JPS6129879B2 - - Google Patents
Info
- Publication number
- JPS6129879B2 JPS6129879B2 JP56035513A JP3551381A JPS6129879B2 JP S6129879 B2 JPS6129879 B2 JP S6129879B2 JP 56035513 A JP56035513 A JP 56035513A JP 3551381 A JP3551381 A JP 3551381A JP S6129879 B2 JPS6129879 B2 JP S6129879B2
- Authority
- JP
- Japan
- Prior art keywords
- ribbon
- ink
- layer
- thermal transfer
- colloidal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 claims description 32
- 238000001246 colloidal dispersion Methods 0.000 claims description 28
- 238000007639 printing Methods 0.000 claims description 12
- 239000000975 dye Substances 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- 239000011230 binding agent Substances 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- 238000010023 transfer printing Methods 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 8
- 239000000084 colloidal system Substances 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- 238000000151 deposition Methods 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 239000000155 melt Substances 0.000 claims description 3
- 238000001962 electrophoresis Methods 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
- 239000004020 conductor Substances 0.000 claims 1
- 239000000976 ink Substances 0.000 description 50
- 239000002245 particle Substances 0.000 description 19
- 229910052751 metal Inorganic materials 0.000 description 14
- 239000002184 metal Substances 0.000 description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 12
- 150000001735 carboxylic acids Chemical class 0.000 description 11
- 239000000243 solution Substances 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 6
- -1 aliphatic amines Chemical class 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 4
- 239000002612 dispersion medium Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- NAPSCFZYZVSQHF-UHFFFAOYSA-N dimantine Chemical compound CCCCCCCCCCCCCCCCCCN(C)C NAPSCFZYZVSQHF-UHFFFAOYSA-N 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920005596 polymer binder Polymers 0.000 description 2
- 239000002491 polymer binding agent Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 229920005692 JONCRYL® Polymers 0.000 description 1
- 239000005041 Mylar⢠Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- IHWJXGQYRBHUIF-UHFFFAOYSA-N [Ag].[Pt] Chemical compound [Ag].[Pt] IHWJXGQYRBHUIF-UHFFFAOYSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229920006397 acrylic thermoplastic Polymers 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003922 charged colloid Substances 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 238000001652 electrophoretic deposition Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000006233 lamp black Substances 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
- B41M5/3825—Electric current carrying heat transfer sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J31/00—Ink ribbons; Renovating or testing ink ribbons
- B41J31/14—Renovating or testing ink ribbons
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D13/00—Electrophoretic coating characterised by the process
- C25D13/12—Electrophoretic coating characterised by the process characterised by the article coated
- C25D13/16—Wires; Strips; Foils
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Impression-Transfer Materials And Handling Thereof (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Electronic Switches (AREA)
Description
æµææ§ãªãã³ç±è»¢åæ³ã«ããå°åã¯ãå€ãã®å©
ç¹ããã€æãŸããå°åæ¹æ³ã§ãããæµææ§ãªãã³
ç±è»¢åã«ãã€ãŠå°åãè¡ãªãéã«ã¯ãé»æ°æµæã®
倧ããªãªãã³ã«ãé»æµãéããŠå°åã®ãã¿ãŒã³ç¶
ã«å ç±ãããå°åã®ãã¿ãŒã³ç¶ã«ãªãã³ãå ç±ã
ãæäœã«ãã€ãŠããªãã³ã®è¡šé¢äžã®è¿åéšåã®ã€
ã³ãå±€ã溶ããŠããªãã³ã®ã€ã³ãè¡šé¢ãå°å·çšçŽ
