JPS6242973B2 - - Google Patents
Info
- Publication number
- JPS6242973B2 JPS6242973B2 JP53030035A JP3003578A JPS6242973B2 JP S6242973 B2 JPS6242973 B2 JP S6242973B2 JP 53030035 A JP53030035 A JP 53030035A JP 3003578 A JP3003578 A JP 3003578A JP S6242973 B2 JPS6242973 B2 JP S6242973B2
- Authority
- JP
- Japan
- Prior art keywords
- seawater
- matrix
- heavy metals
- adsorbent
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000013535 sea water Substances 0.000 claims description 84
- 229910001385 heavy metal Inorganic materials 0.000 claims description 82
- 239000011159 matrix material Substances 0.000 claims description 66
- 239000003463 adsorbent Substances 0.000 claims description 50
- 239000003415 peat Substances 0.000 claims description 48
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 35
- 238000000034 method Methods 0.000 claims description 35
- 239000004021 humic acid Substances 0.000 claims description 31
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 24
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims description 21
- 239000000126 substance Substances 0.000 claims description 19
- 239000002253 acid Substances 0.000 claims description 16
- 239000000243 solution Substances 0.000 claims description 14
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 10
- 238000005868 electrolysis reaction Methods 0.000 claims description 9
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 8
- 238000001179 sorption measurement Methods 0.000 claims description 8
- 239000012141 concentrate Substances 0.000 claims description 7
- 238000010828 elution Methods 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- 239000011780 sodium chloride Substances 0.000 claims description 5
- 238000011084 recovery Methods 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000012670 alkaline solution Substances 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 229910052770 Uranium Inorganic materials 0.000 description 39
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 12
- 239000008187 granular material Substances 0.000 description 12
- 239000010410 layer Substances 0.000 description 11
- 239000002245 particle Substances 0.000 description 11
- 238000005192 partition Methods 0.000 description 7
- 229910052720 vanadium Inorganic materials 0.000 description 7
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 7
- 238000009826 distribution Methods 0.000 description 6
- 229920001778 nylon Polymers 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 239000004677 Nylon Substances 0.000 description 4
- 238000005119 centrifugation Methods 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000003513 alkali Substances 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000002657 fibrous material Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 241001474374 Blennius Species 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 238000007605 air drying Methods 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 230000002542 deteriorative effect Effects 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- 239000003077 lignite Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000008953 bacterial degradation Effects 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000005188 flotation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000002663 humin Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- -1 hydrogen ions Chemical class 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 238000011328 necessary treatment Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
- C22B60/02—Obtaining thorium, uranium, or other actinides
- C22B60/0204—Obtaining thorium, uranium, or other actinides obtaining uranium
- C22B60/0217—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
- C22B60/0252—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries
- C22B60/0256—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries using biological agents, e.g. microorganisms or algae
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/18—Extraction of metal compounds from ores or concentrates by wet processes with the aid of microorganisms or enzymes, e.g. bacteria or algae
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/006—Radioactive compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Environmental & Geological Engineering (AREA)
- Mechanical Engineering (AREA)
- Geology (AREA)
- Manufacturing & Machinery (AREA)
- Microbiology (AREA)
- Geochemistry & Mineralogy (AREA)
- Biotechnology (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Water Treatment By Sorption (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2711609A DE2711609C2 (de) | 1977-03-17 | 1977-03-17 | Verfahren zur Gewinnung von in Meerwasser gelöstem Uran |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS53115604A JPS53115604A (en) | 1978-10-09 |
| JPS6242973B2 true JPS6242973B2 (it) | 1987-09-10 |
Family
ID=6003858
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3003578A Granted JPS53115604A (en) | 1977-03-17 | 1978-03-17 | Recovering of heavy metal solubulized in sea water |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JPS53115604A (it) |
| DE (1) | DE2711609C2 (it) |
| FR (1) | FR2383884A1 (it) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2711587C2 (de) * | 1977-03-17 | 1986-08-07 | Kernforschungsanlage Jülich GmbH, 5170 Jülich | Verwendung eines aus Huminsäuren an einem Trägermaterial bestehenden Adsorbermaterials zur Gewinnung von Schwermetallen aus Meerwasser |
| DE2722838C2 (de) * | 1977-05-20 | 1983-09-15 | Kernforschungsanlage Jülich GmbH, 5170 Jülich | Verfahren zur Gewinnung von in Meerwasser gelöstem Uran |
| DE2842058A1 (de) * | 1978-09-27 | 1980-04-10 | Uranerzbergbau Gmbh & Co Kg | Verfahren und vorrichtung zur gewinnung von geloesten, suspendierten oder chemisch gebundenen stoffen aus einem gewaesser |
| SE417913B (sv) * | 1979-04-18 | 1981-04-27 | Lagstroem Emil Goeran | Sett och anordning for att ur havsvatten uppfanga verdefulla flytande, losta och uppslammade emnen |
| KR900003608B1 (ko) * | 1987-09-30 | 1990-05-26 | 한국에너지연구소 | 도토리와 오배자를 이용한 우라늄 회수 방법 |
| DE4019052A1 (de) * | 1990-06-15 | 1991-12-19 | Basf Ag | Verfahren zur entfernung von schwermetallionen aus waessriger loesung |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB704602A (en) * | 1943-05-12 | 1954-02-24 | Mini Of Supply | Improvements in or relating to radioactive compositions |
| DE2206445C2 (de) * | 1972-02-11 | 1973-09-13 | Rheinische Braunkohlenwerke Ag, 5000 Koeln | Verfahren zum Entfernen von Anionen aus Flüssigkeiten |
| FR2217418A1 (en) * | 1973-02-13 | 1974-09-06 | Ceskoslovenska Komise Atom | Reinforced fungal mycelium - by treatment with polymerisable or polycondensable cpds |
| JPS5097786A (it) * | 1973-12-30 | 1975-08-04 | ||
| JPS5247756B2 (it) * | 1974-05-09 | 1977-12-05 | ||
| DE2711587C2 (de) * | 1977-03-17 | 1986-08-07 | Kernforschungsanlage Jülich GmbH, 5170 Jülich | Verwendung eines aus Huminsäuren an einem Trägermaterial bestehenden Adsorbermaterials zur Gewinnung von Schwermetallen aus Meerwasser |
-
1977
- 1977-03-17 DE DE2711609A patent/DE2711609C2/de not_active Expired
-
1978
- 1978-03-13 FR FR7807119A patent/FR2383884A1/fr active Granted
- 1978-03-17 JP JP3003578A patent/JPS53115604A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| DE2711609C2 (de) | 1987-02-19 |
| FR2383884B1 (it) | 1984-11-23 |
| FR2383884A1 (fr) | 1978-10-13 |
| DE2711609A1 (de) | 1978-09-21 |
| JPS53115604A (en) | 1978-10-09 |
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