹ã«ã¢ã«ã
ã«åºäžã«ççŽ åå10ä¹è³16ããã€é«çŽã¢ã«ãã«ã
ã³ãŒã³ã¹ã«ããªãã€ãã®æ§ãªLASåãäŸãã°ã
ã·ã«ããŠã³ãã·ã«ãããã·ã«ïŒã©ãŠãªã«ïŒãããª
ãã·ã«ãããã©ãã·ã«ããã³ã¿ãã·ã«åã¯ãããµ
ãã·ã«ãã³ãŒã³ã¹ã«ããªãã€ãããã³é«çŽã¢ã«ã
ã«ãã«ãšã³ããã·ã¬ã³ããã³ããšããŒã«ã¹ã«ããª
ãã€ãã®ãããªãŠã å¡©ïŒã¢ã«ãã«ããã¿ã¬ã³ã¹ã«
ããªãã€ããã¢ã³ã¢ããŠã ãžã¢ãã«ããã¿ã¬ã³ã¹
ã«ããªãã€ãããã³ãããªãŠã ãžããã«ããã¿ã¬
ã³ã¹ã«ããªãã€ãã奜ãŸããã ä»ã®é°ã€ãªã³æ§æŽå€ã«ã¯é·éã¢ã«ã±ã³ã¹ã«ããª
ãã€ããé·éããããã·ã¢ã«ã«ã³ã¹ã«ããªãã€ã
åã¯ã¢ã«ã±ã³ã¹ã«ããªãã€ããšããããã·ã¢ã«ã«
ã³ã¹ã«ããªãã€ãã®æ··åç©ãå«ããªã¬ãã€ã³ã¹ã«
ããªãã€ãé¡ãããããã®ãªã¬ãã€ã³ã¹ã«ããªã
ã€ãã¯SO3ãåŒRCHïŒCHR1ïŒäœãã¯ã¢ã«ãã«
ãè¡šãããã€R1ã¯ã¢ã«ãã«åã¯æ°ŽçŽ ãè¡šããïŒ
ããã€é·éãªã¬ãã€ã³ïŒççŽ ååïŒä¹è³25ã奜ãŸ
ããã¯12ä¹è³21ããã€ïŒãšåå¿ãããŠãµã«ãã³ãš
ã¢ã«ã±ã³ã¹ã«ããªã³é žã®æ··åç©ãšããåŸæ··åç©ã
åŠçããŠãµã«ãã³ãã¹ã«ããªãã€ãã«è»¢åããç¥
ãããæ¹æ³ã§è£œé ã§ãããä»ã®ãµã«ããšã€ãåã¯
ã¹ã«ããªãã€ãæŽå€ã®äŸã«ã¯ã¢ã«ãã¢ãªã¬ãã€ã³
ãšéäºç¡«é žå¡©ïŒäŸãã°éäºç¡«é žãããªãŠã ïŒã®å
å¿çæç©ã®æ§ãªãã©ãã€ã³ã¹ã«ããªãã€ããäŸã
ã°ççŽ ååçŽ10â20ã奜ãŸããã¯çŽ15â20ããã€
第ïŒçŽãã©ãã€ã³ã¹ã«ããªãã€ãïŒé«çŽã¢ã«ã³ãŒ
ã«ã®ãµã«ããšã€ããαâã¹ã«ããªèèªé žãšã¹ãã«
ã®å¡©é¡ïŒäŸãã°ã¡ãã«Î±âã¹ã«ããªããªã¹ãã€ã
åã¯Î±âã¹ã«ããªã¿ããŠãšã€ãã®æ§ãªççŽ ååæ°
10â20ããã€ãã®ïŒãããã é«çŽã¢ã«ã³ãŒã«ã®ãµã«ããšã€ãã®äŸã«ã¯ã©ãŠãª
ã«ç¡«é žãããªãŠã ãã¿ããŠã¢ã«ã³ãŒã«ç¡«é žãããª
ãŠã ãã¿ãŒããŒã¬ããæ²¹åã¯ä»ã®ç¡«é žåæ²¹ãåã¯
èèªé žã®ã¢ãâåã¯ãžâã°ãªã»ãªãã®ç¡«é žå¡©ïŒäŸ
ãã°ã¹ãã¢ãªã³é žã¢ãã°ãªã»ãªãã¢ããµã«ããšã€
ãïŒããšãã¬ã³ãªããµã€ããšã©ãŠãªã«ã¢ã«ã³ãŒã«
ã®çž®åçæç©ç¡«é žå¡©ã®æ§ãªã¢ã«ãã«ããªïŒãšãã
ãã·ïŒãšãŒãã«ãµã«ããšã€ãïŒæ®éåååœããšã
ããã·åºïŒä¹è³ïŒããã€ïŒïŒã©ãŠãªã«åã¯ä»ã®ã¢
ã«ãã«ã°ãªã»ãªã«ãšãŒãã«ãµã«ããšã€ãïŒãšãã¬
ã³ãªããµã€ããšããã«ããšããŒã«ã®çž®åçæç©ç¡«
é žå¡©ã®æ§ãªè³éŠæããªïŒãšãããã·ïŒãšãŒãã«ãµ
ã«ããšã€ãïŒæ®éåååœããªãã·ãšãã¬ã³åºïŒä¹
è³20ã奜ãŸããã¯ïŒâ12ããã€ïŒãããã 奜ãŸããé°ã€ãªã³æ§æŽå€ã«ã¯ãŸãã¢ã·ã«ãµã«ã³
ã·ãã€ãïŒäŸãã°ãããªãŠã ã©ãŠãã€ã«ãµã«ã³ã·
ãã€ãïŒãã€ã»ããªãã€ãã®ã¢ã·ã«ãšã¹ãã«ïŒäŸ
ãã°ãªã¬ã€ã³é žãšã¹ãã«ïŒããã³ã¢ã·ã«ïŒ®âã¡ã
ã«ã¿ãŠã©ã€ãïŒäŸãã°ã«ãªãŠã âã¡ãã«ã©ãŠã
ã€ã«åã¯ãªã¬ã€ã«ã¿ãŠã©ã€ãïŒãããã ä»ã®éåžžã«å¥œãŸãã氎溶æ§é°ã€ãªã³æ§æŽå€åå
ç©ã«ã¯é«çŽã¢ã«ãã«ãµã«ããšã€ãããã³é«çŽèèª
é žã¢ãã°ãªã»ãªããµã«ããšã€ãã®ã¢ã³ã¢ããŠã ã
眮æã¢ã³ã¢ããŠã ïŒã¢ãâããžâãããã³ããªâ
ãšã¿ããŒã«ã¢ãã³ã®æ§ãªïŒãã¢ã«ã«ãªéå±ãïŒãã
ãªãŠã ãšã«ãªãŠã ã®æ§ãªïŒãããã³ã¢ã«ã«ãªåé¡
éå±ïŒäŸãã°ã«ã«ã·ãŠã ãšãã°ãã·ãŠã ïŒãå¡©é¡
ããããç¹å®ã®èª¿åããã³å²åã«å¿ããŠç¹å®ã®å¡©
ãé©å®éžã°ããã§ãããã éã€ãªã³æ§è¡šé¢æŽ»æ§å€ã«ã¯ã«ã«ããã·ã¬ã€ãã
ããããã·ã«ãã¢ããåã¯ã¢ããã®æ§ãªæº¶è§£ååº
ãšãšãã¬ã³ãªããµã€ãåã¯ããªãšãã¬ã³ã°ãªã³ãŒ
ã«ã®åå¿çæç©ã§ããææ©çæ°Žæ§åºãšèŠªæ°Žæ§åºã