ã«æ¥è§Šããç¶æ ã§å°åã®ãã¿ãŒã³ç¶ã«è»¢åã§ãã
ããã«ãªãã ãã®ãããªããã»ã¹ã«äœ¿çšã§ããæµææ§ãªãã³
ç±è»¢åçšå°åãªãã³ïŒããã§ã¯ãç±è»¢åãªãã³ã
ãããã¯ç°¡åã«ããªãã³ããšãåŒã¶ïŒã¯ãå žåç
ãªãã®ã§ã¯æ¬¡ã®ïŒã€ã®å±€ãããªãã (1) ããªã«ã«ãããŒããªã©ãäŒå°æ§ççŽ ç²åãå«
ãé«ååç©è³ªã®æµææ§ãã€ã«ã (2) èãéå±å±€ãäŸãã°æµææ§ãã€ã«ã äžã«æ²ç
ãããåãçŽ1000â«ã®èžçã¢ã«ãããŠã è (3) äŸãã°é«ååç©è³ªãšã«ãŒãã³ã»ãã©ãã¯ãã
圢æããããå¯èæ§ã€ã³ãå±€ å±€(2)ã¯å°é»æ§ã®è¯ãç©è³ªã§ããã°ããã ãã®ãããªæµææ§ç±è»¢åãªãã³ãå°å·ã«äœ¿çšã
ãå Žåãã€ã³ãã¯å ç±ãããåæããå°åããã
è¡šé¢ã«è»¢åããããããã«ãã€ãŠå°å·ãã¿ãŒã³ã
ã§ããã®ã«å¿ããŠã€ã³ããæžããã®ã§ããªãã³è¡š
é¢ã«å床å¯èæ§ã€ã³ãã®åäžãªã³ãŒãã€ã³ã°ã圢
æããªãéãããã®ãªãã³ã¯å䜿çšã§ããªããå
äžãªåãã®ã€ã³ãããªãã³ã®å šåã«æ²çãããã
ãã»ã¹ã¯ãã§ãããªãã³ã«åäžãªåãã®ã€ã³ãã
ã®ããªãã®ã§ããã®ã€ã³ãåè£çµŠã«æçšã§ãããš
ã¯æåŸ ãããªãã å è¡æè¡ã§ã¯ãäŸãã°ã¿ã€ãã©ã€ã¿ãŒçšãªãã³
ã®å調æŽã®ããã®ãå€ãã®æ¹æ³ãèšèŒãããŠã
ãã1936幎ïŒæ25æ¥ã«æäžãããç±³åœç¹èš±ç¬¬
2051941å·ã«ã¯ã䜿çšæžã¿ã€ãã©ã€ã¿ãŒã»ãªãã³
ãã³ã³ããæ²¹ãããŒã¹ãšããç¡«é žãã©ã³ããã©ã
ã¯ãã¢ã©ãã¢ãŽã ããå«ãçµæç©ã§ã€ã³ãåè£çµŠ
ããããšãèšèŒãããŠããããã®çµæç©ã䜿çšæž
ã¿ã€ãã©ã€ã¿ãŒã»ãªãã³ã®è¡šé¢ã«å¡åžããããã
ã¿ã€ãã©ã€ã¿ãŒã»ãªãã³ã®çŽ°åäžã«ãã¿èŸŒããŸã§
æéã眮ããåŸãéå°ã®çµæç©ãäŸãã°åŒæ»ããŠ
ãªãã³ã®è¡šé¢ããåé€ãã 1939幎ïŒæ25æ¥ã«æäžãããç±³åœç¹èš±ç¬¬
2155653å·ã«ã¯ãçåæ°ŽçŽ èžæ°ã§åŠçããŠã€ã³ã
ãã¿ã€ãã©ã€ã¿ãŒã»ãªãã³ã®éæ¯æžéšåããæ¯æž
éšåã«ååé ããåäžã«ã€ã³ããã®ã€ããªãã³ã
圢æããæ¹æ³ãèšèŒãããŠããããã¡ããããã®
æ¹æ³ã¯ãååé ãããã€ã³ãã®æ¿åºŠãäœããªã
ãšããã®ãªãã³ã䜿çšããŠå°åãããåã®å質ã
æªããªãã®ã§ãéãããåæ°ã ãããå©çšã§ããª
ãã 1963幎10æïŒæ¥ã«æäžãããç±³åœç¹èš±ç¬¬
3105769å·ã«ã¯ã䜿çšæžã¿ã€ãã©ã€ã¿ãŒã»ãªãã³
ïŒãªã©ïŒäžã«æ®ã€ãŠããè²çŽ ãè»åãããŠååé
ãã溶液äžã«å«ãŸãããæ¬äœãç©è³ªãæ¯ç®¡äœçšã«
ãã€ãŠãªãã³ã«åé ãããããã®ã液ç¶æº¶æ¶²ã«ã€
ããŠèšèŒãããŠããã 1970幎11æ10æ¥ã«æäžãããç±³åœç¹èš±ç¬¬
3539489å·ã«èšèŒãããŠããããã»ã¹ã®ããã«ã
å°ããªé»æ°äŒå°æ§ç²åãé»æ°æ²çã«ãã€ãŠã³ãŒã
ã€ã³ã°ããããã»ã¹ããå è¡æè¡ã§ã¯ç¥ãããŠã
ãã æ¬çºæã«ããã°ã (1) (a) æ°Žã«äžæº¶æ§ã®ãèç¹ã85âã100âã®ç¯
å²ã«ããé«ååçµåå€ããèããŠæ¶²ç¶ã«ãªã
ãŸã§å ç±ããã (b) è²çŽ ãèããé«ååçµåå€ã«å ããŠæ··åã
ãã (c) å ç±ããã«ã«ãã³é žã®èã氎溶液ã(b)ã§åœ¢
æãããçµæç©ã«å ããŠæ··åããã (d) (c)ã§åœ¢æãããçµæç©ã«ã®ã³ãã€ãé»è·åœ¢
æååç©ãå ããŠæ··åãã垯é»ããè²çŽ ãå«
ãé«ååã³ãã€ãã圢æããã (e) (d)ã§åœ¢æãããã³ãã€ãæ§åæ£æ¶²ãå·åŽã
ãã ããšã«ãã€ãŠèª¿è£œããããé»æ°æ³³åã«ãã€ãŠæ²
çã§ããã€ã³ãã®ã³ãã€ãæ§åæ£æ¶²äžã«äœ¿çšæžã®
æµææ§ãªãã³ç±è»¢åçšå°åãªãã³ãå ¥ããã (2) 該ã³ãã€ãæ§åæ£æ¶²ã«ã該ãªãã³ã®å±€ãäžæ¹
ã®é»æ¥µãšããŠé»æµãéããè²çŽ ãå«ãé«ååã³
ãã€ããã該ãªãã³ã®ã€ã³ããæžããé åã«é»
æ°æ³³åã«ãã€ãŠæ²çãããåãã®åäžãªã€ã³ã
å±€ã圢æããã ããšãããªããæµææ§ãªãã³ç±è»¢åçšå°åãªã
ã³ã«ãéžæçã«ã€ã³ããåè£çµŠããããã®æ¹æ³ã
ããããããã æ¬çºæã¯ãŸããé»æ°æ³³åã«ãã€ãŠæ²çã§ããã³
ãã€ãæ§åæ£åªäžŠã³ã«ãã®èª¿è£œæ¹æ³ã«ãé¢ããã
ã®ã§ããã æ¬çºæã®æ¹æ³ã¯ãé»æ°æ³³åã«ãã€ãŠæ²çã§ãã
ã€ã³ãã®ã³ãã€ãæ§åæ£æ¶²ãå³ã¡è²çŽ ãå«ãé«å
åã³ãã€ããå©çšãããã®ã§ããããã®åæ£æ¶²
ã¯ãç±è»¢åãªãã³ã®é»æ°äŒå°æ§ã®å±€ãäžæ¹ã®é»æ¥µ
ãšããŠé»æµãéããå Žåã«ãã³ãã€ãããªãã³ã®
ã€ã³ããæžããé åã«éžæçã«æ²çããããã«ã
ã€ãŠåºæ¬çã«åããåäžã§ãªãã³ãå䜿çšã§ãã
ãããªã€ã³ãå±€ã圢æããæ§è³ªãåããŠããªãã
ã°ãªããªãã æ¬çºæã®æ¹æ³ã«æçšãªã³ãã€ãæ§åæ£åªã¯ã以
äžã®åã¹ãããã«ããšã¥ããŠèª¿è£œããããšãã§ã
ããå ããé«ååçµåå€ãäœéãªããé«éã®ãã¬
ã³ããŒãåã¯å®¹åšãå ç±ããŠããªããŒãè解ãã
æ段ãåãããåæ£æ¶²ã調補ããããã«çšããã
ããã®ä»ã®è£ 眮äžã«å ¥ãããäŸãã°ãæ··å宀ãã
é¢ããŠãã®äžåŽã«äºå宀ããã¡ã液äœå ç±ïŒäŸã
ã°æ°ŽïŒã°ãªã»ããŒã«æ··åç©ã105âã§ç ®æ²žïŒçšã®
å ¥å£åã³åºå£ãåãããäœéãªããé«éã®ãã¬ã³
ããŒã䜿çšããããšãã§ããããã¬ã³ããŒã®å€åŽ
ã®ãŸããã«å·»ãã€ããããŒãã»ããŒã¿ãªã©ã®ãè£
å©å ç±æ段ã䜿çšã§ããã極端ãªæ··åæ¡ä»¶ãäŸã
ã°è¶ é«éæ··åïŒâ§1000rpmïŒã®äœ¿çšã¯ãå®å®ãªå
æ£æ¶²ãã§ããªãã®ã§ãäžè¬çã«æãŸãããªãã é«ååçµåå€ãèãããåŸãè²çŽ ãèããããª
ããŒã«å ããŠãå質ãªå€èŠ³ãããçµæç©ã圢æã
ãããŸã§æ··åããã 次ã«ãå ç±ããèãã«ã«ãã³é žæº¶æ¶²ãå ããŠã
å ç±ãç¶ããªããæ¿ããæ··åãå§ãããã«ã«ãã³
é žæº¶æ¶²ã¯ãèããé«ååçµåå€ãåºåãããæ··å
ãå¯èœãªãããªæž©åºŠã«å ç±ãããäŸãã°ãé ¢é žã®
ïŒïŒ 氎溶液ããã®æ²žç¹ã«ãŸã§å ç±ãããã®ãæçš
ã§ãããå ç±ããã«ã«ãã³é žã¯ãäžåºŠã«ãããã¯
äœåãã«åããŠå ããããšãã§ãããé žæº¶æ¶²ãã
ãã«åžéããããã«æ°Žãå ããŠãããã æåŸã«ãããã«æ··åããªããã³ãã€ãé»è·åœ¢æ
