JPS62287634A - 半導体素子結線用細線 - Google Patents
半導体素子結線用細線Info
- Publication number
- JPS62287634A JPS62287634A JP61132565A JP13256586A JPS62287634A JP S62287634 A JPS62287634 A JP S62287634A JP 61132565 A JP61132565 A JP 61132565A JP 13256586 A JP13256586 A JP 13256586A JP S62287634 A JPS62287634 A JP S62287634A
- Authority
- JP
- Japan
- Prior art keywords
- wire
- core
- surface layer
- purity
- hardness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004065 semiconductor Substances 0.000 title claims description 17
- 238000000034 method Methods 0.000 claims abstract description 12
- 239000002344 surface layer Substances 0.000 claims abstract description 9
- 239000002184 metal Substances 0.000 claims abstract description 6
- 229910052751 metal Inorganic materials 0.000 claims abstract description 6
- 229910052790 beryllium Inorganic materials 0.000 claims abstract description 5
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 5
- 229910052718 tin Inorganic materials 0.000 claims abstract description 5
- 239000011247 coating layer Substances 0.000 claims abstract description 4
- 239000010410 layer Substances 0.000 claims abstract description 4
- 229910052709 silver Inorganic materials 0.000 claims abstract description 4
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 4
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 4
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 3
- 238000009792 diffusion process Methods 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 17
- 239000010949 copper Substances 0.000 description 11
- 229910052802 copper Inorganic materials 0.000 description 9
- 229910000881 Cu alloy Inorganic materials 0.000 description 5
- 238000005491 wire drawing Methods 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000005482 strain hardening Methods 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000002788 crimping Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 241000272201 Columbiformes Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
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Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
め要約のデータは記録されません。
Description
【発明の詳細な説明】
3、発明の詳細な説明
(発明の11用分野)
本発明は、半導体素子上の電極と外部リードとの結線に
用いろ半導体素子結線用細線に関する。
用いろ半導体素子結線用細線に関する。
(従来技術)
IC−?3LSI等の半導体素子において、例えば第3
図に示すようにSi半導体チップ1の電極2と外部リー
ドフレーム3とを結線用細線4で電気接続するようにな
っているが、この接続は作業性に優れたポールポンディ
ング7去が主に用いられている。本方法は第2図に示す
ようにこのボンディング法に用いられるキャピラリ5の
先端部に結線用細線4を露出させて、その先端部を電気
アークあるいは水素アークにより加熱させてポール6を
形成し、これを第3図に示すように半導体チップ1の電
極2に熱圧若により接続し、次に弧を描くようにm線4
