JPS6233560B2 - - Google Patents
Info
- Publication number
- JPS6233560B2 JPS6233560B2 JP53148600A JP14860078A JPS6233560B2 JP S6233560 B2 JPS6233560 B2 JP S6233560B2 JP 53148600 A JP53148600 A JP 53148600A JP 14860078 A JP14860078 A JP 14860078A JP S6233560 B2 JPS6233560 B2 JP S6233560B2
- Authority
- JP
- Japan
- Prior art keywords
- cement
- waste liquid
- bentonite
- leaching
- pellets
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000007788 liquid Substances 0.000 claims description 31
- 239000008188 pellet Substances 0.000 claims description 30
- 239000004568 cement Substances 0.000 claims description 28
- 238000000034 method Methods 0.000 claims description 24
- 239000002699 waste material Substances 0.000 claims description 24
- 239000011230 binding agent Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 14
- 239000000440 bentonite Substances 0.000 claims description 10
- 229910000278 bentonite Inorganic materials 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 10
- 239000002901 radioactive waste Substances 0.000 claims description 10
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 9
- 239000011398 Portland cement Substances 0.000 claims description 6
- 230000002745 absorbent Effects 0.000 claims description 6
- 239000002250 absorbent Substances 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- 239000004927 clay Substances 0.000 claims description 5
- 238000005507 spraying Methods 0.000 claims description 4
- XLYOFNOQVPJJNP-PWCQTSIFSA-N Tritiated water Chemical compound [3H]O[3H] XLYOFNOQVPJJNP-PWCQTSIFSA-N 0.000 claims description 3
- 238000005096 rolling process Methods 0.000 claims description 3
- 239000011400 blast furnace cement Substances 0.000 claims description 2
- 239000002893 slag Substances 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims 1
- 238000002386 leaching Methods 0.000 description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 239000011248 coating agent Substances 0.000 description 10
- 238000000576 coating method Methods 0.000 description 10
- 239000010426 asphalt Substances 0.000 description 9
- 238000007711 solidification Methods 0.000 description 9
- 230000008023 solidification Effects 0.000 description 9
- 239000011159 matrix material Substances 0.000 description 6
- 239000004033 plastic Substances 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- YZCKVEUIGOORGS-NJFSPNSNSA-N Tritium Chemical compound [3H] YZCKVEUIGOORGS-NJFSPNSNSA-N 0.000 description 4
- 229910052792 caesium Inorganic materials 0.000 description 4
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 4
- 238000011068 loading method Methods 0.000 description 4
- 229910052722 tritium Inorganic materials 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 238000005453 pelletization Methods 0.000 description 3
- 239000006223 plastic coating Substances 0.000 description 3
- 238000012958 reprocessing Methods 0.000 description 3
- 239000011343 solid material Substances 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000011449 brick Substances 0.000 description 2
- TVFDJXOCXUVLDH-RNFDNDRNSA-N cesium-137 Chemical compound [137Cs] TVFDJXOCXUVLDH-RNFDNDRNSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000000941 radioactive substance Substances 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000010561 standard procedure Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000003649 tritium Chemical class 0.000 description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 1
- JYFHYPJRHGVZDY-UHFFFAOYSA-N Dibutyl phosphate Chemical compound CCCCOP(O)(=O)OCCCC JYFHYPJRHGVZDY-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical group [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- CIOAGBVUUVVLOB-NJFSPNSNSA-N Strontium-90 Chemical compound [90Sr] CIOAGBVUUVVLOB-NJFSPNSNSA-N 0.000 description 1
- 238000006887 Ullmann reaction Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000002927 high level radioactive waste Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 229940050561 matrix product Drugs 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000011089 mechanical engineering Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000012857 radioactive material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 description 1
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 description 1
- 229940039790 sodium oxalate Drugs 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000001433 sodium tartrate Substances 0.000 description 1
- 229960002167 sodium tartrate Drugs 0.000 description 1
- 235000011004 sodium tartrates Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical group CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