ãã€è¡šé¢æŽ»æ§åã¯æž æµæ§ååç©ãããã 䜿çšã§ããéã€ãªã³æ§è¡šé¢æŽ»æ§å€ã®äŸã«ã¯ã¢ã«
ãã«ããšããŒã«ãšãšãã¬ã³ãªããµã€ãã®çž®åçæ
ç©ãäŸãã°ãªã¯ãã«ããšããŒã«ãšçŽïŒä¹è³30ã®ãš
ãã¬ã³ãªããµã€ãåäœã®åå¿çæç©ïŒã¢ã«ãã«ã
ãªããšããŒã«ãš10ä¹è³15ã®ãšãã¬ã³ãªããµã€ãå
äœã®çž®åçæç©ïŒããªãã·ã«ã¢ã«ã³ãŒã«ã®æ§ãªé«
çŽèèªæã¢ã«ã³ãŒã«ãšãšãã¬ã³ãªããµã€ãã®çž®å
çæç©ïŒãœã«ãããŒã«ã¢ãã©ãŠã¬ã€ãããœã«ãã
ãŒã«ã¢ããªã¬ãšã€ãããã³ãã³ãããŒã«ã¢ããã«
ããã€ãã®æ§ãªïŒäŸ¡ã¢ã«ã³ãŒã«ããã³ãã®å éšãš
ãŒãã«ã®ã¢ãâãšã¹ãã«ã®ãšãã¬ã³ãªããµã€ãçž®
åç©ïŒããã³ããªãããã¬ã³ã°ãªã³ãŒã«ãšãšãã¬
ã³ãªããµã€ãã®çž®åçæç©ãããã éœã€ãªã³æ§è¡šé¢æŽ»æ§å€ã䜿çšã§ããããããã«
ã¯ææ©çæ°Žæ§åºãšéœã€ãªã³æ§æº¶è§£ååºããã€è¡šé¢
掻æ§æž æµæ§ååç©ãããã代衚çéœã€ãªã³æ§æº¶è§£
ååºã¯ã¢ãã³åºãšç¬¬ïŒçŽåºã§ããã 奜ãŸããåæéœã€ãªã³æ§æŽå€ã®äŸã«ã¯åŒ
RNHC2H4NH2ïŒäœãã¯ççŽ ååçŽ12ä¹è³22ã
ãã€ã¢ã«ãã«åºãè¡šããïŒããã€æ§ãªãžã¢ãã³ã
äŸãã°ïŒ®âïŒâã¢ãããšãã«ã¹ãã¢ãªã«ã¢ãã³ã
ãã³ïŒ®âïŒâã¢ãããšãã«ããªã¹ãã«ã¢ãã³ïŒåŒ
R1CONHC2H4NH2ïŒäœãã¯ççŽ ååçŽïŒä¹è³
20ããã€ã¢ã«ãã«åºãè¡šããïŒãããã€æ§ãªã¢ã
ãçµåã¢ãã³ãäŸãã°ïŒ®âïŒâã¢ãããšãã«ã¹ã
ã¢ãªã«ã¢ããããã³ïŒ®âã¢ãããšãã«ããªã¹ãã«
ã¢ããïŒçªçŽ ã«çµåããŠããåºã®ïŒãççŽ ååïŒ
ä¹è³ïŒããã€ã¢ã«ãã«åºã§ããæ§ãªç¬¬ïŒçŽã¢ã³ã¢
ããŠã ååç©ããã³äžèšã¢ã«ãã«åºãããšãã«åº
ã®æ§ãªäžæŽ»æ§çœ®æåºããã€ãã®ããã³ããã²ã³å
ç©ãã¢ã»ãã€ããã¡ããµã«ããšã€ãçã®æ§ãªé°ã€
ãªã³ããããã®ãããã代衚ç第ïŒçŽã¢ã³ã¢ããŠ
ã æŽå€ã«ã¯ãšãã«âãžã¡ãã«âã¹ãã¢ãªã«ã¢ã³ã¢
ããŠã ã¯ãã©ã€ãããã³ãžã«âãžã¡ãã«âã¹ãã¢
ãªã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ããããªã¡ãã«ã¹ãã¢
ãªã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ããããªã¡ãã«ã»ãã«
ã¢ã³ã¢ããŠã ãããã€ãããžã¡ãã«ãšãã«ãžã©ãŠ
ãªã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãããžã¡ãã«âããã
ã«âããªã¹ãã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ããããã³
察å¿ããã¡ããµã«ããšã€ãé¡ããã³ã¢ã»ãã€ãé¡
ãããã 奜ãŸããäž¡æ§æŽå€ã®äŸã¯é°ã€ãªã³æ§ãšéœã€ãªã³
æ§åºäž¡æ¹ããã³å¥œãŸããã¯äŸãã°ççŽ åå10â20
ããã€é«çŽèèªæåºã§ããææ©çæ°Žæ§åºããã€ã
ã®ãããããããã«ã¯äŸãã°åŒïŒ ããã€ïŒ®âé·éã¢ã«ãã«ã¢ããã«ã«ãã³é žïŒäŸã
ã°åŒRNïŒRâ²COOHïŒ2ããã€ïŒ®âé·éã¢ã«ãã«ã€
ãããžâã«ã«ãã³é žïŒããã³äŸãã°åŒïŒ ããã€ïŒ®âé·éã¢ã«ãã«ãã¿ã€ã³ããããäžèšå
åŒã«ãããŠïŒ²ã¯äŸãã°ççŽ åå10ä¹è³20ããã€é·
éã¢ã«ãã«åºã§ãããRâ²ã¯ã¢ããé žã®ã¢ãããš
ã«ã«ããã·ã«éšåãçµåããïŒäŸ¡åºïŒäŸãã°ççŽ
ååïŒâïŒããã€ã¢ã«ãã¬ã³åºïŒã§ãããã¯æ°Ž
çŽ åã¯å¡©çææ§éå±ã§ãããR2ã¯æ°ŽçŽ åã¯ä»ã®
ïŒäŸ¡ã®çœ®æåºïŒäŸãã°ã¡ãã«åã¯ä»ã®äœçŽã¢ã«ã
ã«ïŒã§ãããã€R3ãšR4ã¯ççŽ âçªçŽ çµåã«ãã€
ãŠçªçŽ ã«çµåããŠããïŒäŸ¡ã®çœ®æåºãïŒäŸãã°ã¡
ãã«åã¯ä»ã®äœçŽã¢ã«ãã«çœ®æåºïŒã§ããã奜ãŸ
ããäž¡æ§æŽå€ã®äŸã«ã¯ïŒ®âã¢ã«ãã«âããŒã¿ãŒã¢
ããâããããªã³é žïŒïŒ®âã¢ã«ãã«âããŒã¿âã€
ãããžããããªã³é žããã³ïŒ®âã¢ã«ãã«ãã»ïŒ®
âãžã¡ãã«ã°ãªã·ã³ããããã¢ã«ãã«åºã¯äŸãã°
ã³ã³èèªæã¢ã«ã³ãŒã«ãã©ãŠãªã«ã¢ã«ã³ãŒã«ãã