を延ばし、外部リードフレーム3に細線4の一部を圧接
し、切断するようにしたものである。
図に示すようにSi半導体チップ1の電極2と外部リー
ドフレーム3とを結線用細線4で電気接続するようにな
っているが、この接続は作業性に優れたポールポンディ
ング7去が主に用いられている。本方法は第2図に示す
ようにこのボンディング法に用いられるキャピラリ5の
先端部に結線用細線4を露出させて、その先端部を電気
アークあるいは水素アークにより加熱させてポール6を
形成し、これを第3図に示すように半導体チップ1の電
極2に熱圧若により接続し、次に弧を描くようにm線4
を延ばし、外部リードフレーム3に細線4の一部を圧接
し、切断するようにしたものである。
従ってこの種結線用細線4としては、半導体素子の電極
への圧着に用いるキャピラ゛J5との接触通過時に細粉
がキーピラリに付着して橿粉詰まりを起こさせないよう
にすること、上記電極に充分に均一に圧接するよう安定
したポール6に形成されること、ポール6の電極への接
着強度が高いこと、結線用細線4が上記電極2と外部リ
ードフレーム3と接続されたとき弧を描くよう、卯ちル
ープ状Sこつながれること(このループ線が第3図で一
寺鎖線で示すように寝丁ぎるとポール6の根元で断線さ
れやすい)、などが要求され、従来から主に金線が使用
されている。
への圧着に用いるキャピラ゛J5との接触通過時に細粉
がキーピラリに付着して橿粉詰まりを起こさせないよう
にすること、上記電極に充分に均一に圧接するよう安定
したポール6に形成されること、ポール6の電極への接
着強度が高いこと、結線用細線4が上記電極2と外部リ
ードフレーム3と接続されたとき弧を描くよう、卯ちル
ープ状Sこつながれること(このループ線が第3図で一
寺鎖線で示すように寝丁ぎるとポール6の根元で断線さ
れやすい)、などが要求され、従来から主に金線が使用
されている。
しかし金線は非常に高価であるから(面格的に廉価な銅
線を用いる試みがなされているが、銅線を用いてポール
ボンディング法によって熱圧着すると銅粉が発生してキ
ャピラリの銅粉詰まりを起こしたり、接着強度が充分に
出ないなどの欠点があった。
線を用いる試みがなされているが、銅線を用いてポール
ボンディング法によって熱圧着すると銅粉が発生してキ
ャピラリの銅粉詰まりを起こしたり、接着強度が充分に
出ないなどの欠点があった。
これを改善するために銅にBe、 Sn、 Zn、 A
g、 Zr。
g、 Zr。
Cr、 Fe等を0.1〜2重量%添加した銅合金が提
案されているが、これをポールボンディング法にて使用
した場合次のような欠点があった。
案されているが、これをポールボンディング法にて使用
した場合次のような欠点があった。
まずSi素子上に銅合金ボールを熱圧着する際、銅合金
ポールの硬さが必要以上に大きいため、素子電極面にク
ラックを生しる。
ポールの硬さが必要以上に大きいため、素子電極面にク
ラックを生しる。
銅合金ボールの硬さを小さくするために、熱圧着温度あ
るいはキャピラリ温度を上げるとループ線が寝すぎて良
好なループ形成性をもたすことが不充分になり断線の原
因となる想れがある。
るいはキャピラリ温度を上げるとループ線が寝すぎて良
好なループ形成性をもたすことが不充分になり断線の原
因となる想れがある。
また銅合金のほとんどを占める銅の細粉がキャピラリに
接触する際に多く発生し、キャピラリの銅粉詰まりを起
こし結線作業上支障をきたす事態があった。
接触する際に多く発生し、キャピラリの銅粉詰まりを起
こし結線作業上支障をきたす事態があった。
(発明が解決しようとする問題点)
本発明の目的は銅の物理的特性および低価格性を失うこ
となく、これを最大限に生かし、かつポールボンディン
グに通した硬さで、その作業性に優れた半導体素子結線
用細線を提供しようとするものである。
となく、これを最大限に生かし、かつポールボンディン
グに通した硬さで、その作業性に優れた半導体素子結線
用細線を提供しようとするものである。
(問題点を解決するための手段)
上記目的を達成するために本発明の第1は、純度99重
量%以上のCuからなり、これを伸線加工すると共に、
最終工程でスキンパス加工することにより第1図で示す
ように表面層Bの硬さを芯部Aよりも25〜45%高く
してなる構成を採用するものである。
量%以上のCuからなり、これを伸線加工すると共に、
最終工程でスキンパス加工することにより第1図で示す
ように表面層Bの硬さを芯部Aよりも25〜45%高く
してなる構成を採用するものである。
また本発明の第2は、純度99.99重量%以上のCu
を芯部として、これにAg、 Sn、 Be、 Zr、
Zn、 AI。
を芯部として、これにAg、 Sn、 Be、 Zr、
Zn、 AI。
Crからなる群から選ばれた1種の金属からなる被覆石
を設け、この状態で伸線加工すると共に、最終工程でス
キンパス加工することにより表面層の硬さを芯部よりも
30〜50%高くしてなる構成を採用するものである。
を設け、この状態で伸線加工すると共に、最終工程でス
キンパス加工することにより表面層の硬さを芯部よりも
30〜50%高くしてなる構成を採用するものである。
(作 用)
銅の純度を99.99重量%以上としたのは結線用細線
の変形挙動を金線の場合に近づけ、圧着時にSi半導体
素子を用傷することなく充分安定であり、高導電性と信
頼性に優れた接続を得るためで、99゜99T(i量%
未満では、31半導体素子にクラックを生じさせやすい
ことがわかっている。
の変形挙動を金線の場合に近づけ、圧着時にSi半導体
素子を用傷することなく充分安定であり、高導電性と信
頼性に優れた接続を得るためで、99゜99T(i量%
未満では、31半導体素子にクラックを生じさせやすい
ことがわかっている。