ååç©ãå ¥ããŠãæçµçãªã³ãã€ãæ§åæ£æ¶²ã圢
æãã次ã«å·åŽããã æ¬çºæã«ããšã¥ããŠã³ãã€ãæ§åæ£æ¶²ã圢æã
ãã®ã«äœ¿çšããããæ°Žã«äžæº¶æ§ã®å¯èæ§é«ååçµ
åå€ã¯ãèç¹ãçŽ85âã100âã®ç¯å²ã®ãã®ã§ã
ããããã«ã¯ããã€ãã®çš®é¡ã®ãã®ãããã
Versamideã®ååã§åžè²©ãããŠããããªã¢ãã
é¡ãRhoplexåã³Joncrylã®åæšã§åžè²©ãããŠã
ãã¢ã¯ãªã«é¡ãåã³ãã®ä»ã®é«ååçµåå€ãäŸã
ã°UnirezãStaybeliteãLevisolã®åæšã§åžè²©ã
ããŠãããã®ãªã©ãå«ãŸããããã ããæ°Žã«äžæº¶
æ§ã§èç¹ã85âã100âã§ãããšããåºæ¬çç¹æ§
ããã€ãã®ã§ãªããã°ãªããªãã ãã¡ãããé«ååçµåå€ã¯ãç±è»¢åãªãã³ã®é
å±å±€ã«æ¥çããããšããé©åœãªç±åã³å§åãå ã
ããšå°å·çšçŽã«è»¢åã§ãèçã§ããç¹æ§ããåã
ãŠããã æ¬çºæã®æ¹æ³ã§ã³ãã€ãæ§åæ£æ¶²ã圢æããã®
ã«äœ¿çšã§ããè²çŽ ã¯ãâColour Indexâ第ïŒçã
1971幎Society of Dyers and Colouristsåãè±
åœãã©ããããªãŒãã«èšèŒãããŠãããããªåŸ®çŽ°
ç²æ«ç¶åºäœé¡æã ãã§ãªããçè²çšã«äœ¿çšããã
ææããå«ããå°åæäœã«ãããŠã¯ãå žåçãªè²
çŽ ã¯ã«ãŒãã³ã»ãã©ãã¯ã§ããã ã«ã«ãã³é žæ°Žæº¶æ¶²ã¯ãã³ãã€ãã®åæ£åªãšããŠ
åãããäŸãã°10ééïŒ ãªãããã以äžã®ã«ã«ã
ã³é žãªã©ãã©ããªèãã«ã«ãã³é žæº¶æ¶²ã䜿çšã§ã
ããã§ããã°ãã«ã«ãã³é žã®æ¿åºŠã¯ãçŽ0.5ãïŒ
ïŒ ã®ç¯å²å ãäŸãã°ïŒïŒ ãšãããæ§ã ãªã«ã«ãã³
é žã䜿çšã§ããããã§ããã°ïŒåãªããïŒåã®ç
çŽ ååããã€ã«ã«ãã³é žã䜿çšããã®ãæãŸã
ããé ¢é žãç¹ã«ããã ã³ãã€ãé»è·åœ¢æååç©ã¯ãé©åœãªPHæ¡ä»¶ã§ã
åæ£ããã³ãã€ãç²åã«é»è·ãäžããŠãé»æµãé
ãããšãå¯åæ§ã«ãªãããªãã³é»æ¥µã«åã€ãŠç§»å
ããããã«ãªããã€ãªã³åå¯èœãªååç©ã§ããã
å³ã¡ããªãã³ãé°æ¥µãšããŠäœ¿çšãããšããã³ãã€
ãé»è·åœ¢æååç©ã¯ãã³ãã€ãç²åã«ãã©ã¹ã®é»
è·ãäžãããã®ã§ãªããã°ãªããªããé žæ§æ¡ä»¶äž
å³ã¡PHïŒïŒã§ã¯ãèèªæã¢ãã³ãªã©ã®ååç©ãã
ã³ãã€ãç²åã«ãã©ã¹ã®é»è·ãäžããã®ã«æçšã§
ãããéã«ããªãã³ãéœæ¥µãšããŠäœ¿çšããã®ãæ
ãŸããå Žåãã³ãã€ãé»è·åœ¢æååç©ã¯ã³ãã€ã
ç²åã«ãã€ãã¹ã®é»è·ãäžããªããã°ãªããªãã
äŸãã°PHãïŒïŒã«èª¿ç¯ãã次ã«èèªé žïŒäŸãã°ã¹
ãã¢ãªã³é žïŒãå ãããšããã€ãã¹ã«åž¯é»ããã³
ãã€ããåŸãããšãã§ããã æ¬çºæã«ããšã¥ããŠã³ãã€ãæ§åæ£æ¶²äžã«äœ¿çš
ãããèèªæã¢ãã³ã¯ãæããè²çŽ ãå«ãé«åå
ã³ãã€ãç²åã®è¡šé¢ã«åžçããããšã«ãããåæ£
ããç²åããã©ã¹ã«åž¯é»ãããåãããããæ¬çº
æã®æ¹æ³ã«ã¯ãäžçŽãäºçŽïŒïŒ®çœ®æïŒãåã³äžçŽ
ïŒïŒ®ã眮æïŒèèªæã¢ãã³ã䜿çšããããšãã§
ããã12åã30åã®ççŽ ååãå«ãèèªæã¢ã
ã³ãäŸãã°ïŒ®ãâãžã¡ãã«ãªã¯ã¿ãã·ã«ã¢ãã³
ãç¹ã«ããã æ¬çºæã®ïŒã€ã®æ¹æ³ã§ã¯ã䜿çšæžã®ç±è»¢åãªã
ã³ããæ¬çºæã«ããšã¥ããé»æ°æ³³åã«ãã€ãŠæ²ç
ã§ããã€ã³ãã®ã³ãã€ãæ§åæ£æ¶²äžã«å ¥ãããªã
ã³ã®éå±å±€ãé°æ¥µãšããŠã³ãã€ãæ§åæ£æ¶²ã«é»æµ
ãéãããã®çµæãäŸãã°ãªãã³ãå ã«å°å·ã«äœ¿
çšããããã«ããªãã³ã®ã€ã³ããæ¯æžããéšå
ã«ãè²çŽ ãå«ãé«ååã³ãã€ããé»æ°æ³³åã«ãã€
ãŠæ²çããããªãã³ã¯éæ¢ãããŸãŸã§ããã³ãã€
ãæ§åæ£æ¶²äžãé£ç¶çã«ç§»åãããŠãããããé£
ç¶çã«åããæ¹ãããæå©ã§ããã ç±è»¢åãªãã³ã®éå±å±€ã¯ããã€ãã¹ã«åž¯é»ãã
ã³ãã€ãæ§åæ£æ¶²ã§éœæ¥µãšããŠäœ¿çšããå Žåã«
ã¯ã次åŒã®éœæ¥µé žååå¿ã«ãã€ãŠãéå±å±€ã®è é£
ãèµ·ããã®ã§ããããé²æ¢ããããæ¬çºæã®ãã®
æ¹æ³ã§ã¯é°æ¥µãšããŠçšããã ïŒâïŒn+ïŒne- åŸã€ãŠãæ¬çºæã®æ¹æ³ã«ãããã€ã³ãã®ã³ãã€
ãæ§åæ£æ¶²äžã®é»è·ã¯ãç±è»¢åãªãã³ãæµææ§ã
ã€ã«ã ãšå¯èæ§ã€ã³ãå±€ã®éã«èãéå±å±€ãå«ã
å Žåããã©ã¹ã«ãªããã³ãã€ãç²åã¯é°æ¥µãšããŠ
åãç±è»¢åãªãã³ã®éå±å±€ãžç§»åãããæ¬çºæã§
ã¯ããã©ã¹ã®é»è·ã¯ãæ¬æ¹æ³ã«ããšã¥ããŠæå®ã
ããèèªæã¢ãã³ãã«ã«ãã³é žæ°Žæº¶æ¶²ã«å ãããš
ã圢æããããã¢ã³ã¢ããŠã å¡©ã«ãã€ãŠã³ãã€ã
æ§åæ£æ¶²ã«äžãããããæ¬åºé¡äººã¯ããã®çè«ç
説æã«ææãããããšãåžæããªãããèèªæã¢
ãã³ååã®çåæ°ŽçŽ ééšåãèããé«ååã®å圢
å°æ»Žç²åäžã«åžçãããŠããã©ã¹ã«åž¯é»ããã¢ã³
ã¢ããŠã ã€ãªã³ã䌎ãªãå°æ»Žç²åãåå²ããšä¿¡ã
ãããŠããã æ¬çºæã®é»æ°æ³³åã«ãã€ãŠæ²çã§ããã€ã³ã
ã¯ãã€ã³ãã®åºæ¬çç¹æ§ã«æªåœ±é¿ãäžããªãå°é
ã®è¿œå çååç©ããå«ãããšãã§ãããäŸãã°ã
å¯å¡å€ïŒäŸãã°ããã«âã»ããœã«ãåã¯
Santicizerã®åæšã§åžè²©ãããŠããå¯å¡å€ïŒãé«
ååçµåå€ãšå ±ã«äœ¿çšããããšãã§ããã å³é¢ã®ç¬¬ïŒå³ãªãã第ïŒå³ã¯ãæ¬çºæã®æ¹æ³ã®
ç¹åŸŽãå³ç€ºãããã®ã§ããã 第ïŒå³ã¯ãæ¬çºæã®äžæ¹æ³ã«ããšã¥ããŠãã³ã
ã€ãç²åã䜿çšæžç±è»¢åãªãã³ã®é²åºããéå±è¡š
é¢ã«ç§»åããæãå³ç€ºããæ¡å€§å³ã§ããã ç¹ã«ãé»å°æ§ççŽ ç²åïŒãå«ãæµææ§åºå±€ïŒã
èãéå±å±€ïŒïŒã§ããã°ã¢ã«ãããŠã ïŒåã³ã€ã³
ããæ¯æžããéšåïŒãå«ãã€ã³ãå±€ïŒãããªãã
䜿çšæžç±è»¢åãªãã³ïŒããã³ãã€ãæ§åæ£æ¶²ïŒïŒ
ãå«ãé»è§£æ§œã«æµžãããŠãããã³ãã€ãæ§åæ£æ¶²
ïŒïŒã¯ãé žæ§ã®åæ£åªã®äœçšã«ãã€ãŠãç²åã®è¡š
é¢ã«åžçããïŒãã®çµæãã¢ãã³éšäœã§ãã©ã¹ã«
垯é»ããçªçŽ ååïŒïŒã圢æãïŒãèèªæã¢ãã³
äžã§ãã©ã¹ã«åž¯é»ããŠãããã³ãã€ãç²åïŒïŒã
å«ãã§ãããé»æºïŒäŸãã°ãHewlettâPackard
6521Aé»æºãïŒâ1000ãã«ããïŒâ200mAïŒãã
é»è§£æ§œã«ãç±è»¢åãªãã³ã®é²åºéå±è¡šé¢ïŒããã€