ãªã¹ãã«ã¢ã«ã³ãŒã«ãïŒåã¯ã©ãŠãªã«âããªã¹ã
ã«æ··åç©ïŒãæ°Žæ·»ããã¿ããŠã¢ã«ã³ãŒã«ãã»ã
ã«ãã¹ãã¢ãªã«åã¯ãããã®ã¢ã«ã³ãŒã«æ··åç©ã
ãèªå°ãããã®ã§ãããã眮æãããã¢ãããã
ããªã³é žããã³ã€ãããžããããªã³é žã¯ãã°ãã°
ãããªãŠã å¡©åã¯ä»ã®å¡©åœ¢ã§äŸçµŠããããããã¯
æ¬çºæã«åæ§ã«äœ¿çšã§ãããä»ã®äž¡æ§æŽå€äŸã«ã¯
é·éèèªé žïŒäŸãã°ççŽ åå10â20ããã€ãã®ïŒ
ãšãžãšãã¬ã³ããªã¢ãã³ããã³ççŽ ååïŒâïŒã
ãã€ã¢ãããã«ã«ãã³é žãšã®åå¿ã«ããçæãã
ãèèªæã€ãããŸãªã³ãäŸãã°ïŒâã³ã³âïŒâã
ãããã·ãšãã«âïŒâã«ã«ããã·âã¡ãã«âã€ã
ããŸãªã³ïŒã«ã«ããã·ã«åºã®ä»£ãã«ã¹ã«ããªã³åº
ããã€ãã¿ã€ã³ïŒé·é眮æåºãçªçŽ ååã®ä»åšãª
ãã«ã«ã«ããã·ã«åºã«çµåããŠãããã¿ã€ã³ãäŸ
ãã°ïŒâããªã¡ãã«ã¢ããâã©ãŠãªã³é žã®æ§ãªïŒ
âããªã¡ãã«ã¢ããèèªé žã®å éšå¡©ããã³äžèšå
ã®ååç©ã§ãããçªçŽ ååãããã«ãã€ãŠçœ®æã
ããŠããååç©ãããã æ¬çºæçµæç©ã¯æ®éæž æµå€èª¿åã«å ããããå
ã®æž æµãã«ããŒãå«ã¿ããããã®å Žå䟿å©ãªãã«
ããŒã«ã¯æ®éã®ç¡æ©ããã³ææ©ã®æ°Žæº¶æ§å¡©ãã«ã
ãŒããããæçšãªç¡æ©æž æµãã«ããŒã«ã¯äŸãã°æ°Ž
溶æ§ããé žå¡©ãããããé žå¡©ããªã«ãããé žå¡©ã
ããªããé žå¡©ãã¡ã¿ããé žå¡©ãããé žå¡©ãçé ž
å¡©ããŒãªã©ã€ãããããã倩ç¶ç£ããã³åæãã
ãã®ããããç¡æ©ããé žå¡©ãã«ããŒã®ç¹å®äŸã«ã¯
ããªããªããé žãããããé žãªã«ãããé žããã³
ãããµã¡ã¿ããé žãããªãŠã ããã³ã«ãªãŠã ãã
ããããªããªããé žãããªãŠã ã¯ç¹ã«å¥œãŸããæ°Ž
溶液ç¡æ©ãã«ããŒã§ããã ãããå«ãŸãªãéé¢å€ãæž æµãã«ããŒãšããŠã®
䜿çšã«éžã°ãããç¡ããç¡æ©ãã«ããŒæåã®ç¹å®
äŸã«ã¯æ°Žæº¶æ§ç¡æ©çé žå¡©ãéçé žå¡©ããã³ããé ž
å¡©ããããã¢ã«ã«ãªéå±ãäŸãã°ãããªãŠã ãšã«
ãªãŠã ã®çé žãéçé žããã³ããé žå¡©ã¯ç¹ã«äŸ¿å©
ã§ããã 氎溶æ§ææ©ãã«ããŒãæ¬çºæã«ãããŠäŸ¿å©ã§ã
ããäŸãã°ã¢ã«ã«ãªéå±ãã¢ã³ã¢ããŠã ããã³çœ®
æã¢ã³ã¢ããŠã ã®ããªã¢ã»ãã€ããã«ã«ããã·ã¬
ã€ããããªã«ã«ããã·ã¬ã€ãããã³ããªãããã
ã·âã¹ã«ããªãã€ãã¯æ¬çºæã®çµæç©ãšæ¹æ³ã«äŸ¿
å©ãªãã«ããŒã§ãããããªã¢ã»ãã€ããšããªã«ã«
ããã·ã¬ã€ããã«ããŒã®å¥œãŸããäŸã«ã¯ãšãã¬ã³
ãžã¢ãã³ïŒé ¢é žããããªãïŒé ¢é žããªãã·ïŒãã¯
ãé žãã¡ãªããé žããã³ãŒã³ããªã«ã«ãã³é žïŒå³
ã¡ãã³ã¿âããã³ããã©âïŒãã«ã«ããã·ã¡ãã
ã·ãã¯ãé žããã³ãããé žã®ãããªãŠã ãã«ãªãŠ
ã ããªããŠã ãã¢ã³ã¢ããŠã ããã³çœ®æã¢ã³ã¢ã
ãŠã å¡©ãããã æ¬çºæã«ãããŠéåžžã«å¥œãŸããç¡ãããã«ããŒ
ïŒææ©ãšç¡æ©äž¡æ¹ã®ïŒã¯çé žãããªãŠã ãéçé ž
ãããªãŠã ãããé žãããªãŠã ããããé žãããª
ãŠã ããªãã·ïŒãã¯ãé žãããªãŠã ãã¡ãªããé ž
ãããªãŠã ããããªãïŒé ¢é žãããªãŠã ãããã³
ãšãã¬ã³ãžã¢ãã³ïŒé ¢é žãããªãŠã ããã³ããã
ã®æ··åç©ã§ããã æ¬çºæã«ãããä»ã®å¥œãŸããææ©ãã«ããŒã¯ç±³
åœç¹èš±ç¬¬3308067å·ã«èšèŒã®ããªã«ã«ããã·ã¬ã€
ããã«ããŒã§ãããäžèšç¹èš±ã¯åèãšãæ¬æ现æž
ã«å ããŠããããã®ç©è³ªã®äŸã¯ãã¬ã€ã³é žãã€ã¿
ã³ã³é žãã¡ãµã³ã³é žãããã«é žãã¢ã³ãããé žã
ã·ãã©ã³ã³é žãããã³ã¡ãã¬ã³ããã³é žã®æ§ãªè
èªæã«ã«ãã³é žã®ãã¢âããã³å ±éåäœã®æ°Žæº¶æ§
å¡©é¡ã§ããã äžèšãã«ããŒãç¹ã«ç¡æ©åã®ãã®ã¯ç·©è¡å€ãšã
ãŠäœçšãæŒçœæ¶²ã«å¿ èŠãªã¢ã«ã«ãªæ§ãäžãããã
ã«ããŒããã®ç·©è¡æŽ»æ§ã瀺ããªãå Žåã¯ã¢ã«ã«ãª
æ§ãšããŠåå¿ããå¡©ã調åã«å ããããšãã§ã