さらにこのような高純度の芯線に、最終工程でスキンパ
ス加工(低減面率のもとで軽い冷間伸線を行うこと)を
行うのは、銅の表面のみを硬化させるためで、この場合
表面層の硬さを芯部よりも25〜45%高くすることが
必要で、このためにはスキンパス加工の加工度は5〜2
0%の範囲内で行う。
ス加工(低減面率のもとで軽い冷間伸線を行うこと)を
行うのは、銅の表面のみを硬化させるためで、この場合
表面層の硬さを芯部よりも25〜45%高くすることが
必要で、このためにはスキンパス加工の加工度は5〜2
0%の範囲内で行う。
加工度が4%以下では加工硬化が小さく、また21%以
上では伸線の芯部まで加工硬化し、この種細線の伸びの
低下およびカール発生の原因となる。
上では伸線の芯部まで加工硬化し、この種細線の伸びの
低下およびカール発生の原因となる。
また第2発明において、上記のような高純度の銅を芯部
として使用し、これにAg、 Sn、 Be、 Zr。
として使用し、これにAg、 Sn、 Be、 Zr。
Zn、 Al、 Cr力)らなる群力)ら選ばれた/f
覗の金属からなる被覆層を設け、この状態で伸線加工す
るようにしたのは、最終工程のスキンパス加工による加
工硬化性を一層高め、細線の曲げ強度を高めるためであ
る。なおこの場合スキンパス加工後の被覆層(被覆拡散
N> Aの厚さは第1図に示すように線径D(直径)の
1/10〜3/10の比率に形成することが好ましい。
覗の金属からなる被覆層を設け、この状態で伸線加工す
るようにしたのは、最終工程のスキンパス加工による加
工硬化性を一層高め、細線の曲げ強度を高めるためであ
る。なおこの場合スキンパス加工後の被覆層(被覆拡散
N> Aの厚さは第1図に示すように線径D(直径)の
1/10〜3/10の比率に形成することが好ましい。
(実施例)
以下、この発明の実施例に係る半導体結線用細線1〜6
と比較例の同細線7〜9についてシリコン素子のクラン
ク不良率、細線の硬度(芯部と表面層の硬度)、銅粉の
発生率、ボール形成性、ループ形成性を測定した。下記
表1がそれである。
と比較例の同細線7〜9についてシリコン素子のクラン
ク不良率、細線の硬度(芯部と表面層の硬度)、銅粉の
発生率、ボール形成性、ループ形成性を測定した。下記
表1がそれである。
なおこの発明に係る実旅例阻1〜寛6は次のようにして
製造されたものである。即ち純度99.998%の再電
解銅を素材料としてこれを伸線機によって26μφまで
伸線しかつフル焼鈍を行い、最終工程で5〜20%の加
工度でスキンパス加工により25μφの細線に仕上げた
ものである。また比較例の隘7〜寛9に示すものは、上
記と同一の製造工程でスキンパス加工の加工度を変えた
ものである。
製造されたものである。即ち純度99.998%の再電
解銅を素材料としてこれを伸線機によって26μφまで
伸線しかつフル焼鈍を行い、最終工程で5〜20%の加
工度でスキンパス加工により25μφの細線に仕上げた
ものである。また比較例の隘7〜寛9に示すものは、上
記と同一の製造工程でスキンパス加工の加工度を変えた
ものである。
以下余白
表−1
また第2発明に係る実施例鳩】〜患6に示す芯部Aおよ
び被rxNBは次のようにして製造したものである。即
ち純度99.998%の再電解銅を素材料としてこれを
伸線機によって0 、9 *mφまで伸線加工し、これ
を酸化物および油脂除去の前処理の後に、電気メッキま
たは熔融メッキ法などにより表2に示す元素金属をその
濃度が100〜300ppmになるようメブキ条件を設
定してメッキ処理し、しかる後に全体のIi!径が26
μφになるまで伸線・熱処理(焼鈍)加工をし、更に加
工度10%のスキンパス加工により25μφとし、被覆
拡散1’HBの硬さが芯部Aよりも25〜45%高くな
るような厚さ0.05〜0.2μの被覆拡散層Bを形成
するようにしたものである。また比較例の魚7〜寛9に
示すものは、上記と同一の製造工程で樹の純度を変えた
ものである。この測定結果は下記表2に示すとおりであ
る。
び被rxNBは次のようにして製造したものである。即
ち純度99.998%の再電解銅を素材料としてこれを
伸線機によって0 、9 *mφまで伸線加工し、これ
を酸化物および油脂除去の前処理の後に、電気メッキま
たは熔融メッキ法などにより表2に示す元素金属をその
濃度が100〜300ppmになるようメブキ条件を設
定してメッキ処理し、しかる後に全体のIi!径が26
μφになるまで伸線・熱処理(焼鈍)加工をし、更に加
工度10%のスキンパス加工により25μφとし、被覆
拡散1’HBの硬さが芯部Aよりも25〜45%高くな
るような厚さ0.05〜0.2μの被覆拡散層Bを形成
するようにしたものである。また比較例の魚7〜寛9に
示すものは、上記と同一の製造工程で樹の純度を変えた
ものである。この測定結果は下記表2に示すとおりであ
る。
表−2
(効 果)
本発明によれば、表1及び表2から明らかなように99
.99%以上の純度の高い銅をそのまま細線として採用
するため、高導電性と良好なポール形成性を維持できる
と共に、半導体素子に対するクランク発生度を無(する
ことができ、なおかつ表面石の適度の硬度によって芯部
の銅を保護し、キャピラリ接触時の銅粉の発生が皆無と
なり、更にループの形成性が良好となることが分かる。
.99%以上の純度の高い銅をそのまま細線として採用
するため、高導電性と良好なポール形成性を維持できる
と共に、半導体素子に対するクランク発生度を無(する
ことができ、なおかつ表面石の適度の硬度によって芯部
の銅を保護し、キャピラリ接触時の銅粉の発生が皆無と
なり、更にループの形成性が良好となることが分かる。
第1図は、本発明の一実施例における半導体素子結線用
細線の拡大断面図、第2図は同細線をキャピラリに挿通
