JPS62250948A - メタノールの水蒸気改質による混合ガスの製造方法 - Google Patents
メタノールの水蒸気改質による混合ガスの製造方法Info
- Publication number
- JPS62250948A JPS62250948A JP61096454A JP9645486A JPS62250948A JP S62250948 A JPS62250948 A JP S62250948A JP 61096454 A JP61096454 A JP 61096454A JP 9645486 A JP9645486 A JP 9645486A JP S62250948 A JPS62250948 A JP S62250948A
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- methanol
- metal
- alumina
- metals
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims abstract description 93
- 239000003054 catalyst Substances 0.000 title claims abstract description 37
- 238000000629 steam reforming Methods 0.000 title claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 22
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 17
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 10
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000010953 base metal Substances 0.000 claims abstract description 10
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 8
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 8
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 8
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 8
- 150000001342 alkaline earth metals Chemical class 0.000 claims abstract description 8
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000010457 zeolite Substances 0.000 claims abstract description 8
- -1 alumina Chemical class 0.000 claims abstract description 6
- 229910052878 cordierite Inorganic materials 0.000 claims abstract description 6
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000011651 chromium Substances 0.000 claims abstract description 5
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 5
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052742 iron Inorganic materials 0.000 claims abstract description 5
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 5
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 5
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 5
- 229910052703 rhodium Inorganic materials 0.000 claims abstract description 5
- 239000010948 rhodium Substances 0.000 claims abstract description 5
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims abstract description 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 4
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims abstract description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 4
- 239000011733 molybdenum Substances 0.000 claims abstract description 4
- 239000010941 cobalt Substances 0.000 claims abstract description 3
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000011575 calcium Substances 0.000 claims description 4
- 239000011777 magnesium Substances 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 150000002484 inorganic compounds Chemical class 0.000 claims description 3
- 229910010272 inorganic material Inorganic materials 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 239000010970 precious metal Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 9
- 239000002184 metal Substances 0.000 abstract description 9
- 229910000510 noble metal Inorganic materials 0.000 abstract description 6
- 150000001875 compounds Chemical class 0.000 abstract description 4
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 29
- 239000007789 gas Substances 0.000 description 23
- 238000006243 chemical reaction Methods 0.000 description 16
- 229910002092 carbon dioxide Inorganic materials 0.000 description 13
- 229910052739 hydrogen Inorganic materials 0.000 description 13
- 239000001257 hydrogen Substances 0.000 description 13
- 238000000034 method Methods 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 10
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 10
- 239000002994 raw material Substances 0.000 description 10
- 239000001569 carbon dioxide Substances 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 7
- 229910002090 carbon oxide Inorganic materials 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 6