ãã æ¬çºæçµæç©äžã®äžæ§ç¡æ©å¡©ã¯é垞氎溶æ§ã¢ã«
ã«ãªéå±å¡©ãäŸãã°å¡©åãããªãŠã ããã³ç¡«é žã
ããªãŠã ã§ãããåŸè ãç¹ã«å¥œãŸãããã¢ã«ã«ãª
ç¡æ©å¡©ã¯äžè¬ã«ã¢ã«ã«ãªéå±çé žå¡©é¡ã§ãçé žã
ããªãŠã ã¯ç¹ã«å¥œãŸããã 掻æ§å€ãæ¬çºæçµæç©æåäžã«å«ãŸããããã«
ã€ããŠã¯æ°Žæº¶æ¶²äžã®éé žåæ°ŽçŽ ãšåå¿ãææ©éâ
é žãçæããã掻æ§å€ãäŸãã°ã°ã«ã³ãŒã¹ãã³ã¿
ã¢ã»ãã€ãããªã¯ã¿âã¢ã»ãã«åãããèç³ãã
ãªã¢ã»ãã³ãã¢ã»ããã·ãã³ãŒã³ã¹ã«ããªãã€ã
ããã³ããªã¢ã»ãã«ã·ã¢ãã¬ã€ãã®æ§ãªïœâã¢ã»
ãã«åçæç©ïŒããã©ã¢ã»ãã«ãšãã¬ã³ãžã¢ã
ã³ãããã³ããã©ã¢ã»ãã«ã°ãªã³ã«ãªã³ã®æ§ãªïŒ®
âã¢ã·ã«åçæç©ïŒããã³ç¡æ°Žãã¿ã«é žããã³ç¡
æ°Žãã¯ãé žã®æ§ãªé žç¡æ°Žç©ããã³ãããã®æ··åç©
ããããããã 掻æ§å€ã®åŒ(1)ã4Na2SO4ã»2H2O2ã»NaClããã€
éé žåæ°ŽçŽ ä»å ç©ã«å¯Ÿããæ··åå²åã¯æ¬çºæã«ã
ããŠã¯éèŠã§ã¯ãªãããäžè¬ã«æŽ»æ§å€ïŒä»å ç©ã®
æ··åæ¯ã¯ééæ¯ã§99ïŒïŒããïŒïŒ99ãŸã§ã奜ãŸã
ãã¯ïŒïŒïŒããïŒïŒ20ãŸã§ã§ããã 4Na2SO4ã»2H2Oã»NaClçšæŽ»æ§å€ã䜿çšããå Ž
åäžèšæŒçœçšçµæç©äžã®ãããã®åèšéã¯çŽ25ä¹
è³70ééïŒ ã§ããã 溶液äžæŽ»æ§é žçŽ çŽïŒä¹è³çŽ2000ppmïŒééåº
æºïŒä»¥äžåãïŒãšãªãã«ååã®4Na2SO4ã»
2H2Oã»NaClã䜿çšããã家åºæŒçœçšæŽæµæ°Žã®æŽ»
æ§é žçŽ æ¿åºŠã¯çŽïŒä¹è³100ppmã奜ãŸããã¯çŽ15
ä¹è³60ppmã§ãããäžããããæŒçœçšæº¶æ¶²ã«äœ¿
ãããå®éã®æ¿åºŠã¯æ¶²ã®çšæ³ã«ãã€ãŠåºç¯å²ã«å€
ãããã 次ã®å®æœäŸãåèãšããŠèšè¿°ããããæ¬çºæã
éå®ãããã®ã§ã¯ãªããå®æœäŸäžã®ïŒ ã¯ä»ã«ç¹å¥
ã®èšèŒã®ãªãéãééïŒ ã§ããã å®æœäŸ ïŒ Na2SO428ïŒ ãNaCl3ïŒ ããã³ãããªãããªã¹
ïŒã¡ãã¬ã³ïŒããªãã¹ãã³é žïŒãã¯ãšã¹ã
2000ïŒ0.03ïŒ ãå«ã20ïŒ H2O2溶液ã宀枩ã§æžå§
èžçºããŠçµæ¶æ§çæç©ã®ã¿ãšã4Na2SO4ã»
2H2O2ã»NaClã補é ããããã®çæç©ã宀枩ã§
也ç¥ããåŸåŽå°ä¹Ÿç¥ããã¢ã«ã«ãªæ§æž æµå€ãšä¹ŸåŒ
æ··åããŠæ¬¡ã®æåããã€æŒçœèª¿åç©ãããïŒ 4Na2SO4ã»2H2Oã»NaCl 20ïŒ çé žãããªãŠã 38ïŒ ç·ç¶ã¢ã«ãã«ïŒå¹³åC12ïŒãã³ãŒã³ã¹ã«ããªã³é žã
ããªãŠã ïŒLASïŒ 14ïŒ ããé žãããªãŠã 14ïŒ ç¡«é žãããªãŠã ïŒïŒ æ°Žå ïŒïŒ ã«ã«ããã·ã¡ãã«ã»ã«ããŒã¹ïŒCMCïŒ ïŒïŒ å®æœäŸ ïŒ ãããªãããªã¹ïŒã¡ãã¬ã³ïŒããªãã¹ãã³é ž
ïŒãã¯ãšã¹ã2000ïŒ0.045ïŒ ãå«ã31ïŒ H2O2液250
mläžã«NaCl9ïœãšNa2SO4190ïœãé 次å ããŠ
4Na2SO4ã»2H2O2ã»NaClã補é ããã溶液ã25â
ã§30åéæ¹æãéãä»å ç©ã倧æ°ç¶æ ã§ä¹Ÿç¥ã
ãåŸå®æœäŸïŒã®æŒçœèª¿åç©ã«ä¹ŸåŒæ··åããã å®æœäŸ ïŒ å®æœäŸïŒã®æ¹æ³ãå埩ãããäœãããªãã¹ãã³
é žã¯ããããã·ãšããªãã³âïŒã»ïŒâãžãã¹ãã³
é žïŒãã¯ãšã¹ã2010ïŒãåå¿æº¶æ¶²äž0.065ïŒ æ¿åºŠ
ã§çšããã å®æœäŸ ïŒ Na2SO4200ïœãNaCl20ïœããã³ãããªãããª
ã¹âïŒã¡ãã¬ã³ïŒããªãã¹ãã³é žïŒãã¯ãšã¹ã
2000ïŒ0.10ïŒ ãå«ã20ïŒ H2O2溶液400mlã倧æ°ç¶
æ ã«ãããŠèžçºããŠ4Na2SO4ã»2H2O2ã»NaClã補
é ãããçæç©ãååçµæ¶ããåŸæº¶æ¶²ãéãå
åçæç©ã倧æ°ç¶æ ã§ä¹Ÿç¥ãå®æœäŸïŒã®æŒçœèª¿å
ç©ã«ä¹ŸåŒæ··åããã å®æœäŸ ïŒ ãããªãããªã¹ïŒã¡ãã¬ã³ïŒããªãã¹ãã³é ž
ïŒãã¯ãšã¹ã2000ïŒ0.13ïŒ ãå«ã30ïŒ H2O2170ml
ã«NaCl5.9ïœãšNa2SO450ïœãå ã倧æ°æž©ã§èžçºã
ãŠ4Na2SO4ã»2H2O2ã»NaClã補é ãããçæçµæ¶
ãéã倧æ°ç¶æ ã§ä¹Ÿç¥ããåŸæ··åããŠå®æœäŸïŒ