させて、その先端部で形成されるボールの状態を示す説
明図、第3図は同細線で半導体素子に接続された状態を
示す説明図である。
細線の拡大断面図、第2図は同細線をキャピラリに挿通
させて、その先端部で形成されるボールの状態を示す説
明図、第3図は同細線で半導体素子に接続された状態を
示す説明図である。
Claims (1)
- 【特許請求の範囲】 1、純度99.99重量%以上のCuからなり、これを
伸線加工すると共に、最終工程でスキンパス加工するこ
とにより表面層の硬さを芯部よりも25〜45%高くし
てなる半導体素子結線用細線。 2、純度99.99重量%以上のCuを芯部として、こ
れにAg、Sn、Be、Zr、Zn、Al、Crからな
る群から選ばれた1種の金属からなる被覆層を設け、こ
の状態で伸線加工すると共に、最終工程でスキンパス加
工することにより表面層の硬さを芯部よりも30〜50
%高くしてなる半導体素子結線用細線。 3、前記表面層(被覆拡散層)の厚さは線径の1/10
〜3/10に形成してなる特許請求の範囲第2項記載の
半導体素子結線用細線。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61132565A JPS62287634A (ja) | 1986-06-06 | 1986-06-06 | 半導体素子結線用細線 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61132565A JPS62287634A (ja) | 1986-06-06 | 1986-06-06 | 半導体素子結線用細線 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS62287634A true JPS62287634A (ja) | 1987-12-14 |
JPH0319702B2 JPH0319702B2 (ja) | 1991-03-15 |
Family
ID=15084274
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP61132565A Granted JPS62287634A (ja) | 1986-06-06 | 1986-06-06 | 半導体素子結線用細線 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS62287634A (ja) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011243659A (ja) * | 2010-05-14 | 2011-12-01 | Furukawa Electric Co Ltd:The | 平角銅線及びその製造方法、並びに太陽電池用平角銅線及びその製造方法 |
WO2012022404A2 (de) * | 2010-07-22 | 2012-02-23 | W.C. Heraeus Gmbh & Co. Kg | Kern-mantel-bändchendraht |
JP2015159341A (ja) * | 2015-06-11 | 2015-09-03 | 日立金属株式会社 | 銅ボンディングワイヤ |
WO2020071002A1 (ja) * | 2018-10-01 | 2020-04-09 | 富山住友電工株式会社 | めっき線材の製造方法およびめっき線材の製造装置 |
-
1986
- 1986-06-06 JP JP61132565A patent/JPS62287634A/ja active Granted
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011243659A (ja) * | 2010-05-14 | 2011-12-01 | Furukawa Electric Co Ltd:The | 平角銅線及びその製造方法、並びに太陽電池用平角銅線及びその製造方法 |
WO2012022404A2 (de) * | 2010-07-22 | 2012-02-23 | W.C. Heraeus Gmbh & Co. Kg | Kern-mantel-bändchendraht |
WO2012022404A3 (de) * | 2010-07-22 | 2012-06-28 | W.C. Heraeus Gmbh & Co. Kg | Kern-mantel-bändchendraht |
US9236166B2 (en) | 2010-07-22 | 2016-01-12 | Heraeus Deutschland GmbH & Co. KG | Core-jacket bonding wire |
EP3425665A1 (de) * | 2010-07-22 | 2019-01-09 | Heraeus Deutschland GmbH & Co KG | Verfahren zur herstellung eines bonddrahtes |
JP2015159341A (ja) * | 2015-06-11 | 2015-09-03 | 日立金属株式会社 | 銅ボンディングワイヤ |
WO2020071002A1 (ja) * | 2018-10-01 | 2020-04-09 | 富山住友電工株式会社 | めっき線材の製造方法およびめっき線材の製造装置 |
Also Published As
Publication number | Publication date |
---|---|
JPH0319702B2 (ja) | 1991-03-15 |
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