ãã¹ã«åž¯é»ããé»è§£æ§œã®é°æ¥µãšããŠåããããªã
é»å§ãããã€ãŠãããåŸã€ãŠããã©ã¹ã«åž¯é»ãã
ã³ãã€ãç²åïŒïŒã¯ããã€ãã¹ã«åž¯é»ããé²åºé
å±è¡šé¢ïŒãžãšç§»åããŠããã«åžçãããã€ã³ãã®
æ¯æžããéšåïŒã«å¯èæ§ã€ã³ãã®æ°ããå±€ã圢æ
ããã ã€ã³ãã®æ²çããã€ãŸã§ãé²è¡ããããšãã€ã³
ãã®æ²çé床ã¯æéãšå ±ã«æžå°ããçµå±ã¯äžå®ã®
åããåŸããããå³ã¡ãäžå®ã®é»å§ãããããšã
é»æµå¯åºŠã¯ã第ïŒå³ã«ç€ºãããã«æéãšå ±ã«å€å
ããïŒãã®å³ã§ãæ²ç·ïŒ¡ã¯135ãã«ãã®å®é»å§ã§åŸ
ããã®ãæ²ç·ïŒ¢ã¯202.5ãã«ãã®å®é»å§ã§åŸãã
ã®ã§ããïŒé»æµãã€ã³ãã®æ²çé床ãæéã®çµé
ãšãšãã«æžå°ããçµå±ã¯èªå·±å¶éæ©æ§ã«ãã€ãŠã€
ã³ãå±€ã¯çŽ35ã50ÎŒïœã®æçµåãã«éããããã®
èªå·±å¶éç¶æ ã«ã¯ã90ã120ç§ã§éãããäžè¬
ã«ãé»å§ã¯çŽ15ã250ãã«ãã®éã§å€ããããšã
ã§ãããã®ç¯å²å ã®é«ãé»å§ã§ã¯çµ¶çžç Žå£ãèµ·ã
ãåŸãïŒç¬¬ïŒå³ãåç §ã®ããšïŒãããããèµ·ãã€
ãŠãã€ã³ããåè£çµŠãããªãã³ã®å°å·ç¹æ§ã«æªã
圱é¿ãåã¶ããã«ã¯ã¿ããªãã åŸã€ãŠãæ¬çºæã®æ¹æ³ã§ã¯ãæè¡ã®çç·Žã®ç¯å²
å ã§é»å§ãé»æµåã³ãªãã³ã®æµžæœ€æéãé©åœã«éž
æããããšã«ãããæ°ããæ²çããã€ã³ãã®åã
ã以åã«æªäœ¿çšã®ã€ã³ãå±€ã®åããå³ã¡å žåçãª
å Žåã§ã¯ãçŽïŒÎŒïœãè¶ããªãããã«ãã€ã³ãã®
åè£çµŠãå¶åŸ¡ã§ããããšããããã æ¬çºæã®æ¹æ³ã¯ã䜿çšæžã®ç±è»¢åãªãã³ãéæ¢
é°æ¥µåã¯ç§»åé°æ¥µãšããŠçšããŠå®æœã§ããããåŸ
è ã®æ¹ãæå©ã§ããããªãã³ãé£ç¶çã«é»è§£æ§œã«
éãããã®è£ 眮ã§æ¬æ¹æ³ãå®æœããŠããæã瀺ã
ã第ïŒå³åã³ç¬¬ïŒå³ã«ã¯ãç¹ã«ãã®å Žåãå³ç€ºã
ãŠããã第ïŒå³åã³ç¬¬ïŒå³ã«ãããŠã䜿çšæžã®ç±
転åãªãã³ïŒããéãããŒã«ïŒïŒããã³ãã€ãæ§
åæ£æ¶²ïŒïŒãå«ãé»è§£æ§œïŒïŒã«éãããããã§ãŸ
ãè² é»å§æºïŒïŒã䜿çšæžç±è»¢åãªãã³ã®é²åºãã
é»å°æ§ãªããæµææ§è¡šé¢ã«æ¥è§Šããããã®è² é»å§
ããããç¹å®ã®æç¹ã§ã³ãã€ãæ§åæ£æ¶²äžã«æµžã
ãããäŸãã°é·ã1/2ã®ãªãã³éšåïŒã«äŒéãã
ããåŸã€ãŠããªãã³ã®é²åºéå±è¡šé¢ãé»è§£æ§œã®é°
極ãšããŠåããäžæ¹äŸãã°ã³ãã€ãæ§åæ£æ¶²ãå ¥
ãã容åšïŒïŒããé»è§£æ§œã®éœæ¥µãšããŠåãã é»è§£æ§œãééäžã®ãªãã³ã¯ã以äžã®é¢ä¿åŒãé©
çšãããã â«ïœ ïŒdyïŒXWâ«ïŒŽ ïŒdtãïŒXWT ãã ããã¯ãªãã³ã®å¹ ãïœã¯ãªãã³ã®é·ãã
ã¯ãªãã³ã®é床ãã¯ãã®éšådyãã³ãã€ãæ§
åæ£æ¶²äžã«æ»åšããæéãã¯ã³ãã€ãæ§åæ£æ¶²
ãšæ¥è§Šããé¢ç©ã§ããããããã®é¢ä¿åŒãçšã
ãŠãæ¬çºæã®æ¹æ³ã®ç¹å®ã®å®æœäŸã«å¯Ÿãããæé©
ã«åããã©ã¡ãŒã¿ã決å®ããããšãã§ããã ãªãã³ãåæ£æ¶²äžãééãããšããã³ãã€ãç²
åãæµææ§ãªãã³éœæ¥µã®é²åºéå±è¡šé¢ã«æ²çãåž
çãããŠã€ã³ããåè£çµŠãããåäžã«ã€ã³ãåè£
絊ãããå±€ïŒã圢æããã ã€ã³ãåè£çµŠããããªãã³ã¯ãæžæ¿æ¶²ããåŒäž
ããããåŸãæŽæµããŠã空æ°ä¹Ÿç¥ãããã¯ã§ãã
ã°ç¬¬ïŒå³ã«ç€ºããå ç±çŽ åïŒïŒãªã©ã«ãã€ãŠããŒ
ã¿ãŒä¹Ÿç¥ããç¶ããŠä»åŸã®äœ¿çšã«åããŠãªãŒã«ïŒ
ïŒã«å·»åãã貯èµããããšãã§ãããå¥ã®æ¹æ³ãš
ããŠãæ¥è§Šæ¡çé»æ¥µãçšããŠæµææ§åºå±€äžã«åäž
ãªé»æµãéããŠããªãã³ãåäžã«å ç±ä¹Ÿç¥ããã
ãšã«ãã€ãŠããªãã³ã也ç¥ãããããšãã§ããã å® éš ããªã¢ããé«ååçµåå€ã§ããVersamide 871
ïŒåæšïŒ10gãããã¬ã³ããŒäžã§èãããïŒ105
âïŒã次ã«ã2.4gã®ã«ãŒãã³ã»ãã©ãã¯ãèãã
é«ååçµåå€ã«å ããŠã¹ããã©ã§æ··ããã次ã«ã
ãã®æ··åç©ã500rpmã®é床ã§æ¹ææ··åãã沞隰
ïŒïŒ é ¢é žæ°Žæº¶æ¶²25mlãå ç±ãç¶ããªãããã€ãã
ãšãã¬ã³ããŒã«å ãããæ¹ææ··åãïŒåéç¶ãã
åŸãïŒïŒ é ¢é žæ°Žæº¶æ¶²175mlããã€ãããšå ããã
æ¹ææ··åãããã«ïŒåéç¶ããåŸã200mlã®æ°Žã
å ãããããã§ããâãžã¡ãã«ãªã¯ã¿ãã·ã«
ã¢ãã³1gãå ããŠãæ¹ææ··åãããã«ïŒåéç¶
ãããããããŠåŸãããé»æ°æ³³åã«ãã€ãŠæ²çã§
ããã€ã³ãã®ã³ãã€ãæ§åæ£æ¶²ãå·åŽããããã®
è¡šé¢ã®æ³¡ã䜿çšåã«æ¶å€±ãããã é»æ°æ³³åçæ²çç¹æ§ãè©Šéšãããããäžèšã®ã³
ãã€ãæ§åæ£æ¶²ããäŸãã°éçœéãã¢ã«ãããŠã
ä»MylarïŒããªãšãã¬ã³ã»ãã¬ãã¿ã©ãŒãã»ãã€
ã«ã ã®åæšïŒãããã¯ã¢ã«ãããŠã ä»ç±è»¢åãªã
ã³ïŒç³å¢šç²æ«ãå«ãããªã«ã«ãããŒãã»ãµããŒã
ãå«ãïŒäžã«ã³ãŒãã€ã³ã°ããŠãäžèšã®ããã«è©Š
éšããã å¯èæ§ã€ã³ãã®èãå±€ã¯ãå šãŠã®å Žåã«éåžžã«
çæéã§é°æ¥µè¡šé¢äžã«æ²çããã 次衚ã«ãæ¬çºæã«ããšã¥ããŠé»æ°æ³³åã«ãã€ãŠ
æ²çã§ããããšãããã€ããæ¬çºæã®ç¯å²ã«å«ãŸ
ããå€æ°ã®ã³ãã€ãæ§åæ£æ¶²ããŸãšããŠããã
ç¹ããã€æãŸããå°åæ¹æ³ã§ãããæµææ§ãªãã³
ç±è»¢åã«ãã€ãŠå°åãè¡ãªãéã«ã¯ãé»æ°æµæã®
倧ããªãªãã³ã«ãé»æµãéããŠå°åã®ãã¿ãŒã³ç¶
ã«å ç±ãããå°åã®ãã¿ãŒã³ç¶ã«ãªãã³ãå ç±ã
ãæäœã«ãã€ãŠããªãã³ã®è¡šé¢äžã®è¿åéšåã®ã€
ã³ãå±€ã溶ããŠããªãã³ã®ã€ã³ãè¡šé¢ãå°å·çšçŽ
ã«æ¥è§Šããç¶æ ã§å°åã®ãã¿ãŒã³ç¶ã«è»¢åã§ãã
ããã«ãªãã ãã®ãããªããã»ã¹ã«äœ¿çšã§ããæµææ§ãªãã³
ç±è»¢åçšå°åãªãã³ïŒããã§ã¯ãç±è»¢åãªãã³ã
ãããã¯ç°¡åã«ããªãã³ããšãåŒã¶ïŒã¯ãå žåç
ãªãã®ã§ã¯æ¬¡ã®ïŒã€ã®å±€ãããªãã (1) ããªã«ã«ãããŒããªã©ãäŒå°æ§ççŽ ç²åãå«
ãé«ååç©è³ªã®æµææ§ãã€ã«ã (2) èãéå±å±€ãäŸãã°æµææ§ãã€ã«ã äžã«æ²ç
ãããåãçŽ1000â«ã®èžçã¢ã«ãããŠã è (3) äŸãã°é«ååç©è³ªãšã«ãŒãã³ã»ãã©ãã¯ãã