ã®æŒçœèª¿åç©ãšããã 貯èµå®å®æ§ æ¬çºæã®ããªãã¹ããã€ãåŠçãã4Na2SO4ã»
2H2O2ã»NaClãå«ãäžèšå®æœäŸã®ã¢ã«ã«ãªæ§æŒ
çœèª¿åç©ã®è²¯èµå®å®æ§ã«ã€ããŠè©Šéšããã䜿çšæ³
ã¯å é貯èµå®å®æ§è©ŠéšãšããŠç¥ãããŠããããã®
è©Šéšæ³ã¯è©Šéšèª¿åç©ãåééæ§å²ãããã€ïŒãªã³
ã¹ãžã€ãŒäžã«å ¥ã容åšãçŽ40ä¹è³50âãçžå¯Ÿæ¹¿åºŠ
çŽ90ïŒ ã«ãããŠïŒæ¥éæŸçœ®ããã調åç©ãåæã
ãŠæŽ»æ§é žçŽ å«éã枬å®ããã ããªãã¹ããã€ããé€ãå®æœäŸãšåæ§ã«è£œé ã
ãäžé£ã®æ¯èŒå¯Ÿç §èª¿åç©ãåæ§ã«è²¯èµå®å®æ§ã«ã€
ããŠè©Šéšãããå®æœäŸãšå¯Ÿç §èª¿åç©ã®è©Šéšçµæã
è¡šã«ç€ºããŠããã容æã«ãããæ§ã«æ¬çºæã®ã
ãªãã¹ããã€ãã§å®å®åãã4Na2SO4ã»2H2O2ã»
NaClæŒçœå€ãå«ãæŒçœçšçµæç©ã¯ããªãã¹ãã
ã€ãã§åŠçããªã4Na2SO4ã»2H2O2ã»NaClãå«ã
çµæç©ã«æ¯ã¹ãŠåªç§ãªè²¯èµå®å®æ§ã瀺ãããå®æœ
äŸïŒãïŒããã³ïŒã¯ç¹ã«é«ã貯èµå®å®æ§ã瀺ãã
ã®ã§ãããããã¯ãããã®å®æœäŸã«ãããŠ
4Na2SO4ã»2H2O2ã»NaClã¯ä»ã®å®æœäŸã«ãããã
ããããªãã¹ããã€ãã®ååšã«ãããŠãããã€ã
ããšçµæ¶åãããããšä¿¡ããããã
ãè¡šã
察ç
§ â â â
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ã¢ã«ãã¬ã³éãçªçŽ ååã®ä»åšããŠããã¢ã«
ãã¬ã³éããã³ããããã·çœ®æåºããã€ã¢ã«ãã¬
ã³éããæã矀ããããã°ããïŒäŸ¡ã®éãä»ããŠ
ããååã©ãããçµåããŠããâPO3ïŒå®èœåºã
ïŒå以äžãã€ææ©ããªãã¹ããã€ãååç©ã®å®å®
åéãã4Na2SO4ã»2H2O2ã»NaClã®çµæ¶æ§é äžã«
ååšãããŠæãããšãç¹åŸŽãšããã¢ã«ã«ãªæ§èª¿å
ç©äžã«ãããæ¹è¯ããã貯èµå®å®æ§ããã€
4Na2SO442H2O2ã»NaClçµæç©ã ïŒ ããªãã¹ããã€ãã åã¯ãã®ã¢ã«ã«ãªéå±å¡©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé ã«èšèŒã®çµæç©ã ïŒ ããªãã¹ããã€ãã åã¯ãã®ã¢ã«ã«ãªéå±å¡©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé ã«èšèŒã®çµæç©ã ïŒ ããªãã¹ããã€ãã ïŒH2O3PCH2ïŒ2NïŒCH2ïŒ2âïŒCH2PO3H2ïŒ2 åã¯ãã®ã¢ã«ã«ãªéå±å¡©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé ã«èšèŒã®çµæç©ã ïŒ ããªãã¹ããã€ãã ïŒH2O3PCH2ïŒ2NïŒCH2ïŒ6NïŒCH2PO3H2ïŒ2 åã¯ãã®ã¢ã«ã«ãªéå±å¡©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé ã«èšèŒã®çµæç©ã ïŒ ããªãã¹ããã€ãã åã¯ãã®ã¢ã«ã«ãªéå±å¡©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé ã«èšèŒã®çµæç©ã ïŒ ã¢ã«ãã¬ã³éãçªçŽ ååã®ä»åšããŠããã¢ã«
ãã¬ã³éããã³ããããã·çœ®æåºããã€ã¢ã«ãã¬
ã³éããæã矀ããããã°ããïŒäŸ¡ã®éãä»ããŠ
ããååã©ãããçµåããŠããâPO3ïŒå®èœåºã
ïŒå以äžãã€ææ©ããªãã¹ããã€ãååç©ã®å®å®
åéãã4Na2SO4ã»2H2O2ã»NaClã®çµæ¶æ§é äžã«
ååšãããŠæãéé žçŽ æŒçœå€ãå¿ é æåãšããŠå«
ãããšãç¹åŸŽãšããæ°Žæ§åªè³ªã«æº¶è§£ããæïŒä»¥äž
ã®PHããã€ã¢ã«ã«ãªæ§éé žçŽ æŒçœçµæç©ã ïŒ ããªãã¹ããã€ãã åã¯ãã®ã¢ã«ã«ãªéå±å¡©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé ã«èšèŒã®æŒçœçµæç©ã ïŒ ããªãã¹ããã€ãã åã¯ãã®ã¢ã«ã«ãªéå±å¡©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé ã«èšèŒã®æŒçœçµæç©ã ïŒïŒ ããªãã¹ããã€ãã ïŒH2O3PCH2ïŒ2NïŒCH2ïŒ2NïŒCH2PO3H2ïŒ2 åã¯ãã®ã¢ã«ã«ãªéå±å¡©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé ã«èšèŒã®æŒçœçµæç©ã ïŒïŒ ããªãã¹ããã€ãã ïŒH2O3PCH2ïŒ2NïŒCH2ïŒ6NïŒCH2PO3H2ïŒ2 åã¯ãã®ã¢ã«ã«ãªéå±å¡©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé ã«èšèŒã®æŒçœçµæç©ã ïŒïŒ ããªãã¹ããã€ãã åã¯ãã®ã¢ã«ã«ãªéå±å¡©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé ã«èšèŒã®æŒçœçµæç©ã ïŒïŒ (a)ã¢ã«ãã¬ã³éãçªçŽ ååã®ä»åšããŠãã
