JPS6134747B2 - - Google Patents
Info
- Publication number
- JPS6134747B2 JPS6134747B2 JP53057695A JP5769578A JPS6134747B2 JP S6134747 B2 JPS6134747 B2 JP S6134747B2 JP 53057695 A JP53057695 A JP 53057695A JP 5769578 A JP5769578 A JP 5769578A JP S6134747 B2 JPS6134747 B2 JP S6134747B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- styrene
- polybutadiene
- methyl methacrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 claims description 38
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 32
- 239000000178 monomer Substances 0.000 claims description 23
- 229920002857 polybutadiene Polymers 0.000 claims description 20
- 239000005062 Polybutadiene Substances 0.000 claims description 19
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 15
- 229920001897 terpolymer Polymers 0.000 claims description 11
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 10
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 10
- 239000011347 resin Substances 0.000 claims description 9
- 229920005989 resin Polymers 0.000 claims description 9
- 238000005336 cracking Methods 0.000 claims description 3
- 238000000465 moulding Methods 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 6
- 229920001971 elastomer Polymers 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000005060 rubber Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 229920000126 latex Polymers 0.000 description 3
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- -1 alkyl mercaptan Chemical compound 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- UENWRTRMUIOCKN-UHFFFAOYSA-N benzyl thiol Chemical compound SCC1=CC=CC=C1 UENWRTRMUIOCKN-UHFFFAOYSA-N 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 229940044631 ferric chloride hexahydrate Drugs 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- NQXWGWZJXJUMQB-UHFFFAOYSA-K iron trichloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].Cl[Fe+]Cl NQXWGWZJXJUMQB-UHFFFAOYSA-K 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- KZCOBXFFBQJQHH-UHFFFAOYSA-N octane-1-thiol Chemical compound CCCCCCCCS KZCOBXFFBQJQHH-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 238000009757 thermoplastic moulding Methods 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/798,200 US4085166A (en) | 1977-05-18 | 1977-05-18 | Impact resistant acrylic polymer composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5416557A JPS5416557A (en) | 1979-02-07 |
| JPS6134747B2 true JPS6134747B2 (US20110009641A1-20110113-C00116.png) | 1986-08-09 |
Family
ID=25172783
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5769578A Granted JPS5416557A (en) | 1977-05-18 | 1978-05-17 | Molding composition |
Country Status (15)
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2030154B (en) * | 1978-09-18 | 1983-03-30 | American Cyanamid Co | Resin rubber polymeric blends |
| DE3002394A1 (de) * | 1980-01-24 | 1981-07-30 | Röhm GmbH, 6100 Darmstadt | Verfahren zur herstellung schlagzaeher formmassen |
| JPS56154039A (en) * | 1980-05-01 | 1981-11-28 | Teijin Ltd | Manufacture of polyester vessel |
| DE3113627A1 (de) * | 1981-04-04 | 1982-10-21 | Basf Ag, 6700 Ludwigshafen | Transparente, schlagzaehe formmasse |
| JPS581727A (ja) * | 1981-06-26 | 1983-01-07 | Teijin Ltd | 易接着性ポリエステルフイルムの製造法 |
| JPS5878761A (ja) * | 1981-11-04 | 1983-05-12 | ダイアホイル株式会社 | 易接着性二軸延伸ポリエステルフイルム |
| US4493872A (en) * | 1983-12-05 | 1985-01-15 | American Hoechst Corporation | Polyester film coated with metal adhesion promoting copolyester |
| JPS60192754A (ja) * | 1984-03-15 | 1985-10-01 | Kureha Chem Ind Co Ltd | 熱可塑性樹脂組成物 |
| JPS6140197A (ja) * | 1984-07-31 | 1986-02-26 | 株式会社きもと | 製図用マツトフイルム |
| EP0247648B1 (en) * | 1986-05-26 | 1989-08-23 | Agfa-Gevaert N.V. | A sheet or web carrying an antistatic layer |