圢æããããå¯èæ§ã€ã³ãå±€ å±€(2)ã¯å°é»æ§ã®è¯ãç©è³ªã§ããã°ããã ãã®ãããªæµææ§ç±è»¢åãªãã³ãå°å·ã«äœ¿çšã
ãå Žåãã€ã³ãã¯å ç±ãããåæããå°åããã
è¡šé¢ã«è»¢åããããããã«ãã€ãŠå°å·ãã¿ãŒã³ã
ã§ããã®ã«å¿ããŠã€ã³ããæžããã®ã§ããªãã³è¡š
é¢ã«å床å¯èæ§ã€ã³ãã®åäžãªã³ãŒãã€ã³ã°ã圢
æããªãéãããã®ãªãã³ã¯å䜿çšã§ããªããå
äžãªåãã®ã€ã³ãããªãã³ã®å šåã«æ²çãããã
ãã»ã¹ã¯ãã§ãããªãã³ã«åäžãªåãã®ã€ã³ãã
ã®ããªãã®ã§ããã®ã€ã³ãåè£çµŠã«æçšã§ãããš
ã¯æåŸ ãããªãã å è¡æè¡ã§ã¯ãäŸãã°ã¿ã€ãã©ã€ã¿ãŒçšãªãã³
ã®å調æŽã®ããã®ãå€ãã®æ¹æ³ãèšèŒãããŠã
ãã1936幎ïŒæ25æ¥ã«æäžãããç±³åœç¹èš±ç¬¬
2051941å·ã«ã¯ã䜿çšæžã¿ã€ãã©ã€ã¿ãŒã»ãªãã³
ãã³ã³ããæ²¹ãããŒã¹ãšããç¡«é žãã©ã³ããã©ã
ã¯ãã¢ã©ãã¢ãŽã ããå«ãçµæç©ã§ã€ã³ãåè£çµŠ
ããããšãèšèŒãããŠããããã®çµæç©ã䜿çšæž
ã¿ã€ãã©ã€ã¿ãŒã»ãªãã³ã®è¡šé¢ã«å¡åžããããã
ã¿ã€ãã©ã€ã¿ãŒã»ãªãã³ã®çŽ°åäžã«ãã¿èŸŒããŸã§
æéã眮ããåŸãéå°ã®çµæç©ãäŸãã°åŒæ»ããŠ
ãªãã³ã®è¡šé¢ããåé€ãã 1939幎ïŒæ25æ¥ã«æäžãããç±³åœç¹èš±ç¬¬
2155653å·ã«ã¯ãçåæ°ŽçŽ èžæ°ã§åŠçããŠã€ã³ã
ãã¿ã€ãã©ã€ã¿ãŒã»ãªãã³ã®éæ¯æžéšåããæ¯æž
éšåã«ååé ããåäžã«ã€ã³ããã®ã€ããªãã³ã
圢æããæ¹æ³ãèšèŒãããŠããããã¡ããããã®
æ¹æ³ã¯ãååé ãããã€ã³ãã®æ¿åºŠãäœããªã
ãšããã®ãªãã³ã䜿çšããŠå°åãããåã®å質ã
æªããªãã®ã§ãéãããåæ°ã ãããå©çšã§ããª
ãã 1963幎10æïŒæ¥ã«æäžãããç±³åœç¹èš±ç¬¬
3105769å·ã«ã¯ã䜿çšæžã¿ã€ãã©ã€ã¿ãŒã»ãªãã³
ïŒãªã©ïŒäžã«æ®ã€ãŠããè²çŽ ãè»åãããŠååé
ãã溶液äžã«å«ãŸãããæ¬äœãç©è³ªãæ¯ç®¡äœçšã«
ãã€ãŠãªãã³ã«åé ãããããã®ã液ç¶æº¶æ¶²ã«ã€
ããŠèšèŒãããŠããã 1970幎11æ10æ¥ã«æäžãããç±³åœç¹èš±ç¬¬
3539489å·ã«èšèŒãããŠããããã»ã¹ã®ããã«ã
å°ããªé»æ°äŒå°æ§ç²åãé»æ°æ²çã«ãã€ãŠã³ãŒã
ã€ã³ã°ããããã»ã¹ããå è¡æè¡ã§ã¯ç¥ãããŠã
ãã æ¬çºæã«ããã°ã (1) (a) æ°Žã«äžæº¶æ§ã®ãèç¹ã85âã100âã®ç¯
å²ã«ããé«ååçµåå€ããèããŠæ¶²ç¶ã«ãªã
ãŸã§å ç±ããã (b) è²çŽ ãèããé«ååçµåå€ã«å ããŠæ··åã
ãã (c) å ç±ããã«ã«ãã³é žã®èã氎溶液ã(b)ã§åœ¢
æãããçµæç©ã«å ããŠæ··åããã (d) (c)ã§åœ¢æãããçµæç©ã«ã®ã³ãã€ãé»è·åœ¢
æååç©ãå ããŠæ··åãã垯é»ããè²çŽ ãå«
ãé«ååã³ãã€ãã圢æããã (e) (d)ã§åœ¢æãããã³ãã€ãæ§åæ£æ¶²ãå·åŽã
ãã ããšã«ãã€ãŠèª¿è£œããããé»æ°æ³³åã«ãã€ãŠæ²
çã§ããã€ã³ãã®ã³ãã€ãæ§åæ£æ¶²äžã«äœ¿çšæžã®
æµææ§ãªãã³ç±è»¢åçšå°åãªãã³ãå ¥ããã (2) 該ã³ãã€ãæ§åæ£æ¶²ã«ã該ãªãã³ã®å±€ãäžæ¹
ã®é»æ¥µãšããŠé»æµãéããè²çŽ ãå«ãé«ååã³
ãã€ããã該ãªãã³ã®ã€ã³ããæžããé åã«é»
æ°æ³³åã«ãã€ãŠæ²çãããåãã®åäžãªã€ã³ã
å±€ã圢æããã ããšãããªããæµææ§ãªãã³ç±è»¢åçšå°åãªã
ã³ã«ãéžæçã«ã€ã³ããåè£çµŠããããã®æ¹æ³ã
ããããããã æ¬çºæã¯ãŸããé»æ°æ³³åã«ãã€ãŠæ²çã§ããã³
ãã€ãæ§åæ£åªäžŠã³ã«ãã®èª¿è£œæ¹æ³ã«ãé¢ããã
ã®ã§ããã æ¬çºæã®æ¹æ³ã¯ãé»æ°æ³³åã«ãã€ãŠæ²çã§ãã
ã€ã³ãã®ã³ãã€ãæ§åæ£æ¶²ãå³ã¡è²çŽ ãå«ãé«å
åã³ãã€ããå©çšãããã®ã§ããããã®åæ£æ¶²
ã¯ãç±è»¢åãªãã³ã®é»æ°äŒå°æ§ã®å±€ãäžæ¹ã®é»æ¥µ
ãšããŠé»æµãéããå Žåã«ãã³ãã€ãããªãã³ã®
ã€ã³ããæžããé åã«éžæçã«æ²çããããã«ã
ã€ãŠåºæ¬çã«åããåäžã§ãªãã³ãå䜿çšã§ãã
ãããªã€ã³ãå±€ã圢æããæ§è³ªãåããŠããªãã
ã°ãªããªãã æ¬çºæã®æ¹æ³ã«æçšãªã³ãã€ãæ§åæ£åªã¯ã以
äžã®åã¹ãããã«ããšã¥ããŠèª¿è£œããããšãã§ã
ããå ããé«ååçµåå€ãäœéãªããé«éã®ãã¬
ã³ããŒãåã¯å®¹åšãå ç±ããŠããªããŒãè解ãã
æ段ãåãããåæ£æ¶²ã調補ããããã«çšããã
ããã®ä»ã®è£ 眮äžã«å ¥ãããäŸãã°ãæ··å宀ãã
é¢ããŠãã®äžåŽã«äºå宀ããã¡ã液äœå ç±ïŒäŸã
ã°æ°ŽïŒã°ãªã»ããŒã«æ··åç©ã105âã§ç ®æ²žïŒçšã®
å ¥å£åã³åºå£ãåãããäœéãªããé«éã®ãã¬ã³
ããŒã䜿çšããããšãã§ããããã¬ã³ããŒã®å€åŽ
ã®ãŸããã«å·»ãã€ããããŒãã»ããŒã¿ãªã©ã®ãè£
å©å ç±æ段ã䜿çšã§ããã極端ãªæ··åæ¡ä»¶ãäŸã
ã°è¶ é«éæ··åïŒâ§1000rpmïŒã®äœ¿çšã¯ãå®å®ãªå
æ£æ¶²ãã§ããªãã®ã§ãäžè¬çã«æãŸãããªãã é«ååçµåå€ãèãããåŸãè²çŽ ãèããããª
ããŒã«å ããŠãå質ãªå€èŠ³ãããçµæç©ã圢æã
ãããŸã§æ··åããã 次ã«ãå ç±ããèãã«ã«ãã³é žæº¶æ¶²ãå ããŠã
å ç±ãç¶ããªããæ¿ããæ··åãå§ãããã«ã«ãã³
é žæº¶æ¶²ã¯ãèããé«ååçµåå€ãåºåãããæ··å
ãå¯èœãªãããªæž©åºŠã«å ç±ãããäŸãã°ãé ¢é žã®
ïŒïŒ 氎溶液ããã®æ²žç¹ã«ãŸã§å ç±ãããã®ãæçš
ã§ãããå ç±ããã«ã«ãã³é žã¯ãäžåºŠã«ãããã¯
äœåãã«åããŠå ããããšãã§ãããé žæº¶æ¶²ãã
ãã«åžéããããã«æ°Žãå ããŠãããã æåŸã«ãããã«æ··åããªããã³ãã€ãé»è·åœ¢æ
ååç©ãå ¥ããŠãæçµçãªã³ãã€ãæ§åæ£æ¶²ã圢
æãã次ã«å·åŽããã æ¬çºæã«ããšã¥ããŠã³ãã€ãæ§åæ£æ¶²ã圢æã
ãã®ã«äœ¿çšããããæ°Žã«äžæº¶æ§ã®å¯èæ§é«ååçµ
åå€ã¯ãèç¹ãçŽ85âã100âã®ç¯å²ã®ãã®ã§ã
ããããã«ã¯ããã€ãã®çš®é¡ã®ãã®ãããã
Versamideã®ååã§åžè²©ãããŠããããªã¢ãã
é¡ãRhoplexåã³Joncrylã®åæšã§åžè²©ãããŠã
ãã¢ã¯ãªã«é¡ãåã³ãã®ä»ã®é«ååçµåå€ãäŸã
ã°UnirezãStaybeliteãLevisolã®åæšã§åžè²©ã
ããŠãããã®ãªã©ãå«ãŸããããã ããæ°Žã«äžæº¶
