JPS62179592A - 共反応剤としてメタノ−ルを用いる分散された触媒のクラツキング方法 - Google Patents
共反応剤としてメタノ−ルを用いる分散された触媒のクラツキング方法Info
- Publication number
- JPS62179592A JPS62179592A JP1830886A JP1830886A JPS62179592A JP S62179592 A JPS62179592 A JP S62179592A JP 1830886 A JP1830886 A JP 1830886A JP 1830886 A JP1830886 A JP 1830886A JP S62179592 A JPS62179592 A JP S62179592A
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- hydrocarbon
- oxygen
- reaction
- methanol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims description 132
- 239000003054 catalyst Substances 0.000 title claims description 98
- 238000005336 cracking Methods 0.000 title claims description 30
- 239000000376 reactant Substances 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 claims description 91
- 229930195733 hydrocarbon Natural products 0.000 claims description 49
- 150000002430 hydrocarbons Chemical class 0.000 claims description 49
- 238000000034 method Methods 0.000 claims description 32
- 239000004215 Carbon black (E152) Substances 0.000 claims description 31
- 239000010457 zeolite Substances 0.000 claims description 31
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 25
- 239000001301 oxygen Substances 0.000 claims description 25
- 229910052760 oxygen Inorganic materials 0.000 claims description 25
- 229910021536 Zeolite Inorganic materials 0.000 claims description 22
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical group O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 21
- 230000000694 effects Effects 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 17
- 238000004523 catalytic cracking Methods 0.000 claims description 15
- 150000001722 carbon compounds Chemical class 0.000 claims description 11
- 230000008569 process Effects 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 8
- 230000002378 acidificating effect Effects 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 150000002170 ethers Chemical class 0.000 claims description 3
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 150000001299 aldehydes Chemical class 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 58
- 239000003921 oil Substances 0.000 description 24
- 150000001875 compounds Chemical class 0.000 description 17
- 238000002474 experimental method Methods 0.000 description 16
- 239000002253 acid Substances 0.000 description 14
- 239000000463 material Substances 0.000 description 13
- 230000008929 regeneration Effects 0.000 description 13
- 238000011069 regeneration method Methods 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 238000004231 fluid catalytic cracking Methods 0.000 description 10
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
- 239000000571 coke Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 8
- 239000007789 gas Substances 0.000 description 8
- 238000012546 transfer Methods 0.000 description 8
- 230000004913 activation Effects 0.000 description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 5
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- 238000007792 addition Methods 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- -1 for example Chemical compound 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000011149 active material Substances 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 229910052680 mordenite Inorganic materials 0.000 description 2
- 125000003367 polycyclic group Chemical group 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000000386 donor Substances 0.000 description 1
- 239000012013 faujasite Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- OSXJFKGXCJXRJC-UHFFFAOYSA-N hexadec-3-en-2-one Chemical compound CCCCCCCCCCCCC=CC(C)=O OSXJFKGXCJXRJC-UHFFFAOYSA-N 0.000 description 1
- DCAYPVUWAIABOU-NJFSPNSNSA-N hexadecane Chemical class CCCCCCCCCCCCCCC[14CH3] DCAYPVUWAIABOU-NJFSPNSNSA-N 0.000 description 1