- 229910002091 carbon monoxide Inorganic materials 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- AOPCKOPZYFFEDA-UHFFFAOYSA-N nickel(2+);dinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O AOPCKOPZYFFEDA-UHFFFAOYSA-N 0.000 description 5
- 239000004323 potassium nitrate Substances 0.000 description 5
- 235000010333 potassium nitrate Nutrition 0.000 description 5
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 4
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 238000001651 catalytic steam reforming of methanol Methods 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000001354 calcination Methods 0.000 description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- GVHCUJZTWMCYJM-UHFFFAOYSA-N chromium(3+);trinitrate;nonahydrate Chemical compound O.O.O.O.O.O.O.O.O.[Cr+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O GVHCUJZTWMCYJM-UHFFFAOYSA-N 0.000 description 2
- QGUAJWGNOXCYJF-UHFFFAOYSA-N cobalt dinitrate hexahydrate Chemical compound O.O.O.O.O.O.[Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O QGUAJWGNOXCYJF-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- MFUVDXOKPBAHMC-UHFFFAOYSA-N magnesium;dinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MFUVDXOKPBAHMC-UHFFFAOYSA-N 0.000 description 2
- 150000002823 nitrates Chemical class 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 238000007086 side reaction Methods 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910020679 Co—K Inorganic materials 0.000 description 1
- 229910018493 Ni—K Inorganic materials 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000012378 ammonium molybdate tetrahydrate Substances 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- FIXLYHHVMHXSCP-UHFFFAOYSA-H azane;dihydroxy(dioxo)molybdenum;trioxomolybdenum;tetrahydrate Chemical compound N.N.N.N.N.N.O.O.O.O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O[Mo](O)(=O)=O.O[Mo](O)(=O)=O.O[Mo](O)(=O)=O FIXLYHHVMHXSCP-UHFFFAOYSA-H 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 1
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N dimethylmethane Natural products CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- SZQUEWJRBJDHSM-UHFFFAOYSA-N iron(3+);trinitrate;nonahydrate Chemical compound O.O.O.O.O.O.O.O.O.[Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O SZQUEWJRBJDHSM-UHFFFAOYSA-N 0.000 description 1
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
Landscapes
- Hydrogen, Water And Hydrids (AREA)
- Catalysts (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61096454A JPS62250948A (ja) | 1986-04-24 | 1986-04-24 | メタノールの水蒸気改質による混合ガスの製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61096454A JPS62250948A (ja) | 1986-04-24 | 1986-04-24 | メタノールの水蒸気改質による混合ガスの製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62250948A true JPS62250948A (ja) | 1987-10-31 |
| JPH0582321B2 JPH0582321B2 (OSRAM) | 1993-11-18 |
Family
ID=14165469
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61096454A Granted JPS62250948A (ja) | 1986-04-24 | 1986-04-24 | メタノールの水蒸気改質による混合ガスの製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62250948A (OSRAM) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0226801A (ja) * | 1988-07-14 | 1990-01-29 | Mitsubishi Heavy Ind Ltd | メタノール改質方法 |
| WO2002048039A1 (en) * | 2000-12-13 | 2002-06-20 | Victoria Link Limited | Catalysts and the hydroformylation of olefins |
Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52156194A (en) * | 1976-06-22 | 1977-12-26 | Nippon Soken | Catalysts for reforming methyl alchol |
| JPS5310389A (en) * | 1976-07-15 | 1978-01-30 | Nippon Soken | Catalysts for reforming methyl alchol |
| JPS5768140A (en) * | 1980-10-13 | 1982-04-26 | Mitsubishi Heavy Ind Ltd | Catalyst for modification of methanol |
| JPS57144031A (en) * | 1981-03-04 | 1982-09-06 | Agency Of Ind Science & Technol | Catalyst for decomposition of methanol for production of hydrogen and carbon monoxide |
| JPS5870839A (ja) * | 1981-10-26 | 1983-04-27 | Mitsui Toatsu Chem Inc | メタノ−ルのスチ−ムリフオ−ミング用触媒 |