æ§ã§èç¹ã85âã100âã§ãããšããåºæ¬çç¹æ§
ããã€ãã®ã§ãªããã°ãªããªãã ãã¡ãããé«ååçµåå€ã¯ãç±è»¢åãªãã³ã®é
å±å±€ã«æ¥çããããšããé©åœãªç±åã³å§åãå ã
ããšå°å·çšçŽã«è»¢åã§ãèçã§ããç¹æ§ããåã
ãŠããã æ¬çºæã®æ¹æ³ã§ã³ãã€ãæ§åæ£æ¶²ã圢æããã®
ã«äœ¿çšã§ããè²çŽ ã¯ãâColour Indexâ第ïŒçã
1971幎Society of Dyers and Colouristsåãè±
åœãã©ããããªãŒãã«èšèŒãããŠãããããªåŸ®çŽ°
ç²æ«ç¶åºäœé¡æã ãã§ãªããçè²çšã«äœ¿çšããã
ææããå«ããå°åæäœã«ãããŠã¯ãå žåçãªè²
çŽ ã¯ã«ãŒãã³ã»ãã©ãã¯ã§ããã ã«ã«ãã³é žæ°Žæº¶æ¶²ã¯ãã³ãã€ãã®åæ£åªãšããŠ
åãããäŸãã°10ééïŒ ãªãããã以äžã®ã«ã«ã
ã³é žãªã©ãã©ããªèãã«ã«ãã³é žæº¶æ¶²ã䜿çšã§ã
ããã§ããã°ãã«ã«ãã³é žã®æ¿åºŠã¯ãçŽ0.5ãïŒ
ïŒ ã®ç¯å²å ãäŸãã°ïŒïŒ ãšãããæ§ã ãªã«ã«ãã³
é žã䜿çšã§ããããã§ããã°ïŒåãªããïŒåã®ç
çŽ ååããã€ã«ã«ãã³é žã䜿çšããã®ãæãŸã
ããé ¢é žãç¹ã«ããã ã³ãã€ãé»è·åœ¢æååç©ã¯ãé©åœãªPHæ¡ä»¶ã§ã
åæ£ããã³ãã€ãç²åã«é»è·ãäžããŠãé»æµãé
ãããšãå¯åæ§ã«ãªãããªãã³é»æ¥µã«åã€ãŠç§»å
ããããã«ãªããã€ãªã³åå¯èœãªååç©ã§ããã
å³ã¡ããªãã³ãé°æ¥µãšããŠäœ¿çšãããšããã³ãã€
ãé»è·åœ¢æååç©ã¯ãã³ãã€ãç²åã«ãã©ã¹ã®é»
è·ãäžãããã®ã§ãªããã°ãªããªããé žæ§æ¡ä»¶äž
å³ã¡PHïŒïŒã§ã¯ãèèªæã¢ãã³ãªã©ã®ååç©ãã
ã³ãã€ãç²åã«ãã©ã¹ã®é»è·ãäžããã®ã«æçšã§
ãããéã«ããªãã³ãéœæ¥µãšããŠäœ¿çšããã®ãæ
ãŸããå Žåãã³ãã€ãé»è·åœ¢æååç©ã¯ã³ãã€ã
ç²åã«ãã€ãã¹ã®é»è·ãäžããªããã°ãªããªãã
äŸãã°PHãïŒïŒã«èª¿ç¯ãã次ã«èèªé žïŒäŸãã°ã¹
ãã¢ãªã³é žïŒãå ãããšããã€ãã¹ã«åž¯é»ããã³
ãã€ããåŸãããšãã§ããã æ¬çºæã«ããšã¥ããŠã³ãã€ãæ§åæ£æ¶²äžã«äœ¿çš
ãããèèªæã¢ãã³ã¯ãæããè²çŽ ãå«ãé«åå
ã³ãã€ãç²åã®è¡šé¢ã«åžçããããšã«ãããåæ£
ããç²åããã©ã¹ã«åž¯é»ãããåãããããæ¬çº
æã®æ¹æ³ã«ã¯ãäžçŽãäºçŽïŒïŒ®çœ®æïŒãåã³äžçŽ
ïŒïŒ®ã眮æïŒèèªæã¢ãã³ã䜿çšããããšãã§
ããã12åã30åã®ççŽ ååãå«ãèèªæã¢ã
ã³ãäŸãã°ïŒ®ãâãžã¡ãã«ãªã¯ã¿ãã·ã«ã¢ãã³
ãç¹ã«ããã æ¬çºæã®ïŒã€ã®æ¹æ³ã§ã¯ã䜿çšæžã®ç±è»¢åãªã
ã³ããæ¬çºæã«ããšã¥ããé»æ°æ³³åã«ãã€ãŠæ²ç
ã§ããã€ã³ãã®ã³ãã€ãæ§åæ£æ¶²äžã«å ¥ãããªã
ã³ã®éå±å±€ãé°æ¥µãšããŠã³ãã€ãæ§åæ£æ¶²ã«é»æµ
ãéãããã®çµæãäŸãã°ãªãã³ãå ã«å°å·ã«äœ¿
çšããããã«ããªãã³ã®ã€ã³ããæ¯æžããéšå
ã«ãè²çŽ ãå«ãé«ååã³ãã€ããé»æ°æ³³åã«ãã€
ãŠæ²çããããªãã³ã¯éæ¢ãããŸãŸã§ããã³ãã€
ãæ§åæ£æ¶²äžãé£ç¶çã«ç§»åãããŠãããããé£
ç¶çã«åããæ¹ãããæå©ã§ããã ç±è»¢åãªãã³ã®éå±å±€ã¯ããã€ãã¹ã«åž¯é»ãã
ã³ãã€ãæ§åæ£æ¶²ã§éœæ¥µãšããŠäœ¿çšããå Žåã«
ã¯ã次åŒã®éœæ¥µé žååå¿ã«ãã€ãŠãéå±å±€ã®è é£
ãèµ·ããã®ã§ããããé²æ¢ããããæ¬çºæã®ãã®
æ¹æ³ã§ã¯é°æ¥µãšããŠçšããã ïŒâïŒn+ïŒne- åŸã€ãŠãæ¬çºæã®æ¹æ³ã«ãããã€ã³ãã®ã³ãã€
ãæ§åæ£æ¶²äžã®é»è·ã¯ãç±è»¢åãªãã³ãæµææ§ã
ã€ã«ã ãšå¯èæ§ã€ã³ãå±€ã®éã«èãéå±å±€ãå«ã
å Žåããã©ã¹ã«ãªããã³ãã€ãç²åã¯é°æ¥µãšããŠ
åãç±è»¢åãªãã³ã®éå±å±€ãžç§»åãããæ¬çºæã§
ã¯ããã©ã¹ã®é»è·ã¯ãæ¬æ¹æ³ã«ããšã¥ããŠæå®ã
ããèèªæã¢ãã³ãã«ã«ãã³é žæ°Žæº¶æ¶²ã«å ãããš
ã圢æããããã¢ã³ã¢ããŠã å¡©ã«ãã€ãŠã³ãã€ã
æ§åæ£æ¶²ã«äžãããããæ¬åºé¡äººã¯ããã®çè«ç
説æã«ææãããããšãåžæããªãããèèªæã¢
ãã³ååã®çåæ°ŽçŽ ééšåãèããé«ååã®å圢
å°æ»Žç²åäžã«åžçãããŠããã©ã¹ã«åž¯é»ããã¢ã³
ã¢ããŠã ã€ãªã³ã䌎ãªãå°æ»Žç²åãåå²ããšä¿¡ã
ãããŠããã æ¬çºæã®é»æ°æ³³åã«ãã€ãŠæ²çã§ããã€ã³ã
ã¯ãã€ã³ãã®åºæ¬çç¹æ§ã«æªåœ±é¿ãäžããªãå°é
ã®è¿œå çååç©ããå«ãããšãã§ãããäŸãã°ã
å¯å¡å€ïŒäŸãã°ããã«âã»ããœã«ãåã¯
Santicizerã®åæšã§åžè²©ãããŠããå¯å¡å€ïŒãé«
ååçµåå€ãšå ±ã«äœ¿çšããããšãã§ããã å³é¢ã®ç¬¬ïŒå³ãªãã第ïŒå³ã¯ãæ¬çºæã®æ¹æ³ã®
ç¹åŸŽãå³ç€ºãããã®ã§ããã 第ïŒå³ã¯ãæ¬çºæã®äžæ¹æ³ã«ããšã¥ããŠãã³ã
ã€ãç²åã䜿çšæžç±è»¢åãªãã³ã®é²åºããéå±è¡š
é¢ã«ç§»åããæãå³ç€ºããæ¡å€§å³ã§ããã ç¹ã«ãé»å°æ§ççŽ ç²åïŒãå«ãæµææ§åºå±€ïŒã
èãéå±å±€ïŒïŒã§ããã°ã¢ã«ãããŠã ïŒåã³ã€ã³
ããæ¯æžããéšåïŒãå«ãã€ã³ãå±€ïŒãããªãã
䜿çšæžç±è»¢åãªãã³ïŒããã³ãã€ãæ§åæ£æ¶²ïŒïŒ
ãå«ãé»è§£æ§œã«æµžãããŠãããã³ãã€ãæ§åæ£æ¶²
ïŒïŒã¯ãé žæ§ã®åæ£åªã®äœçšã«ãã€ãŠãç²åã®è¡š
é¢ã«åžçããïŒãã®çµæãã¢ãã³éšäœã§ãã©ã¹ã«
垯é»ããçªçŽ ååïŒïŒã圢æãïŒãèèªæã¢ãã³
äžã§ãã©ã¹ã«åž¯é»ããŠãããã³ãã€ãç²åïŒïŒã
å«ãã§ãããé»æºïŒäŸãã°ãHewlettâPackard
6521Aé»æºãïŒâ1000ãã«ããïŒâ200mAïŒãã
é»è§£æ§œã«ãç±è»¢åãªãã³ã®é²åºéå±è¡šé¢ïŒããã€
ãã¹ã«åž¯é»ããé»è§£æ§œã®é°æ¥µãšããŠåããããªã
é»å§ãããã€ãŠãããåŸã€ãŠããã©ã¹ã«åž¯é»ãã
ã³ãã€ãç²åïŒïŒã¯ããã€ãã¹ã«åž¯é»ããé²åºé
å±è¡šé¢ïŒãžãšç§»åããŠããã«åžçãããã€ã³ãã®
æ¯æžããéšåïŒã«å¯èæ§ã€ã³ãã®æ°ããå±€ã圢æ
ããã ã€ã³ãã®æ²çããã€ãŸã§ãé²è¡ããããšãã€ã³
ãã®æ²çé床ã¯æéãšå ±ã«æžå°ããçµå±ã¯äžå®ã®
åããåŸããããå³ã¡ãäžå®ã®é»å§ãããããšã
é»æµå¯åºŠã¯ã第ïŒå³ã«ç€ºãããã«æéãšå ±ã«å€å