Classifications
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/04—Treating liquids
- G21F9/06—Processing
- G21F9/16—Processing by fixation in stable solid media
- G21F9/167—Processing by fixation in stable solid media in polymeric matrix, e.g. resins, tars
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/04—Treating liquids
- G21F9/06—Processing
- G21F9/16—Processing by fixation in stable solid media
- G21F9/162—Processing by fixation in stable solid media in an inorganic matrix, e.g. clays, zeolites
- G21F9/165—Cement or cement-like matrix
Landscapes
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2819086A DE2819086C2 (de) | 1978-04-29 | 1978-04-29 | Verfahren zur Verfestigung von radioaktiven, wäßrigen Abfallflüssigkeiten |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS54144600A JPS54144600A (en) | 1979-11-10 |
| JPS6233560B2 true JPS6233560B2 ( ) | 1987-07-21 |
Family
ID=6038429
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14860078A Granted JPS54144600A (en) | 1978-04-29 | 1978-11-30 | Method of solidifying raioactive waste liquid |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4363757A ( ) |
| JP (1) | JPS54144600A ( ) |
| BR (1) | BR7902659A ( ) |
| DE (1) | DE2819086C2 ( ) |
| FR (1) | FR2424611B1 ( ) |
| GB (1) | GB2026228B ( ) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2917060C2 (de) * | 1979-04-27 | 1983-10-27 | Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe | Verfahren zur Verfestigung von tritiumhaltigem Wasser |
| DE3070886D1 (en) * | 1979-12-07 | 1985-08-22 | Hitachi Ltd | Method and apparatus for treatment of radioactive waste |
| DE3018745C2 (de) * | 1980-05-16 | 1984-02-02 | Nukem Gmbh, 6450 Hanau | Verfahren zum Einbetten von Tritium oder tritiumhaltigen radioaktiven Gasen |
| US4424148A (en) * | 1981-02-17 | 1984-01-03 | United States Gypsum Company | Process for preparing wastes for non-pollutant disposal |
| DE3142356A1 (de) * | 1981-10-26 | 1983-05-11 | Alkem Gmbh, 6450 Hanau | "verfahren zum endkonditionieren von radioaktivem und/oder toxischem abfall" |
| DE3150419A1 (de) * | 1981-12-19 | 1983-06-30 | F.J. Gattys Ingenieurbüro für chem. Maschinen- und Apparatebau, 6078 Neu Isenburg | Verfahren zur aufbereitung von pulvrigen, schlammigen oder geloesten materialien, insbesondere umweltgifte oder anderweit umweltschadstoffe enthaltenden abfaellen, fuer den transport sowie anschlissendes recycling bzw. langzeitlagerung |
| DE3215508C2 (de) * | 1982-04-26 | 1986-11-06 | Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe | Verfahren zur Verbesserung der Radionuklid-Rückhalteeigenschaften von Verfestigungen radioaktiver Abfälle |
| DE3225199A1 (de) * | 1982-07-06 | 1984-01-12 | F.J. Gattys Ingenieurbüro für chem. Maschinen- und Apparatebau, 6078 Neu Isenburg | Verfahren zur aufbereitung von abgebrannten brennelementen aus kernreaktoren |
| JPS5919899A (ja) * | 1982-07-26 | 1984-02-01 | 株式会社日立製作所 | 放射性固形廃棄物の固化方法 |
| US4522769A (en) * | 1982-08-24 | 1985-06-11 | General Electric Company | Method for the manufacture of nuclear fuel products |
| US4664895A (en) * | 1984-07-10 | 1987-05-12 | Westinghouse Electric Corp. | High concentration boric acid solidification process |
| DE3426800C2 (de) * | 1984-07-20 | 1986-08-21 | Nukem Gmbh, 6450 Hanau | Verfahren zur Herstellung deponierbarer Produkte aus umweltgefährdenden Salzgemischen |
| FR2585503A1 (fr) * | 1985-07-25 | 1987-01-30 | Barret Jean Louis | Procede de conditionnement par solidification de dechets dangereux d'origine industrielle ou nucleaire |
| DE3642975C1 (de) * | 1986-12-17 | 1988-02-11 | Wiederaufarbeitung Von Kernbre | Verfahren zur Herstellung eines zur Endlagerung tritiumhaltiger Abwaesser geeigneten Festprodukts |
| FR2623202B1 (fr) * | 1987-11-18 | 1990-03-30 | Soletanche | Procede pour resorber les fuites de liquides |
| US5037286A (en) * | 1988-06-24 | 1991-08-06 | Rolite, Inc. | Incineration residue treatment apparatus |
| US5439527A (en) * | 1991-08-28 | 1995-08-08 | The Tdj Group, Inc. | Method for fixing blast/cleaning waste |
| US5266122A (en) * | 1991-08-28 | 1993-11-30 | The Tdj Group, Inc. | Method for fixing blast/cleaning waste |
| US5273661A (en) * | 1992-02-21 | 1993-12-28 | Pickett John B | Method for processing aqueous wastes |
| US5414197A (en) * | 1994-06-03 | 1995-05-09 | The United States Of America As Represented By The Secretary Of The Army | Method of containing and isolating toxic or hazardous wastes |
| US5595561A (en) * | 1995-08-29 | 1997-01-21 | The United States Of America As Represented By The Secretary Of The Army | Low-temperature method for containing thermally degradable hazardous wastes |