ã¢ã«ãã¬ã³éããã³ããããã·çœ®æåºããã€ã¢ã«
ãã¬ã³éããæã矀ããããã°ããïŒäŸ¡ã®éãä»
ããŠããååã©ãããçµåããŠããâPO3ïŒå®èœ
åºãïŒå以äžãã€ææ©ããªãã¹ããã€ãååç©ã®
å®å®åéãã4Na2SO4ã»2H2O2ã»NaClã®çµæ¶æ§é
äžã«ååšãããŠæãå®å®åããã4Na2SO4ã»
2H2O2ã»NaCl3ä¹è³70ééïŒ ã(b)æž æµãã«ããŒ10
ä¹è³80ééïŒ ã(c)è¡šé¢æŽ»æ§å€ïŒä¹è³20ééïŒ ãã
ãã³(d)äžæ§ãŸãã¯ã¢ã«ã«ãªæ§ã®å¡©å å¡«å€ïŒä¹è³50
ééïŒ ããæãããšãç¹åŸŽãšããæ°Žæ§åªè³ªã«æº¶è§£
ããæïŒä»¥äžã®PHããã€ã¢ã«ã«ãªæ§æž æµå€çµæ
ç©ã ïŒïŒ ããªãã¹ããã€ãã åã¯ãã®ã¢ã«ã«ãªéå±å¡©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒïŒé ã«èšèŒã®æž æµå€çµæç©ã ïŒïŒ ããªãã¹ããã€ãã åã¯ãã®ã¢ã«ã«ãªéå±å¡©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒïŒé ã«èšèŒã®æž æµå€çµæç©ã ïŒïŒ ããªãã¹ããã€ãã ïŒH2O3PCH2ïŒ2NïŒCH2ïŒ2âïŒCH2PO3H2ïŒ2 åã¯ãã®ã¢ã«ã«ãªéå±å¡©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒïŒé ã«èšèŒã®æž æµå€çµæç©ã ïŒïŒ ããªãã¹ããã€ãã ïŒH2O3PCH2ïŒ2NïŒCH2ïŒ6NïŒCH2PO3H2ïŒ2 åã¯ãã®ã¢ã«ã«ãªéå±å¡©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒïŒé ã«èšèŒã®æž æµå€çµæç©ã ïŒïŒ ããªãã¹ããã€ãã åã¯ãã®ã¢ã«ã«ãªéå±å¡©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒïŒé ã«èšèŒã®æž æµå€çµæç©ã
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/256,621 US4323465A (en) | 1981-04-23 | 1981-04-23 | Stabilized sodium sulfate-hydrogen peroxide-sodium chloride adduct and alkaline bleach composition containing same |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS57175708A JPS57175708A (en) | 1982-10-28 |
JPS6243923B2 true JPS6243923B2 (ja) | 1987-09-17 |
Family
ID=22972926
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP57047502A Granted JPS57175708A (en) | 1981-04-23 | 1982-03-26 | Stabilized sodium sulfate-hydrogen peroxide-sodium chloride additive and alkalic bleaching composition containing said additive |
Country Status (3)
Country | Link |
---|---|
US (1) | US4323465A (ja) |
JP (1) | JPS57175708A (ja) |
ES (1) | ES511586A0 (ja) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4496472A (en) * | 1981-12-23 | 1985-01-29 | Ciba-Geigy Corporation | Process for bleaching cellulosic fibre materials using oligomers of phosphonic acid esters as stabilizers in alkaline, peroxide-containing bleaching liquors |