- YFWVGAWDQRIPRT-UHFFFAOYSA-N hexadecane;methanol Chemical compound OC.CCCCCCCCCCCCCCCC YFWVGAWDQRIPRT-UHFFFAOYSA-N 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000000852 hydrogen donor Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 230000016507 interphase Effects 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 150000002927 oxygen compounds Chemical class 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000003079 shale oil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 239000011882 ultra-fine particle Substances 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US76766685A | 1985-08-21 | 1985-08-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62179592A true JPS62179592A (ja) | 1987-08-06 |
Family
ID=25080190
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1830886A Pending JPS62179592A (ja) | 1985-08-21 | 1986-01-31 | 共反応剤としてメタノ−ルを用いる分散された触媒のクラツキング方法 |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP0229437A1 (de) |
| JP (1) | JPS62179592A (de) |
| AU (1) | AU583335B2 (de) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008029631A1 (fr) | 2006-08-30 | 2008-03-13 | Jgc Corporation | Procédé de production de propylène et appareil de production de propylène |
| JP2009505983A (ja) * | 2005-08-15 | 2009-02-12 | チャイナ ペトロリウム アンド ケミカル コーポレイション | 陰圧下での低級オレフィン製造法 |
| JP2009520839A (ja) * | 2005-12-23 | 2009-05-28 | 中國石油化工股▲分▼有限公司 | 低級オレフィンの収率を増大させるための接触変換方法 |
| WO2012015060A1 (ja) * | 2010-07-30 | 2012-02-02 | 日本ガス合成株式会社 | プロピレンの製造方法 |
| US8450550B2 (en) | 2006-09-28 | 2013-05-28 | Jgc Corporation | Process and apparatus for producing propylene |
| JP2018048326A (ja) * | 2012-02-14 | 2018-03-29 | リライアンス インダストリーズ リミテッドＲｅｌｉａｎｃｅ Ｉｎｄｕｓｔｒｉｅｓ Ｌｔｄ． | 低価炭化水素ストリームの軽質オレフィンへの接触転化プロセス |
| JP2019518824A (ja) * | 2016-05-12 | 2019-07-04 | サウジ アラビアン オイル カンパニーＳａｕｄｉ Ａｒａｂｉａｎ Ｏｉｌ Ｃｏｍｐａｎｙ | 内部発熱材料と結合した炭化水素分解 |
| JP2020019660A (ja) * | 2018-07-30 | 2020-02-06 | 株式会社デンソー | 燃料改質装置 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3254023A (en) * | 1964-06-08 | 1966-05-31 | Socony Mobil Oil Co Inc | Method of heat balancing in organic catalytic reactions |
| US4012455A (en) * | 1974-07-31 | 1977-03-15 | Mobil Oil Corporation | Upgrading refinery light olefins with hydrogen contributor |
| US4112056A (en) * | 1977-05-02 | 1978-09-05 | Mobil Oil Corporation | Preparation of zeolites |
| BR7807475A (pt) * | 1978-11-14 | 1980-05-13 | Petroleo Brasileiro Sa | Processo de obtencao de correntes gasosas ricas em eteno |
| US4431519A (en) * | 1982-10-13 | 1984-02-14 | Mobil Oil Corporation | Method for catalytically dewaxing oils |
-
1986
- 1986-01-09 AU AU52129/86A patent/AU583335B2/en not_active Ceased
- 1986-01-15 EP EP86300225A patent/EP0229437A1/de not_active Withdrawn
- 1986-01-31 JP JP1830886A patent/JPS62179592A/ja active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009505983A (ja) * | 2005-08-15 | 2009-02-12 | チャイナ ペトロリウム アンド ケミカル コーポレイション | 陰圧下での低級オレフィン製造法 |
| JP2009520839A (ja) * | 2005-12-23 | 2009-05-28 | 中國石油化工股▲分▼有限公司 | 低級オレフィンの収率を増大させるための接触変換方法 |
| WO2008029631A1 (fr) | 2006-08-30 | 2008-03-13 | Jgc Corporation | Procédé de production de propylène et appareil de production de propylène |
| US8450550B2 (en) | 2006-09-28 | 2013-05-28 | Jgc Corporation | Process and apparatus for producing propylene |
| WO2012015060A1 (ja) * | 2010-07-30 | 2012-02-02 | 日本ガス合成株式会社 | プロピレンの製造方法 |
| JP2018048326A (ja) * | 2012-02-14 | 2018-03-29 | リライアンス インダストリーズ リミテッドＲｅｌｉａｎｃｅ Ｉｎｄｕｓｔｒｉｅｓ Ｌｔｄ． | 低価炭化水素ストリームの軽質オレフィンへの接触転化プロセス |
| JP2019518824A (ja) * | 2016-05-12 | 2019-07-04 | サウジ アラビアン オイル カンパニーＳａｕｄｉ Ａｒａｂｉａｎ Ｏｉｌ Ｃｏｍｐａｎｙ | 内部発熱材料と結合した炭化水素分解 |
| JP2020019660A (ja) * | 2018-07-30 | 2020-02-06 | 株式会社デンソー | 燃料改質装置 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0229437A1 (de) | 1987-07-22 |
| AU583335B2 (en) | 1989-04-27 |
| AU5212986A (en) | 1987-07-16 |
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