ããïŒãã®å³ã§ãæ²ç·ïŒ¡ã¯135ãã«ãã®å®é»å§ã§åŸ
ããã®ãæ²ç·ïŒ¢ã¯202.5ãã«ãã®å®é»å§ã§åŸãã
ã®ã§ããïŒé»æµãã€ã³ãã®æ²çé床ãæéã®çµé
ãšãšãã«æžå°ããçµå±ã¯èªå·±å¶éæ©æ§ã«ãã€ãŠã€
ã³ãå±€ã¯çŽ35ã50ÎŒïœã®æçµåãã«éããããã®
èªå·±å¶éç¶æ ã«ã¯ã90ã120ç§ã§éãããäžè¬
ã«ãé»å§ã¯çŽ15ã250ãã«ãã®éã§å€ããããšã
ã§ãããã®ç¯å²å ã®é«ãé»å§ã§ã¯çµ¶çžç Žå£ãèµ·ã
ãåŸãïŒç¬¬ïŒå³ãåç §ã®ããšïŒãããããèµ·ãã€
ãŠãã€ã³ããåè£çµŠãããªãã³ã®å°å·ç¹æ§ã«æªã
圱é¿ãåã¶ããã«ã¯ã¿ããªãã åŸã€ãŠãæ¬çºæã®æ¹æ³ã§ã¯ãæè¡ã®çç·Žã®ç¯å²
å ã§é»å§ãé»æµåã³ãªãã³ã®æµžæœ€æéãé©åœã«éž
æããããšã«ãããæ°ããæ²çããã€ã³ãã®åã
ã以åã«æªäœ¿çšã®ã€ã³ãå±€ã®åããå³ã¡å žåçãª
å Žåã§ã¯ãçŽïŒÎŒïœãè¶ããªãããã«ãã€ã³ãã®
åè£çµŠãå¶åŸ¡ã§ããããšããããã æ¬çºæã®æ¹æ³ã¯ã䜿çšæžã®ç±è»¢åãªãã³ãéæ¢
é°æ¥µåã¯ç§»åé°æ¥µãšããŠçšããŠå®æœã§ããããåŸ
è ã®æ¹ãæå©ã§ããããªãã³ãé£ç¶çã«é»è§£æ§œã«
éãããã®è£ 眮ã§æ¬æ¹æ³ãå®æœããŠããæã瀺ã
ã第ïŒå³åã³ç¬¬ïŒå³ã«ã¯ãç¹ã«ãã®å Žåãå³ç€ºã
ãŠããã第ïŒå³åã³ç¬¬ïŒå³ã«ãããŠã䜿çšæžã®ç±
転åãªãã³ïŒããéãããŒã«ïŒïŒããã³ãã€ãæ§
åæ£æ¶²ïŒïŒãå«ãé»è§£æ§œïŒïŒã«éãããããã§ãŸ
ãè² é»å§æºïŒïŒã䜿çšæžç±è»¢åãªãã³ã®é²åºãã
é»å°æ§ãªããæµææ§è¡šé¢ã«æ¥è§Šããããã®è² é»å§
ããããç¹å®ã®æç¹ã§ã³ãã€ãæ§åæ£æ¶²äžã«æµžã
ãããäŸãã°é·ã1/2ã®ãªãã³éšåïŒã«äŒéãã
ããåŸã€ãŠããªãã³ã®é²åºéå±è¡šé¢ãé»è§£æ§œã®é°
極ãšããŠåããäžæ¹äŸãã°ã³ãã€ãæ§åæ£æ¶²ãå ¥
ãã容åšïŒïŒããé»è§£æ§œã®éœæ¥µãšããŠåãã é»è§£æ§œãééäžã®ãªãã³ã¯ã以äžã®é¢ä¿åŒãé©
çšãããã â«ïœ ïŒdyïŒXWâ«ïŒŽ ïŒdtãïŒXWT ãã ããã¯ãªãã³ã®å¹ ãïœã¯ãªãã³ã®é·ãã
ã¯ãªãã³ã®é床ãã¯ãã®éšådyãã³ãã€ãæ§
åæ£æ¶²äžã«æ»åšããæéãã¯ã³ãã€ãæ§åæ£æ¶²
ãšæ¥è§Šããé¢ç©ã§ããããããã®é¢ä¿åŒãçšã
ãŠãæ¬çºæã®æ¹æ³ã®ç¹å®ã®å®æœäŸã«å¯Ÿãããæé©
ã«åããã©ã¡ãŒã¿ã決å®ããããšãã§ããã ãªãã³ãåæ£æ¶²äžãééãããšããã³ãã€ãç²
åãæµææ§ãªãã³éœæ¥µã®é²åºéå±è¡šé¢ã«æ²çãåž
çãããŠã€ã³ããåè£çµŠãããåäžã«ã€ã³ãåè£
絊ãããå±€ïŒã圢æããã ã€ã³ãåè£çµŠããããªãã³ã¯ãæžæ¿æ¶²ããåŒäž
ããããåŸãæŽæµããŠã空æ°ä¹Ÿç¥ãããã¯ã§ãã
ã°ç¬¬ïŒå³ã«ç€ºããå ç±çŽ åïŒïŒãªã©ã«ãã€ãŠããŒ
ã¿ãŒä¹Ÿç¥ããç¶ããŠä»åŸã®äœ¿çšã«åããŠãªãŒã«ïŒ
ïŒã«å·»åãã貯èµããããšãã§ãããå¥ã®æ¹æ³ãš
ããŠãæ¥è§Šæ¡çé»æ¥µãçšããŠæµææ§åºå±€äžã«åäž
ãªé»æµãéããŠããªãã³ãåäžã«å ç±ä¹Ÿç¥ããã
ãšã«ãã€ãŠããªãã³ã也ç¥ãããããšãã§ããã å® éš ããªã¢ããé«ååçµåå€ã§ããVersamide 871
ïŒåæšïŒ10gãããã¬ã³ããŒäžã§èãããïŒ105
âïŒã次ã«ã2.4gã®ã«ãŒãã³ã»ãã©ãã¯ãèãã
é«ååçµåå€ã«å ããŠã¹ããã©ã§æ··ããã次ã«ã
ãã®æ··åç©ã500rpmã®é床ã§æ¹ææ··åãã沞隰
ïŒïŒ é ¢é žæ°Žæº¶æ¶²25mlãå ç±ãç¶ããªãããã€ãã
ãšãã¬ã³ããŒã«å ãããæ¹ææ··åãïŒåéç¶ãã
åŸãïŒïŒ é ¢é žæ°Žæº¶æ¶²175mlããã€ãããšå ããã
æ¹ææ··åãããã«ïŒåéç¶ããåŸã200mlã®æ°Žã
å ãããããã§ããâãžã¡ãã«ãªã¯ã¿ãã·ã«
ã¢ãã³1gãå ããŠãæ¹ææ··åãããã«ïŒåéç¶
ãããããããŠåŸãããé»æ°æ³³åã«ãã€ãŠæ²çã§
ããã€ã³ãã®ã³ãã€ãæ§åæ£æ¶²ãå·åŽããããã®
è¡šé¢ã®æ³¡ã䜿çšåã«æ¶å€±ãããã é»æ°æ³³åçæ²çç¹æ§ãè©Šéšãããããäžèšã®ã³
ãã€ãæ§åæ£æ¶²ããäŸãã°éçœéãã¢ã«ãããŠã
ä»MylarïŒããªãšãã¬ã³ã»ãã¬ãã¿ã©ãŒãã»ãã€
ã«ã ã®åæšïŒãããã¯ã¢ã«ãããŠã ä»ç±è»¢åãªã
ã³ïŒç³å¢šç²æ«ãå«ãããªã«ã«ãããŒãã»ãµããŒã
ãå«ãïŒäžã«ã³ãŒãã€ã³ã°ããŠãäžèšã®ããã«è©Š
éšããã å¯èæ§ã€ã³ãã®èãå±€ã¯ãå šãŠã®å Žåã«éåžžã«
çæéã§é°æ¥µè¡šé¢äžã«æ²çããã 次衚ã«ãæ¬çºæã«ããšã¥ããŠé»æ°æ³³åã«ãã€ãŠ
æ²çã§ããããšãããã€ããæ¬çºæã®ç¯å²ã«å«ãŸ
ããå€æ°ã®ã³ãã€ãæ§åæ£æ¶²ããŸãšããŠããã
ãè¡šã
ãè¡šã
åè¡šã«é¢ããŠãã€ã³ãNo.100ãšåãæåãåã
éã ãå«ãã§ããã€ã³ãNo.200ã¯ã調補æ¹æ³ã®äž
貫æ§ã瀺ãããã«èª¿è£œãããã®ã§ãããåæ§ã«ã€
ã³ãNo.900ã¯ãVersamide871é«ååçµåå€ã®æ°ã
ããããã䜿çšããããã€ã³ããé»æ°æ³³åã«ãã€
ãŠæ²çãããèœåã«åºæ¬çã«å€åããªãã€ãããš
ãé€ããŠã¯ãåºæ¬çã«ã€ã³ãNo.ã®ç¹°è¿ãã§ãã€
ããã€ã³ãNo.300ã400ã500ã600ã¯è¡šã«ç€ºããã
ãã«å¯å¡å€ãå«ããã®ã§ãã€ãããã€ã³ããé»æ°
æ³³åã«ãã€ãŠæ²çãããèœåã«ã¯åºæ¬çã«å€åã
ãªãã€ããæãåªããç¹æ§ã瀺ããã€ã³ãã¯ãNo.
1300åã³1400ã§ãã€ããã€ã³ãNo.1700ã¯ãæåã®
çžå¯Ÿéãã€ã³ãNo.1200ãšåãã§ãã€ãããè¶ é«é
Super DispaxedïŒåæšïŒãã¬ã³ããŒãçšããŠ
1000rpmã§æ··åãããã®ã§ãããã€ã³ãã¯ããã®
ãããªæ¥µç«¯ãªæ··åæ¡ä»¶ã§èª¿è£œããå ŽåãæãŸãã
ãªãååºã瀺ããã
éã ãå«ãã§ããã€ã³ãNo.200ã¯ã調補æ¹æ³ã®äž
貫æ§ã瀺ãããã«èª¿è£œãããã®ã§ãããåæ§ã«ã€
ã³ãNo.900ã¯ãVersamide871é«ååçµåå€ã®æ°ã
ããããã䜿çšããããã€ã³ããé»æ°æ³³åã«ãã€
ãŠæ²çãããèœåã«åºæ¬çã«å€åããªãã€ãããš
ãé€ããŠã¯ãåºæ¬çã«ã€ã³ãNo.ã®ç¹°è¿ãã§ãã€
ããã€ã³ãNo.300ã400ã500ã600ã¯è¡šã«ç€ºããã
ãã«å¯å¡å€ãå«ããã®ã§ãã€ãããã€ã³ããé»æ°
æ³³åã«ãã€ãŠæ²çãããèœåã«ã¯åºæ¬çã«å€åã
ãªãã€ããæãåªããç¹æ§ã瀺ããã€ã³ãã¯ãNo.