| JPH0745234B2 (ja) * | 1988-01-28 | 1995-05-17 | 東レ株式会社 | ポリエステル複合フィルム |
| MX9102498A (es) * | 1990-12-14 | 1993-01-01 | Cyro Ind | Mezclas de multipolimeros de acrilico modificados con caucho, u policarbonatos; y metodo para la fabricacion de las mismas. |
| US5186993A (en) * | 1991-10-11 | 1993-02-16 | Rohm And Haas Company | Polymer blends |
| US5599863A (en) * | 1994-06-17 | 1997-02-04 | Cyro Industries | Gamma radiation sterilizable acrylic polymer |
| US6673873B1 (en) | 1999-08-25 | 2004-01-06 | Cyro Industries | Electrostatic-dissipative multipolymer compositions |
| US6734230B1 (en) | 2000-04-26 | 2004-05-11 | Plastiglas De Mexico, S.A. De C.V. | Procedure for obtaining modified acrylic sheets of high impact resistance |
| US20020167112A1 (en) * | 2001-02-06 | 2002-11-14 | Colburn Peter D. | Modified acrylic based compositions of enhanced optics and low temperature impact strength |
| BR112013020047A2 (pt) | 2011-02-07 | 2016-10-25 | Evonik Roehm Gmbh | método para fabricação de materiais acrílicos antimicrobianos |
| US11807699B2 (en) | 2018-12-19 | 2023-11-07 | Röhm Gmbh | Acrylic composition having an increased resistance to alcohols, oils and fats |
| EP4370601A1 (en) | 2021-07-16 | 2024-05-22 | Röhm GmbH | Transparent acrylic polymer composition having an increased resistance to alcohols and fats |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA643619A (en) * | 1958-02-14 | 1962-06-26 | Dominion Rubber Company | Polymethylmethacrylate polybutadiene and styrene composition |
| US3354238A (en) * | 1966-12-20 | 1967-11-21 | American Cyanamid Co | Blends of methyl methacrylate resinous copolymers and grafted elastomers |
| DE2364875B2 (de) * | 1972-12-28 | 1978-07-20 | Kureha Kagaku Kogyo K.K., Tokio | Photolytisch abbaubare Formmassen und deren Verwendung |
| JPS5427383B2 (US20110009641A1-20110113-C00116.png) * | 1973-06-16 | 1979-09-10 |
-
1977
- 1977-05-18 US US05/798,200 patent/US4085166A/en not_active Expired - Lifetime
-
1978
- 1978-04-10 CA CA300,755A patent/CA1110377A/en not_active Expired
- 1978-04-14 GB GB14843/78A patent/GB1572886A/en not_active Expired
- 1978-04-17 AU AU35159/78A patent/AU520030B2/en not_active Expired
- 1978-04-25 AR AR271884A patent/AR215295A1/es active
- 1978-05-10 IT IT49281/78A patent/IT1103479B/it active
- 1978-05-12 DE DE19782820977 patent/DE2820977A1/de active Pending
- 1978-05-15 BR BR7803040A patent/BR7803040A/pt unknown
- 1978-05-16 NL NL7805277A patent/NL190642C/xx not_active IP Right Cessation
- 1978-05-17 BE BE187768A patent/BE867163A/xx not_active IP Right Cessation
- 1978-05-17 CH CH536578A patent/CH634592A5/de not_active IP Right Cessation
- 1978-05-17 JP JP5769578A patent/JPS5416557A/ja active Granted
- 1978-05-17 SE SE7805683A patent/SE424999B/sv not_active IP Right Cessation
- 1978-05-18 ES ES470003A patent/ES470003A1/es not_active Expired
- 1978-05-18 FR FR7814774A patent/FR2391246A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| SE7805683L (sv) | 1978-11-19 |
| NL7805277A (nl) | 1978-11-21 |
| ES470003A1 (es) | 1980-09-01 |
| IT7849281A0 (it) | 1978-05-10 |
| JPS5416557A (en) | 1979-02-07 |
| FR2391246B1 (US20110009641A1-20110113-C00116.png) | 1983-05-13 |
| BE867163A (fr) | 1978-11-17 |
| SE424999B (sv) | 1982-08-23 |
| NL190642B (nl) | 1994-01-03 |
| NL190642C (nl) | 1994-06-01 |
| FR2391246A1 (fr) | 1978-12-15 |
| BR7803040A (pt) | 1979-01-02 |
| GB1572886A (en) | 1980-08-06 |
| US4085166A (en) | 1978-04-18 |
| DE2820977A1 (de) | 1978-11-23 |
| IT1103479B (it) | 1985-10-14 |
| AU3515978A (en) | 1979-10-25 |
| CA1110377A (en) | 1981-10-06 |
| CH634592A5 (de) | 1983-02-15 |
| AU520030B2 (en) | 1982-01-14 |
| AR215295A1 (es) | 1979-09-28 |
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