| US6348153B1 (en) | 1998-03-25 | 2002-02-19 | James A. Patterson | Method for separating heavy isotopes of hydrogen oxide from water |
| JP4672962B2 (ja) * | 2000-06-12 | 2011-04-20 | ジオマトリクス ソリューションズ，インコーポレイテッド | 放射性及び有害廃棄物の処理方法並びに封入廃棄品 |
| WO2005084756A1 (en) | 2004-02-23 | 2005-09-15 | Geomatrix Solutions, Inc. | Process and composition for immobilization wastes in borosilicate glass |
| US7550645B2 (en) * | 2004-02-23 | 2009-06-23 | Geomatrix Solutions, Inc. | Process and composition for the immobilization of radioactive and hazardous wastes in borosilicate glass |
| US6984327B1 (en) | 2004-11-23 | 2006-01-10 | Patterson James A | System and method for separating heavy isotopes of hydrogen oxide from water |
| FR2885040B1 (fr) | 2005-04-29 | 2008-12-26 | Oreal | Procede de mise en forme semi-permanente des cheveux |
| CN101448752B (zh) | 2006-03-20 | 2012-05-30 | 地理矩阵解决方案公司 | 在硅酸盐基玻璃中固定高碱性的放射性和有害废料的方法和组合物 |
| CA2893114A1 (en) * | 2013-01-30 | 2014-08-07 | Sofia Invest & Engineering | Method and practical device composition for purification of air from gaseous tritium and concentration of tritium in a constant volume of water |
| RU2550367C1 (ru) * | 2013-12-18 | 2015-05-10 | Федеральное государственное унитарное предприятие "Научно-исследовательский институт Научно-производственное объединение "ЛУЧ" (ФГУП "НИИ НПО "ЛУЧ") | Способ очистки жидкостей, содержащих радионуклиды, и устройство для его осуществления |
| US9978470B2 (en) * | 2015-12-14 | 2018-05-22 | Uchicago Argonne, Llc | Immobilization of organic radioactive and non-radioactive liquid waste in a composite matrix |
| RU2616447C1 (ru) * | 2016-06-30 | 2017-04-17 | Федеральное государственное унитарное предприятие "Научно-исследовательский институт Научно-производственное объединение "ЛУЧ" (ФГУП "НИИ НПО "ЛУЧ") | Способ очистки жидкости, содержащей радионуклиды, и устройство для его осуществления |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5273300A (en) * | 1975-12-15 | 1977-06-18 | Nippon Atom Ind Group Co Ltd | Solidifying treatment for radioactive pellet waste |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL235423A ( ) * | 1959-01-19 | |||
| US3249551A (en) * | 1963-06-03 | 1966-05-03 | David L Neil | Method and product for the disposal of radioactive wastes |
| DE2012785C3 (de) * | 1970-03-18 | 1974-08-08 | Kraftwerk Union Ag, 4330 Muelheim | Verfahren zur Behandlung von zu beseitigenden radioaktive Konzentrate enthaltenden flüssigen Abfallstoffen |
| DE2061870A1 (en) * | 1970-12-16 | 1972-07-06 | Siemens Ag | Radioactive waste waters or solns, stored by concentrating to - powders, and embedding in casting resins |
| GB1456980A (en) * | 1973-12-20 | 1976-12-01 | Atomic Energy Authority Uk | Preparation of storage of fission products |
| DE2363475C3 (de) * | 1973-12-20 | 1986-06-19 | Steag Kernenergie Gmbh, 4300 Essen | Verfahren zum Aufbereiten von radioaktive oder toxische Stoffe enthaltenden, festen Abfällen zur sicheren Handhabung, Transportierung und Endlagerung |
| US4031175A (en) * | 1974-09-04 | 1977-06-21 | Ppg Industries, Inc. | Glass batch pelletizing method |
| JPS538880A (en) * | 1976-07-12 | 1978-01-26 | Nissan Motor Co Ltd | Process and apparatus for releasing hot molded corrugated fiberboard from dies |
| DE2726087C2 (de) * | 1977-06-10 | 1978-12-21 | Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe | Verfahren zur endlagerreifen, umweltfreundlichen Verfestigung von" und mittelradioaktiven und/oder Actiniden enthaltenden, wäßrigen Abfallkonzentraten oder von in Wasser aufgeschlämmten, feinkörnigen festen Abfällen |
-
1978
- 1978-04-29 DE DE2819086A patent/DE2819086C2/de not_active Expired
- 1978-11-30 FR FR7833864A patent/FR2424611B1/fr not_active Expired
- 1978-11-30 JP JP14860078A patent/JPS54144600A/ja active Granted
-
1979
- 1979-04-30 US US06/034,690 patent/US4363757A/en not_active Expired - Lifetime
- 1979-04-30 BR BR7902659A patent/BR7902659A/pt unknown
- 1979-04-30 GB GB7914971A patent/GB2026228B/en not_active Expired
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5273300A (en) * | 1975-12-15 | 1977-06-18 | Nippon Atom Ind Group Co Ltd | Solidifying treatment for radioactive pellet waste |
Also Published As
| Publication number | Publication date |
|---|---|
| BR7902659A (pt) | 1980-01-15 |
| GB2026228B (en) | 1982-08-11 |
| US4363757A (en) | 1982-12-14 |
| DE2819086A1 (de) | 1979-10-31 |
| FR2424611B1 (fr) | 1986-01-31 |
| GB2026228A (en) | 1980-01-30 |
| JPS54144600A (en) | 1979-11-10 |
| DE2819086C2 (de) | 1985-09-12 |
| FR2424611A1 (fr) | 1979-11-23 |
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