| JPS58193737A (ja) * | 1982-05-04 | 1983-11-11 | Mitsubishi Heavy Ind Ltd | 水素富化ガス製造用触媒 |
| JPS59199043A (ja) * | 1983-04-27 | 1984-11-12 | Mitsubishi Heavy Ind Ltd | メタノ−ル改質用触媒 |
| JPS6060902A (ja) * | 1983-08-06 | 1985-04-08 | ザ ブリテイツシユ ピトロ−リアム コンパニ− ピ−．エル．シ−． | メタノ−ル変換法 |
| JPS6082136A (ja) * | 1983-10-14 | 1985-05-10 | Mitsubishi Heavy Ind Ltd | メタノ−ル改質用触媒 |
| JPS60122038A (ja) * | 1983-12-06 | 1985-06-29 | Mitsubishi Heavy Ind Ltd | メタノ−ル改質用触媒 |
| JPS60122039A (ja) * | 1983-12-06 | 1985-06-29 | Mitsubishi Heavy Ind Ltd | メタノ−ル改質用触媒 |
| JPS60202739A (ja) * | 1984-03-22 | 1985-10-14 | Mitsubishi Heavy Ind Ltd | メタノ−ル改質用触媒 |
| JPS60257837A (ja) * | 1984-06-06 | 1985-12-19 | Jgc Corp | メタノ−ル分解／改質用触媒およびその調製方法 |
-
1986
- 1986-04-24 JP JP61096454A patent/JPS62250948A/ja active Granted
Patent Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52156194A (en) * | 1976-06-22 | 1977-12-26 | Nippon Soken | Catalysts for reforming methyl alchol |
| JPS5310389A (en) * | 1976-07-15 | 1978-01-30 | Nippon Soken | Catalysts for reforming methyl alchol |
| JPS5768140A (en) * | 1980-10-13 | 1982-04-26 | Mitsubishi Heavy Ind Ltd | Catalyst for modification of methanol |
| JPS57144031A (en) * | 1981-03-04 | 1982-09-06 | Agency Of Ind Science & Technol | Catalyst for decomposition of methanol for production of hydrogen and carbon monoxide |
| JPS5870839A (ja) * | 1981-10-26 | 1983-04-27 | Mitsui Toatsu Chem Inc | メタノ−ルのスチ−ムリフオ−ミング用触媒 |
| JPS58193737A (ja) * | 1982-05-04 | 1983-11-11 | Mitsubishi Heavy Ind Ltd | 水素富化ガス製造用触媒 |
| JPS59199043A (ja) * | 1983-04-27 | 1984-11-12 | Mitsubishi Heavy Ind Ltd | メタノ−ル改質用触媒 |
| JPS6060902A (ja) * | 1983-08-06 | 1985-04-08 | ザ ブリテイツシユ ピトロ−リアム コンパニ− ピ−．エル．シ−． | メタノ−ル変換法 |
| JPS6082136A (ja) * | 1983-10-14 | 1985-05-10 | Mitsubishi Heavy Ind Ltd | メタノ−ル改質用触媒 |
| JPS60122038A (ja) * | 1983-12-06 | 1985-06-29 | Mitsubishi Heavy Ind Ltd | メタノ−ル改質用触媒 |
| JPS60122039A (ja) * | 1983-12-06 | 1985-06-29 | Mitsubishi Heavy Ind Ltd | メタノ−ル改質用触媒 |
| JPS60202739A (ja) * | 1984-03-22 | 1985-10-14 | Mitsubishi Heavy Ind Ltd | メタノ−ル改質用触媒 |
| JPS60257837A (ja) * | 1984-06-06 | 1985-12-19 | Jgc Corp | メタノ−ル分解／改質用触媒およびその調製方法 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0226801A (ja) * | 1988-07-14 | 1990-01-29 | Mitsubishi Heavy Ind Ltd | メタノール改質方法 |
| WO2002048039A1 (en) * | 2000-12-13 | 2002-06-20 | Victoria Link Limited | Catalysts and the hydroformylation of olefins |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0582321B2 (OSRAM) | 1993-11-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5592250B2 (ja) | 二酸化炭素の合成ガスへの接触水素化 | |
| JP2847018B2 (ja) | 二酸化炭素還元反応触媒 | |
| US7771702B2 (en) | Sulfur-tolerant catalysts and related precursors and processes | |
| WO2002078840A1 (en) | Catalyst for reforming hydrocarbon and method for preparation thereof, and process for reforming hydrocarbon using said catalyst | |
| JPH0336571B2 (OSRAM) | ||
| JP3761947B2 (ja) | 合成ガス製造用触媒組成物およびこれを用いて合成ガスを製造する方法 | |
| CS213333B2 (en) | Method of making the catalyser | |
| KR900003942B1 (ko) | 디엔 존재하의 알킨의 선택적 수소화용 촉매 | |
| CN110975884A (zh) | 一种用于选择性氧化甲苯制备苯甲醛的含过渡金属催化剂的制备方法 | |
| EP1312412B1 (en) | Process for producing hydrogen-containing gas | |
| US6238640B1 (en) | Conversion method of carbon monoxide and catalyst | |
| JPH11179204A (ja) | 一酸化炭素及び二酸化炭素を含有するガスのメタン化触媒及びその製造方法 | |
| JPS5929633B2 (ja) | 炭化水素の低温水蒸気改質法 | |
| JP2545734B2 (ja) | 炭化水素製造用触媒及び炭化水素の製造方法 | |
| JPS62250948A (ja) | メタノールの水蒸気改質による混合ガスの製造方法 | |
| JPS5998024A (ja) | 混合アルコ−ルの合成方法 | |
| EP1110907A1 (en) | Process for reducing concentration of carbon monoxide in hydrogen-containing gas and catalyst used therefor | |
| KR102296609B1 (ko) | 탄화수소 제조용 촉매 및 이의 제조 방법 | |
| JP2500357B2 (ja) | 二酸化炭素からメタンを製造する方法 | |
| JPH0371174B2 (OSRAM) | ||
| JPH09253495A (ja) | メタノール合成触媒 | |
| CN114618470B (zh) | 一种复合型催化剂及其制备方法和应用 | |
| JPH0311813B2 (OSRAM) | ||
| CN88100605A (zh) | 负载型铜镍基甲醇分解催化剂 | |
| JPH0567336B2 (OSRAM) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| EXPY | Cancellation because of completion of term |