GB8313941D0 (en) * | 1983-05-19 | 1983-06-22 | Unilever Plc | Peroxide bleach and compositions |
US4839086A (en) * | 1988-02-12 | 1989-06-13 | Zaid Najib H | Composition for regenerating cation exchange resin |
FR2643093B1 (fr) * | 1989-02-15 | 1991-08-16 | Protex Manuf Prod Chimiq | Procedes ameliores de blanchiment oxydant de fibres cellulosiques |
DE19730648A1 (de) * | 1997-07-17 | 1999-01-21 | Henkel Kgaa | Verwendung von Elektrolytgemischen als Sequestriermittel |
DE60110382D1 (de) * | 2001-05-17 | 2005-06-02 | Fmc Foret Sa | Verfahren zur Herstellung von Körnchen eines stabilen Adduktes von Natriumsulfat und Wasserstoffperoxid das auch Natriumchlorid enthÀlt |
EP1258455A1 (en) * | 2001-05-17 | 2002-11-20 | FMC Foret S.A. | Industrial procedure for obtaining a stable adduct of NA2S04, NaCl and H2O2 |
CN106398908B (zh) * | 2016-08-26 | 2018-12-14 | äžçéåçåæéèŽ£ä»»å ¬åž | äžç§éçšåºåºèç¡å¶å€ç¡«é žé -è¿æ°§åæ°¢-æ°¯åé å åç©çæ¹æ³ |
US11355161B2 (en) | 2019-08-07 | 2022-06-07 | Seagate Technology Llc | Electronic device that includes a composition that can release and optionally generate a gaseous oxidizing agent component into an interior space of the electronic device, and related subassemblies and methods |
US11783867B2 (en) | 2019-08-07 | 2023-10-10 | Seagate Technology Llc | Electronic device that includes a composition that can actively generate and release a gaseous oxidizing agent component into an interior space of the electronic device, and related subassemblies and methods |
US11763853B2 (en) | 2019-08-07 | 2023-09-19 | Seagate Technology Llc | Electronic device that includes a composition that can actively generate and release a gaseous oxidizing agent component into an interior space of the electronic device, and related subassemblies and methods |
CN111109289A (zh) * | 2019-12-31 | 2020-05-08 | å京çŠæ¯ç¹ç§äžç§ææéå ¬åž | äžç§çš³å®æ§åºäœè¿æ°§åæ°¢å åç©åå ¶åšç犜ãæ°Žäº§å »æ®é¢åçåºçš |
US11270739B1 (en) | 2021-02-09 | 2022-03-08 | Seagate Technology Llc | Electronic device that includes one or more reactants that generate a gaseous oxidizing agent component inside the electronic device, and related subassemblies and methods |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3308067A (en) * | 1963-04-01 | 1967-03-07 | Procter & Gamble | Polyelectrolyte builders and detergent compositions |
JPS5210123B2 (ja) * | 1974-07-12 | 1977-03-22 | ||