1300åã³1400ã§ãã€ããã€ã³ãNo.1700ã¯ãæåã®
çžå¯Ÿéãã€ã³ãNo.1200ãšåãã§ãã€ãããè¶ é«é
Super DispaxedïŒåæšïŒãã¬ã³ããŒãçšããŠ
1000rpmã§æ··åãããã®ã§ãããã€ã³ãã¯ããã®
ãããªæ¥µç«¯ãªæ··åæ¡ä»¶ã§èª¿è£œããå ŽåãæãŸãã
ãªãååºã瀺ããã
第ïŒå³ã¯ãæ¬çºæã®æ¹æ³ã«ããšã¥ããŠãã³ãã€
ãç²åãæµææ§ãªãã³ç±è»¢åçšå°åãªãã³ã®ã€ã³
ããæ¯æžããéšåã§éå±åºå±€äžã«æ²çããæãæ¡
倧ããŠïŒçž®å°ºäžåïŒç€ºãå³ã第ïŒå³ã¯ãæ¬çºæã®
æ¹æ³ã«ã€ããŠå®é»å§ã§æéã®çµéã«ã€ããŠã®é»æµ
å¯åºŠã®å€åã瀺ãå³ã第ïŒå³ã¯ãæ¬çºæã«ããšã¥
ãã䜿çšæžæµææ§ãªãã³ç±è»¢åçšå°åãªãã³ãé£
ç¶ããŠéžæçã«ã€ã³ãåè£çµŠããããã®æ¹æ³åã³
è£ çœ®ã®èšç»å³ã第ïŒå³ã¯ãç¹ã«ãªãã³ãã³ãã€ã
æ§åæ£æ¶²äžãééããéã®ãæ¯æžãããªãã³ã®ã€
ã³ãåè£çµŠãæããã第ïŒå³ã«ç€ºãã€ã³ãåè£çµŠ
æ¹æ³ã®æ¡å€§å³ïŒçž®å°ºäžåïŒã§ããã ïŒâŠâŠåºå±€ãïŒâŠâŠççŽ ç²åãïŒâŠâŠã€ã³ã
å±€ãïŒïŒâŠâŠåæ£æ¶²ã
ãç²åãæµææ§ãªãã³ç±è»¢åçšå°åãªãã³ã®ã€ã³
ããæ¯æžããéšåã§éå±åºå±€äžã«æ²çããæãæ¡
倧ããŠïŒçž®å°ºäžåïŒç€ºãå³ã第ïŒå³ã¯ãæ¬çºæã®
æ¹æ³ã«ã€ããŠå®é»å§ã§æéã®çµéã«ã€ããŠã®é»æµ
å¯åºŠã®å€åã瀺ãå³ã第ïŒå³ã¯ãæ¬çºæã«ããšã¥
ãã䜿çšæžæµææ§ãªãã³ç±è»¢åçšå°åãªãã³ãé£
ç¶ããŠéžæçã«ã€ã³ãåè£çµŠããããã®æ¹æ³åã³
è£ çœ®ã®èšç»å³ã第ïŒå³ã¯ãç¹ã«ãªãã³ãã³ãã€ã
æ§åæ£æ¶²äžãééããéã®ãæ¯æžãããªãã³ã®ã€
ã³ãåè£çµŠãæããã第ïŒå³ã«ç€ºãã€ã³ãåè£çµŠ
æ¹æ³ã®æ¡å€§å³ïŒçž®å°ºäžåïŒã§ããã ïŒâŠâŠåºå±€ãïŒâŠâŠççŽ ç²åãïŒâŠâŠã€ã³ã
å±€ãïŒïŒâŠâŠåæ£æ¶²ã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ç±è»¢åå°å·çšã®ã€ã³ãã®å±€ãšãå°é»æ§ç©è³ªã®
å±€ãšãéžæçã«éé»ããçºç±ããã®éšåã«è¿æ¥ã
ãŠããã€ã³ããå°å·å¯Ÿè±¡ã«ä»çãããå±€ãšãæã
ãç±è»¢åã€ã³ãã»ãªãã³ã«ã€ã³ããåè£çµŠããæ¹
æ³ã«ãããŠã (1)(a) èç¹ã85âã100âã®ç¯å²ã«ããæ°Žã«äžæº¶
æ§ã®é«ååçµåå€ãèããŠæ¶²ç¶ã«ãªããŸã§å
ç±ãã (b) è²çŽ ãèããé«ååçµåå€ã«å ããŠæ··å
ãã (c) å ç±ããã«ã«ãã³é žã®èã氎溶液ã(b)ã§åœ¢
æãããçµæç©ã«å ããŠæ··åãã (d) (c)ã§åœ¢æãããçµæç©ã®PHã調ç¯ããåŸã³
ãã€ãé»è·åœ¢æååç©ãå ããŠæ··åãã垯é»
ããè²çŽ ãå«ãé«ååã³ãã€ãã®æ°Žæ§åæ£æ¶²
ã圢æãã (e) (d)ã§åœ¢æãããã³ãã€ãæ§åæ£æ¶²ãå·åŽã
ãŠãé»æ°æ³³åã«ãã€ãŠæ²çã§ããã€ã³ãã®ã³
ãã€ãæ§åæ£æ¶²ãäœãã (2) 該ã³ãã€ãæ§åæ£æ¶²ã«ã€ã³ãã®æžããéšåã®
ããæµææ§ãªãã³ç±è»¢åçšå°åãªãã³ãå ¥ãã
該ãªãã³ã®å°é»æ§ç©è³ªã®å±€ãäžæ¹ã®é»æ¥µãšããŠ
äžèšåæ£æ¶²ãšã®éã«é»æµãéããè²çŽ ãå«ãé«
ååã³ãã€ããã該ãªãã³ã®ã€ã³ããæžããé
åã«é»æ°æ³³åã«ãã€ãŠæ²çãããåãã®åäžãª
ã€ã³ãå±€ã圢æãããããšãããªãç±è»¢åçšå°
åãªãã³ã«ã€ã³ããåè£çµŠããæ¹æ³ã
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/133,152 US4268368A (en) | 1980-03-24 | 1980-03-24 | Electrophoretical method for selectively reinking resistive ribbon thermal transfer printing ribbons |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS56144980A JPS56144980A (en) | 1981-11-11 |
JPS6129879B2 true JPS6129879B2 (ja) | 1986-07-09 |
Family
ID=22457256
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP3551381A Granted JPS56144980A (en) | 1980-03-24 | 1981-03-13 | Method of selectively resupplying ink to printing ribbon for resisting ribbon thermo-transcription |
Country Status (4)
Country | Link |
---|---|
US (1) | US4268368A (ja) |
EP (1) | EP0037464B1 (ja) |
JP (1) | JPS56144980A (ja) |
DE (1) | DE3164510D1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01122884U (ja) * | 1988-01-29 | 1989-08-21 |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4470714A (en) * | 1982-03-10 | 1984-09-11 | International Business Machines Corporation | Metal-semiconductor resistive ribbon for thermal transfer printing and method for using |
US4414555A (en) * | 1982-05-07 | 1983-11-08 | Xerox Corporation | Method and apparatus for replenishing marking material to a donor ribbon in a thermal marking printer system |
US4491432A (en) * | 1982-12-30 | 1985-01-01 | International Business Machines Corporation | Chemical heat amplification in thermal transfer printing |
US4491431A (en) * | 1982-12-30 | 1985-01-01 | International Business Machines Corporation | Metal-insulator resistive ribbon for thermal transfer printing |
US4549824A (en) * | 1983-12-30 | 1985-10-29 | International Business Machines Corporation | Ink additives for efficient thermal ink transfer printing processes |
US4687360A (en) * | 1986-01-15 | 1987-08-18 | Pitney Bowes Inc. | Thermal imaging ribbon including a partially crystalline polymer |
US4789260A (en) * | 1986-10-08 | 1988-12-06 | Alps Electric Co., Ltd. | Thermal printer |
DE3635114C1 (de) * | 1986-10-15 | 1988-07-14 | Caribonum Ltd | UEberlappend ueberschreibbares Farbband sowie seine Verwendung in endlos gestopften Kassetten |
JPH04122668A (ja) * | 1990-01-25 | 1992-04-23 | Seiko Epson Corp | ã€ã³ã¯ã·ãŒãã®åçæ³ããã³ãã®è£ 眮 |
JPH0698814B2 (ja) * | 1990-03-13 | 1994-12-07 | å¯å£«ãŒããã¯ã¹æ ªåŒäŒç€Ÿ | ã€ã³ã¯èšé²åªäœã®åçæ¹æ³ |
JP4320920B2 (ja) | 2000-05-31 | 2009-08-26 | ãœããŒæ ªåŒäŒç€Ÿ | åä¿¡è£ çœ®ããã³åä¿¡æ¹æ³ |
DE10036560B4 (de) * | 2000-07-27 | 2005-03-31 | Basf Coatings Ag | Elektrotauchlacke, sowie Verfahren zu ihrer Herstellung und deren Verwendung |
US10449781B2 (en) | 2013-10-09 | 2019-10-22 | Dover Europe Sarl | Apparatus and method for thermal transfer printing |
US8922611B1 (en) | 2013-10-09 | 2014-12-30 | Markem-Imaje Corporation | Apparatus and method for thermal transfer printing |
US11040548B1 (en) | 2019-12-10 | 2021-06-22 | Dover Europe Sarl | Thermal transfer printers for deposition of thin ink layers including a carrier belt and rigid blade |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL111927C (ja) * | 1956-06-14 | |||
US3170809A (en) * | 1962-05-04 | 1965-02-23 | Oxford Paper Co | Transfer sheet and process of making |
GB1180731A (en) * | 1966-03-16 | 1970-02-11 | Ici Ltd | Electrodeposition Coating Process and Apparatus |
US3885518A (en) * | 1972-08-29 | 1975-05-27 | Burroughs Corp | Ribbon inking apparatus |
GB2010515B (en) * | 1977-12-15 | 1982-04-15 | Ibm | Ribbon for non-impact printing |
US4253775A (en) * | 1979-06-29 | 1981-03-03 | Ibm Corporation | Apparatus for re-inking a ribbon in a thermal transfer printing system |
-
1980
- 1980-03-24 US US06/133,152 patent/US4268368A/en not_active Expired - Lifetime
-
1981
- 1981-03-06 EP EP81101640A patent/EP0037464B1/en not_active Expired
- 1981-03-06 DE DE8181101640T patent/DE3164510D1/de not_active Expired
- 1981-03-13 JP JP3551381A patent/JPS56144980A/ja active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01122884U (ja) * | 1988-01-29 | 1989-08-21 |
Also Published As
Publication number | Publication date |
---|---|
DE3164510D1 (en) | 1984-08-09 |
EP0037464A3 (en) | 1982-05-05 |
EP0037464B1 (en) | 1984-07-04 |
US4268368A (en) | 1981-05-19 |
EP0037464A2 (en) | 1981-10-14 |
JPS56144980A (en) | 1981-11-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPS6129879B2 (ja) | ||
JPS6344078B2 (ja) | ||
EP0306947A2 (en) | Image recording ink | |
EP0082270B1 (en) | Ribbon for non-impact thermal transfer printing and manufacturing method thereof | |
US5090828A (en) | Apparatus for replenishing a depleted ink sheet | |
US5122409A (en) | Ink transfer medium of the electrically fusible type | |
AÄamoviÄ et al. | Influence of substrate on the formation and growth kinetics of cathodic electrocoat paint | |
EP0193978B1 (en) | Process for incorporating powders into a polymer layer | |
US5961806A (en) | Image forming method, image forming medium, image receiving medium, and image forming apparatus | |
US4419024A (en) | Silicon dioxide intermediate layer in thermal transfer medium | |
JPH068444A (ja) | é»æ°ååŠæµææ§ã€ã³ã¯ãžã§ããããã | |
US5892529A (en) | Image forming method and image forming apparatus including electroconductive polymer layer for dye intake and release | |
JPH0548750B2 (ja) | ||
JPH0286067A (ja) | çæé»æ± åºç€ã®è£œé æ¹æ³ | |
US4680097A (en) | Method of preventing undesirable gas generation between electrodes of an electrocoagulation printing system | |
US5690803A (en) | Method of enhancing transfer of coagulated colloid onto a substrate during electrocoagulation printing | |
JP3002475B2 (ja) | ç»åèšé²æ¹æ³ããã³è£ 眮 | |
JPH02299878A (ja) | ç»åèšé²çšã€ã³ã¯ | |
CA1249238A (en) | Method of preventing undesirable gas generation between electrodes of an electrocoagulation printing system | |
JPH0458799B2 (ja) | ||
JPS59165692A (ja) | ç±è»¢åã€ã³ã¯ã·âã | |
JP2753580B2 (ja) | éé»è»¢åèšé²æ¹æ³ | |
Oguchi et al. | Formation of Precise Electrically-Conductive Pattern Using Metal Colloid IJ Ink | |
JPH0113438B2 (ja) | ||
JP3512871B2 (ja) | ã¢ã«ãããŠã åã¯ã¢ã«ãããŠã åéé žåç®èã®å å¡«çè²çšãã¿ãã·ã¢ãã³ç³»é¡æåæ£äœ |