JPS526946B2 (ja) * | 1974-10-03 | 1977-02-25 | ||
US4005182A (en) * | 1975-07-07 | 1977-01-25 | Kao Soap Co., Ltd. | Stable sodium sulfate-hydrogen peroxide-sodium chloride adduct and process for preparing same |
-
1981
- 1981-04-23 US US06/256,621 patent/US4323465A/en not_active Expired - Lifetime
-
1982
- 1982-03-26 JP JP57047502A patent/JPS57175708A/ja active Granted
- 1982-04-22 ES ES511586A patent/ES511586A0/es active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS57175708A (en) | 1982-10-28 |
ES8306677A1 (es) | 1983-06-01 |
US4323465A (en) | 1982-04-06 |
ES511586A0 (es) | 1983-06-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP3238406B2 (ja) | 眮æãã³ãŸã€ã«ã«ããã©ã¯ã¿ã æŒçœæŽ»æ§å€ãå«ãæŒçœã³ã³ããŠã³ã | |
US4100095A (en) | Peroxyacid bleach composition having improved exotherm control | |
JPS6243923B2 (ja) | ||
JPH09501743A (ja) | ã¢ã·ã«ãã¬ãã©ã¯ã¿ã æŒçœæŽ»æ§å€ãå«ãã§ãªãæŒçœã³ã³ããŠã³ã | |
US4119660A (en) | Method for making diperoxyacids | |
JPS5840400A (ja) | æ¹åãããæŒçœåãæããæ··åãã«ãªãã·é žæŒçœå€ | |
US3850832A (en) | Washing, rinsing and cleansing agent compositions containing furan-maleic anhydride copolymer sequestering agents | |
SU446974A1 (ru) | ÐПÑÑее ÑÑеЎÑÑвП | |
DK159209B (da) | Stabiliseret blegende rensemiddel og fremgangsmaade til blegning | |
JPH08508746A (ja) | ãããããµã é žåã³ãããããµã é žãšãŒãã«äžŠã³ã«é¯åå€ãšããŠã®ãã®äœ¿çš | |
US4455249A (en) | Stabilized bleach and laundering composition | |
US4115060A (en) | N-sulfonylimidazoles as peroxygen activators | |
US4164395A (en) | Peroxygen bleaching and compositions therefor | |
US4115058A (en) | Aromatic sulfonic anhydrides as peroxygen activators | |
US4120652A (en) | Aromatic sulfonyl azides as peroxygen activators | |
US4115059A (en) | Aromatic sulfonyl fluorides as peroxygen activators | |
ES2222565T3 (es) | Carbonato sodico peroxihidratado estabilizado. | |
US4169805A (en) | Sulfonic anhydrides as peroxygen activators | |
US4128490A (en) | Phenyl sulfonate esters as peroxygen activators | |
US4110074A (en) | Mixed carboxylic/sulfonic anhydrides in peroxygen bleaching | |
US4124356A (en) | Organophosphorus azides as peroxygen activators | |
US4111651A (en) | Sulfonic anhydrides in peroxygen bleaching | |
US4133637A (en) | Oxybis(diacyloxyboranes) as peroxygen activators | |
US4164394A (en) | Peroxygen bleaching and compositions therefor | |
DE2132898A1 (de) | Schwachschaeumendes wasch-, reinigungsund enthaertungsmittel |